Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “CEOS”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Visualizing Size-Dependent Dynamics of CeO 2-δ {100}-Supported CoO x Nanoparticles Under CO 2 Hydrogenation Conditions

Carbon dioxide is a major greenhouse gas. In order to optimize processes focused on its chemical valorization, one needs detailed information about the effects of CO 2 and/or CO 2 /H 2 mixtures on the structure and morphology of metal/oxide catalysts. Here, in this study, the evolution of a catalyst with cobalt supported on CeO 2 -cube nanostructures under CO 2 hydrogenation conditions was investigated by using a set of in situ characterization techniques (X-ray absorption fine structure, X-ray diffraction, diffuse reflectance infrared Fourier transform spectroscopy, and environmental transmission electron microscopy (TEM)). The {100} facets of the ceria support displayed an unexpectedly high stability due to strong interactions with the aggregates of cobalt oxide. A significant influence of interfacial bonding between CoO x and CeO 2-δ {100} is evident through a clear preference in the orientation of CoO x nanoparticles (NPs) with respect to the substrate. For initially reduced Co/CeO 2 -cube nanostructures, a kinetically controlled oxidation of cobalt upon the introduction of CO 2 was observed during the early stages of CO 2 hydrogenation. Environmental TEM revealed the size-dependent morphological behavior of cobalt oxide NPs due to strong interactions with the CeO 2 {100} surface. When the environment was switched from H 2 to a mixture of H 2 and CO 2 at 250 °C, small CoO x NPs (in the largest dimension < 2.5 nm) rapidly transformed from a pyramidal three-dimensional (3D) form to a planar, monatomic layer attached to the concurrently oxidized CeO 2-δ {100} surface. This maximizes the number of sites available for the binding of CO 2 or reaction intermediates. The shape transformation reflected the oxophilic character of cobalt and strong metal–support interactions. The removal of CO 2 from the gas phase led to a reduction of the cobalt oxide NPs by hydrogen and a reversible two-dimensional → 3D transformation. In contrast, no significant morphological changes, apart from further oxidation, were observed for big CoO x NPs (in the largest dimension > 3 nm). These trends are not seen for nanoparticles of noble metals. The observed morphological and structural changes in the small CoO x NPs affected the stability of reaction intermediates and modified the selectivity of the CoO x /CeO 2 catalyst system for methane production.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Sparsely Dispersed CeO x ‑Stabilized Pt Nanoparticles Overcome Pt Loading–Durability Trade-Off for Highly Durable Heavy-Duty Fuel Cells

Proton-exchange-membrane fuel cells (PEMFCs) are clean and sustainable mobile power sources for transportation. Recently, their deployment in heavy-duty vehicles (HDVs) has attracted growing interest owing to their high energy scalability and lower infrastructure requirements. However, to meet the stringent requirements for efficiency and long-term durability for HDV applications, PEMFCs typically employ a relatively high platinum group metal (PGM) loading (>0.2 mg PGM /cm 2 ). This elevated PGM loading significantly increases the stack and system costs, surpassing the U.S. Department of Energy (DOE) target of $\$ 60$/kW for commercial viability. Reducing PGM loading while maintaining performance and durability remains a central challenge for HDV fuel cells. Here we exploit metal oxide–Pt interactions and utilize the strong CeO x –Pt interaction to design a CeO x @Pt catalyst structure with exceptional durability. At a low total PGM loading (0.1 mg PGM /cm 2 ), the CeO x @Pt/C catalyst demonstrates high fuel cell performance (8.8 kW/g PGM ) and stability (power retention >90%) after the challenging HDV durability testing (90,000 accelerated-stress-test cycles). With the CeO x @Pt/C catalyst, we showcase over 70% reduction in Pt cost from the M2FCT target (to $\$ 9$/kW), highlighting its promising potential for enabling stable and cost-effective fuel cell systems for heavy-duty applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

Origin of Active Oxygen in a Ternary CuO x /Co 3 O 4 –CeO 2 Catalyst for CO Oxidation

