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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Effect of Aging and Demand for Reliability Analysis of Degrading Components

According to the U.S Energy Information Administration (EIA), the U.S fossil fuel share of energy consumption in 2015 was 67%. Furthermore, the Ecotricity UK report based on the CIA World Factbook states that with the current rate of consumption of fossil fuels, petroleum would run out by 2052, natural gas by 2060, and coal by 2088. No fossil fuel will remain by the next century. Besides the limited reserves of fossil fuel, massive consumption of fossil fuel also raises concerns about global warming and pollution. Therefore, there has been a growing interest in reducing fossil fuel consumption in the energy structure and in increasing the proportion of clean energy. Renewable energy (e.g. wind, solar) has the potential for distributed generation. However, the availability for renewable energy fluctuates and is uncontrollable. Therefore, additional energy sources need to be coupled with renewable energy to produce a stable electricity generation profile. Nuclear energy can serve this purpose as it is a clean energy source, has low greenhouse gas emission and possesses high power density and baseload power supply with low fuel cost. It is desirable to develop a hybrid energy system that combines both renewable energy and nuclear energy to meet low carbon emission goals and to utilize renewable energy. Such a nuclear hybrid energy system, consisting of different energy subsystems such as nuclear, solar, and wind, involves frequent switching between different energy subsystems. Since the primary loop in a nuclear power plant generates constant heat, the turbine bypass line in the secondary loop is required to switch frequently to meet the gap in the energy demand and that generated by the renewables. The increased usage of the turbine bypass system is considered to be the major difference between a nuclear hybrid energy system and a traditional nuclear power plant. Reliability analysis for designing such a complex system involves both high level fault propagation analysis at the conceptual design stage and low level failure prediction for specific components. The main focus of this summary to derive a degradation model of hardware components which can later help in the high level fault propagation analysis. The degradation model is a low level failure mode model that combines the effects of natural aging and frequent switching. The model can be used for predicting components' failure due to specific failure modes. The results can serve as indicators for conducting repair actions and maintenance to minimize Operation and Maintenance (O and M) costs. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2017

The Effects of Magnetic Fields on the Dynamics of Radiation Pressure–dominated Massive Star Envelopes

We use three-dimensional radiation magnetohydrodynamic simulations to study the effects of magnetic fields on the energy transport and structure of radiation pressure–dominated main sequence massive star envelopes at the region of the iron opacity peak. We focus on the regime where the local thermal timescale is shorter than the dynamical timescale, corresponding to inefficient convective energy transport. We begin with initially weak magnetic fields relative to the thermal pressure, from 100 to 1000 G in differing geometries. The unstable density inversion amplifies the magnetic field, increasing the magnetic energy density to values close to equipartition with the turbulent kinetic energy density. By providing pressure support, the magnetic field's presence significantly increases the density fluctuations in the turbulent envelope, thereby enhancing the radiative energy transport by allowing photons to diffuse out through low-density regions. Magnetic buoyancy brings small-scale magnetic fields to the photosphere and increases the vertical energy transport, with the energy advection velocity proportional to the Alfvén velocity, although in all cases we study, photon diffusion still dominates the energy transport. The increased radiative and advective energy transport causes the stellar envelope to shrink by several scale heights. We also find larger turbulent velocity fluctuations compared with the purely hydrodynamic case, reaching $\approx 100\,{{\rm{km}}{\rm{s}}}^{-1}$ at the stellar photosphere. The photosphere also shows vertical oscillations with similar averaged velocities and periods of a few hours. The increased turbulent velocity and oscillations will have strong impacts on the line broadening and periodic signals in massive stars.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Semi-empirical scaling for ion–atom single charge exchange cross sections in the intermediate velocity regime

