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NASA NTRS2000

An Interpretation of Banded Magnetospheric Radio Emissions

Recently-published Active Magnetospheric Particle Tracer Explorer/Isothermal Remanent Magnetization (AMPTE/IRM) banded magnetospheric emissions, commonly referred to as '(n + 1/2)f(sub ce)' emissions where f(sub ce) is the electron gyrofrequency, are analyzed by treating them as analogous to sounder-stimulated ionospheric emissions. We show that both individual AMPTE/IRM spectra of magnetospheric banded emissions, and a statistically-derived spectra observed over the two-year lifetime of the mission, can be interpreted in a self-consistent manner. The analysis, which predicts all spectral peaks within 4% of the observed peaks, interprets the higher-frequency emissions as due to low group-velocity Bernstein-mode waves and the lower-frequency emissions as eigen modes of cylindrical-electromagnetic-plasma-oscillations. The demarcation between these two classes of emissions is the electron plasma frequency f(sub pe), where an emission is often observed. This f(sub pe), emission is not necessarily the strongest. None of the observed banded emissions were attributed to the upper-hybrid frequency. We present Alouette-2 and ISIS-1 plasma-resonance data, and model electron temperature (T(sub e)) values, to support the argument that the frequency-spectrum of ionospheric sounder-stimulated emissions is not strongly temperature dependent and thus that the interpretation of these emissions in the ionosphere is relevant to other plasmas (such as the magnetosphere) where N(sub e) and T(sub e) can be quite different but where the ratio f(sub pe)/f(sub ce) is identical.

Benson, Robert F.↗
NASA NTRS2000

SeaWIFS Postlaunch Technical Report Series: The SeaWiFS Photometer Revision for Incident Surface Measurement (SeaPRISM) Field Commissioning - Volume 13

This report documents the scientific activities that took place at the Acqua Alta Oceanographic Tower (AAOT) in the northern Adriatic Sea off the coast of Italy from 2-6 August 1999. The ultimate objective of the field campaign was to evaluate the capabilities of a new instrument called the SeaWiFS Photometer Revision for Incident Surface Measurements (SeaPRISM). SeaPRISM is based on a CE-318 sun photometer made by CIMEL Electronique (Paris, France). The CE-318 is an automated, robotic system which measures the direct sun irradiance plus the sky radiance in the sun plane and in the almucantar plane. The data are transmitted over a satellite link, and this remote operation capability has made the device very useful for atmospheric measurements. The revision to the CE-318 that makes the instrument potentially useful for SeaWiFS calibration and validation activities is to include a capability for measuring the radiance leaving the sea surface in wavelengths suitable for the determination of chlorophyll a concentration. The initial evaluation of this new capability involved above- and in-water measurement protocols. An intercomparison of the water-leaving radiances derived from SeaPRISM and an in-water system showed the overall spectral agreement was approximately 8.6%, but the blue-green channels intercompared at the 5% level. A blue-green band ratio comparison was at the 4% level.

Hooker, Stanford B.↗
NASA NTRS2000

Estimation of the oxalate content of foods and daily oxalate intake

BACKGROUND: The amount of oxalate ingested may be an important risk factor in the development of idiopathic calcium oxalate nephrolithiasis. Reliable food tables listing the oxalate content of foods are currently not available. The aim of this research was to develop an accurate and reliable method to measure the food content of oxalate. METHODS: Capillary electrophoresis (CE) and ion chromatography (IC) were compared as direct techniques for the estimation of the oxalate content of foods. Foods were thoroughly homogenized in acid, heat extracted, and clarified by centrifugation and filtration before dilution in water for analysis. Five individuals consuming self-selected diets maintained food records for three days to determine their mean daily oxalate intakes. RESULTS: Both techniques were capable of adequately measuring the oxalate in foods with a significant oxalate content. With foods of very low oxalate content (<1.8 mg/100 g), IC was more reliable than CE. The mean daily intake of oxalate by the five individuals tested was 152 +/- 83 mg, ranging from 44 to 352 mg/day. CONCLUSIONS: CE appears to be the method of choice over IC for estimating the oxalate content of foods with a medium (>10 mg/100 g) to high oxalate content due to a faster analysis time and lower running costs, whereas IC may be better suited for the analysis of foods with a low oxalate content. Accurate estimates of the oxalate content of foods should permit the role of dietary oxalate in urinary oxalate excretion and stone formation to be clarified. Other factors, apart from the amount of oxalate ingested, appear to exert a major influence over the amount of oxalate excreted in the urine.

