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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS1986

Radiative forcing of the Venus mesosphere. I - Solar fluxes and heating rates

A radiative-transfer model has been used to derive the structure and amplitude of the solar fluxes and heating rates in the Venus mesosphere, accounting for absorption and scattering extinction sources that encompass CO2, H2O, SO2, and H2SO4 aerosols as well as an unidentified UV absorber. The unknown substance that causes the observed cloud-top UV contrasts is responsible for most of the absorption of sunlight within the upper cloud deck; this contributes to solar heating rates of the order of 6 K/day at levels near 65 km. These results are judged sufficiently reliable for use in numerical dynamical models of the Venus atmosphere.

Crisp, D.↗
NASA NTRS2014

Nanophase Carbonates on Mars: Implications for Carbonate Formation and Habitability

Despite having an atmosphere composed primarily of CO2 and evidence for abundant water in the past, carbonate minerals have only been discovered in small amounts in martian dust [1], in outcrops of very limited extent [2, 3], in soils in the Northern Plains (the landing site of the 2007 Phoenix Mars Scout Mission) [4] and may have recently been detected in aeolian material and drilled and powdered sedimentary rock in Gale Crater (the Mars Science Laboratory [MSL] landing site) [5]. Thermal analysis of martian soils by instruments on Phoenix and MSL has demonstrated a release of CO2 at temperatures as low as 250-300 degC, much lower than the traditional decomposition temperatures of calcium or magnesium carbonates. Thermal decomposition temperature can depend on a number of factors such as instrument pressure and ramp rate, and sample particle size [6]. However, if the CO2 released at low temperatures is from carbonates, small particle size is the only effect that could have such a large impact on decomposition temperature, implying the presence of extremely fine-grained (i.e., "nanophase" or clay-sized) carbonates. We hypothesize that this lower temperature release is the signature of small particle-sized (clay-sized) carbonates formed by the weathering of primary minerals in dust or soils through interactions with atmospheric water and carbon dioxide and that this process may persist under current martian conditions. Preliminary work has shown that clay-sized carbonate grains can decompose at much lower temperatures than previously thought. The first work took carbonate, decomposed it to CaO, then flowed CO2 over these samples held at temperatures >100 degC to reform carbonates. Thermal analysis confirmed that carbonates were indeed formed and transmission electron microsopy was used to determine crystal sized were on the order of 10 nm. The next step used minerals such as diopside and wollastonite that were sealed in a glass tube with a CO2 and H2O source. After reacting these materials for a number of hours, thermal analysis demonstrated the formations of carbonates that decomposed at temperatures as low as 500 degC [7]. Further work is underway to carry out the weathering process under more Mars-like conditions (low pressure and low temperature) to determine if the carbonate decomposition temperature can be shifted to even lower temperatures, consistent with what has been detected by thermal analysis instruments on Mars.

Archer, P. Douglas, Jr.↗
NASA NTRS2018

The Relevance of Mars Samples to Planning for Potential Future In-Situ Resource Utilization

Considerable recent planning has focused on the potential importance of Mars in-situ resources to support future human missions. While atmospheric CO2 provides a source of oxygen, the regolith offers other potential resources. The most significant surface asset is water, which could be used for propellant generation, life support, habitat sustainment, and agriculture. In regard to the latter, the regolith could also provide a source of nutrients to supplement terrestrial fertilizers and/or act as a substrate to buffer plant roots. Local material could also be used as feedstock for construction, including for structures, roads, and additive manufacturing. Native salts (e.g. perchlorates or chlorides) in the Martian regolith could be used as water absorbents for closed loop life support systems or for capture of the limited atmospheric water.

