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At least 109 records · Page 6

Carbon dioxide in the atmosphere: isotopic exchange with ozone and its use as a tracer in the middle atmosphere

Atmospheric heavy ozone is enriched in the isotopes 18O and 17O. The magnitude of this enhancement, of the order of 100%, is very large compared with that commonly known in atmospheric chemistry and geochemistry. The heavy oxygen atom in heavy ozone is therefore useful as a tracer of chemical species and pathways that involve ozone or its derived products. As a test of the isotopic exchange reactions, we successfully carry out a series of numerical experiments to simulate the results of the laboratory experiments performed by Wen and Thiemens [1993] on ozone and CO2. A small discrepancy between the experimental and the model values for 17O exchange is also revealed. The results are used to compute the magnitude of isotopic exchange between ozone and carbon dioxide via the excited atom O(1D) in the middle atmosphere. The model for 18O is in good agreement with the observed values.

NASA Discipline Exobiology

Estimate of Top-of-Atmosphere Albedo for a Molecular Atmosphere over Ocean using Clouds and the Earth's Radiant Energy System (CERES) Measurements

The shortwave broadband albedo at the top of a molecular atmosphere over ocean between 40deg N and 40deg S is estimated using radiance measurements from the Clouds and the Earth's Radiant Energy System (CERES) instrument and the Visible Infrared Scanner (VIRS) aboard the Tropical Rainfall Measuring Mission (TRMM) satellite. The albedo monotonically increases from 0.059 at a solar zenith angle of 10deg to 0.107 at a solar zenith angle of 60deg. The estimated uncertainty in the albedo is 3.5 x 10(exp -3) caused by the uncertainty in CERES-derived irradiances, uncertainty in VIRS-derived aerosol optical thicknesses, variations in ozone and water vapor, and variations in surface wind speed. The estimated uncertainty is similar in magnitude to the standard deviation of 0.003 that is derived from 72 areas divided by 20deg latitude by 20deg longitude grid boxes. The empirically estimated albedo is compared with the modeled albedo using a radiative transfer model combined with an ocean surface bidirectional reflectivity model. The modeled albedo with standard tropical atmosphere is 0.061 and 0.111 at the solar zenith angles of 10deg and 60deg, respectively. This empirically estimated albedo can be used to estimate the direct radiative effect of aerosols at the top of the atmosphere over oceans.

Kato, S.

The Huygens Atmospheric Structure Instrument (HASI): Expected Results at Titan and Performance Verification in Terrestrial Atmosphere

The Huygens ASI is a multi-sensor package resulting from an international cooperation, it has been designed to measure the physical quantities characterizing Titan's atmosphere during the Huygens probe mission. On 14th January, 2005, HASI will measure acceleration, pressure, temperature and electrical properties all along the Huygens probe descent on Titan in order to study Titan s atmospheric structure, dynamics and electric properties. Monitoring axial and normal accelerations and providing direct pressure and temperature measurements during the descent, HASI will mainly contribute to the Huygens probe entry and trajectory reconstruction. In order to simulate the Huygens probe descent and verify HASI sensors performance in terrestrial environment, stratospheric balloon flight experiment campaigns have been performed, in collaboration with the Italian Space Agency (ASI). The results of flight experiments have allowed to determine the atmospheric vertical profiles and to obtain a set of data for the analysis of probe trajectory and attitude reconstruction.

Ferri, F.

Calculation of top-of-atmosphere, surface and atmospheric cloud radiative kernels and feedbacks based on ISCCP-H datasets

This study aims to create observation-based cloud radiative kernel (CRK) datasets and evaluate them by direct comparison of CRK and the CRK-derived cloud feedback datasets. Based on the International Satellite Cloud Climatology Project (ISCCP) H datasets, we calculate CRKs (called FH CRKs) as 2D joint function/histogram of cloud optical depth and cloud top pressure for shortwave, longwave, and their sum, Net, at the top of atmosphere (TOA), as well as, for the first time, at the surface (SFC) and in the atmosphere (ATM). The direct comparison shows that FH agrees reasonably well with three other TOA CRK datasets. With cloud fraction change (CFC) datasets of the same histogram for doubled-CO2 simulation from 10 CFMIP1 models, we derive all the TOA, SFC and ATM cloud feedback using the FH CRKs. Our TOA cloud feedback is highly similar to the previous counterparts. Based on the comparison for the 4 CRK datasets and the 10 CFC datasets, we estimate the uncertainty budget for the CRK-derived cloud feedback and show that the CFC-associated uncertainty contributes > 98.5% of the total cloud feedback uncertainty while CRK’s is very small. Our preliminary evaluation shows that some near-zero/small cloud feedback in the TOA-alone feedback indeed results from the compensation of sizable cloud feedback of the SFC and ATM feedback, demonstrating that they help reveal some significant surface and atmospheric cloud feedback whose sum appears insignificant in TOA-alone feedback