In this paper, we have studied CO oxidation over a ternary CuO x /Co 3 O 4 -CeO 2 catalyst and employed the techniques of N 2 adsorption/desporption, XRD, TPR, TEM, in situ DRIFTS and QMS (Quadrupole mass spectrometer) to explore the origin of active oxygen. DRIFTS-QMS results with labeled 18O2 indicate that the origin of active oxygens in CuO x /Co 3 O 4 -CeO 2 obeys a model, called as queue mechanism. Namely gas-phase molecular oxygens are dissociated to atomic oxygens and then incorporate in oxygen vacancies located at the interface of Co 3 O 4 -CeO 2 to form active crystalline oxygens, and these active oxygens diffuse to the CO-Cu + sites thanks to the oxygen vacancy concentration magnitude and react with the activated CO to form CO 2 . This process, obeying a queue rule, provides active oxygens to form CO 2 from gas-phase O 2 via oxygen vacancies and crystalline oxygen at the interface of Co 3 O 4 -CeO 2 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO 2 (111) catalysts: An in situ study of C–C and O–H bond scission

Ambient-Pressure X-ray Photoelectron Spectroscopy (AP-XPS) and Infrared Reflection Absorption Spectroscopy (AP-IRRAS) have been used to elucidate the active sites and mechanistic steps associated with the ethanol steam reforming reaction (ESR) over Ni–CeO 2 (111) model catalysts. Our results reveal that surface layers of the ceria substrate are both highly reduced and hydroxylated under reaction conditions while the small supported Ni nanoparticles are present as Ni 0 /NixC. A multifunctional, synergistic role is highlighted in which Ni, CeO x and the interface provide an ensemble effect in the active chemistry that leads to H 2 . Ni 0 is the active phase leading to both C–C and C–H bond cleavage in ethanol and it is also responsible for carbon accumulation. On the other hand, CeO x is important for the deprotonation of ethanol/water to ethoxy and OH intermediates. The active state of CeO x is a Ce 3+ (OH) x compound that results from extensive reduction by ethanol and the efficient dissociation of water. Additionally, we gain an important insight into the stability and selectivity of the catalyst by its effective water dissociation, where the accumulation of surface carbon can be mitigated by the increased presence of surface OH groups. As a result, the co-existence and cooperative interplay of Ni 0 and Ce 3+ (OH) x through a metal–support interaction facilitate oxygen transfer, activation of ethanol/water as well as the removal of coke.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2013

Photocatalytic degradation mechanisms of self-assembled rose-flower-like CeO{sub 2} hierarchical nanostructures

Hierarchical rose-flower-like CeO{sub 2} nanostructures were formed by using solvothermal and thermal annealing processes. The CeCO{sub 3}OH thin film was transformed into CeO{sub 2} roses due to thermal annealing. CeO{sub 2} nanostructured roses exhibited excellent photocatalytic activity with a degradation rate of 65% for the azo dye acid orange 7 (AO7) under ultraviolet illumination. The fitting of the absorbance maximum versus time showed that the degradation of AO7 obeyed pseudo-first-order reaction kinetics. The enhancement of the photocatalytic activity for the CeO{sub 2} roses was attributed to the high adsorptivity resulting from the surface active sites and special 4f electron configuration.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2013

Effect of CeO{sub 2} addition on the properties of FeAl based alloy produced by mechanical alloying technique

Iron aluminides based on FeAl is notable for their low materials cost, ease of fabrication and good corrosion, suffixation and oxidation resistance. However, the application based on these unique properties still require the development of Fe-Al based alloy since it shows some drawbacks such as a lack of high temperature strength and low ductility. To improve the mechanical properties of FeAl based alloy, ceria (CeO{sub 2}) will be added to this compound. FeAl based alloy produced by the mechanical alloying (MA) technique. The developed specimens then assessed with respect to oxidation behaviour in high temperature, scale microstructure and hardness. The surface morphologies of the alloy evaluated and observed using scanning electron microscopy (SEM) with an energy dispersive X-ray spectroscopy (EDX). The phase structures of oxide scale formed on them were identified by X-ray diffraction (XRD). The results found that the FeAl intermetallic compound containing CeO{sub 2} 0.5 wt.% is less pores and CeO{sub 2} 1.0 wt.% is more homogen in powder and solid form, higher hardness and increase in their resistance to oxidation behaviour in high temperature compared with another percentage of CeO{sub 2}.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Ultraviolet-visible electroluminescence from metal-oxide-semiconductor devices with CeO{sub 2} films on silicon