We present a semi-empirical scaling law for non-resonant ion–atom single charge exchange cross sections for collisions with velocities from ${10}^{7}\,{\rm{t}}{\rm{o}}\,{10}^{9}\,\mathrm{cm}\,{{\rm{s}}}^{-1}$ and ions with positive charge $q\lt 8$. Non-resonant cross sections tend to have a velocity peak at collision velocities $v\lesssim 1\ {\rm{a}}{\rm{u}}$ with exponential decay around this peak. We construct a scaling formula for the location of this peak then choose a functional form for the cross section curve and scale it. The velocity at which the cross section peaks, v m , is proportional to the energy defect of the collision, ${\rm{\Delta }}E$, which we predict with the decay approximation. The value of the cross section maximum is proportional to the charge state q, inversely proportional to the target ionization energy I T , and inversely proportional to v m . For the shape of the cross section curve, we use a function that decays exponentially asymptotically at high and low velocities. We scale this function with parameters ${v}_{{\rm{m}}},{I}_{{\rm{T}}},{Z}_{{\rm{T}}},\mathrm{and}\ {Z}_{{\rm{P}}}$, where the ${Z}_{{\rm{T}},{\rm{P}}}$ are the target and projectile atomic numbers. In conclusion, for the more than 100 cross section curves that we use to find the scaling rules, the scaling law predicts cross sections within a little over a factor of 2 on average.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2015

THE ENERGETICS OF A GLOBAL SHOCK WAVE IN THE LOW SOLAR CORONA

As the most energetic eruptions in the solar system, coronal mass ejections (CMEs) can produce shock waves at both their front and flanks as they erupt from the Sun into the heliosphere. However, the amount of energy produced in these eruptions, and the proportion of their energy required to produce the waves, is not well characterized. Here we use observations of a solar eruption from 2014 February 25 to estimate the energy budget of an erupting CME and the globally propagating ''EIT wave'' produced by the rapid expansion of the CME flanks in the low solar corona. The ''EIT wave'' is shown using a combination of radio spectra and extreme ultraviolet images to be a shock front with a Mach number greater than one. Its initial energy is then calculated using the Sedov-Taylor blast-wave approximation, which provides an approximation for a shock front propagating through a region of variable density. This approach provides an initial energy estimate of ≈2.8 × 10{sup 31} erg to produce the ''EIT wave'', which is approximately 10% the kinetic energy of the associated CME (shown to be ≈2.5 × 10{sup 32} erg). These results indicate that the energy of the ''EIT wave'' may be significant and must be considered when estimating the total energy budget of solar eruptions.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1999

An analysis of energy deposition in a tissue equivalent proportional counter onboard the space shuttle

An improved prediction for space radiations in the lower earth orbits measured by the shuttle TEPC is obtained when energy loss straggling and chord length distribution of the detector are considered. A generalized analytic model is used to describe the energy deposition of direct ion interaction events in a micron-size detector. The transport calculation accounting for the shuttle configuration is accomplished by using a new version of HZETRN that has been extensively verified with laboratory and flight data. The agreement of predicted and measured lineal energy spectra is within 70% for the region above 2 keV/micrometer but within a factor of 2.3 underpredicted for the region below this value. The inclusion of indirect delta ray events in the model is needed before possible causes for the underprediction below 2 keV/micrometer can be assessed.

Flight Experiment↗
NASA NTRS2012

Mathematical Simulation for Integrated Linear Fresnel Spectrometer Chip

A miniaturized solid-state optical spectrometer chip was designed with a linear gradient-gap Fresnel grating which was mounted perpendicularly to a sensor array surface and simulated for its performance and functionality. Unlike common spectrometers which are based on Fraunhoffer diffraction with a regular periodic line grating, the new linear gradient grating Fresnel spectrometer chip can be miniaturized to a much smaller form-factor into the Fresnel regime exceeding the limit of conventional spectrometers. This mathematical calculation shows that building a tiny motionless multi-pixel microspectrometer chip which is smaller than 1 cubic millimter of optical path volume is possible. The new Fresnel spectrometer chip is proportional to the energy scale (hc/lambda), while the conventional spectrometers are proportional to the wavelength scale (lambda). We report the theoretical optical working principle and new data collection algorithm of the new Fresnel spectrometer to build a compact integrated optical chip.

