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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
NASA NTRS1997

Cr(+2) Diffusion Doping in ZnSe

Chromium doped zinc selenides crystals have recently been demonstrated to be a promising material for near-IR room temperature tunable lasers which has an emission range of 2-3 pm. In this study, a new diffusion doping process has been developed for incorporation of Cr(+2) ion into ZnSe wafers. This process has been successfully performed under isothermal conditions, at temperatures above 800 degrees Celsius. Concentrations in excess of 10(exp 19) Cr(+2) ions/cu cm, an order of magnitude larger than previously reported in melt grown ZnSe material, have been obtained. The diffusivity was estimated to be about 10-* sq cm/sec using a classical diffusion model. Resistivity was derived from current-voltage measurements and in the 107-10(exp 16) Ohms-cm and increased as function of Cr concentration.

Journigan, Troy D.↗
NASA NTRS2000

Comparison of Os and Cr Isotopic Methods for the Detection of Meteoritic Components in Impact Melt Rocks from the Morokweng and Vredefort Impact Structures, South Africa

The verification of an extraterrestrial component in impact-derived melt rocks or breccias can be of diagnostic value to provide confirming evidence for an impact origin of a geological structure. Geochemical methods are used to determine the presence of the traces of such a component. In the absence of actual meteorite fragments, it is necessary to search for traces of meteoritic material that is mixed in with the target rocks in breccias and melt rocks. Meteoritic components have been identified for just over 40 impact structures (out of more than 160 known on Earth), which reflects also the detail in which these structures were studied. The identification of a meteoritic component can be achieved by determining the concentrations and interelement ratios of siderophile elements, especially the platinum group elements (PGE), which are several orders of magnitude more abundant in meteorites than in terrestrial upper crustal rocks. The usage of platinum group element abundances and ratios avoids some of the ambiguities that may result if only common siderophile elements (e.g., Cr, Co, Ni) are considered. However, problems may arise if the target rocks have high abundances of siderophile elements, or if the siderophile element concentrations in the impactites are very low. In such cases, the Os and Cr isotopic systems have recently been used for establishing the presence of a meteoritic component in a number of impact melt rocks and breccias. In the past it was attempted to use PGE data to determine the type or class of meteorite for the impactor, but these attempts were not always successful. It is difficult to decide between chondrite types based on PGE abundances, which has led to conflicting identifications for a number of impact structures. Clearly, the identification of a meteoritic component in impactites is not a trivial problem. In this study, we are using a combination of trace element (PGE) analyses and the results from both, Os and Cr isotopic studies, to illustrate the pros and cons of each method on two case studies, namely the Vredefort and Morokweng impact structures. Additional information is contained in the original extended abstract.

Koeberl, Christian↗
NASA NTRS2001

Membership and Coronal Activity in the NGC 2232 and Cr 140 Open Clusters

This is the second annual performance report for our grant "Membership and Coronal Activity in the NGC 2232 and Cr 140 Open Clusters." We propose to identify X-ray sources and extract net source counts in 8 archival ROSAT HRI images in the regions of the NGC 2232 and Cr 140 open clusters. These X-ray data will be combined with ground-based photometry and spectroscopy in order to identify G, K, and early-M type cluster members. At present, no members later than approximately F5 are currently known for either cluster. With ages of approximately 25 Myr and at a distance of just 320 - 360 pc, the combined late-type membership of the NGC 2232 and Cr 140 clusters will yield an almost unique sample of solar-type stars in the post-T Tauri/pre-main sequence phase of evolution. These stars will be used to assess the level and dispersion in coronal activity levels, as part of a probe of the importance of magnetic braking and the level of magnetic dynamo activity, for solar-type stars just before they reach the ZAMS. Over the past year we have successfully acquired all of the ground-based data necessary to support the analysis of the archival ROSAT X-ray data in the regions around both of these clusters. By the end of 2001 we expect to have completed the reduction and analysis of the ground-based photometry and spectroscopy and will begin the integration of these data with the ROSAT X-ray data. A certain amount of pressure to complete the work on NGC 2232 is coming from the SIRTF project, as this cluster may be a key component to a circumstellar disk evolution GTO program. We are only too happy to try to help and have worked to speed the analysis as much as possible. The primary activity to be undertaken in the next few months is the integration of the groundbased photometry and spectroscopy with the archival ROSAT X-ray data and then writing the paper summarizing our results. The most time consuming portion of this next phase is, of course, seeing the paper through publication in a peer-reviewed journal. Therefore, we have requested a no-cost extension to the grant to allow us to bring this project to a conclusion.

