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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

An experimental study of tone excited heated jets

The objective of this investigation was to obtain detailed experimental data on the effects of upstream acoustic excitation on the mixing of heated jets with the surrounding air. Based on the information gathered in the literature survey, a technical approach was developed to carry out a systematic set of mean flowfield measurements for a broad range of jet operating and acoustic excitation conditions. Most of the results were obtained at Mach numbers of 0.3 and 0.8 and total temperatures of up to 800 K. Some measurements were made also for the fully expanded supersonic jet of Mj = 1.15. The maximum level of excitation was Le equal to or less than 150 dB and a range of excitation frequencies up to fe = 4 kHz was used. The important results derived from this study can be summarized as follows: (1) the sensitivity of heated jets to upstream acoustic excitation varies strongly with the jet operating conditions, (2) the threshold excitation level increases with increasing jet temperature, and (3) the preferred Strouhal number does not change significantly with a change of the jet operating conditions.

Lepicovsky, J.↗
NASA NTRS1986

Some unresolved questions on hot-jet mixing control through artificial excitation

The problem of the mixing enhancement of heated jets through acoustic excitation is addressed using a 5.08 cm diameter jet operating at Mach numbers as high as 1.12 and at temperatures reaching 670 K. An experimental investigation is carried out to determine why high-speed heated jets are not as responsive to internal excitation as low-speed heated jets. Results are also presented which are related to the flow structure in the presence of screech and under the influence of external excitation. It is shown that, if sufficiently high excitation levels are used, the heated jets, even at high levels, can be modified by artificial excitation. Nonetheless, it is concluded that, for the test facility and test conditions used in the present study, the high-Mach-number heated jets are considerably less excitable than the similarly heated low-Mach-number jets.

Ahuja, K. K.↗
NASA NTRS1988

Acoustically excited heated jets. 2: In search of a better understanding

The second part of a three-part report on the effects of acoustic excitation on jet mixing includes the results of an experimental investigation directed at resolving the question of poor excitability of some of the heated jets. The theoretical predictions discussed in Part 1 are examined to find explanations for the observed discrepancies between the measured and the predicted results. Additional testing was performed by studying the self excitation of the shock containing hot jets and also by exciting the jet by sound radiated through source tubes located externally around the periphery of the jet. The effects of nozzle-exit boundary layer conditions on jet excitability was also investigated. It is concluded that high-speed, heated jet mixing rates and consequently also the jet excitability strongly depends on nozzle exit boundary layer conditions.

Lepicovsky, J.↗
NASA NTRS1988

The design and performance of a real-time self excited vocoder

This paper is concerned with a generic class of predictive speech coders that includes the newly proposed Self Excited Vocoder (SEV) and the well known Code-Excited Linear Predictive Coder (CELPC). All members of this class form an excitation sequence for a linear predictive model filter using the same general model for the excitation signal. The general excitation model is based on a block coding technique where each sequence is drawn from an ensemble of sequences. This paper reports on two developments related to this general model. The first development is a new type of excitation ensemble that can in general be populated by many different types of sequences. The second development is a means of populating this new type of ensemble based on a vector quantizer design procedure using a new distortion measure.

Rose, Richard C.↗
NASA NTRS1991

Collisional excitation of formaldehyde in 'hot' interstellar molecular regions

Earlier calculations for rotational excitation of formaldehyde by collisions with He atoms are extended to include the lowest 81 rotational levels and kinetic temperatures to 300 K. Calculations are generally based on Green et al. (1978) but coupled differential equations are solved via a modified log-derivative propagator at low energies (Manolopoulos, 1986) and an R-matrix propagator at higher energies (Stechel, Walker, and Light, 1978). Consideration is given to the expected accuracy of the rates for excitation of formaldehyde by collisions with He atoms which are calculated in the present paper and to the expected differences between these rates and those for excitation by H2 molecules which comprise a larger fraction of the interstellar gas. The comparisons performed indicate that, for excitation by He, calculated state-to-state rates are likely to be 50 percent accurate, and total excitation rates, better than 20 percent. For excitation by H2, the rates should be increased by a factor of 2.2.