Park, Yeonjoon↗
NASA NTRS1986

On the energy resolution obtained with a multistep proportional counter

Results of laboratory experiments with a standard multiwire imaging proportional counter (MWPC), modified to include a parallel grid preamplification stage are presented. Both argon and xenon were used as the primary absorbing gas in conjunction with a number of quench gases. It is found that extremely good energy resolution is obtained from the preamplification stage, almost independent of the ionization potential of the quench gas and over a broad range of gains. Furthermore, regardless of absorbing gas or quench agent, there was no difficulty in transferring a portion of this preamplified charge to the MWPC section for multistep mode operation. Finally, even for overall system gains greater than 10,000, the energy resolution from the second stage is found to be significantly improved, as long as the preamplification stage is operating. These results should have wide application and are of special interest for X-ray astronomy.

Ramsey, B. D.↗
DOE OSTI2012

Strontium vapour laser with a pulse repetition rate of up to 1 MHz

For the first time it has been shown that the pulse repetition rate of the lasers on the self-terminating transitions of metal atoms may be as high as {approx}1 MHz. The highest pulse repetition rate equal to {approx}830 kHz was realised on self-terminating IR transitions in Sr I atoms ({lambda} = 6.456 {mu}m and {approx}3 {mu}m) and in Sr II ions ({lambda} {approx} 1 {mu}m) in a strontium vapour laser operating in a self-heating pulse periodic regime. The energy yield of a Sr laser was found to be proportional to the energy input into the active medium in a wide range of excitation pulse repetition frequencies; in this case, the average total specific output laser power is equal to 30 - 40 mW cm{sup -3}. (lasers)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1999

A High-Energy Focal-Plane Gas Scintillation Proportional Counter

We have developed a high-pressure Gas Scintillation Proportional Counter (GSPC) for the focus of a hard-x-ray telescope. It features an absorption region 50 mm in diameter and 50 mm deep, filled with Xenon + 4% He at 10(exp 6) Pa total pressure, which gives useful response (greater than 75% efficiency) up to the mirror cut-off of 70 keV. Tests with a prototype unit show an energy resolution of 3.5% at 60 keV and a spatial resolution of 0.35 mm from 30-50 keV. Two flight units are currently under construction for a balloon flight in September 1999. Full details of their design and performance will be presented together with available quick-look background data from the flight.

Ramsey, B. D.↗
NASA NTRS1995

Toward a theory of interstellar turbulence. 2: Strong alfvenic turbulence

We continue to investigate the possibility that interstellar turbulence is caused by nonlinear interactions among shear Alfven waves. Here, we restrict attention to the symmetric case where the oppositely directed waves carry equal energy fluxes. This precludes application to the solar wind in which the outward flux significantly exceeds the ingoing one. All our detailed calculations are carried out for an incompressible magnetized fluid. In incompressible magnetohydrodynamics (MHD), nonlinear interactions only occur between oppositely direct waves. We present a theory for the strong turbulence of shear Alfven waves. It has the following main characteristics. (1) The inertial-stage energy spectrum exhibits a critical balance between linear wave periods and nonlinear turnover timescales. (2) The 'eddies' are elongated in the direction of the field on small spatial scales; the parallel and perpendicular components of the wave vector, k(sub z) and k(perpendicular) are related by k(sub z) approximately equals k(sub perpendicular to)(exp 2/3) L(exp -1/3), where L is the outer scale of the turbulence. (3) The 'one-dimensional' energy spectrum is proportional to k(sub perpendicular)(exp -5/3)-an anisotropic Kolmogorov energy spectrum. Shear Alfvenic turbulence mixes specific entropy as a passive contaminant. This gives rise to an electron density power spectrum whose form mimics the energy spectrum of the turbulence. Radio wave scattering by these electron density fluctuations produces anisotropic scatter-broadened images. Damping by ion-neutral collisions restricts Alfvenic turbulence to highly ionized regions of the interstellar medium.

