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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 109 records · Page 6
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Proton-controlled molecular ionic ferroelectrics

Abstract Molecular ferroelectric materials consist of organic and inorganic ions held together by hydrogen bonds, electrostatic forces, and van der Waals interactions. However, ionically tailored multifunctionality in molecular ferroelectrics has been a missing component despite of their peculiar stimuli-responsive structure and building blocks. Here we report molecular ionic ferroelectrics exhibiting the coexistence of room-temperature ionic conductivity (6.1 × 10 −5 S/cm) and ferroelectricity, which triggers the ionic-coupled ferroelectric properties. Such ionic ferroelectrics with the absorbed water molecules further present the controlled tunability in polarization from 0.68 to 1.39 μC/cm 2 , thermal conductivity by 13% and electrical resistivity by 86% due to the proton transfer in an ionic lattice under external stimuli. These findings enlighten the development of molecular ionic ferroelectrics towards multifunctionality.

42 ENGINEERING↗
DOE OSTI2025

Evidence of isospin-symmetry violation in high-energy collisions of atomic nuclei

Strong interactions preserve an approximate isospin symmetry between up (u) and down (d) quarks, part of the more general flavor symmetry. In the case of K meson production, if this isospin symmetry were exact, it would result in equal numbers of charged (K + and K − ) and neutral (K 0 and ${\overline{K}}^{0}$) mesons produced in collisions of isospin-symmetric atomic nuclei. Here, we report results on the relative abundance of charged over neutral K meson production in argon and scandium nuclei collisions at a center-of-mass energy of 11.9 GeV per nucleon pair. We find that the production of K + and K − mesons at mid-rapidity is (18.4 ± 6.1)% higher than that of the neutral K mesons. Although with large uncertainties, earlier data on nucleus-nucleus collisions in the collision center-of-mass energy range $2.6 \, < \, \sqrt{{s}_{NN}} \, < \, 200$ GeV are consistent with the present result. Using well-established models for hadron production, we demonstrate that known isospin-symmetry breaking effects and the initial nuclei containing more neutrons than protons lead only to a small (few percent) deviation of the charged-to-neutral kaon ratio from unity at high energies. Thus, they cannot explain the measurements. The significance of the flavor-symmetry violation beyond the known effects is 4.7σ when the compilation of world data with uncertainties quoted by the experiments is used. New systematic, high-precision measurements and theoretical efforts are needed to establish the origin of the observed large isospin-symmetry breaking.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Drivers and impacts of sediment deposition in Amazonian floodplains

Abstract The Amazon River carries enormous amounts of sediment from the Andes mountains, much of which is deposited in its floodplains. However, accurate quantification of the sediment sink at fine spatiotemporal scales is still challenging. Here, we present a high-resolution hydrodynamic-sediment model to simulate sediment deposition in a representative Amazon/Solimões floodplain. The process is found to be jointly driven by inundation, suspended sediment concentration in the Amazon River, and floodplain hydrodynamics and only weakly correlated with inundation level. By upscaling the sediment deposition rate (1.33 ± 0.24 kg m −2 yr −1 ), we estimate the trapping of 77.3 ± 13.9 Mt (or 6.1 ± 1%) of the Amazon River sediment by the Amazon/Solimões floodplains every year. Widespread deforestation would reduce the trapping efficiency of the floodplains over time, exacerbating downstream river aggradation. Additionally, we show that the deposition of sediment-associated organic carbon plays a minor role in fueling carbon dioxide and methane emissions in the Amazon.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2026

Hierarchal structures tuned electrocaloric and electromechanical performance in PVDF-based tetrapolymers