NASA Discipline Regulatory Physiology↗
NASA NTRS1994

Comparing the effects of two in-flight aerobic exercise protocols on standing heart rates and VO(2peak) before and after space flight

The effects of regular aerobic exercise on orthostatic tolerance have been the subject of a long-standing controversy that will influence the use of exercise during space flight. To examine these effects, astronauts performed continuous (CE) aerobic exercise (n = 8), interval (IE) aerobic exercise (n = 4), or no (NE) exercise (n = 5) during flights of 7 to 11 days. Heart rate (HR) responses to an orthostatic challenge (stand test) were measured 10 days before flight and on landing day. VO(2peak) (graded treadmill exercise) was measured 7 to 21 days before and 2 days after flight. No significant differences across the groups were observed in standing HRs before or after flight. However, the within-group mean HRs significantly increased in the NE (71-89 beats/min) and CE (60-85 beats/min) groups after space flight. The HRs for the IE group did not significantly increase (75-86 beats/min) after space flight. VO(2peak) decreased (P < .05) in the NE (-9.5%) group, but did not change in the CE (-2.4%) and IE (1%) groups. The relationship (r = 0.237) between the delta HR and delta VO(2peak) was not significant. These preliminary results indicate that: (1) continuous exercise does not affect the orthostatic HR response after space flight; (2) interval exercise may minimize an increase in the postflight orthostatic HR; and (3) both exercise protocols can maintain VO(2peak).

NASA Discipline Musculoskeletal↗
NASA NTRS2008

The Effect of Habitual Smoking on VO2max

VO2max is associated with many factors, including age, gender, physical activity, and body composition. It is popularly believed that habitual smoking lowers aerobic fitness. PURPOSE: to determine the effect of habitual smoking on VO2max after controlling for age, gender, activity and BMI. METHODS: 2374 men and 375 women employed at the NASA/Johnson Space Center were measured for VO2max by indirect calorimetry (RER>=1.1), activity by the 11 point (0-10) NASA Physical Activity Status Scale (PASS), BMI and smoking pack-yrs (packs day*y of smoking). Age was recorded in years and gender was coded as M=1, W=0. Pack.y was made a categorical variable consisting of four levels as follows: Never Smoked (0), Light (1-10), Regular (11-20), Heavy (>20). Group differences were verified by ANOVA. A General Linear Models (GLM) was used to develop two models to examine the relationship of smoking behavior on VO2max. GLM #1(without smoking) determined the combined effects of age, gender, PASS and BMI on VO2max. GLM #2 (with smoking) determined the added effects of smoking (pack.y groupings) on VO2max after controlling for age, gender, PASS and BMI. Constant errors (CE) were calculated to compare the accuracy of the two models for estimating the VO2max of the smoking subgroups. RESULTS: ANOVA affirmed the mean VO2max of each pack.y grouping decreased significantly (p<0.01) as the level of smoking exposure increased. GLM #1 showed that age, gender, PASS and BMI were independently related with VO2max (R2 = 0.642, SEE = 4.90, p<0.001). The added pack.y variables in GLM #2 were statistically significant (R2 change = 0.7%, p<0.01). Post hoc analysis showed that compared to Never Smoked, the effects on VO2max from Light and Regular smoking habits were -0.83 and -0.85 ml.kg- 1.min-1 respectively (p<0.05). The effect of Heavy smoking on VO2max was -2.56 ml.kg- 1.min-1 (p<0.001). The CE s of each smoking group in GLM #2 was smaller than the CE s of the smoking group counterparts in GLM #1. CONCLUSIONS: After accounting for the effects of gender, age, PASS and BMI the effect of habitual smoking on reducing VO2max is minimal, about 0.85 ml/kg/min, until the habit exceeds 20 pack.y at which point an additional decrease of 1.71 ml/kg/min is noted. Adding pack.y data improves the accuracy of predicting the VO2max of smokers.

