Perfection of materials technology for producing improved Gunn-effect devices
Chemical vapor deposition system for improved Gunn effect devices using arsenic chloride 3 method
Baxter, R. D.↗
SEARCH · Engineering Papers
Results for “Arsenic”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Vapor Phase Growth Technique and System for Several III-V Compound Semiconductors Interim Scientific Report
Vapor phase crystal growth and preparation of gallium, indium, arsenic, phosphorous, and antimony alloy semiconductor materials
Clough, R.↗
The preparation and properties of vapor- deposited epitaxial InAs sub 1-x P sub x using arsine and phosphine.
Vapor phase epitaxial production of indium arsenic phosphide crystalline layers, discussing electron mobilities, electrical resistivities and doping
Clough, R. B.↗
The chalcogenide semiconductor system - As sub 2 Se sub 3-Sb sub 2 Se sub 3.
Glass formation region of chalcogenide semiconductor arsenic triselenide-antimony triselenide system and vitreous-crystalline transformation, investigating electrical and optical properties
Gatos, H. C.↗
Photogrammetric and photometric investigation of a smoke plume viewed from space.
Use of detailed analyses of an Apollo 6 stereographic photograph of a smoke plume which originated in southern Arizona and crossed over into Mexico to illustrate how high-resolution photography can aid meteorologists in evaluating specific air pollution events. Photogrammetric analysis of the visible smoke plume revealed that the plume was 8.06 miles long and attained a maximum width of 4000 ft, 3.0 miles from the 570-ft chimney emitting the effluent. Stereometric analysis showed that the visible top of the plume rose nearly 2400 ft above stack top, attaining 90% of this total rise 1.75 miles downwind from the source. Photometric analysis of the plume revealed a field of plume optical density that portrayed leptokurtic and bimodal distributions rather than a true Gaussian distribution. A horizontal eddy diffusivity of about 650,000 sq cm/sec and a vertical eddy diffusivity of 230,000 sq cm/sec were determined from the plume dimensions. Neutron activation analysis of plume samples revealed the elemental composition of the smoke to be copper, arsenic, selenium, indium and antimony, with trace amounts of vanadium and scandium.
Randerson, D.↗
The measurement of radiation exposure of astronauts by radiochemical techniques
Cosmic radiation doses to the crews of the Apollo 14, 15, and 16 missions of 142 + or - 80, 340 + or - 80, and 210 + or - 130 mR respectively were calculated from the specific activities of Na-22 and Na-24 in the postflight urine specimens of the astronauts. The specific activity of Fe-59 was higher in the urine than in the feces of the Apollo 14 and 15 astronauts, and a possible explanation is given. The concentrations of K-40, K-42, Cr-51, Co-60, and Cs-137 in the urine are also reported for these astronauts. The radiation doses received by pilots and navigators flying high altitude missions during the solar flare of March 27 to 30, 1972 were calculated from the specific activity of Na-24 in their urine. These values are compared with the expected radiation dose calculated from the known shape and intensity of the proton spectrum and demonstrate the magnitude of atmospheric shielding. The concentrations of Na, K, Rb, Cs, Fe, Co, Ag, Zn, Hg, As, Sb, Se, and Br were measured in the urine specimens from the Apollo 14 and 15 astronauts by neutron activation analysis. The mercury and arsenic levels were much higher than expected.
Brodzinski, R. L.↗
Nuclear quadrupole resonance studies in semi-metallic structures
Both experimental and theoretical studies are presented on spectrum analysis of nuclear quadrupole resonance of antimony and arsenic tellurides. Numerical solutions for secular equations of the quadrupole interaction energy are also discussed.
Murty, A. N.↗
Feasibility investigation of growing gallium arsenide single crystals in ribbon form
Polycrystalline GaAs ribbons have been grown in graphite boats by passage of a wide zone through B2O3 encapsulated feed stock, confined by a quartz cover plate. By controlling the heat flow in the graphite boat and controlling the zoning rate, large grained, single phase polycrystalline samples with directional solidification and good thickness control were achieved. Arsenic vaporization was effectively suppressed at the melting point of GaAs by the B2O3 moat and 3 atmospheres of pressure. A vertical constrained-zone-melting apparatus with a B2O3 moat seal, rf heating, and water cooling on the bottom will be used to control the heat flow and temperature patterns required for growth of single crystal ribbons.