Ferroelectrics with multifunctionalities are gaining increased interest in self-actuated electrocaloric effect (ECE) refrigerators. However, achieving high ECE and electromechanical (EM) coupling concomitantly for maximum heat transfer remains challenging. Here we present the structure-property relationship for poly(vinylidene fluoride-co-trifluoroethylene-co-chlorofluoroethylene-co-double bond), P(VDF-TrFE-CFE-DB), tetrapolymer, which exhibited a high ECE entropy change of 66.5 J Kg −1 K −1 and EM strain of −6.1%. We show that thermal treatment can be a key factor influencing multifunctional properties. High-temperature annealing incorporates DB and CFE units into crystalline grains to form extended-chain crystals, enabling CFE units to induce relaxor behavior and DB units to induce large structural changes at low electric fields. This synergy leads to an enhancement in both ECE and EM performances. Furthermore, at an optimized temperature of 50 °C, the annealed films exhibit giant cross-energy coupling, achieving ECE and EM performances of 100.8 J Kg −1 K −1 and −7.6%. This study provides insights into developing new ferroelectric polymers with electroactive multifunctionalities.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Tuning collective anion motion enables superionic conductivity in solid-state halide electrolytes

Halides of the family Li 3 MX 6 (M = Y, In, Sc and so on, X = halogen) are emerging solid electrolyte materials for all-solid-state Li-ion batteries. They show greater chemical stability and wider electrochemical stability windows than existing sulfide solid electrolytes, but have lower room-temperature ionic conductivities. Here, in this work, we report the discovery that the superionic transition in Li 3 YCl 6 is triggered by the collective motion of anions, as evidenced by synchrotron X-ray and neutron scattering characterizations and ab initio molecular dynamics simulations. Based on this finding, we used a rational design strategy to lower the transition temperature and thus improve the room-temperature ionic conductivity of this family of compounds. We accordingly synthesized Li 3 YCl x Br 6-x and Li 3 GdCl 3 Br 3 and achieved very high room-temperature conductivities of 6.1 and 11 mS cm -1 for Li 3 YCl 4.5 Br 1.5 and Li 3 GdCl 3 Br 3 , respectively. These findings open new routes to the design of room-temperature superionic conductors for high-performance solid batteries.

25 ENERGY STORAGE↗
DOE OSTI2024

Evaluating community solar as a measure to promote equitable clean energy access

Rooftop and community solar are alternative product classes for residential solar in the United States. Community solar, where multiple households buy solar from shared systems, could make solar more accessible by reducing initial costs and removing adoption barriers for renters and multifamily building occupants. Here we test whether community solar has expanded solar access in the United States. On the basis of a sample of 11 states, we find that community solar adopters are about 6.1 times more likely to live in multifamily buildings than rooftop solar adopters, 4.4 times more likely to rent and earn 23% less annual income. In this study, we do not find that community solar expands access in terms of race. These differences are driven, roughly evenly, by inherent differences between the two solar products and by policies to promote low-income community solar adoption. The results suggest that alternative solar products can expand solar access and that policy could augment such benefits.

14 SOLAR ENERGY↗
DOE OSTI2023

Global tropical cyclone precipitation scaling with sea surface temperature

Understanding the relationship between tropical cyclone (TC) precipitation and sea surface temperature (SST) is essential for both TC hazard forecasting and projecting how these hazards will change in the future due to climate change. This work untangles how global TC precipitation is impacted by present-day SST variability (known as apparent scaling) and by long-term changes in SST caused by climate change (known as climate scaling). A variety of datasets are used including precipitation and SST observations, realistic climate model simulations, and idealized climate model simulations. The apparent scaling rates depend on precipitation metric; examples shown here have ranges of 6.1 to 9.5% per K versus 5.9 to 9.8% per K for two different metrics. The climate scaling is estimated at about 5% per K, which is slightly less than the atmospheric moisture scaling based on thermodynamic principles of about 7% per K (i.e., the Clausius–Clapeyron scaling). The apparent scaling is greater than the climate scaling, which implies that the relationship between TC precipitation and present-day SST variability should not be used to project the long-term response of TC precipitation to climate change.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