Wier, Larry T.↗
NASA NTRS2012

Automated Lab-on-a-Chip Electrophoresis System

Capillary electrophoresis is an analytical technique that can be used to detect and quantify extremely small amounts of various biological molecules. In the search for biochemical traces of life on other planets, part of this search involves an examination of amino acids, which are the building blocks of life on Earth. The most sensitive method for detecting amino acids is the use of laser induced fluorescence. However, since amino acids do not, in general, fluoresce, they first must be reacted with a fluorescent dye label prior to analysis. After this process is completed, the liquid sample then must be transported into the electrophoresis system. If the system is to be reused multiple times, samples must be added and removed each time. In typical laboratories, this process is performed manually by skilled human operators using standard laboratory equipment. This level of human intervention is not possible if this technology is to be implemented on extraterrestrial targets. Microchip capillary electrophoresis (CE) combined with laser induced fluorescence detection (LIF) was selected as an extremely sensitive method to detect amino acids and other compounds that can be tagged with a fluorescent dye. It is highly desirable to package this technology into an integrated, autonomous, in situ instrument capable of performing CE-LIF on the surface of an extraterrestrial body. However, to be fully autonomous, the CE device must be able to perform a large number of sample preparation and analysis operations without the direct intervention of a human.

Willis, Peter A.↗
NASA NTRS2013

Distributed Prognostics and Health Management with a Wireless Network Architecture

A heterogeneous set of system components monitored by a varied suite of sensors and a particle-filtering (PF) framework, with the power and the flexibility to adapt to the different diagnostic and prognostic needs, has been developed. Both the diagnostic and prognostic tasks are formulated as a particle-filtering problem in order to explicitly represent and manage uncertainties in state estimation and remaining life estimation. Current state-of-the-art prognostic health management (PHM) systems are mostly centralized in nature, where all the processing is reliant on a single processor. This can lead to a loss in functionality in case of a crash of the central processor or monitor. Furthermore, with increases in the volume of sensor data as well as the complexity of algorithms, traditional centralized systems become for a number of reasons somewhat ungainly for successful deployment, and efficient distributed architectures can be more beneficial. The distributed health management architecture is comprised of a network of smart sensor devices. These devices monitor the health of various subsystems or modules. They perform diagnostics operations and trigger prognostics operations based on user-defined thresholds and rules. The sensor devices, called computing elements (CEs), consist of a sensor, or set of sensors, and a communication device (i.e., a wireless transceiver beside an embedded processing element). The CE runs in either a diagnostic or prognostic operating mode. The diagnostic mode is the default mode where a CE monitors a given subsystem or component through a low-weight diagnostic algorithm. If a CE detects a critical condition during monitoring, it raises a flag. Depending on availability of resources, a networked local cluster of CEs is formed that then carries out prognostics and fault mitigation by efficient distribution of the tasks. It should be noted that the CEs are expected not to suspend their previous tasks in the prognostic mode. When the prognostics task is over, and after appropriate actions have been taken, all CEs return to their original default configuration. Wireless technology-based implementation would ensure more flexibility in terms of sensor placement. It would also allow more sensors to be deployed because the overhead related to weights of wired systems is not present. Distributed architectures are furthermore generally robust with regard to recovery from node failures.

Goebel, Kai↗
NASA NTRS2014

Assessment of NASA GISS CMIP5 and Post-CMIP5 Simulated Clouds and TOA Radiation Budgets Using Satellite Observations: TOA Radiation Budget and CREs - Part 2

In Part I of this study, the NASA GISS Coupled Model Intercomparison Project (CMIP5) and post-CMIP5 (herein called C5 and P5, respectively) simulated cloud properties were assessed utilizing multiple satellite observations, with a particular focus on the southern midlatitudes (SMLs). This study applies the knowledge gained from Part I of this series to evaluate the modeled TOA radiation budgets and cloud radiative effects (CREs) globally using CERES EBAF (CE) satellite observations and the impact of regional cloud properties and water vapor on the TOA radiation budgets. Comparisons revealed that the P5- and C5-simulated global means of clear-sky and all-sky outgoing longwave radiation (OLR) match well with CE observations, while biases are observed regionally. Negative biases are found in both P5- and C5-simulated clear-sky OLR. P5-simulated all-sky albedo slightly increased over the SMLs due to the increase in low-level cloud fraction from the new planetary boundary layer (PBL) scheme. Shortwave, longwave, and net CRE are quantitatively analyzed as well. Regions of strong large-scale atmospheric upwelling/downwelling motion are also defined to compare regional differences across multiple cloud and radiative variables. In general, the P5 and C5 simulations agree with the observations better over the downwelling regime than over the upwelling regime. Comparing the results herein with the cloud property comparisons presented in Part I, the modeled TOA radiation budgets and CREs agree well with the CE observations. These results, combined with results in Part I, have quantitatively estimated how much improvement is found in the P5-simulated cloud and radiative properties, particularly over the SMLs and tropics, due to the implementation of the new PBL and convection schemes.