Source record↗
NASA NTRSDate not supplied

Surface Temperature and the Compositional Effects of Electron Bombardment on Dione

Saturn’s icy moons are composed of mostly water ice with minor “contaminants,” such as CO2 ice, and a dark component thought to be organics, hematite and/or metallic Fe [1]. The space weathering process of electron bombardment is expected to be particularly important on the surfaces of Saturn’s inner moons (Mimas, Tethys, Dione, and Rhea), as they orbit within the extended plasma sheet of Saturn’s magnetosphere. Terrains exhibiting thermal anomalies (i.e., colder temperatures in the day and warmer temperatures at night than surrounding areas) correspond to regions of high energy electron bombardment [2; 3]. Energetic electrons impact the surfaces, fracturing ice particles into sub-micron sized grains, and this process becomes more effective for increasing particle energies [4]. In addition to alteration of ices, the dark material may also be modified or generated within icy surfaces by interaction with solar UV radiation, cosmic rays, or by particles trapped in Saturn’s magnetic field [5]. CO2 could be sourced from irradiation of dark organic material [7]. Many of these alterations should be observable in Visible and Infrared Mapping Spectrometer (VIMS) spectra [8]. We used surface temperatures derived from Cassini’s Composite Infrared Spectrometer (CIRS) to help isolate areas where space weathering due to electron bombardment is more predominant and investigated the subtle changes in VIMS spectra using machine learning techniques. We present our results here for Dione. On ocean worlds, space weathering products would be present along with any potential indications of life. We will need to understand the manifestation of space weathering in the data to separate the two processes.

Cindy Lee Young↗
NASA NTRSDate not supplied

Electron Bombardment on Dione: Surface Compositional Effects and Temperature Anomalies

Saturn’s icy moons are composed primarily of water ice with minor other “contaminants,” such as CO2 ice, and a dark component thought to be organics, hematite and/or metallic Fe [1]. The space weathering process of electron bombardment is expected to be particularly important on the surfaces of Saturn’s inner moons (Mimas, Tethys, Dione, and Rhea), as they orbit within Saturn’s inner magnetosphere. Terrains exhibiting thermal anomalies (i.e., colder temperatures in the day and warmer temperatures at night than surrounding areas) correspond to regions of high energy electron bombardment [2; 3; 4; 5]. Energetic electrons impact the surfaces, sintering ice grains together, and this process becomes more effective for increasing particle energies [6]. Solar UV radiation, cosmic rays, dust in-fall, and cold plasma particles trapped in Saturn’s magnetic field also play an important role in altering the nature and the structure of the native surface ices by the implantation of contaminants, ionization, sputtering, and dissociation of water ice molecules [7]. Additionally, CO2 could be sourced from irradiation of dark organic material [8]. Many of these surface alterations are observable in Cassini’s Visible and Infrared Mapping Spectrometer (VIMS) spectra [9]. We used similar methodologies as have been employed in previous works [e.g., 10] to derive surface temperatures from Cassini’s Composite Infrared Spectrometer (CIRS), which helped to isolate areas where space weathering due to electron bombardment is more predominant. The subtle changes in VIMS spectra were investigated using machine learning techniques. We present here our results for Dione.

Cindy Lee Young↗
NASA NTRSDate not supplied

Electron Bombardment on Dione: Surface Compositional Effects and Temperature Anomalies

Saturn’s icy moons are composed primarily of water ice with minor other “contaminants,” such as CO2 ice, and a dark component thought to be organics, hematite and/or metallic Fe. The space weathering process of electron bombardment is expected to be particularly important on the surfaces of Saturn’s inner moons (Mimas, Tethys, Dione, and Rhea), as they orbit within Saturn’s inner magnetosphere. Terrains exhibiting thermal anomalies (i.e., colder temperatures in the day and warmer temperatures at night than surrounding areas) correspond to regions of high energy electron bombardment. Energetic electrons impact the surfaces, sintering ice grains together, and this process becomes more effective for increasing particle energies. Solar UV radiation, cosmic rays, dust in-fall, and cold plasma particles trapped in Saturn’s magnetic field also play an important role in altering the nature and the structure of the native surface ices by the implantation of contaminants, ionization, sputtering, and dissociation of water ice molecules. Additionally, CO2 could be sourced from irradiation of dark organic material. Many of these surface alterations are observable in Cassini’s Visible and Infrared Mapping Spectrometer (VIMS) spectra. We used similar methodologies as have been employed in previous works to derive surface temperatures from Cassini’s Composite Infrared Spectrometer (CIRS), which helped to isolate areas where space weathering due to electron bombardment is more predominant. The subtle changes in VIMS spectra were investigated using machine learning techniques. We present here our results for Dione.