The water trimer reaction OH + (H 2 O) 3 → (H 2 O) 2 OH + H 2 O

All important stationary points on the potential energy surface (PES) for the reaction OH + (H 2 O) 3 → (H 2 O) 2 OH + H 2 O have been fully optimized using the “gold standard” CCSD(T) method with the large Dunning correlation-consistent cc-pVQZ basis sets. Three types of pathways were found. For the pathway without hydrogen abstraction, the barrier height of the transition state (TS1) is predicted to lie 5.9 kcal mol -1 below the reactants. The two major complexes (H 2 O) 3 ∙∙∙OH (CP1 and CP2a) are found to lie 6.3 and 11.0 kcal mol -1 , respectively, below the reactants [OH + (H 2 O) 3 ]. For one of the H-abstraction pathways the lowest classical barrier height is predicted to be much higher, 6.1 kcal mol -1 (TS2a) above the reactants. For the other H-abstraction pathway the barrier height is even higher, 15.0 (TS3) kcal mol -1 . Vibrational frequencies and the zero-point vibrational energies connected to the PES are also reported. Fianlly, the energy barriers for the H-abstraction pathways are compared with those for the OH + (H 2 O) 2 and OH + H 2 O reactions, and the effects of the third water on the energetics are usually minor (0.2 kcal mol -1 ).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Kinetics of Radiation-induced Cr( II ) and Cr( III ) Redox Chemistry in Molten LiCl-KCl Eutectic

Chromium (Cr) is a frequent constituent of the metal alloys proposed for molten salt nuclear reactor (MSR) applications, and is typically the least noble metal ion present. Consequently, chromium is preferentially corroded into molten salt solutions. Here, the redox poise and redox cycling of chromium ions in the salt can greatly influence its corrosivity towards structural alloys, ultimately impacting the longevity of MSR systems. Radiation-induced chemistry is expected to play a significant role in determining the chromium oxidation state distribution during MSR operations. In the present research, electron pulse radiolysis techniques were employed to characterize the reactivity of Cr(II) and Cr(III) ions with primary radiolysis products in molten lithium chloride–potassium chloride (LiCl–KCl) eutectic over a temperature range of 400–600 °C. Both chromium oxidation states were found to rapidly react with the primary products of molten chloride salt radiolysis, i.e., the solvated electron (e S - ) and the dichlorine radical anion (Cl 2 ˙ - ). For reactions with the e S - , second-order rate coefficients (k) of k = (4.1 ± 0.2) and (6.1 ± 0.3) × 10 10 M -1 s -1 at 400 °C for Cr(II) and Cr(III), respectively, were determined. Temperature-dependent measurements allowed for the derivation of activation parameters for electron capture by Cr(II) and Cr(III). Both chromium ions also react with Cl 2 ˙ - , k = (7.2 ± 0.3) and (1.4 ± 0.1) × 10 9 M -1 s -1 at 400 °C for Cr(II) and Cr(III), respectively.

37 - INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL C↗
DOE OSTI2025

Metal ion dopant-induced famatinite to chalcostibite phase transformation of copper antimony sulphide colloidal nanostructures: effect on photophysical and pseudocapacitance properties

Here, the strategic doping of transition metal ions into copper antimony sulphide (CAS) semiconducting nanostructures can significantly influence their photophysical and pseudocapacitive properties, for which there are few reports and therefore is the focus of this study. Accordingly, highly crystalline metal ion (Mn 2+ , Fe 2+ , Co 2+ , Ni 2+ and Zn 2+ ) doped off-stoichiometric copper rich/poor, antimony-rich/poor, and sulphur-poor CAS nanostructures (10–23 nm) were grown via colloidal (hot-injection) synthesis using metal diethyldithiocarbamate precursors. Importantly, metal ion doping significantly influences the structure and composition of the off-stoichiometric CAS nanostructures. Data from powder X-ray diffraction, Raman spectroscopy, high-resolution scanning/transmission electron microscopy, and energy dispersive X-ray spectroscopy confirm that the heavier metal ion dopants induce a novel phase transformation from famatinite (fCAS) to chalcostibite (cCAS) nanostructures. The influence of the metal ion dopants is also observed in the optical properties of as-synthesized nanostructures. This involves blue-shifted ultraviolet-visible absorption, reduced Urbach tailing, and tunable bandgaps between 2.17 and 2.38 eV. Also, the doped nanostructures display broad visible-near infrared photoluminescence via a triple radiative pathway with relatively short decay lifetimes between 0.2 and 6.1 ns. This is mediated by electronic transitions involving intrinsic (copper/antimony/sulphur interstitial) and extrinsic (metal ion interstitial) defect states. Additionally, electrodes prepared from Mn 2+ -doped fCAS nanostructures show enhanced pseudocapacitance via Na+ surface adsorption and intercalation relative to undoped fCAS electrodes, while Zn 2+ -doped cCAS electrodes exhibit pseudocapacitance via a combination of Na+ surface adsorption, intercalation, and redox reactions. These electrodes exhibit reduced charge transfer resistance, improved electronic conductivity and notably enhanced specific capacitance (∼222 F g −1 ), and charge transport, as measured in 1 M Na 2 SO 4 electrolyte via cyclic voltammetry and electrochemical impedance spectroscopy. To this end, the discovery of the metal ion-induced phase transformation presents a new avenue for optimizing the functional properties of fCAS and cCAS nanostructures, highlighting the critical role of metal ion-related defects in controlling the optical and electrochemical properties, towards potential solar absorption and energy storage applications.