Model comparison↗
NASA NTRS2014

Humic Acid Complexation of Th, Hf and Zr in Ligand Competition Experiments: Metal Loading and Ph Effects

The mobility of metals in soils and subsurface aquifers is strongly affected by sorption and complexation with dissolved organic matter, oxyhydroxides, clay minerals, and inorganic ligands. Humic substances (HS) are organic macromolecules with functional groups that have a strong affinity for binding metals, such as actinides. Thorium, often studied as an analog for tetravalent actinides, has also been shown to strongly associate with dissolved and colloidal HS in natural waters. The effects of HS on the mobilization dynamics of actinides are of particular interest in risk assessment of nuclear waste repositories. Here, we present conditional equilibrium binding constants (Kc, MHA) of thorium, hafnium, and zirconium-humic acid complexes from ligand competition experiments using capillary electrophoresis coupled with ICP-MS (CE- ICP-MS). Equilibrium dialysis ligand exchange (EDLE) experiments using size exclusion via a 1000 Damembrane were also performed to validate the CE-ICP-MS analysis. Experiments were performed at pH 3.5-7 with solutions containing one tetravalent metal (Th, Hf, or Zr), Elliot soil humic acid (EHA) or Pahokee peat humic acid (PHA), and EDTA. CE-ICP-MS and EDLE experiments yielded nearly identical binding constants for the metal- humic acid complexes, indicating that both methods are appropriate for examining metal speciation at conditions lower than neutral pH. We find that tetravalent metals form strong complexes with humic acids, with Kc, MHA several orders of magnitude above REE-humic complexes. Experiments were conducted at a range of dissolved HA concentrations to examine the effect of [HA]/[Th] molar ratio on Kc, MHA. At low metal loading conditions (i.e. elevated [HA]/[Th] ratios) the ThHA binding constant reached values that were not affected by the relative abundance of humic acid and thorium. The importance of [HA]/[Th] molar ratios on constraining the equilibrium of MHA complexation is apparent when our estimated Kc, MHA values attained at very low metal loading conditions are compared to existing literature data. Overall, experimental data suggest that the tetravalent transition metal/-actinide-humic acid complexation is important over a wide range of pH values, including mildly acidic conditions, and thus, these complexes should be included in speciation models.

humic acid↗
NASA NTRS2016

Exploring the Role of Humans and Climate over the Balkan Landscape: 500 Years of Vegetational History of Serbia

We present the first, well-dated, high-resolution record of vegetation and landscape change from Serbia, which spans the past 500 years. Biological proxies (pollen, spores, and charcoal), geochemical analysis through X-ray Fluorescence (XRF), and a detailed chronology based on AMS C-14 dating from a western Serbian sinkhole core suggest complex woodland-grassland dynamics and strong erosional signals throughout the Little Ice Age (LIA). An open landscape with prominent steppe vegetation (e.g. Poaceae, Chenopodiaceae) and minor woodland exists during 1540-1720 CE (early LIA), while the late LIA (1720-1850 CE) in this record shows higher tree percentages possibly due to increased moisture availability. The post LIA Era (1850-2012 CE) brings a disturbed type of vegetation with the presence of weedy genera and an increase in regional woodland. Anthropogenic indicators for agricultural, pastoral and fire practices in the region together attest to the dominant role of humans in shaping this Balkan landscape throughout the interval. The changing nature of human interference, potentially as a response to underlying climatic transitions, is evident through large-scale soil depletion resulting from grazing and land clearance during the early LIA and stabilization of arable lands during the late and post-LIA eras.