Patten, Brian M.↗
NASA NTRS2002

Experimental Verification of the Theoretical Prediction of the Phase Structure of a Ni-Al-Ti-Cr-Cu Alloy

The Bozzolo-Ferrante-Smith (BFS) method for alloys was applied to the study of NiAl-based materials to assess the effect of alloying additions on structure. Ternary, quaternary and even pentalloys based on NiAl with additions of Ti, Cr and Cu were studied and experimental verification of the theoretical predictions including the phase structure of a Ni-Al-Ti-Cr-Cu alloy is presented. Two approaches were used, Monte Carlo simulations to determine low energy structures, and analytical calculations of the energy of high symmetry configurations which give physical insight into preferred structures. The energetics for site occupancy in ternary and quaternary systems were calculated leading to an indirect determination of solubility limits at 0 K. Precipitate formation with information concerning structure and lattice parameter were also 'observed' computationally and the general characteristics of a Ni-Al-Ti-Cr-Cu alloy were correctly predicted. The results indicate that the BFS method for alloys can be a useful tool for alloy design and can be used to complement experimental alloy design programs.

Wilson, A.↗
NASA NTRS2003

Antiprotons in CR: What Do They Tell Us?

Recent measurements of the CR antiproton flux have been shown to pose a problem for conventional propagation models (Moskalenko et al. 2002). In particular, models consistent with secondary/primary nuclei ratio in CR produce too few antiprotons, while matching the ratio and the antiproton flux requires some artificial assumptions. This may indicate an additional local CR component or new phenomena in particle propagation in the Galaxy. We discuss several possibilities which may cause this problem.

Moskalenko, I. V.↗
NASA NTRS2003

Protection of Advanced Copper Alloys With Lean Cu-Cr Coatings

Advanced copper alloys are used as liners of rocket thrusters and nozzle ramps to ensure dissipation of the high thermal load generated during launch, and Cr-lean coatings are preferred for the protection of these liners from the aggressive ambient environment. It is shown that adequate protection can be achieved with thin Cu-Cr coatings containing as little as 17 percent Cr.

Greenbauer-Seng, L.↗
NASA NTRS2003

Vanadium, Cr, Si, and the Mg/Si Ratio of the Earth

Experiments investigating the partitioning of V, Cr, and Si between metal and silicate at various pressures, temperatures, redox state, and composition demonstrate that V and Cr are always more siderophile than Si. The relatively high abundances of V and Cr in the Earth's upper mantle indicate that the high Mg/Si ratio of the Earth's upper mantle cannot be attributed to extraction of Si into the core and must be an intrinsic bulk property of the silicate Earth.

Drake, Michael J.↗
NASA NTRS2005

Energetics of Oxygen Interstitials in Cr and V

Dissolved oxygen in group IIIA-VA (Nb, Ti, Zr, Y) based alloys is a fundamental problem, affecting both mechanical properties and oxidation resistance, yet details of the phenomenon are poorly understood. In these alloys, oxygen is more stable dissolved in the metal than as an oxide-compound. In contrast, alloys based on Ni, Fe, Al and Cr exhibit almost no oxygen solubility. To improve the performance of Nb and Ti based alloys it is necessary to understand the differences in oxygen solubility between these two groups of metals. As a first step we considered the energetics of interstitial oxygen in alpha-V and alpha-Cr. Both of these metals have a BCC structure, yet the oxygen solubility in V is much higher than that in Cr. We obtain total energies, densities of states and population analyses using the CASTEP plane-wave pseudopotential density functional computer code. The differences in the energetics and electronic structures of the two materials, particularly the partial densities of states associated with the interstitial oxygen, are discussed.