We report on ultraviolet-visible (UV-Vis) electroluminescence (EL) from metal-oxide-semiconductor (MOS) devices with the CeO{sub 2} films annealed at low temperatures. At the same injection current, the UV-Vis EL from the MOS device with the 550 °C-annealed CeO{sub 2} film is much stronger than that from the counterpart with the 450 °C-annealed CeO{sub 2} film. This is due to that the 550 °C-annealed CeO{sub 2} film contains more Ce{sup 3+} ions and oxygen vacancies. It is tentatively proposed that the recombination of the electrons in multiple oxygen-vacancy–related energy levels with the holes in Ce 4f{sup 1} energy band pertaining to Ce{sup 3+} ions leads to the UV-Vis EL.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Influence of grain size on optical properties of Sr{sub 2}CeO{sub 4} nanocrystals

The absorption, excitation, and emission spectra of the Sr{sub 2}CeO{sub 4} nanocrystals prepared by the modified sol–gel method were investigated. The impact of the average grain size of Sr{sub 2}CeO{sub 4} nanocrystals on their optical properties was investigated. It was observed that with increasing the average grain size of Sr{sub 2}CeO{sub 4} nanocrystals, the emission decay times decreased significantly. A similar behavior was observed for the emission quantum efficiencies and the Huang–Rhys factors. The grain size dependence of optical parameters of Sr{sub 2}CeO{sub 4} nanocrystals was found well fitted by functions of the reciprocal of the grain diameter. It was shown that this dependence may be rationalized assuming that the correction for electric local field associated with effective refractive index affecting the spherical nanoparticle is governed by its shell.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Effect of annealing temperature on the structural and optical properties of CeO{sub 2}:Ni thin films

High quality Ni-doped CeO{sub 2} (CeO{sub 2}:Ni) thin films were deposited on glass substrates at room temperature by using radio frequency magnetron sputtering. The effect of annealing temperature on structural and optical properties of the CeO{sub 2}:Ni films was investigated. The structural, optical and vibrational properties of the films were determined using X-ray diffraction (XRD), photoluminescence spectrometer (PL) and Raman spectrometer. It was found that the as-deposited film has a fluorite cubic structure. By increasing annealing temperature from 100°C to 300°C, the crystalline quality of the thin films could be improved. The UV and visible band emissions were observed in the photoluminescence spectra, due to exciton, defect related emissions respectively. The micro-Raman results show the characteristic peak of CeO{sub 2} F{sub 2g} at 465 cm{sup −1} and 2L0 at 1142 cm{sup −1}. Defect peaks like D and 0 bands were observed at 641 cm{sup −1} and 548 cm{sup −1} respectively. It is found from the spectra that the peak intensity of the films increased with increase of annealing temperature.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

(U) Pre-shot Report: Complex Loading of CeO 2 Powder

A cylindrically converging shock compaction experiment is designed utilizing the Precision High Energy-density Liner Implosion eXperiment (PHELIX) platform to dynamically load CeO 2 powder. Parametric analyses investigating the effect of PHELIX cassette geometry, PHELIX total capacitor charge, and powder compaction model on the predicted shocked density profile of the CeO 2 powder are performed using the LANL codes FLAG and RAVEN. One PHELIX cassette geometry is designed to be used in two compaction experiments using PHELIX capacitor charges of 85 and 90 kV. Predictions of the shocked density profile in the CeO 2 powder are presented for each experimental configuration using both the Ramp and P-α compaction models. The two compaction models predict shocked density profiles in the CeO 2 powder that are significantly different and should be distinguishable using proton radiography as a diagnostic.

36 MATERIALS SCIENCE↗
NASA NTRS2019

Role of CEOS Working Group on Calibration and Validation in Analysis Ready Data Products

The Committee on Earth Observation Satellites (CEOS) is leading the CEOS Analysis Ready Data for Land (CARD4L) initiative. A goal of analysis ready data products is to limit the effort needed by users to pre-process the data allowing them to concentrate on the end products. CARD4L provides a set of specifications that data providers need to meet to be considered to satisfy CARD4L. One of the working groups within CEOS, the Working Group on Calibration and Validation (WGCV) is providing a peer review process to evaluate the documentation of the data providers validation and data product accuracy assessment. The approach makes use of the expertise within WGCV to collaborate with both the CEOS Land Surface Imaging Virtual Constellation and the data providers to work towards acceptance of the...