Richardson, D. L.↗
Mineral target areas in Nevada from geological analysis of LANDSAT-1 imagery
Geological analysis of LANDSAT-1 Scene MSS 1053-17540 suggests that certain known mineral districts in east-central Nevada frequently occur near faults or at faults or lineament intersections and areas of complex deformation and flexures. Seventeen (17) areas of analogous characteristics were identified as favorable targets for mineral exploration. During reconnaissance field trips eleven areas were visited. In three areas evidence was found of mining and/or prospecting not known before the field trips. In four areas favorable structural and alteration features were observed which call for more detailed field studies. In one of the four areas limonitic iron oxide samples were found in the regolith of a brecciated dolomite ridge. This area contains quartz veins, granitic and volcanic rocks and lies near the intersection of two linear fault structures identified in the LANDSAT-1 imagery. Semiquantitative spectroscopic analysis of selected portions of the samples showed abnormal contents of arsenic, molybdenum, copper, lead, zinc, and silver. These limonitic samples found were not in situ and further field studies are required to assess their source and significance.
Abdel-Gawad, M.↗
Fire-retardant epoxy polymers
Phosphorus atoms in molecular structure of epoxies make them fire-retardant without degrading their adhesive strength. Moreover, polymers are transparent, unlike compounds that contain arsenic or other inorganics. They have been used to bond polyvinylfluoride and polyether sulfone films onto polyimide glass laminates.
Akawie, R. I.↗
Activation analysis of admixtures in certain semiconductive materials
The use of extractions and chromatographic operations to separate macrobases, and to divide elements into groups convenient for gamma-spectrometric analysis is discussed. Methods are described for the activation detection of some impurities in silicon, arsenic, thallium, and trichloromethylsilane, on the basis of the extraction properties of bis(2-chlorethyl ether) and dimethylbenzylalkylammonium chloride. A schematic diagram of the extraction separation of elements-admixture is presented showing the aqueous and organic phases. The content percentage of the various elements are given in tables.
Artyukhin, P. I.↗
High performance, inexpensive solar cell process capable of a high degree of automation
This paper proposes a process for inexpensive high performance solar cell fabrication that can be automated for further cost reduction and higher throughputs. The unique feature of the process is the use of oxides as doping sources for simultaneous n(+) junction formation and back p(+) layer, as a mask for metallization and as an in situ AR coating for spectrum matching. Cost analysis is performed to show that significant cost reductions over the conventional process is possible using the proposed scheme and the cost intensive steps are identified which can be further reduced to make the process compatible with the needed price goals of 50 cents/watt. The process was demonstrated by fabricating n(+)-p cells using Arsenic doped oxides. Simple n(+)-p structure cells showed corrected efficiencies of 14.5% (AMO) and 12% with doped oxide as an in situ antireflection coating.
Shah, P.↗
Long-term temperature effects on GaAs solar cells
The thermal degradation of AlGaAs solar cells resulting from a long-term operation in a space environment is investigated. The solar cell degradation effects caused by zinc and aluminum diffusion as well as deterioration by arsenic evaporation are presented. Also, the results are presented of experimental testing and measurements of various GaAs solar cell properties while the solar cell was operating in the temperature range of 27 C to 350 C. In particular, the properties of light current voltage curves, dark current voltage curves, and spectral response characteristics are given. Finally, some theoretical models for the annealing of radiation damage over various times and temperatures are included.
Heinbockel, J. H.↗
Investigation of electrical noise in selenium-immersed thermistor bolometers
The selenium immersed, thermistor bolometer, IR detector failed due to spurious and escalating electrical noise outburst as a function of time at elevated temperatures during routine ground based testing in a space simulated environment. Spectrographic analysis of failed bolometers revealed selenium pure zones in the insulating selenium arsenic (Se-As) glass film which surrounds the active sintered Mn, Ni, Co oxide flake. The selenium pure film was identified as a potentially serious failure mechanism. Significant changes were instituted in the manufacturing techniques along with more stringent process controls which eliminated the selenium pure film and successfully produced 22study bolometers.