C L Young↗
NASA NTRSDate not supplied

Electron Bombardment on Dione: Surface Compositional Effects and Temperature Abnormalities

Saturn’s icy moons are composed primarily of water ice with minor other “contaminants,” such as CO2 ice, and a dark component thought to be organics, hematite and/or metallic Fe [1]. The space weathering process of electron bombardment is expected to be particularly important on the surfaces of Saturn’s inner moons (Mimas, Tethys, Dione, and Rhea), as they orbit within Saturn’s inner magnetosphere. Terrains exhibiting thermal anomalies (i.e., colder temperatures in the day and warmer temperatures at night than surrounding areas) correspond to regions of high energy electron bombardment [2; 3; 4; 5]. Energetic electrons impact the surfaces, sintering ice grains together, and this process becomes more effective for increasing particle energies [6]. Solar UV radiation, cosmic rays, dust in-fall, and cold plasma particles trapped in Saturn’s magnetic field also play an important role in altering the nature and the structure of the native surface ices by the implantation of contaminants, ionization, sputtering, and dissociation of water ice molecules [7]. Additionally, CO2 could be sourced from irradiation of dark organic material [8]. Many of these surface alterations are observable in Cassini’s Visible and Infrared Mapping Spectrometer (VIMS) spectra [9]. We used similar methodologies as have been employed in previous works [e.g., 10] to derive surface temperatures from Cassini’s Composite Infrared Spectrometer (CIRS), which helped to isolate areas where space weathering due to electron bombardment is more predominant. The subtle changes in VIMS spectra were investigated using machine learning techniques. We present here our results for Dione. [1] Clark, R. N., et al. (2012) Icarus, 218, 831–860 [2] Howett, C. J. A., et al. (2020) Icarus, 113745 [3] Nordheim, T. A., et al. (2017) Icarus, 286, 56-68 [4] Paranicas, C., et al. (2012) Planetary and Space Science, 61, 60–65 [5] Paranicas, C., et al. (2014) Icarus, 234, 155–161 [6] Schaible, M. J., et al. (2016) Icarus, 0, 1–13 [7] Baragiola, R. A., et al., (2013) Astrophysics and Space Science Library, vol. 356. Springer [8] Mennella, V., et al. (2006) The Astrophysical Journal, 643(2), 923 [9] Scipioni, F., et al. (2017) Icarus, 290, 183-200 [10] Howett, C. J. A., et al. (2014) Icarus, 241, 239-247

C L Young↗
NASA NTRS1997

Laboratory Kinetic Studies of OH and CO2 Relevant to Upper Atmospheric Radiation Balance

The purpose of this project was to quantify the rates of two processes which are crucial to our understanding of radiative energy balance in the upper atmosphere. The first process is radiative emission from vibrationally hot OH radicals following the H + O3 reaction in the upper mesosphere. The importance of this process depends strongly on the OH radiative emission coefficients. Our goal was to measure the OH permanent dipole moment in excited vibrational states and to use these measurements to construct an improved OH dipole moment function and improved radiative emission coefficients. Significant progress was made on these experiments including the construction of a supersonic jet source for vibrationally excited OH radicals. Unfortunately, our efforts to transport the OH radicals into a second lower pressure vacuum chamber were not successful, and we were unable to make improved dipole moment measurements for OH. The second key kinetic process which we attempted to quantify during this project is the rate of relaxation of bend-excited CO2 by oxygen atoms. Since excitation of the bending vibrational mode of CO2 is the major cooling mechanism in the upper mesosphere/lower thermosphere, the cooling rate of this region depends crucially on the rate of energy transfer out of this state. It is believed that the most efficient transfer mechanism is via atomic oxygen but the rate for this process has not been directly measured in the laboratory at appropriate temperatures and even the room temperature rate remains controversial. We attempted to directly measure the relaxation rate Of CO2 (010) by oxygen atoms using the discharge flow technique. This experiment was set up at Aerodyne Research. Again, significant progress was achieved in this experiment. A hot CO2 source was set up, bend excited CO2 was detected and the rate of relaxation of bend excited CO2 by He atoms was measured. Unfortunately, the project ran out of time before the oxygen atom kinetic studies could be implemented.