Thome, K.↗
NASA NTRSDate not supplied

CEOS Enabling Open Science via Science Data Systems

The Committee on Earth Observation Satellites (CEOS) strives to enhance international coordination and data exchange and to optimize societal benefit. CEOS contributes to NASA’s core mission and is critical to NASA’s Earth Science program and to the future of Earth observations community as a whole because it advances mission planning, interagency coordination and technical implementation. Within NASA, the CEOS Working Group on Information System and Services (WGISS) is a forum for the Earth Sciences Data Systems (ESDS) Program to collaborate with other international and domestic agencies in the development of Earth observation data systems and services. NASA leads the development and demonstration of multiple prototypes supporting CEOS and Group on Earth Observations (GEO) requirements. NASA’s participation in WGISS influences NASA’s Earth Observing System Data and Information System’s (EOSDIS) ability to make high-quality data products available to the broad science community both nationally and internationally. Combined with NASA’s free and open data policy, EOSDIS’s involvement in WGISS is essential to widespread use of research satellite measurements. This presentation focuses on an overview and recent status of NASA’s EOSDIS.

Diane Davies↗
DOE OSTI2019

Catalytic fast co-pyrolysis of bamboo sawdust and waste plastics for enhanced aromatic hydrocarbons production using synthesized CeO 2 /γ-Al 2 O 3 and HZSM-5

Fast co-pyrolysis of bamboo sawdust and waste plastic (linear low-density polyethylene, LLDPE) over a dual catalytic stage of synthesized CeO 2 /γ-Al 2 O 3 and HZSM-5 was conducted to enhance aromatic hydrocarbons production. Experimental results indicated that the catalyst to biomass (C/B) mass ratio played a determining role in the formation of hydrocarbon intermediates and a C/B mass ratio of 4 facilitated the production of aromatic hydrocarbons. Dual catalytic fast co-pyrolysis of bamboo sawdust and LLDPE using synthesized CeO 2 /γ-Al 2 O 3 and HZSM-5 increased the concentration of aromatic hydrocarbons and a CeO 2 /γ-Al 2 O 3 to HZSM-5 mass ratio of 1:3 maximized the target products. The content of aromatic hydrocarbons was increased at first and then decreased as the LLDPE percentage was elevated from 20% to 100% during the dual catalytic fast co-pyrolysis process, with the highest concentration obtained at 75% LLDPE percentage. In addition, the additive effect of monocyclic aromatic hydrocarbons was enhanced with the increasing of LLDPE percentage in the feedstock blends, and higher LLDPE proportion favored the production of xylenes, ethylbenzene, and alkylbenzenes as the additive effects were significantly promoted.

09 BIOMASS FUELS↗
DOE OSTI2017

In situ Investigation of Methane Dry Reforming on M-CeO 2 (111) {M= Co, Ni, Cu} Surfaces: Metal-Support Interactions and the activation of C-H bonds at Low Temperature

Studies with a series of M-CeO 2 (111) {M= Co, Ni, Cu} surfaces indicate that metal-oxide interactions can play a very important role for the activation of methane and its reforming with CO 2 at relatively low temperatures (600-700 K). Among the systems examined, Co-CeO 2 (111) exhibits the best performance and Cu-CeO 2 (111) has negligible activity. Experiments using ambient pressure XPS indicate that methane dissociates on Co-CeO2(111), at temperatures as low as 300 K, generating CH x and CO x species on the catalyst surface. The results of density-functional calculations show a reduction in the methane activation barrier from 1.07 eV on Co(0001) to 0.87 eV on Co 2+ /CeO 2 (111), and to only 0.05 eV on Co 0 /CeO 2-x (111). At 700 K, under methane dry reforming conditions, CO 2 dissociates on the oxide surface and a catalytic cycle is established without coke deposition. In conclusion, a significant part of the CH x formed on the Co 0 /CeO 2-x (111) catalyst recombines to yield ethane or ethylene.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2019

Origin of the High CO Oxidation Activity on CeO 2 Supported Pt Nanoparticles: Weaker Binding of CO or Facile Oxygen Transfer from the Support?