Good, Brian S.↗
NASA NTRS2005

TEMPORAL EVOLUTION OF SUB-NANOMETER COMPOSITIONAL PROFILES ACROSS THE GAMMA/GAMMA' INTERFACE IN A MODEL Ni-Al-Cr SUPERALLOY

Early-stage phase separation in a Ni-5.2 Al-14.2 Cr at.% superalloy, isothermally decomposing at 873 K, is investigated with atom-probe tomography. Sub-nanometer scale compositional profiles across the gamma/gamma'(L12) interfaces demonstrate that both the gamma-matrix and the gamma'-precipitate compositions evolve with time. Observed chemical gradients of Al depletion and Cr enrichment adjacent to the gamma'-precipitates are transient, consistent with well-established model predictions for diffusion-limited growth, and mark the first detailed observation of this phenomenon. Furthermore, it is shown that Cr atoms are kinetically trapped in the growing precipitates.

Sudbrack, Chantal K.↗
NASA NTRS2006

Radiation measured with TEPC and CR-39 PNTDs in low Earth orbit

The radiation impact to astronauts depends strongly on the particles linear energy transfer (LET) and is dominated by high LET radiation. It is important to investigate the LET spectrum for the radiation field in low Earth orbit (LEO) and the influence of radiation on astronauts. The best active dosimeter used for all LET is the tissue equivalent proportional counter (TEPC); the best passive dosimeter used for high LET is CR-39 plastic nuclear track dosimeter (PNTD). TEPC and CR-39 PNTDs were used to investigate the radiation in LEO. LET spectra and radiation quantities were obtained for STS-112 and STS-114 missions with TEPC and CR-39 PNTDs. This paper introduces the operation principles for the two types of dosimeters, presents radiation results measured and compares the results obtained with different dosimeters.

Zhou, D.↗
NASA NTRS2008

Effects of Solute Concentrations on Kinetic Pathways in Ni-Al-Cr Alloys

The kinetic pathways resulting from the formation of coherent gamma'-precipitates from the gamma-matrix are studied for two Ni-Al-Cr alloys with similar gamma'-precipitate volume fractions at 873 K. The details of the phase decompositions of Ni-7.5Al-8.5Cr at.% and Ni-5.2Al-14.2Cr at.% for aging times from 1/6 to 1024 h are investigated by atom-probe tomography, and are found to differ significantly from a mean-field description of coarsening. The morphologies of the gamma'-precipitates of the alloys are similar, though the degrees of gamma'-precipitate coagulation and coalescence differ. Quantification within the framework of classical nucleation theory reveals that differences in the chemical driving forces for phase decomposition result in differences in the nucleation behavior of the two alloys. The temporal evolution of the gamma'-precipitate average radii and the gamma-matrix supersaturations follow the predictions of classical coarsening models. The compositional trajectories of the gamma-matrix phases of the alloys are found to follow approximately the equilibrium tie-lines, while the trajectories of the gamma'-precipitates do not, resulting in significant differences in the partitioning ratios of the solute elements.

Booth-Morrison, Christopher↗
NASA NTRS2009

Effects of Tantalum on the Temporal Evolution of a Model Ni-Al-Cr Superalloy During Phase Decomposition

The effects of a 2.0 at.% addition of Ta to a model Ni-10.0Al-8.5Cr (at.%) superalloy aged at 1073 K are assessed using scanning electron microscopy and atom-probe tomography. The gamma'(Ll2)-precipitate morphology that develops as a result of gamma-(fcc)matrix phase decomposition is found to evolve from a bimodal distribution of spheroidal precipitates, to {001}-faceted cuboids and parallelepipeds aligned along the elastically soft {001}-type directions. The phase compositions and the widths of the gamma'-precipitate/gamma-matrix heterophase interfaces evolve temporally as the Ni-Al-Cr-Ta alloy undergoes quasi-stationary state coarsening after 1 h of aging. Tantalum is observed to partition preferentially to the gamma'-precipitate phase, and suppresses the mobility of Ni in the gamma-matrix sufficiently to cause an accumulation of Ni on the gamma-matrix side of the gamma'/gamma interface. Additionally, computational modeling, employing Thermo-Calc, Dictra and PrecipiCalc, is employed to elucidate the kinetic pathways that lead to phase decomposition in this concentrated Ni-Al-Cr-Ta alloy.