Nelson, David D.↗
NASA NTRS2002

Toward a Comprehensive Carbon Budget for North America: Potential Applications of Adjoint Methods with Diverse Datasets

A detailed mechanistic understanding of the sources and sinks of CO2 will be required to reliably predict future COS levels and climate. A commonly used technique for deriving information about CO2 exchange with surface reservoirs is to solve an "inverse problem," where CO2 observations are used with an atmospheric transport model to find the optimal distribution of sources and sinks. Synthesis inversion methods are powerful tools for addressing this question, but the results are disturbingly sensitive to the details of the calculation. Studies done using different atmospheric transport models and combinations of surface station data have produced substantially different distributions of surface fluxes. Adjoint methods are now being developed that will more effectively incorporate diverse datasets in estimates of surface fluxes of CO2. In an adjoint framework, it will be possible to combine CO2 concentration data from long-term surface monitoring stations with data from intensive field campaigns and with proposed future satellite observations. A major advantage of the adjoint approach is that meteorological and surface data, as well as data for other atmospheric constituents and pollutants can be efficiently included in addition to observations of CO2 mixing ratios. This presentation will provide an overview of potentially useful datasets for carbon cycle research in general with an emphasis on planning for the North American Carbon Project. Areas of overlap with ongoing and proposed work on air quality/air pollution issues will be highlighted.

Andrews, A.↗
NASA NTRS2004

Radiolytic Model for Chemical Composition of Europa's Atmosphere and Surface

The overall objective of the present effort is to produce models for major and selected minor components of Europa s neutral atmosphere in 1-D versus altitude and in 2-D versus altitude and longitude or latitude. A 3-D model versus all three coordinates (alt, long, lat) will be studied but development on this is at present limited by computing facilities available to the investigation team. In this first year we have focused on 1-D modeling with Co-I Valery Shematovich s Direct Simulation Monte Carlo (DSMC) code for water group species (H2O, O2, O, OH) and on 2-D with Co-I Mau Wong's version of a similar code for O2, O, CO, CO2, and Na. Surface source rates of H2O and O2 from sputtering and radiolysis are used in the 1-D model, while observations for CO2 at the Europa surface and Na detected in a neutral cloud ejected from Europa are used, along with the O2 sputtering rate, to constrain source rates in the 2-D version. With these separate approaches we are investigating a range of processes important to eventual implementation of a comprehensive 3-D atmospheric model which could be used to understand present observations and develop science requirements for future observations, e.g. from Earth and in Europa orbit. Within the second year we expect to merge the full water group calculations into the 2-D version of the DSMC code which can then be extended to 3-D, pending availability of computing resources. Another important goal in the second year would be the inclusion of sulk and its more volatile oxides (SO, SO2).

Cooper, John F.↗
NASA NTRS1984

Three dimensional global modeling of atmospheric CO2

The initial attempts to model the atmospheric CO2 distribution, including couplings to the ocean and biosphere as sources and sinks of atmospheric CO2, encourage the notion that this approach will lead to useful quantitative constraints on CO2 fluxes. Realization of this objective will require: (1) continued improvement in the realism of the global transport modeling; (2) extended timeline of atmospheric CO2 monitoring, which improved precision and improved definition of the uncertainties in the measured CO2 amounts; and (3) given an accurate knowledge of model capabilities and limitations and given a good understanding of CO2 observations and their limitations, there is a need for good ideas concerning what quantitative information on the carbon cycle can be inferred from global modeling.

Hanse, J.↗
NASA NTRS1991

Isotopic exchange between carbon dioxide and ozone via O(1D) in the stratosphere

A novel mechanism for isotropic exchange between CO2 and O3 via O(1D) + CO2 - CO3(asterisk) followed by CO3(asterisk) - CO2 + O(3P). A one-dimensional model calculation shows that this mechanism can account for the enrichment in O-18 in the stratospheric CO2 observed by Gamo et al. (1989), using the heavy O3 profile observed by Mauersberger (1981). The implications of this mechanism for other stratospheric species and as a source of isotopically heavy CO2 in the troposphere are briefly discussed.