Pt clusters supported on CeO 2 are highly active for low temperature CO oxidation. The enhanced reactivity could be caused by weakening of the CO binding on Pt, allowing adsorbed oxygen to more effectively compete for sites. An alternative explanation is that interfacial sites allow adsorbed CO on Pt to react with lattice oxygen in the ceria. Here we explore the origins of enhanced CO oxidation reactivity on Pt/CeO 2 using in-situ/operando infrared and x-ray spectroscopies, microcalorimetry, and reaction kinetics. Iin this work we show that CO adsorbs strongly (~110–120 kJ/mol) on Pt clusters (~1.5 nm) and Pt is almost fully covered by CO during reaction, indicating that the high activity can be related to reactive interfacial O* species. Using in-situ infrared spectroscopy we show that when the reaction mixture of CO and O 2 stops flowing over the catalyst, the adsorbed CO on Pt is lost since it reacts with interfacial O*, but if this O* is depleted, the CO band does not disappear. The role of CeO 2 is not to alter the binding of CO, but rather to enhance the reactivity of the interfacial metal-support lattice oxygens. The reaction mechanism involving the interfacial Pt–CeO 2 sites (two-site mechanism) is further confirmed by kinetic measurements which show near zero order dependence on CO and O 2 partial pressures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Hyper-Raman spectroscopy of CeO 2

Cerium dioxide (CeO 2 ) belongs to the fluorite structure group (Oh 5 point group) resulting in one Raman active T 2g mode and two IR active T 1u TO and LO modes. The T 2g Raman band in CeO 2 has been used to probe the symmetric Ce-O vibrational mode of different sized nanoparticulates. Far infrared studies of the Ce-O interactions are difficult to conduct due to low optical transmission, efficiency of the detector and water absorption bands interfering with the measurements. The selection rules of hyper-Raman spectroscopy (HRS) allow the study of IR bands in the far infrared spectral region, such as the motion of the Ce atoms. For the first time, HRS was used to investigate the T 1u TO and LO IR modes in CeO 2 . The position and full-width half-maximum (FWHM) of the TO and LO bands in the HRS spectrum were used to investigate the spectral response in relation to particle size (i.e., phonon confinement). The investigation of CeO2 with HRS provides a research platform for future work in the study of ThO 2 , UO 2 and PuO 2 IR modes.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2025

Porous CeO 2 /CuO Heterostructure for Efficient Hydrogen Evolution Reaction in an Acidic Medium

A composite electrocatalyst CeO 2 /CuO is fabricated for the hydrogen evolution reaction (HER) via a simple, facile, one‐step hydrothermal method, using F‐127 as a template and structure directing agent. The prepared composite CeO 2 /CuO shows top‐notch HER activities with a small overpotential of 98 mV at 10 mA cm −2 and just 160 mV overpotential to attain a current density of 50 mA cm −2 with good stability for 20 h in an acidic medium. The enhanced catalytic activities of CeO 2 /CuO nanocomposite are attributed to their synergetic interface interaction, which lead to improved conductivity, reactive sites, and oxygen vacancies in their lattices. This study aims to advance the development of earth‐abundant transition metal oxides–based electrocatalysts as economical, durable, and efficient HER electrocatalysts to replace noble metal–based materials in the future.

Chemistry↗
DOE OSTI2023

Time dependent chlorination of CeO 2 , La 2 O 3 and Nd 2 O 3 by ZrCl 4 dissolved in eutectic LiCl–KCl

Partial chlorination of CeO 2 , La 2 O 3 , and Nd 2 O 3 was achieved using ZrCl 4 dissolved in molten LiCl-KCl at 450°C over a period of 4-5 hr. ZrCl 4 was pre-volatilized into an argon stream to maintain a constant vapor pressure for equilibration with the salt. This approach was effective at maintaining the ZrCl 4 concentration at the solubility limit of 1.3 mol% in the molten salt throughout the duration of two of the chlorination experiments and within about 60% of the solubility limit in the third experiment. Based on the analysis of salt samples, fractional conversion after four hours of reaction for CeO 2 , and five hours for La 2 O 3 , and Nd 2 O 3 were calculated to be 0.97, 0.28, and 0.65 respectively. Assuming a shrinking core diffusion-limited model, the diffusivity of ZrCl 4 through the hypothesized ZrO 2 layer was calculated for the chlorination of CeO 2 , La 2 O 3 , and Nd 2 O 3 were 1.76 x 10 -10 cm 2 /sec, 7.85 x 10 -12 cm 2 /sec, and 7.42 x 10 -12 cm 2 /sec, respectively. Given the extremely low values calculated for diffusivity, it was concluded that the process is chemical reaction rate limited and that a complete reaction of each rare earth oxide could be achieved. Furthermore, a chemically controlled shrinking core model was shown to also fit the experimental data closely.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