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Unsteady diffusion with recombination in ternary mixture of diatomic molecules, dissociated atoms, and an inert gas
Atomic nitrogen has been detected in the upper atmosphere of Venus by the Pioneer-Venus Orbiter Neutral Mass Spectrometer (ONMS). Surface recombination of atomic nitrogen with atomic oxygen to form nitric oxide in the ion source allows it to be detected at mass 30. The scale height temperature of the mass 30 peak agrees with the scale height temperatures of the other species if it is assumed to be derived from atomic nitrogen. The diurnal variation of atomic nitrogen is approximately proportional to that of atomic oxygen with an estimated N/O ratio of 1.5% at 150 km.
Altitude distribution of atmospheric molecular and atomic hydrogen, showing results of Lyman alpha absorption measurements
The wave-driven fluctuations in the O2(0-1) atmospheric nightglow is modeled and the parameter (eta) is calculated using a model that accounts for either three-body recombination of atomic oxygen atoms alone to form the O2(b exp 1 Sigma(g)(+)) state directly, or by the further inclusion of the process that allows the formation of the O2(c exp 1 Sigma(u)(-)) intermediate state. The calculations are performed for a latitude of 18 deg N and for the months of March and June. The general results, which display how (eta) varies with wave period, horizontal wavelength, season, and chemical scheme, show that for given values of wave period and horizontal wavelength it is not possible to discriminate between seasonal effects and between the effects of different chemical schemes at evanescent and short gravity wave periods. It is shown that, when quenching by atomic oxygen is ignored, the resulting values of (eta) calculated with the complete chemistry are similar to those obtained from the three-body recombination scheme alone.
Several experiments on the formation of solid hydrogen particles in liquid helium were recently conducted at the NASA Glenn Research Center at Lewis Field. The solid hydrogen experiments are the first step toward seeing these particles and determining their shape and size. The particles will ultimately store atoms of boron, carbon, or hydrogen, forming an atomic propellant. Atomic propellants will allow rocket vehicles to carry payloads many times heavier than possible with existing rockets or allow them to be much smaller and lighter. Solid hydrogen particles are preferred for storing atoms. Hydrogen is generally an excellent fuel with a low molecular weight. Very low temperature hydrogen particles (T < 4 K) can prevent the atoms from recombining, making it possible for their lifetime to be controlled. Also, particles that are less than 1 mm in diameter are preferred because they can flow easily into a pipe when suspended in liquid helium. The particles and atoms must remain at this low temperature until the fuel is introduced into the engine combustion (or recombination) chamber. Experiments were, therefore, planned to look at the particles and observe their formation and any changes while in liquid helium.
Exhaust nozzle recombination for hydrogen-fueled subsonic combustion ramjet engines
The internal energy, pressure, and compressibility of ground-state, spin-aligned atomic hydrogen, deuterium, and tritium are calculated assuming that all pair interactions occur via the atomic triplet (spin-aligned) potential. The conditions required to obtain atomic hydrogen and its isotopes in bulk are discussed; such a development would be of value in propulsion systems because of the light mass and energetic recombination of atomic hydrogen. Results show that atomic triplet hydrogen and deuterium remain gaseous at 0 K, and that tritium forms a liquid with a binding energy of approximately -0.75 K per atom at a molar volume of 130 cu cm per mole. The pair distribution function for these systems is calculated, and the predicted superfluid behavior of atomic triplet hydrogen and tritium is briefly discussed.
Effect of high energy electron irradiation on surface recombination properties of germanium p-n junction photovoltaic cells
An apparatus is described in which hydrogen atoms were trapped at temperatures down to 1.1 K in the 11 T field of a large volume superconducting magnet. A high sensitivity thermal detector was used to study trapping and recombination of atoms on the detector surface. The apparatus permits the application of extremely high steady state magnetic fields to study the potential effects of electron spin polarization on the stabilization of hydrogen atoms.
Exhaust nozzle recombination for hydrogen-fueled subsonic combustion ramjet engines
Effect of ionization and recombination on the electron distribution function of a slightly ionized gas in the presence of an external magnetic and electric field
The 30-day reports from the Voyager Ultraviolet Spectrometer team characterize the atomic hydrogen observed near Saturn as a torus with a half width of 7 Saturnian radii. The atomic processes occurring in the inner magnetosphere are modelled, including sputtering, ionization, charge exchange, ion-atom interchange, recombination, and transport, and a neutral hydrogen source is added to test the proposal that a hydrogen cloud exists in this region. Plasma observations in the inner magnetosphere are found to be inconsistent with the presence of a dense atomic hydrogen cloud. Thus, it is concluded that the hydrogen cloud must be a torus as originally reported, and that the cloud does not extend inward to the orbits of the inner satellites of Saturn.