Green, Sheldon↗
NASA NTRS1993

Calculation of molecular excitation rates

State-to-state collisional excitation rates for interstellar molecules observed by radio astronomers continue to be required to interpret observed line intensities in terms of local temperatures and densities. A problem of particular interest is collisional excitation of water which is important for modeling the observed interstellar masers. In earlier work supported by a different NASA Grant, excitation of water in collisions with He atoms was studied; after many years of successively more refined calculations that problem now seems to be well understood, and discrepancies with earlier experimental data for related (pressure broadening) phenomena are believed to reflect experimental errors. Because of interstellar abundances, excitation by H2, the dominant interstellar species, is much more important than excitation by He, although it has been argued that rates for excitation by these are similar. Under the current grant theoretical study of this problem has begun which is greatly complicated by the additional degrees of freedom which must be included both in determining the interaction potential and also in the molecular scattering calculation. We have now computed the interaction forces for nearly a thousand molecular geometries and are close to having an acceptable global fit to these points which is necessary for the molecular dynamics calculations. Also, extensive modifications have been made to the molecular scattering code, MOLSCAT. These included coding the rotational basis sets and coupling matrix elements required for collisions of an asymmetric top with a linear rotor. A new method for numerical solution of the coupled equations has been incorporated. Because of the long-ranged nature of the water-hydrogen interaction it is necessary to integrate the equations to rather large intermolecular separations, and the integration methods previously available in MOLSCAT are not ideal for such cases. However, the method used by Alexander in his HIBRIDON code is particularly suited for such cases. We have obtained this code and incorporated that part which solves the coupled differential equations as an option in the MOLSCAT program.

Flynn, George↗
NASA NTRS1994

Investigating the 3.3 micron infrared fluorescence from naphthalene following ultraviolet excitation

Polycyclic aromatic hydrocarbon (PAH) type molecules are proposed as the carriers of the unidentified infrared (UIR) bands. Detailed studies of the 3.3 micrometer infrared emission features from naphthalene, the simplest PAH, following ultraviolet laser excitation are used in the interpretation of the 3.29 micrometer (3040 cm(sup -1)) UIR band. A time-resolved Fourier transform spectrometer is used to record the infrared emission spectrum of gas-phase naphthalene subsequent to ultraviolet excitation facilitated by an excimer laser operated at either 193 nm or 248 nm. The emission spectra differ significantly from the absorption spectrum in the same spectral region. Following 193 nm excitation the maximum in the emission profile is red-shifted 45 cm(sup -1) relative to the absorption maximum; a 25 cm(sup -1) red-shift is observed after 248 nm excitation. The red-shifting of the emission spectrum is reduced as collisional and radiative relaxation removes energy from the highly vibrationally excited molecules. Coupling between the various vibrational modes is thought to account for the differences between absorption and emission spectra. Strong visible emission is also observed following ultraviolet excitation. Visible emission may play an important role in the rate of radiative relaxation, which according to the interstellar PAH hypothesis occurs only by the slow emission of infrared photons. Studying the visible emission properties of PAH type molecules may be useful in the interpretation of the DIB's observed in absorption.

Williams, Richard M.↗
NASA NTRS1993

Atmospheric excitation of nonseasonal polar motion

Analysis of nonseasonal polar motion excitation and atmospheric mass equatorial angular momentum (EAM) over land for the period 1980-1989 reveals a clear pattern of high power and correlation during the northern hemisphere (NH) winter followed by low power and correlation during the NH summer. A special case of this pattern occurs for longer than 14 months (from January 1987 to March 1988) when the correlation throughout the NH summer remains statistically significant. During this epoch an average of 72% of the nonseasonal polar motion excitation power at frequencies between -30 and +12 cycles/yr linearly related to atmospheric EAM over land. During the southern hemisphere winter there is significant correlation between the atmospheric EAM over midlatitude southern oceans and polar motion excitation indicating the existence of a dynamic atmosphere-ocean excitation. The atmospheric excitation power is too small to explain the large correlation during the NH winter. The effects of winds probably account for the deficit in power. The implication of these results is that there are two main excitation sources each dominant at different seasons. Atmospheric mass redistribution over land forces polar motion during the NH winter, and a dynamic atmpshere-ocean response is important during the SH winter.

Kuehne, John↗
NASA NTRS1997

Tailored Excitation for Multivariable Stability-Margin Measurement Applied to the X-31A Nonlinear Simulation

Safety and productivity of the initial flight test phase of a new vehicle have been enhanced by developing the ability to measure the stability margins of the combined control system and vehicle in flight. One shortcoming of performing this analysis is the long duration of the excitation signal required to provide results over a wide frequency range. For flight regimes such as high angle of attack or hypersonic flight, the ability to maintain flight condition for this time duration is difficult. Significantly reducing the required duration of the excitation input is possible by tailoring the input to excite only the frequency range where the lowest stability margin is expected. For a multiple-input/multiple-output system, the inputs can be simultaneously applied to the control effectors by creating each excitation input with a unique set of frequency components. Chirp-Z transformation algorithms can be used to match the analysis of the results to the specific frequencies used in the excitation input. This report discusses the application of a tailored excitation input to a high-fidelity X-31A linear model and nonlinear simulation. Depending on the frequency range, the results indicate the potential to significantly reduce the time required for stability measurement.