Topography↗
NASA NTRS2016

A Fly-Through Mission Strategy Targeting Peptide as a Signature of Chemical Evolution and Possible Life in Enceladus Plumes

In situ detection of organic molecules in the extraterrestrial environment provides a key step towards better understanding the variety and the distribution of building blocks of life and it may ultimately lead to finding extraterrestrial life within the Solar System. Here we present combined results of two separate experiments that enable us to realize such in situ life signature detection from the deep habitats of the "Ocean World": a hydrothermal reactor experiment simulating complex organic synthesis and a simulated fly-through capture experiment of organic-bearing microparticles using silica aerogels, followed by subsequent analysis. Both experiments employ peptide as a plausible organics existing in Encleadus plume particles produced in its subsurface ocean. Recent laboratory hydrothermal experiments and a theoretical model on silica saturation indicated an on going hydrothermal reactions in subsurface Enceladus ocean. Given the porous chondritic origin of the core, it is likely that organic compounds originated by radiation chemistry such as amino acid precursors could have been provided, leached, and altered through widespread water-rock interactions. By using the same laboratory experimental setup from the latest water-rock interaction study, we performed amino acid polymerization experiments for 144 days and monitored the organic complexity changing over time. So far over 3,000 peaks up to the size of greater than 600 MW were observed through the analysis of capillary electrophoresis time-of-flight mass spectrometry (CE-TOF-MS) with an indication of amino acid derivatives and short peptides. Generally abiotic polymerization of enantiomeric amino acids results in forming stereoisomeric peptides with identical molecular weight and formula as opposed to homochiral biopolymers. Assuming Enceladus plume particles may contain a mixture of stereoisomeric peptides, we were able to distinguish 16 of the 17 stereoisomeric tripeptides as a test sample using capillary electrophoresis (CE) under optimized conditions. We further conducted Enceladus plume fly-through capture experiment by accelerating peptides soaked in rock particles up to a speed of 5.7 km/s and capturing with originally developed hydrophobic silica aerogels. Direct peptide extraction with acetonitrile-water followed by CE analysis led to detection of only but two stereoisomeric acidic peptide peaks, presenting the first run-through hypervelocuty impact sample analysis targeting peptides as key molecule to to understand the ongoing astrobiology on Enceladus.

organic molecules↗
NASA NTRS2016

Controlled Environments Enable Adaptive Management in Aquatic Ecosystems Under Altered Environments

Ecosystems worldwide are impacted by altered environment conditions resulting from climate, drought, and land use changes. Gaps in the science knowledge base regarding plant community response to these novel and rapid changes limit both science understanding and management of ecosystems. We describe how CE Technologies have enabled the rapid supply of gap-filling science, development of ecosystem simulation models, and remote sensing assessment tools to provide science-informed, adaptive management methods in the impacted aquatic ecosystem of the California Sacramento-San Joaquin River Delta. The Delta is the hub for California's water, supplying Southern California agriculture and urban communities as well as the San Francisco Bay area. The changes in environmental conditions including temperature, light, and water quality and associated expansion of invasive aquatic plants negatively impact water distribution and ecology of the San Francisco Bay/Delta complex. CE technologies define changes in resource use efficiencies, photosynthetic productivity, evapotranspiration, phenology, reproductive strategies, and spectral reflectance modifications in native and invasive species in response to altered conditions. We will discuss how the CE technologies play an enabling role in filling knowledge gaps regarding plant response to altered environments, parameterization and validation of ecosystem models, development of satellite-based, remote sensing tools, and operational management strategies.

Remote Sensing↗
NASA NTRS2018

The Little Ice Age and Human-Environmental Interactions in the Central Balkans: Insights from a New Serbian Paleorecord

This paper presents a 600-year well-dated, high-resolution Central Balkan paleo-record including the Little Ice Age (LIA; 1450-850 CE). Utilizing pollen-based REVEALS modelling estimates, geochemical indicators, rarefaction analyses and the AMS 14C-based Bacon age model, this first-hand record from the Sava Basin reveals the transformation of the Central Balkan landscape involving linkages between changing climatic and socio-political regimes. The pre-LIA interval (1370-1418 CE) in the Sava Region reveals a wooded steppe and increased cultivation under warmer/stable climatic and socio-political conditions. In contrast, the LIA interval in the region is expressed through continuous transitions between forest and grassland, extensive land erosion and stressed agriculture, potentially as a collective artifact of the climatic variability and human impact associated with socio- political stressors of the time. The post-LIA/Industrial Era interval (1850-2012 CE) in the Sava Region shows an overall increase in woodland as well as agriculture following the exit of the Ottomans. However, increased population pressures and the subsequent onset of the Industrial Revolution as well as increased trade led to intense deforestation throughout the 20th Century, which continued during the Socialist period.