25 ENERGY STORAGE↗
DOE OSTI2025

Design principles of spacer cations for suppressing phase segregation in 2D halide perovskites

Suppression of photoinduced halide segregation in mixed halide perovskites remains a significant challenge for their application as wide bandgap semiconductors in solar cells. In addition to stability issues, halide segregation leads to a loss in power conversion efficiency in solar cells and a shift in emission wavelength in light-emitting devices. However, employing low-dimensional halide perovskites, such as two-dimensional (2D) or quasi-2D structures, offers a strategy to mitigate this segregation. Here, we have systematically studied how the molecular structure and binding configuration of spacer cations, ranging from linear alkyl chains to aromatic structures, affect photoinduced halide segregation across both Ruddlesden–Popper (RP) and Dion–Jacobson (DJ) frameworks in 2D mixed halide perovskites (Br : I = 50 : 50). Aromatic spacer cations within the DJ perovskite configuration were found to suppress segregation most effectively. For example, the halide segregation rate in a 2D mixed halide perovskite film with the DJ phase using the aromatic spacer cation 1,4-phenylenedimethanammonium (PDMA) was 9.3 × 10 −4 s −1 —an order of magnitude lower than that observed with linear 2D RP perovskites employing butylammonium (BA) as the spacer cation (6.1 × 10 −3 s −1 ). Spectroscopic studies detailing the influence of spacer cation selection in mixed halide perovskites for suppressing phase segregation are discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

TDCOSMO - IV. Hierarchical time-delay cosmography – joint inference of the Hubble constant and galaxy density profiles

The H0LiCOW collaboration inferred via strong gravitational lensing time delays a Hubble constant value of H0 = 73.3−1.8+1.7 km s−1 Mpc−1, describing deflector mass density profiles by either a power-law or stars (constant mass-to-light ratio) plus standard dark matter halos. The mass-sheet transform (MST) that leaves the lensing observables unchanged is considered the dominant source of residual uncertainty in H0. We quantify any potential effect of the MST with a flexible family of mass models, which directly encodes it, and they are hence maximally degenerate with H0. Our calculation is based on a new hierarchical Bayesian approach in which the MST is only constrained by stellar kinematics. The approach is validated on mock lenses, which are generated from hydrodynamic simulations. We first applied the inference to the TDCOSMO sample of seven lenses, six of which are from H0LiCOW, and measured H0 = 74.5−6.1+5.6 km s−1 Mpc−1. Secondly, in order to further constrain the deflector mass density profiles, we added imaging and spectroscopy for a set of 33 strong gravitational lenses from the Sloan Lens ACS (SLACS) sample. For nine of the 33 SLAC lenses, we used resolved kinematics to constrain the stellar anisotropy. From the joint hierarchical analysis of the TDCOSMO+SLACS sample, we measured H0 = 67.4−3.2+4.1 km s−1 Mpc−1. This measurement assumes that the TDCOSMO and SLACS galaxies are drawn from the same parent population. The blind H0LiCOW, TDCOSMO-only and TDCOSMO+SLACS analyses are in mutual statistical agreement. The TDCOSMO+SLACS analysis prefers marginally shallower mass profiles than H0LiCOW or TDCOSMO-only. Without relying on the form of the mass density profile used by H0LiCOW, we achieve a ∼5% measurement of H0. While our new hierarchical analysis does not statistically invalidate the mass profile assumptions by H0LiCOW – and thus the H0 measurement relying on them – it demonstrates the importance of understanding the mass density profile of elliptical galaxies. The uncertainties on H0 derived in this paper can be reduced by physical or observational priors on the form of the mass profile, or by additional data.Key words: gravitational lensing: strong / galaxies: general / galaxies: kinematics and dynamics / distance scale / cosmological parameters / cosmology: observations⋆ The full analysis is available at https://github.com/TDCOSMO/hierarchy_analysis_2020_public.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