Goldreich, P.↗
DOE OSTI2014

Physical origins of weak H{sub 2} binding on carbon nanostructures: Insight from ab initio studies of chemically functionalized graphene nanoribbons

We have performed ab initio density functional theory calculations, incorporating London dispersion corrections, to study the absorption of molecular hydrogen on zigzag graphene nanoribbons whose edges have been functionalized by OH, NH{sub 2}, COOH, NO{sub 2}, or H{sub 2}PO{sub 3}. We find that hydrogen molecules always preferentially bind at or near the functionalized edge, and display induced dipole moments. Binding is generally enhanced by the presence of polar functional groups. The largest gains are observed for groups with oxygen lone pairs that can facilitate local charge reorganization, with the biggest single enhancement in adsorption energy found for “strong functionalization” by H{sub 2}PO{sub 3} (115 meV/H{sub 2} versus 52 meV/H{sub 2} on bare graphene). We show that for binding on the “outer edge” near the functional group, the presence of the group can introduce appreciable contributions from Debye interactions and higher-order multipole electrostatic terms, in addition to the dominant London dispersion interactions. For those functional groups that contain the OH moiety, the adsorption energy is linearly proportional to the number of lone pairs on oxygen atoms. Mixed functionalization with two different functional groups on a graphene edge can also have a synergistic effect, particularly when electron-donating and electron-withdrawing groups are combined. For binding on the “inner edge” somewhat farther from the functional group, most of the binding again arises from London interactions; however, there is also significant charge redistribution in the π manifold, which directly reflects the electron donating or withdrawing capacity of the functional group. Our results offer insight into the specific origins of weak binding of gas molecules on graphene, and suggest that edge functionalization could perhaps be used in combination with other strategies to increase the uptake of hydrogen in graphene. They also have relevance for the storage of hydrogen in porous carbon materials, such as activated carbons.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Predicted Structures of the Active Sites Responsible for the Improved Reduction of Carbon Dioxide by Gold Nanoparticles

Gold (Au) nanoparticles (NPs) are known experimentally to reduce carbon dioxide (CO 2 ) to carbon monoxide (CO), with far superior performance to Au foils. To obtain guidance in designing improved CO 2 catalysts, we want to understand the nature of the active sites on Au NPs. Here, we employed multiscale atomistic simulations to computationally synthesize and characterize a 10 nm thick Au NP on a carbon nanotube (CNT) support, and then we located active sites from quantum mechanics (QM) calculations on 269 randomly selected sites. The standard scaling relation is that the formation energy of *COOH (ΔE*COOH) is proportional to the binding energy of *CO (Ebinding*CO); therefore, decreasing ΔE*COOH to boost the CO 2 reduction reaction (CO 2 RR) causes an increase of Ebinding*CO that retards CO 2 RR. We show that the NPs have superior CO 2 RR because there are many sites at the twin boundaries that significantly break this scaling relation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Multiresolution quantum chemistry in multiwavelet bases: excited states from time-dependent Hartree–Fock and density functional theory via linear response

Using the fully numerical method for time-dependent Hartree–Fock and density functional theory (TD-HF/DFT) with the Tamm–Dancoff (TD) approximation we use a multiresolution analysis (MRA) approach to present our findings. From a reformulation with effective use of the density matrix operator, we obtain a general form of the HF/DFT linear response equation in the first quantization formalism. It can be readily rewritten as an integral equation with the bound-state Helmholtz (BSH) kernel for the Green's function. The MRA implementation of the resultant equation permits excited state calculations without virtual orbitals. Moreover, the integral equation is efficiently and adaptively solved using a numerical multiresolution solver with multiwavelet bases. Our implementation of the TD-HF/DFT methods is applied for calculating the excitation energies of H 2 , Be, N 2 , H 2 O, and C 2 H 4 molecules. The numerical errors of the calculated excitation energies converge in proportion to the residuals of the equation in the molecular orbitals and response functions. The energies of the excited states at a variety of length scales ranging from short-range valence excitations to long-range Rydberg-type ones are consistently accurate. It is shown that the multiresolution calculations yield the correct exponential asymptotic tails for the response functions, whereas those computed with Gaussian basis functions are too diffuse or decay too rapidly. Finally, we introduce a simple asymptotic correction to the local spin-density approximation (LSDA) so that in the TDDFT calculations, the excited states are correctly bound.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1975

Constant energy partitioning in the photoionization of NO and O2

Published data on the photoelectron spectra of NO and O2 are analyzed, and the energy distributions are found to have averages proportional to the available energy. Hence, vibration takes a constant fraction of the energy. Average distributions are found as a function of the fraction of available energy.