Tarpley, J. L.↗
Effects of heavy metals on the absorbance and reflectance spectra of plants
The spectral responses of plants to various concentrations of heavy metals in their rooting media are investigated in relation to the application of remote sensing methods to the detection of vegetation under stress. Absorption photometry of chloroplasts, measurements of metal and chlorophyll concentrations and reflectance spectrometry were performed on leaves of pea, sunflower and soybean plants grown under greenhouse conditions with the addition of various concentrations of Cd, Cu, Pb and Zn to their rooting media and on leaves of oak trees growing naturally in an area of a copper-arsenic mineralization. Under laboratory conditions, the most general effect observed was growth inhibition and ultimately death, with pea plants also exhibiting changes of chlorophyll a/ chlorophyll b ratios with Cd and Cu and reflectance increases in the visible and decreases in the infrared. Although results for other species indicate that reflectance effects are dependent on species, correlations between reflectance and metal exposure is confirmed by the field investigations. It is concluded that a remote sensing system would be improved by the inclusion of bands around 1.65 and 2.20 microns to detect soil mineralization from plant spectra.
Horler, D. N. H.↗
Chemical depth profiles of the GaAs/native oxide interface
The final-state oxidation products and their distribution in thin native oxides (30-40 A) on GaAs have been studied using X-ray photoelectron spectroscopy in conjunction with chemical depth profiling. Extended room-temperature-oxidation conditions have been chosen to allow the native oxide to attain its equilibrium composition and structure. The work emphasizes the use of chemical depth-profiling methods which make it possible to examine the variation in chemical reactivity of the oxide structure. A minimum of two distinct regions of Ga2O3 with differing chemical reactivity is observed. Chemical shift data indicate the presence of As2O3 in the oxide together with an elemental As overlayer at the interface. A change in relative charge transfer between oxygen and both arsenic and gallium-oxide species is observed in the region of the interface.
Grunthaner, P. J.↗
Some aspects of analytical chemistry as applied to water quality assurance techniques for reclaimed water: The potential use of X-ray fluorescence spectrometry for automated on-line fast real-time simultaneous multi-component analysis of inorganic pollutants in reclaimed water
The potential use of isotopically excited energy dispersive X-ray fluorescence (XRF) spectrometry for automated on line fast real time (5 to 15 minutes) simultaneous multicomponent (up to 20) trace (1 to 10 parts per billion) analysis of inorganic pollutants in reclaimed water was examined. Three anionic elements (chromium 6, arsenic and selenium) were studied. The inherent lack of sensitivity of XRF spectrometry for these elements mandates use of a preconcentration technique and various methods were examined, including: several direct and indirect evaporation methods; ion exchange membranes; selective and nonselective precipitation; and complexation processes. It is shown tha XRF spectrometry itself is well suited for automated on line quality assurance, and can provide a nondestructive (and thus sample storage and repeat analysis capabilities) and particularly convenient analytical method. Further, the use of an isotopically excited energy dispersive unit (50 mCi Cd-109 source) coupled with a suitable preconcentration process can provide sufficient sensitivity to achieve the current mandated minimum levels of detection without the need for high power X-ray generating tubes.
Ling, A. C.↗
Infrared spectra of some sulfides and their analogs of binary composition in the long-wave region
The far infrared spectra (500-60/cm) of some simple sulfides and their analogs were studied. In all, 22 minerals with different structure types were investigated, out of which 14 are sulfides (galena, alabandite, pyrrhotite, sphalerite, wurtzite, cinnabar, realgar, orpiment, getchelite antimonite, molybdenite, pyrite, marcasite and heazlewoodite) 6 arsenides (niccolite, domeykite, arsenopyrite, lollingite, rammelsbergite and skutterudite), one telluride (tetradymite) and native arsenic. The main bands of infrared absorption spectra of the minerals are compared with the relative strength of the interatomic bonds and their interpretation is given.
Povarennykh, A. S.↗