Booth, Morrison, Christopher↗
NASA NTRS2009

Coronal Transient Ejections and Outflows During the CR 2068 WHI Campaign

The Whole Heliospheric Interval (WHI) campaigns began with a set of coordinated observations over Carrington Rotation (CR) 2068, which was from March~20 to April~16, 2008. An ultimate objective of WHI to understand the 3-D nature of the heliosphere. Activity on the Sun is the engine that drives the dynamics of the heliosphere, and therefore delineation of the characteristics of the Sun's atmosphere and its output over the period of study is vital to the success of WHI\@. Here we discuss the origins of solar structures that can lead to heliospheric effects, with an emphasis on observations during the CR~2068 WHI interval. These structures include both outflows from open-field regions, and transients originating from closed-field regions. Our focus will be mainly on the latter, and we will specifically consider the coronal source regions of coronal mass ejections (CMEs), and other transients that escape out into the heliosphere, for example in the form of slow expansions or as narrow jets. Over the CR~2068 period we have identified about 30 such transients, with about 20\% of them being moderately to very prominent. We will consider these feature s source regions by examining low-coronal data, along with solar surface magnetograms that provide the magnetic setting of the eruptions. Through intercomparisons of these data, we infer the coronal setup for different eruptions, and the implications for models that attempt to describe eruption-onset mechanisms.

Sterling, Alphonse C.↗
NASA NTRS2010

Distinct Distribution of Purines in CM and CR Carbonaceous Chondrites

Carbonaceous meteorites contain a diverse suite of organic molecules and delivered pre biotic organic compounds, including purines and pyrimidines, to the early Earth (and other planetary bodies), seeding it with the ingredients likely required for the first genetic material. We have investigated the distribution of nucleobases in six different CM and CR type carbonaceous chondrites, including fivc Antarctic meteorites never before analyzed for nucleobases. We employed a traditional formic acid extraction protocol and a recently developed solid phase extraction method to isolate nucleobases. We analyzed these extracts by high performance liquid chromatography with UV absorbance detection and tandem mass spectrometry (HPLC-UV -MS/MS) targeting the five canonical RNAIDNA bases and hypoxanthine and xanthine. We detected parts-per-billion levels of nucleobases in both CM and CR meteorites. The relative abundances of the purines found in Antarctic CM and CR meteorites were clearly distinct from each other suggesting that these compounds are not terrestrial contaminants. One likely source of these purines is formation by HCN oligomerization (with other small molecules) during aqueous alteration inside the meteorite parent body. The detection of the purines adenine (A), guanine (0), hypoxanthine (HX), and xanthine (X) in carbonaceous meteorites indicates that these compounds should have been available on the early Earth prior to the origin of the first genetic material.

Callahan, Michael P.↗
NASA NTRS2016

Petrology of Amoeboid Olivine Aggregates in Antarctic CR Chondrites: Comparison With Other Carbonaceous Chondrites

Amoeboid olivine aggregates (AOAs) are important refractory components of carbonaceous chondrites and have been interpreted to represent solar nebular condensates that experienced high-temperature annealing, but largely escaped melting. In addition, because AOAs in primitive chondrites are composed of fine-grained minerals (forsterite, anorthite, spinel) that are easily modified during post crystallization alteration, the mineralogy of AOAs can be used as a sensitive indicator of metamorphic or alteration processes. AOAs in CR chondrites are particularly important because they show little evidence for secondary alteration. In addition, some CR AOAs contain Mn-enriched forsterite (aka low-iron, Mn-enriched or LIME olivine), which is an indicator of nebular formation conditions. Here we report preliminary results of the mineralogy and petrology of AOAs in Antarctic CR chondrites, and compare them to those in other carbonaceous chondrites.

Komatsu, M.↗
NASA NTRS2016

The Cr Redox Record of fO2 Variation in Angrites. Evidence for Redox Conditions of Angrite Petrogenesis and Parent Body