Bosworth, John T.↗
NASA NTRS1996

Evidence for Excitation of Polar Motion by Fortnightly Ocean Tides

The second-degree zonal tide raising potential, which is responsible for tidal changes in the Earth's rotation rate and length-of-day, is symmetric about the polar axis and hence can excite the Earth's polar motion only through its action upon nonaxisymmetric features of the Earth such as the oceans. Ocean tidal excitation of polar motion in the diurnal and semidiurnal tidal bands has been previously detected and examined. Here, the detection of ocean tidal excitation of polar motion in the long-period tidal band, specifically at the Mf' (13.63-day) and Mf (13.66-day) tidal frequencies, is reported. Spectra of the SPACE94 polar motion excitation series exhibit peaks at the prograde and retrograde fortnightly tidal periods. After removing effects of atmospheric wind and pressure changes, an empirical model for the effect of the fortnightly ocean tides upon polar motion excitation is obtained by least-squares fitting periodic terms at the Mf and Mf' tidal frequencies to the residual polar motion excitation series. The resulting empirical model is then compared with the predictions of two hydrodynamic ocean tide models.

Gross, Richard S.↗
NASA NTRS1997

Reversal in Spreading of a Tabbed Circular Jet Under Controlled Excitation

Detailed flow field measurements have been carried out for a turbulent circular jet perturbed by tabs and artificial excitation. Two "delta tabs" were placed at the nozzle exit at diametrically opposite locations. The excitation condition involved subharmonic resonance that manifested in a periodic vortex pairing in the near flow field. While the excitation and the tabs independently increased jet spreading, a combination of the two diminished the effect. The jet spreading was most pronounced with the tabs but was reduced when excitation was applied to the tabbed jet. The tabs generated streamwise vortex pairs that caused a lateral spreading of the jet in a direction perpendicular to the plane containing the tabs. The excitation, on the other band, organized the azimuthal vorticity into coherent ring structures whose evolution and pairing also increased entrainment by the jet. In the tabbed case, the excitation produced coherent azimuthal structures that were distorted and asymmetric in shape. The self-induction of these structures produced an effect that opposed the tendency for the lateral spreading of the streamwise vortex pairs. The passage of the distorted vortices, and their pairing, also had a cancellation effect on the time-averaged streamwise vorticity field. These led to the reduction in jet spreading.

Zaman, K. B. M. Q.↗
NASA NTRS1997

Reversal in Spreading of a Tabbed Circular Jet Under Controlled Excitation

Detailed flow field measurements have been carried out for a turbulent circular jet perturbed by tabs and artificial excitation. Two "delta tabs" were placed at the nozzle exit at diametricall opposite y locations. The excitation condition involved subharmonic resonance that manifested in a periodic vortex pairing in the near flow field. While the excitation and the tabs independently increased jet spreading, a combination of the two diminished the effect. The jet spreading was most pronounced with the tabs but was reduced when excitation was applied to the tabbed jet. The tabs generated streamwise vortex pairs that caused a lateral spreading of the jet in a direction perpendicular to the plane containing the tabs. ne excitation, on the other hand, organized the azimuthal vorticity into coherent ring structures whose evolution and pairing also increased entrainment by the jet. In the tabbed case, the excitation produced coherent azimuthal structures that were distorted and asymmetric in shape. The self-induction of these structures produced an effect that opposed the tendency for the lateral spreading of the streamwise vortex pairs. The passage of the distorted vortices, and their pairing, also had a cancellation effect on the time-averaged streamwise vorticity field. These led to the reduction in jet spreading.