cloud radiative kernel (CRK) datasets

Atmospheric Structure Investigation: Planetary in Situ Measurements of Atmospheric State Including Clouds/Aerosols.

The Atmospheric Structure Investigation (ASI) is a sensor suite designed for descent probes into planetary atmospheres, primarily aimed at Giant planets like Saturn and Uranus, and applicable to Venus, Titan, and Earth-specific missions. ASI aims to provide essential measurements of atmospheric structure, including probe acceleration, rotation, pressure, temperature, vertical winds, aerosol properties, and hydrogen and helium composition, crucial for contextualizing other probe data.

V Jha

Pressure Sounding of the Middle Atmosphere from ATMOS Solar Occultation Measurements of Atmospheric CO(sub 2) Absorption Lines

A method for retrieving the atmospheric pressure corresponding to the tangent point of an infrared spectrum recorded in the solar occultation mode is described and applied to measurements made by the Atmospheric Trace Molecule Spectroscopy (ATMOS) Fourier transform spectrometer. Tangent pressure values are inferred from measurements of isolated CO(sub 2) lines with temperature-insensitive intensities. Tangent pressures are determined with a spectroscopic precision of 1-3%, corresponding to a tangent point height precision, depending on the scale height, of 70-210 meters.

Atmospheric Trace Molecule Spectroscopy ATMOS atmo

Chemical Imaging of Atmospheric Biomass Burning Particles from North American Wildfires

The effects of biomass burning aerosols (BBA) on radiative forcing and cloud formation depend on chemical composition and the internal structures of individual particles within smoke plumes. To improve our understanding of the chemical and physical properties of BBA emitted at different times of the day and their evolution during atmospheric aging, we conducted a study as a part of the Fire Influence on Regional to Global Environments and Air Quality field campaign. Particle samples were collected onboard a research aircraft from smoke plumes from a wildfire in eastern Oregon during late afternoon and nighttime flights on August 28, 2019. A time-resolved aerosol collector was used to collect samples on substrates for offline spectromicroscopic imaging to investigate the single-particle characteristics of BBA particles. Approximately 20,400 individual particles from 10 selected samples were analyzed using computer-controlled scanning electron microscopy coupled with energy-dispersive X-ray microanalysis, revealing their elemental composition, morphology, and viscosity. Elemental microanalysis indicated that aged potassium is likely found in the form of K 2 SO 4 , KNO 3 , and possible K-organic salts. Further chemical speciation and carbon bonding mapping within individual particles were conducted using synchrotron-based scanning transmission X-ray microscopy (STXM) coupled with near edge X-ray absorption fine structure (NEXAFS) spectroscopy. Real-time, water-soluble light absorption measurements were acquired using a particle-into-liquid sampler instrument coupled to a liquid waveguide capillary cell and total organic analyzer. In the late afternoon samples, 65% of the total particle number population consisted entirely of organic components, compared to 46% in the nighttime particles. These differences were attributed to discrepancies in composition at the time of emission and to the daytime condensation and accumulation of photochemically formed secondary organic material on existing BBA particles, a process that halts at night. Microscopy images indicated that particle viscosity was lower in the nighttime particles (<10 1 Pa·s), likely due to increased relative humidity and a higher contribution from hygroscopic inorganic components. The chemical heterogeneity of individual particles was quantified using STXM-derived mixing state parameters. The nature of carbon bonding within individual particles was inferred from the extent of carbon sp 2 hybridization derived from NEXAFS spectra. Average percentages of sp 2 hybridization range between 40% and 60%, with no noticeable differences between late afternoon and nighttime flights. These findings were compared with the online optical properties of both late afternoon and nighttime smoke plumes, providing valuable insights into the complex relationship between chemical composition and optical properties of BBA particles at different times of the day.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

To Exascale and Beyond—The Simple Cloud-Resolving E3SM Atmosphere Model (SCREAM), a Performance Portable Global Atmosphere Model for Cloud-Resolving Scales