Angrites represent some of the earliest stages of planetesimal differentiation. Not surprisingly, there is no simple petrogenetic model for their origin. Petrogenesis has been linked to both magmatic and impact processes. Studies demonstrated that melting of chondritic material (e.g. CM, CV) at redox conditions where pure iron metal is unstable (e.g., IW+1 to IW+2) produced angrite-like melts. Alternatively, angrites were produced at more reducing conditions (<IW) with their exotic melt compositions resulting from carbonates in the source or from nebular condensation. Clearly, understanding what role fO2 plays in producing angrite magmas is critical for deciphering their petrogenesis and extending our understanding of primordial melting of asteroids. Calculations for the fO2 conditions of angrite crystallization are limited, and only preliminary attempts been made to understand the changes in fO2 that occurred during petrogenesis. Many of the angrites have phase assemblages which provide conflicting signals about redox conditions during crystallization (e.g., Fe metal and a Fe-Ti oxide with potential Fe3+. There have been several estimates of fO2 for angrites. Most notably, experiments examined the variation of DEu/DGd with fO2, between plagioclase and fassaitic pyroxene in equilibrium with an angrite melt composition. They used their observations to estimate the fO2 of crystallization to be approximately IW+0.6 for angrite LEW 86010. This estimate is only a "snapshot" of fO2 conditions during co-crystallization of plagioclase and pyroxene. Preliminary XANES analyses of V redox state in pyroxenes from D'Orbigny reported changes in fO2 from IW-0.7 during early pyroxene crystallization to IW+0.5 during latter episodes of pyroxene crystallization [15]. As this was a preliminary report, it presented limited information concerning the effects of pyroxene orientation and composition on the V valence measurements, and the effect of melt composition on valence and partitioning behavior of V. A closer examination of fO2 as recorded by Cr valence state in olivine will allow us to test models for primordial melting of chondritic material to produce the angrite parent melts. Here, we report the our initial stages of examining the origin and conditions of primordial melting on the angrite parent body and test some of the above models by integrating an experimental study of Cr and V valence partitioning between olivine [OL] and an angrite melt, with micro-scale determinations of Cr and V oxidation state in OL in selected "volcanic" angrites.

Shearer, Charles K.↗
NASA NTRS2016

Temperature Mapping of Air Film-Cooled Thermal Barrier Coated Surfaces Using Cr-Doped GdAlO3 Phosphor Thermography

It has been recently shown that the high luminescence intensity from a Cr-doped GdAlO3 (Cr:GdAlO3) thermographic phosphor enables non-rastered full-field temperature mapping of thermal barrier coating (TBC) surfaces to temperatures above 1000C. In this presentation, temperature mapping by Cr:GdAlO3 based phosphor thermometry of air film-cooled TBC-coated surfaces is demonstrated for both scaled-up cooling hole geometries as well as for actual components in a burner rig test environment. The effects of thermal background radiation and flame chemiluminescence on the measurements are investigated, and advantages of this method over infrared thermography as well as the limitations of this method for studying air film cooling are discussed.

thermographic phoshor↗
NASA NTRS2017

Valence State Partitioning of Cr and V Between Olivine-Melt and Pyroxene-Melt in Experimental Basalts of a Eucritic Composition

The partitioning of multivalent elements in basaltic systems can elucidate the oxygen fugacity (fO2) conditions under which basalts formed on planetary bodies (Earth, Moon, Mars, asteroids). Chromium and V are minor and trace elements in basaltic melts, partition into several minerals that crystallize from basaltic melts, exist in multiple valence states at differing fO2 conditions, and can therefore be used as oxybarometers for basaltic melts. Chromium is mostly 3+ in terrestrial basaltic melts at relatively high fO2 values (≥ IW+3.5), and mostly 2+ in melts at low fO2 values (≤ IW-1), such as those on the Moon and some asteroids. At intermediate fO2s, (i.e., IW-1 to IW+3.5), basaltic melts contain both Cr3+ and Cr2+. Vanadium in basaltic melts is mostly 4+ at high fO2, mostly 3+ at low fO2, and a mix of V3+ and V4+ at intermediate fO2 con-ditions. Understanding the partitioning of Cr and V into silicate phases with changing fO2 is therefore critical to the employment of Cr and V oxybarometers. In this abstract we examine the equilibrium partitioning of Cr and V between olivine/melt and pyroxene/melt in experimental charges of a eucritic composition produced at differing fO2 conditions. This study will add to the experimental data on DCr and DV (i.e., olivine/melt, pyroxene/melt) at differing fO2, and in turn these D values will be used to assess the fO2 of eucrite basalts and perhaps other compositionally similar planetary basalts.

Karner, J. M.↗