Zaman, K. B. M. Q.↗
NASA NTRS2001

Theoretical Studies of Possible Synthetic Routes for the High Energy Density Material Td N4: Excited Electronic States

Vertical electronic excitation energies for single states have been computed for the high energy density material (HEDM) Td N4 in order to assess possible synthetic routes that originate from excited electronic states of N2 molecules. Several ab initio theoretical approaches have been used, including complete active space self-consistent field (CASSCF), state averaged CASSCF (SA-CASSCF), singles configuration interaction (CIS), CIS with second-order and third-order correlation corrections [CIS(D)) and CIS(3)], and linear response singles and doubles coupled-cluster (LRCCSD), which is the highest level of theory employed. Standard double zeta polarized (DZP) and triple zeta double polarized (TZ2P) one-particle basis sets were used. The CASSCF calculations are found to overestimate the excitation energies, while the SA-CASSCF approach rectifies this error to some extent, but not completely. The accuracy of the CIS calculations varied depending on the particular state, while the CIS(D), CIS(3), and LRCCSD results are in generally good agreement. Based on the LRCCSD calculations, the lowest six excited singlet states are 9.35(l(sup)T1), 10.01(l(sup)T2), 10.04(1(sup)A2), 10.07(1(sup)E), 10.12(2(sup)T1), and 10.42(2(sup)T2) eV above the ground state, respectively. Comparison of these excited state energies with the energies of possible excited states of N2+N2 fragments, leads us to propose that the most likely synthetic route for Td N4 involving this mechanism arises from combination of two bound quintet states of N2.

Lee, Timothy J.↗
NASA NTRS2002

Ground and Flight Test Structural Excitation Using Piezoelectric Actuators

A flight flutter experiment at the National Aeronautics and Space Administration (NASA) Dryden Flight Research Center, Edwards, California, used an 18-inch half-span composite model called the Aerostructures Test Wing (ATW). The ATW was mounted on a centerline flight test fixture on the NASA F-15B and used distributed piezoelectric strain actuators for in-flight structural excitation. The main focus of this paper is to investigate the performance of the piezoelectric actuators and test their ability to excite the first-bending and first-torsion modes of the ATW on the ground and in-flight. On the ground, wing response resulting from piezoelectric and impact excitation was recorded and compared. The comparison shows less than a 1-percent difference in modal frequency and a 3-percent increase in damping. A comparison of in-flight response resulting from piezoelectric excitation and atmospheric turbulence shows that the piezoelectric excitation consistently created an increased response in the wing throughout the flight envelope tested. The data also showed that to obtain a good correlation between the piezoelectric input and the wing accelerometer response, the input had to be nearly 3.5 times greater than the turbulence excitation on the wing.

Voracek, David F.↗
NASA NTRS2002

Effect of Electronic Excitation on Hydrogen Atom Transfer (Tautomerization) Reactions for the DNA Base Adenine

Geometrical structures and energetic properties for four different tautomers of adenine are calculated in this study, using multi-configurational wave functions. Both the ground and the lowest single excited state potential energy surface are studied. The energetic order of the tautomers on the ground state potential surface is 9H less than 7H less than 3H less than 1H, while on the excited state surface this order is found to be different: 3H less than 1H less than 9H less than 7H. Minimum energy reaction paths are obtained for hydrogen atom transfer (9 yields 3 tautomerization) reactions in the ground and the lowest excited electronic state. It is found that the barrier heights and the shapes of the reaction paths are different for the ground and the excited electronic state, suggesting that the probability of such tautomerization reaction is higher on the excited state potential energy surface. The barrier for this reaction in the excited state may become very low in the presence of water or other polar solvent molecules, and therefore such tautomerization reaction may play an important role in the solution phase photochemistry of adenine.

Chaban, Galina M.↗
NASA NTRS2005

The electron excited ultraviolet spectrum of HD : cross sections and transition probabilities