Societal impacts of climate change↗
NASA NTRS2017

Formation and Past Evolution of the Showers of 96P/Machholz Complex

In this work we model the dynamical evolution of meteoroid streams of comet 96P/Machholz, and the largest member of the Marsden sunskirters, comet P/1999 J6. We simultaneously fit the characteristics of eight meteor showers which have been proposed to be linked to the complex, using observations from a range of techniques - visual, video, TV and radar. The aim is to obtain a self-consistent scenario of past capture of a large comet into a short-period orbit, and its subsequent fragmentation history. Moreover, we also aim to constrain the dominant parent of these showers. The fit of our simulated shower characteristics to observations is consistent with the scenario of a capture of a proto-comet 96P/Machholz by Jupiter circa 20000 BCE (Before Christian Era), and a subsequent major breakup around 100-950 CE (Christian Era) which resulted in the formation of the Marsden group of comets. We find that the Marsden group of comets are not the immediate parents of the daytime Arietids and Northern and Southern delta-Aquariids, as previously suggested. In fact, the hypothesis that the Northern delta-Aquariids are related to the Marsden group of comets is not supported by this study. The bulk of the observational characteristics of all eight showers can be explained by meteoroid ejection primarily from comet 96P/Machholz between 10000 BCE and 20000 BCE. Assuming the Marsden group of comets originated between 100 CE-950 CE, we conclude that sunskirting comets contribute mainly to the meteoroid stream near the time of the peak of the daytime Arietids, Southern delta-Aquariids, kappa-Velids. Finally, we find that the meteor showers identified by Babadzhanov and Obrubov (1992) as the alpha-Cetids, the Ursids and Carinids correspond to the daytime lambda-Taurids, the November iota-Draconids or December alpha-Draconids and the theta-Carinids.

Abedin, Abedin↗
NASA NTRS2019

Evidence for Dry Carbonatite Metasomatism in the Oceanic Lithosphere from Peridotite Xenoliths of Samoa and Lanzarote

Water in Earth’s mantle affects processes like magmatism and plate tectonics. Experiments show that CO2-rich fluids lower the water solubility in olivine, implying that CO2-rich melts/fluids may dehydrate the lithosphere during metasomatism. To test this hypothesis, we report water concentrations (by polarized FTIR) of olivines, orthopyroxenes (OPX) and clinopyroxenes (CPX) from Savai’i (Samoa) and Lanzarote (Canary Islands) peridotite xenoliths with evidence of carbonatite metasomatism. Savai’i peridotites are highly depleted harzburgites and dunites with spinel Cr# (Cr/(Cr+Al)) ranging from 0.4 to 0.76 (estimated degree of melting: 191.5%). Strong Light Rare Earth Element (LREE) enrichments with Ti and Zr depletions in OPX and CO2-rich fluid inclusions (via Raman spectroscopy) are consistent with carbonatite metasomatism. Olivine, OPX and reconstructed bulk rock water concentrations (0.67-3.8, 17-89 and 4-26 ppm H2O, respectively) are low and show no apparent relationship with extent of carbonatite metasomatism. Calculated water concentrations of melts in equilibrium with Savai’i OPX (OPX/melt partitioning of water 0.0063 to 0.011) are, on average (0.540.32 wt% H2O), lower than host Samoan lavas (0.63 to 1.5 wt% H2O), despite the LREE enrichments in OPX. Lanzarote peridotites are also highly depleted (degree of melting from spinel Cr#: 171.8%).Water concentrations are low in olivines (1.7-5.3 ppm H2O) and variable in pyroxenes (OPX: 42-103 ppm H2O; CPX: 105-301 ppm H2O), and show no apparent correlation with indicators of carbonatite metasomatism. Both Savai’i and Lanzarote peridotites show negative correlations between water and degree of melting (i.e. Mg/(Mg+Fe), Cr#), suggesting melt depletion rather than metasomatism may have influenced their water concentrations. Calculated water concentrations of melts in equilibrium with Lanzarote CPX (average 1.90.75 wt% H2O; CPX/melt partitioning of water 0.011 to 0.012) are similar to those for Western Canaries lavas (average 1.80.31 wt%; CPX/melt partitioning of water 0.016 to 0.021) inferred from their CPX phenocrysts. However, calculated Ce concentrations in such melts (352 to 378 ppm; CPX/melt partitioning of Ce 0.07) are an order of magnitude greater than the lavas, and similar to carbonatites. This leads to H2O/Ce to be an order of magnitude lower in the inferred melts (26 to 57) than estimates for Western Canary lavas (280150). These low H2O/Ce ratios may suggest H2O loss from CPX during ascent, but the lack of strong water diffusion gradients in Lanzarote minerals does not support this. Instead we hypothesize that carbonatite metasomatism resulted in greater enrichment of Ce over H2O. Assuming carbonatite magmas are water rich, this implies a lower partitioning of water between minerals and melts during metasomatism, as suggested by experiments. Our data suggests carbonatite metasomatism does not result in significant re-hydration of the lithosphere, in contrast to silicate metasomatism as previously observed in Hawaiian peridotites.