The new generation of heterogeneous CPU/GPU computer systems offer much greater computational performance but are not yet widely used for climate modeling. One reason for this is that traditional climate models were written before GPUs were available and would require an extensive overhaul to run on these new machines. In addition, even conventional “high–resolution” simulations don't currently provide enough parallel work to keep GPUs busy, so the benefits of such overhaul would be limited for the types of simulations climate scientists are accustomed to. The vision of the Simple Cloud-Resolving Energy Exascale Earth System (E3SM) Atmosphere Model (SCREAM) project is to create a global atmospheric model with the architecture to efficiently use GPUs and horizontal resolution sufficient to fully take advantage of GPU parallelism. After 5 years of model development, SCREAM is finally ready for use. In this paper, we describe the design of this new code, its performance on both CPU and heterogeneous machines, and its ability to simulate real-world climate via a set of four 40 day simulations covering all 4 seasons of the year.

54 ENVIRONMENTAL SCIENCES

Satellite Constellations for Atmospheric Sounding with GPS: A Revolution in Atmospheric and Ionospheric Research

Spaceborne Global Positioning System (GPS) atmospheric science is blossoming. Proposed missions require high performance GPS flight receivers with capabilities beyond most space needs. With GPS technology maturing, and lower cost spaceborne receivers, GPS usage is expanding rapidly for space flight projects. Several of these are discussed, such as atmospheric occultation, ionospheric imaging, etc.

Global Positioning System GPS Atmospheric Science

The Atmospheric Infrared Sounder (AIRS) on the NASA Aqua Spacecraft: A General Remote Sensing Tool for Understanding Atmospheric Structure, Dynamics and Composition

The Atmospheric Infrared Sounder (AIRS) on the EOS Aqua Spacecraft was launched on May 4, 2002. Early in the mission, the AIRS instrument demonstrated its value to the weather forecasting community with better than 6 hours of improvement on the 5 day forecast. Now with over eight years of consistent and stable data from AIRS, scientists are able to examine processes governing weather and climate and look at seasonal and interannual trends from the AIRSdata with high statistical confidence. Naturally, long-term climate trends require a longer data set, but indications are that the Aqua spacecraft and the AIRS instrument should last beyond 2018. This paper briefly describes the AIRS data products and presents some of the most significant findings involving the use of AIRS data in the areas of weather forecast improvement, climate processes and model validation, cloud and polar processes, and atmospheric composition (chemistry and dust).

Temperature

Assessment of Geo-Kompsat-2A Atmospheric Motion Vector Data and Its Assimilation Impact in the GEOS Atmospheric Data Assimilation System

Korea’s second geostationary meteorological satellite, Geo-Kompsat-2A (Geostationary-Korean Multi-Purpose Satellite-2A, GK2A), was successfully launched on 4 December 2018. GK2Agenerates Atmospheric Motion Vectors (AMVs) every 10 min in the full disk area. This data hasbeen disseminated via Global Telecommunication System (GTS) since 25 October 2019. This articleevaluates the quality of GK2A AMVs in the Goddard Earth Observing System (GEOS) atmosphericdata assimilation system (ADAS). The data show slow wind speed biases at 200–300 hPa and 600–800hPa in the northern and southern hemispheres. These biases are caused by observation heightassignment errors near jet streams. The Equivalent Blackbody Temperature (EBBT) method of GK2Atends to assign clouds at higher altitude, which mainly causes slow wind speed biases, especially inthe lower atmosphere. The IR/WV intercept method of GK2A assigns clouds slightly lower in theatmospheric layers below the altitude of 400 hPa, which causes positive biases. Quality control (QC)criteria to select the most suitable GK2A AMV data for assimilation are presented based on thesequality assessments. A new QC criterion utilizing height errors within the GEOS ADAS is introducedto exclude data with slow wind speed biases and large errors. GEOS forecast accuracy is slightlyimproved after assimilating GK2A AMVs along with other conventional, radiance, and satellitewinds which include AMVs made by the Himawari-8 satellite in nearly the same observational areaof GK2A. Additionally, the present work shows that GEOS forecasts can be significantly improved,especially in the tropics and southern hemisphere after assimilating GK2A data in the absence ofHimawari-8 AMVs. This study demonstrates that GK2A AMV data is a valuable data source toenhance the robustness of GEOS ADAS.

Atmospheric Motion Vectors