Lawrence, G. M.↗
DOE OSTI2021

A simulation-based assessment of technologies to reduce heat emissions from buildings

Heat emissions from buildings are part of anthropogenic heat leading to urban overheating. This paper aims to assess how technologies (i.e., energy conservation measures - ECMs), used to decrease energy use, may also reduce heat emissions from buildings. This study employs the physics-based engine EnergyPlus to simulate the main components of heat emissions from buildings to ambient air: envelope, zone, and systems. Hourly simulations are run for IECC single- and multi-family reference models with three representative climates: Miami, Baltimore, and Chicago. The results show that the performance of ECMs varies among weather, seasons, and residential typologies. Particularly, some ECMs (i.e., cool coatings, heat pumps, additional insulation, energy-awareness occupants) show a strong decrease in heat emissions, yet they are not always correlated with proportional decreases in energy use. When all ECMs are combined, the reductions are larger on heat emissions (89%) than on site energy (65%) from the base cases. During summer in Miami, the combination of ECMs shows a decrease in heat emissions from the building surface component of 80% during daytime, 92% for the HVAC component and a counterbalanced increase in the zone component of 88%, bringing to a daily decrease in total heat emissions. The main contributions of this study are quantifying how typical ECMs influence residential building heat emissions using EnergyPlus simulations and informing urban planners and stakeholders on prioritizing measures for mitigating urban overheating problems.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2011

The use of commercial and industrial waste in energy recovery systems - A UK preliminary study

Highlights: > Commercial and industrial waste samples collected. > Samples analysed for calorific value, moisture, ash and elemental composition. > Values similar to those of municipal solid waste and refuse derived fuel. > Sampled waste could be used in current energy recovery systems with minimal retrofitting. > Sampled waste could account 6.5% towards the UK's 2020 renewable electricity target if all qualifying waste is used. - Abstract: With 2020 energy targets set out by the EU fast approaching, the UK is trying to source a higher proportion of its energy from renewable resources. Coupled with this, a growing population and increasing trends in consumer demand have resulted in national waste loads increasing. A possible solution to both issues is energy-from-waste (EfW) technologies. Many studies have focused on municipal solid waste (MSW) as a potential feedstock, but appear to overlook the potential benefits of commercial and industrial waste (C and IW). In this study, samples of C and IW were collected from three North West waste management companies and Lancaster University campus. The samples were tested for their gross and net calorific value, moisture content, ash content, volatile matter, and also elemental composition to determine their suitability in EfW systems. Intra-sample analysis showed there to be little variation between samples with the exception two samples, from waste management site 3, which showed extensive variation with regards to net calorific value, ash content, and elemental analysis. Comparisons with known fuel types revealed similarities between the sampled C and IW, MSW, and refuse derived fuel (RDF) thereby justifying its potential for use in EfW systems. Mean net calorific value (NCV) was calculated as 9.47 MJ/kg and concentrations of sulphur, nitrogen, and chlorine were found to be below 2%. Potential electrical output was calculated using the NCV of the sampled C and IW coupled with four differing energy generation technologies. Using a conventional incinerator with steam cycle, total electrical output was calculated as 24.9 GWh, based on a plant operating at 100,000 tpa. This value rose to 27.0 GWh when using an integrated gasification combined cycle. A final aspect of this study was to deduce the potential total national electrical output if all suitable C and IW were to be used in EfW systems. Using incineration coupled with a steam turbine, this was determined to be 6 TWh, 1.9% of the national demand thereby contributing 6.5% towards the UK's 2020 renewable electricity target.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