Ashley, Aaron↗
NASA NTRS2021

A persistently low level of atmospheric oxygen in Earth’s middle age

Resolving how Earth surface redox conditions evolved through the Proterozoic Eon is fundamental to understanding how biogeochemical cycles have changed through time. The redox sensitivity of cerium relative to other rare earth elements and its uptake in carbonate minerals make the Ce anomaly (Ce/Ce*) a particularly useful proxy for capturing redox conditions in the local marine environment. Here, we report Ce/Ce* data in marine carbonate rocks through 3.5 billion years of Earth’s history, focusing in particular on the mid-Proterozoic Eon (i.e., 1.8 – 0.8 Ga). To better understand the role of atmospheric oxygenation, we use Ce/ Ce* data to estimate the partial pressure of atmospheric oxygen (pO2) through this time. Our thermodynamics-based modeling supports a major rise in atmospheric oxygen level in the aftermath of the Great Oxidation Event (~ 2.4 Ga), followed by invariant pO2 of about 1% of present atmospheric level through most of the Proterozoic Eon (2.4 to 0.65 Ga).

Xiao-Ming Liu↗
NASA NTRS1975

Resonance lines of Cs II, Ba III, and La IV

The resonance line spectra of ions in the Xe I isoelectronic sequence, consisting of the five transitions to the 5p6 150 ground state from levels with J = 1 in the 5p5 5d and 6s configurations, have been observed for Cs II, Ba III, and La IV. The observations were made with a sliding spark on the 10.7-m normal-incidence vacuum spectrograph at NBS. The resonance transitions from the 5p5 6d and 7s configurations were also observed for these ions, except for that from 5p5 6d 3P1 of Ba III. Several resonance transitions from higher nd and ns levels were also observed. Estimated values for the J = 1 levels of the 5p5 7s configuration of Ce V were obtained by extrapolation. The derived ionization energies in eV are Cs II 23.17(4), Ba III 35.79(6), La IV 45.95(6), Ce V 65.55(25).

Reader, J.↗
NASA NTRS1977

Redox equilibria of multivalent ions in silicate glasses

Experimental studies were made on the compositional dependence of the redox equilibrium of Eu in synthetic silicate liquids, together with an empirical model describing the observed compositional dependence. Electron paramagnetic resonance (EPR) was used to measure the concentration ratio of Eu(2+) to Eu(3+) in various glasses formed by rapidly quenching silicate liquids. The compositional field studied comprised mixtures of SiO2, TiO2, Al2O3, CaO, MgO, and Na2O. The proposed model describes the Eu(2+)/Eu(3+) ratio over the entire compositional field in terms of parameters easily related to each glass composition. The general applicability and utility of the model is further demonstrated by its application to the Fe(2+)-Fe(3+), Ce(3+)-Ce(4+), and Cr(3+)-Cr(6+) redox reactions in binary alkali oxide silicate glasses of Li, Na, and K.

Lauer, H. V., Jr.↗