Yung, Yuk L.↗
NASA NTRS1997

Roto-Translational Collision-Induced Absorption of CO2 for the Atmosphere of Venus at Frequencies from 0 to 250 cm(exp -1), at Temperatures from 200 to 800 K

The collision-induced absorption (CIA)of gaseous CO2 is the primary source of far-infrared opacity of the atmosphere of Venus. At the temperatures and densities of the venusian atmosphere, the absorption is due mainly to binary collisions of CO2 molecules. Using a realistic anisotropic intermolecular potential and assuming the absorbing dipole to be due to the electrostatic induction and a quantum overlap, a series of molecular dynamics simulations were performed for the temperature range 200 to 800 K, and the roto-translational (RT) collision-induced absorption spectra at frequencies from 0 to 250 cm(exp -1) were derived. The absorption coefficient in the submillimeter region, used in constituency retrieval studies, decreases more than 10 times in the temperature range 200 to 800 K. On the other hand, the absorption coefficient at 800 K and at the frequency range above 150 cm(exp -1) was found to be almost 10 times higher than at 200 K. Earlier works relied on experimental RT CIA data at a fixed temperature of 300 K. The new, temperature-dependent absorption bands may, when included in the analysis of the atmospheric radiative transfer of the planet, help explain the observed high far-infrared opacity of the lower layers of the atmosphere. To make the results of the simulations readily available for atmospheric abundance and radiative transfer analysis, an analytic model of the roto-translational collision-induced absorption spectral profile, applicable from 200 to 800 K, is being proposed here. The FORTRAN computer code of this newly developed model is available from the authors on request.

Gruszka, Marcin↗
NASA NTRS2021

VESIcal Part I: An open-source thermodynamic model engine for mixed volatile (H2O-CO2) solubility in silicate melts

Thermodynamics has been fundamental to the interpretation of geologic data and modeling of geologic systems for decades. However, more recent advancements in computational capabilities and a marked increase in researchers’ accessibility to computing tools has outpaced the functionality and extensibility of currently available modeling tools. Here we present VESIcal (Volatile Equilibria and Saturation Identification calculator): the first comprehensive modeling tool for H 2 O, CO 2 , and mixed (H 2 O-CO 2 ) solubility in silicate melts that: a) allows users access to seven commonly used models, plus easy inter-comparison between models; b) provides universal functionality for all models (e.g., functions for calculating saturation pressures, degassing paths, etc.); c) can process large datasets (1,000’s of samples) automatically; d) can output computed data into an excel spreadsheet for simple post-modeling analysis; e) integrates advanced plotting capabilities directly within the tool; and f) provides all of these within the framework of a python library, making the tool extensible by the user and allowing any of the model functions to be incorporated into any other code capable of calling python. The tool is presented within this manuscript, which is a Jupyter notebook containing worked examples accessible to python users with a range of skill levels. The basic functions of VESIcal can also be access via a web app (https://vesical.anvil.app). The VESIcal python library is open-source and available for download at https://github.com/kaylai/VESIcal.

K. Iacovino↗
NASA NTRS2008

Development of Laser, Detector, and Receiver Systems for an Atmospheric CO2 Lidar Profiling System

A ground-based Differential Absorption Lidar (DIAL) is being developed with the capability to measure range-resolved and column amounts of atmospheric CO2. This system is also capable of providing high-resolution aerosol profiles and cloud distributions. It is being developed as part of the NASA Earth Science Technology Office s Instrument Incubator Program. This three year program involves the design, development, evaluation, and fielding of a ground-based CO2 profiling system. At the end of a three-year development this instrument is expected to be capable of making measurements in the lower troposphere and boundary layer where the sources and sinks of CO2 are located. It will be a valuable tool in the validation of NASA Orbiting Carbon Observatory (OCO) measurements of column CO2 and suitable for deployment in the North American Carbon Program (NACP) regional intensive field campaigns. The system can also be used as a test-bed for the evaluation of lidar technologies for space-application. This DIAL system leverages 2-micron laser technology developed under a number of NASA programs to develop new solid-state laser technology that provides high pulse energy, tunable, wavelength-stabilized, and double-pulsed lasers that are operable over pre-selected temperature insensitive strong CO2 absorption lines suitable for profiling of lower tropospheric CO2. It also incorporates new high quantum efficiency, high gain, and relatively low noise phototransistors, and a new receiver/signal processor system to achieve high precision DIAL measurements.