Quantum interferometer gravity gradiometer for 3D mapping is a project for developing the technology of atom interferometer-based gravity sensor in space. The atom interferometer utilizes atomic particles as free fall test masses to measure inertial forces with unprecedented sensitivity and precision. It also allows measurements of the gravity gradient tensor components for 3D mapping of subsurface mass distribution. The overall approach is based on recent advances of laser cooling and manipulation of atoms in atomic and optical physics. Atom interferometers have been demonstrated in research laboratories for gravity and gravity gradient measurements. In this approach, atoms are first laser cooled to micro-kelvin temperatures. Then they are allowed to freefall in vacuum as true drag-free test masses. During the free fall, a sequence of laser pulses is used to split and recombine the atom waves to realize the interferometric measurements. We have demonstrated atom interferometer operation in the Phase I period, and we are implementing the second generation for a complete gradiometer demonstration unit in the laboratory. Along with this development, we are developing technologies at component levels that will be more suited for realization of a space instrument. We will present an update of these developments and discuss the future directions of the quantum gravity gradiometer project.
Catalytic surface recombination for measuring diffusion coefficients of atomic oxygen
Chemical mixing laser investigations were conducted (1) to investigate the properties of a bimolecular exchange laser system pumped by the H + Cl2 yields HCl(v) + Cl reaction, initiated by arc-dissociated H2, with lasing occurring between wavelengths of 3.4 and 4.0 microns, and (2) to establish the feasibility of an atom recombination-transfer laser employing recombination of arc-dissociated nitrogen with subsequent transfer of vibrational energy to CO2 for lasing at 10.6 microns. One-dimensional analytical results indicate higher results should be obtained with up to v = 3 to 2 transitions participating. Diagnostic and analytical results show that the reaction mechanism during mixing, a back reaction of HCl(v) with H atoms, reaction of Cl with H2(v), moderately fast V-V, V-T processes, and possible HCl(o) initial contaminant level may explain the low performance. N2-CO2 thermal mixing laser studies were extended to measure the efficiency of transfer of recombination energy in such a nonequilibrium N2 source to 10.6 microns optical energy. The low level of efficiency suggests that V-T decay processes may prevent vibrational energy freezing until much lower temperatures are achieved and that trapping of energy in long-lived electronic excitation of N2 may be a factor.
Measured altitude profiles of atomic oxygen, 557.7-nm emissions, and Herzberg I emission between 80 and 120 km were used to test the proposed mechanisms leading to these emissions. As generally assumed, the O2(A 3 Sigma u +) that emits the Herzberg I bands is excited by three-body recombination of atomic oxygen. The quenching of this state is by N2 or O2; for N2 the lifetime times the rate is 2.75 x 10 to the -13th per cu cm; other quenchers are insignificant. It is found that the atomic oxygen O(1S) emitting the green line is excited by the Barth mechanism.
Calculations have been made of the diurnal variations in minor neutral constituents in the mesosphere and lower thermosphere for the condition of 60 deg latitude, summer and winter. Excited molecular oxygen has been added, and the effects of absorption of Schumann-Runge bands have been taken into account. The results show significant seasonal differences, which may be interpreted mainly in terms of the difference of penetration of solar radiation and the duration of sunlit hours. However, the comparison of the observed seasonal and diurnal variations in the airglow emissions from hydroxyl, atomic oxygen (5577 A), and excited molecular oxygen with those calculated from models suggests that effects of large-scale meridional circulation (horizontal and vertical transports) may be important in explaining these observations. It is shown that the concentration of the constituents whose main loss mechanism is recombination with atomic oxygen decreases sharply above 80 km.
WINDII, the Wind Imaging Interferometer on the Upper Atmosphere Research Satellite, began atmospheric observations on September 28, 1991 and since then has been collecting data on winds, temperatures and emissions rates from atomic, molecular and ionized oxygen species, as well as hydroxyl. The validation of winds and temperatures is not yet complete, and scientific interpretation has barely begun, but the dominant characteristic of these data so far is the remarkable structure in the emission rate from the excited species produced by the recombination of atomic oxygen. The latitudinal and temporal variability has been noted before by many others. In this preliminary report on WINDII results we draw attention to the dramatic longitudinal variations of planetary wave character in atomic oxygen concentration, as reflected in the OI 557.7 nm emission, and to similar variations seen in the Meine1 hydroxyl band emission.