We have analyzed the high-resolution ultraviolet (UV) emission spectrum of molecular deuterium hydride (HD) excited by electron impact at 100 eV under optically thin, single-scattering experimental conditions. The high-resolution spectrum (FWHM=160 mA) spans the wavelength range from 900 to 1650 A and contains the two Rydberg series of HD: (sup 1)Sigma(sub u)(sup +)1s(sigma), np(si n=2, 3, 4) --> X(sup 1)Sigma(sub g)(sup +) and (sup 1)Pi(sub u)(sup +)1s(sigma), np(pi)(C,D,D',D'', n=2, 3, 4, 5) -->X(sup 1)Sigma(sub g)(sup +). A model spectrum of HD, based on newly calculated tra rovibrational coupling for the strongest band systems, B (sup 1)Sigma(sub u)(sup +)-X(sup 1)Sigma(sub g)(sup +),B'(sup 1)Sigma(sub g)(sup +)-X(sup 1)Sigma(sub g)(sup +),C(sup 1)Pi(sub u)-X(sup 1)Sigm sections for direct excitation at 100 eV of the B (sup 1)Sigma(sub u)(sup +), B' (sup 1)Sigma(sub u)(sup +), C(sup 1)Pi(sub u), and D(sup 1)Pi(sub u) states were derived from a model analysis of the state. The absolute cross section values for excitation to the B (sup 1)Sigma(sub u)(sup +), B' (sup 1)Sigma(sub u)(sup +), C(sup 1)Pi(sub u), and D(sup 1)Pi(sub u) states were found to be (2.57+/-0. and (0.17+/-0.04)x10(exp -17) sq cm, respectively. We have also determined the dissociative excitation cross sections at 100 eV for the emission of Ly(alpha) at 1216 A and Ly(Beta) at 1025 A lines, which are (7.98+/-1.12)x10(exp -18) and (0.40+/-0.10)x10(exp -18) sq cm, respectively. The summed excitation function of the closely spaced pair of lines, H Ly(alpha) and D Ly(Beta), resulting from excitation of HD, has been measured from the threshold to 800 eV and is analytically modeled with a semiempirical relation. The model cross sections are in good agreement with the corrected Ly(alpha) cross sections of Mohlmann et al. up to 2 keV. Based on measurements of H, D (2s) production cross section values by Mohlmann et al., the H, D (n=2) cross section is estimated to be 1.6 x 10(exp -17) sq cm at 100 eV.

molecular data↗
NASA NTRS2010

Effect of Turbulence Modeling on an Excited Jet

The flow dynamics in a high-speed jet are dominated by unsteady turbulent flow structures in the plume. Jet excitation seeks to control these flow structures through the natural instabilities present in the initial shear layer of the jet. Understanding and optimizing the excitation input, for jet noise reduction or plume mixing enhancement, requires many trials that may be done experimentally or computationally at a significant cost savings. Numerical simulations, which model various parts of the unsteady dynamics to reduce the computational expense of the simulation, must adequately capture the unsteady flow dynamics in the excited jet for the results are to be used. Four CFD methods are considered for use in an excited jet problem, including two turbulence models with an Unsteady Reynolds Averaged Navier-Stokes (URANS) solver, one Large Eddy Simulation (LES) solver, and one URANS/LES hybrid method. Each method is used to simulate a simplified excited jet and the results are evaluated based on the flow data, computation time, and numerical stability. The knowledge gained about the effect of turbulence modeling and CFD methods from these basic simulations will guide and assist future three-dimensional (3-D) simulations that will be used to understand and optimize a realistic excited jet for a particular application.

Brown, Clifford A.↗
DOE OSTI2026

Complex and Unusual Excited-State Relaxation Dynamics of 9,9′-Bifluorenylidene Revealed by Comprehensive Time-Resolved Spectroscopy and MRSF-TDDFT Calculations

Design of novel photochemical molecular motors often requires molecular building blocks that exhibit rather unusual photoactivity, for which conventional analyses of spectroscopic data can lead to conflicting interpretations. We here systematically investigated the excited-state relaxation dynamics of one such molecule, 9,9′-bifluorenylidene (BF), through comprehensive and complementary integration of ultrafast transient absorption (TA) and femtosecond stimulated Raman (FSRS) spectroscopies and first-principles mixed-reference spin-flip time-dependent density functional theory (MRSF-TDDFT). TA and FSRS identified two sequentially formed transients following photoexcitation. The decay kinetics of the two intermediates differ in response to excitation wavelengths and the viscosity/polarity of solvents. MRSF-TDDFT calculations reveal a direct, barrierless internal-conversion pathway from the bright Franck−Condon state to a dark S1 minimum, where the excited-state population is transiently trapped, accounting for the first transient species observed in spectroscopic experiments. Further tracking down along the PES with MRSF-TDDFT mapped out two nonradiative relaxation pathways via conical intersections that connect the dark S 1 state to three configurations in the ground-state manifolds, within which a ring structure with a C8−C8′ bond and the vibrationally excited ground-state BF were identified from spectroscopic and kinetic data. The complexity of relaxation kinetics was attributed to the flexible torsional and twisting motions about the C9−C9′ bridge bond enabled by the diradical character of the S 1 state. These findings clarify unusual photoactive relaxation dynamics stemming from a novel correlation between structural flexibility and shifting electronic characteristics, and they demonstrate the importance of integrating spectroscopic and advanced electronic structure calculation studies for judicious clarification of complex, competing relaxation pathways of excited states.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