Ismail, Syed↗
NASA NTRS2018

Measuring Atmospheric Carbon Dioxide from the NASA Orbiting Carbon Observatory-2 (OCO-2)

Fossil fuel combustion, deforestation, and other human activities are now adding almost 40 billion tons of carbon dioxide (CO2) to the atmosphere each year. These emissions are superimposed on an active natural carbon cycle that adds about 20 times as much CO2 to the atmosphere annually, and then reabsorbs a comparable amount, along with over half of the CO2 contributed by human activities. Interestingly, the identity and location of the natural “sinks” in the land biosphere and ocean that are responsible for absorbing this anthropogenic CO2 are still poorly understood. Because of this, it is impossible to accurately predict how these sinks will respond to a warming climate. Space based remote sensing provides new tools for studying the sources and sinks of CO2. The NASA Orbiting Carbon Observatory-2 (OCO-2) was launched in July 2014 and was inserted at the head of the 705-km Afternoon Constellation (A-Train) a month later.

Crisp, David↗
NASA NTRSDate not supplied

Electrochemical Recycling of CO2

Carbon dioxide (CO2) is a molecule that plays multiple roles in our universe. Currently, its impact on global warming has rightfully given CO2 a label as a harmful waste product that must be amply handled. Nonetheless, under other circumstances, and from other perspectives, CO2 could be regarded as a valuable resource. As example, in nature CO2 is an essential building block in photosynthesis ultimately yielding molecules and materials that we harvest for numerous applications ranging from energy storage and construction to medicines and food. In a similar manner, there is a growing interest to utilize atmospheric CO2 to generate renewable fuels and platform chemicals through artificial processes. These processes can replace fossil based industrial processes on earth alleviating climate impact, but they can also find uses far away from our planet. In space, CO2 is an important source of precious oxygen, however, it can also serve as feedstock for carbon-based molecules and materials that are needed to sustain societies at distant planets such as Mars. In this presentation, I will discuss the contemporary understanding of electrochemical reduction of CO2 for selective production of desired molecules. We will zoom in to the very atomic scale to gain mechanistic understanding of how the structure and composition of the cathode electrode affects product distributions. This information is used as guide in the design of new materials that convert CO2 more efficiently and more selectively. On this basis, opportunities for recycling CO2 under different conditions will be discussed, as will remaining challenges for the ultimate application towards the sustainable human living on earth and in space.

electrochemistry↗
NASA NTRS2001

Model Simulations of CO2 Transport Using Assimilated Meteorological Fields

The numerical simulation of CO2 transport (and other tracers such as CO, CH4, and biomass burning tracers) in the atmosphere is required to determine the fate of anthropogenic source gases. Estimation of the CO2 exchange between the ocean surface, the terrestrial biosphere, and the atmosphere is of first-order importance to understanding the global carbon cycle and the processes that are most crucial in determining the atmospheric CO2 concentration. Forward transport simulations have been conducted using two-dimensional, time-dependent grids of average surface fluxes (from TRANSCOM) and three-dimensional wind data from a prototype data assimilation system (FV-DAS) run by the Goddard Data Assimilation Office. The objective is to better understand the contribution of meteorological variability to changes in CO2 and other constituents, By accurately accounting for meteorological variability, through use of assimilated winds, we hope to better characterize the distribution of surface sources and sinks (and chemistry where applicable). With assimilated meteorology such chemistry/transport runs provide the basic framework to analyze existing (and proposed) measurement data on a point-by-point, real-time basis. We compare with measured CO2 concentration gradients on a daily, seasonal, regional, and interhemispheric basis to examine the consistency of sources, sinks, and transport formulation. We will also examine the inter-annual variability of atmospheric CO2 due to atmospheric circulation changes using longer runs with assimilated winds.

Kaea, S. R.↗