Fossil group origins

Aims: We analyse the large-scale structure out to 100 Mpc around a sample of 16 confirmed fossil systems using spectroscopic information from the Sloan Digital Sky Survey Data Release 16. Methods: We computed the distance between our fossil groups (FGs) and the centres of filaments and nodes from the literature. We also studied the density of bright galaxies, since this parameter is thought to be a good mass tracers, as well as the projected over-densities of galaxies. Finally, we applied a friends-of-friends (FoF) algorithm to detect virialised structures around our FGs and obtain an estimate of the mass available in their surroundings. Results: We find that FGs are mainly located close to filaments, with a mean distance of 3.7 ± 1.1 R 200 and a minimum distance of 0.05 R 200 . On the other hand, none of our FGs were found close to intersections, with a mean and minimum distance of 19.3 ± 3.6 and 6.1 R 200 , respectively. There is a correlation that indicates FGs at higher redshifts are found in denser regions, when we use bright galaxies as tracers of the mass. At the same time, FGs with the largest magnitude gaps (Δm 12 > 2.5) are found in less dense environments and tend to host (on average) smaller central galaxies. Conclusions: Our results suggest that FGs formed in a peculiar position within the cosmic web, close to filaments and far from nodes, whereby their interaction with the cosmic web itself may be limited. We deduce that FGs with brightest central galaxies (BCGs) that are relatively faint, high values of Δm 12 , and low redshifts could, in fact, be systems that are at the very last stage of their evolution. Moreover, we confirm theoretical predictions that systems with the largest magnitude gap are not massive.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2025

ZTF SN Ia DR2: An environmental study of Type Ia supernovae using host galaxy image decomposition

The second data release of Type Ia supernovae (SNe Ia) observed by the Zwicky Transient Facility has provided a homogeneous sample of 3628 SNe Ia with photometric and spectral information. This unprecedented sample size enables us to better explore our currently tentative understanding of the dependence of the host environment on SN Ia properties. In this paper, we make use of two-dimensional image decomposition to model the host galaxies of SNe Ia. We model elliptical galaxies as well as disc and spiral galaxies with or without central bulges and bars. This allows for the categorisation of SN Ia based on their morphological host environment, as well as the extraction of intrinsic galaxy properties corrected for both cosmological and atmospheric effects, through point-spread-function (PSF) convolution. We find that although this image decomposition technique leads to a significant bias towards elliptical galaxies in our final sample of processed galaxies, the overall results are still robust. By successfully modelling 728 host galaxies, we find that the photometric properties of SNe Ia found in discs and in elliptical galaxies correlate fundamentally differently with their host environment. We identified strong linear relations between light-curve stretch and our model-derived galaxy colour for both the elliptical (16.8σ) and disc (5.1σ) subpopulations of SNe Ia. Lower-stretch SNe Ia are found in redder environments, which we identify as an age and/or metallicity effect. Within the subpopulation of SNe Ia found in disc-containing galaxies, we find a significant linear trend (6.1σ) between light-curve stretch and model-derived local r-band surface brightness, which we link to the age and metallicity gradients found in disc galaxies. SN Ia colour shows little correlation with the host environment, as is seen in the literature. We do identify a possible dust effect in our model-derived surface brightness (3.3σ) for SNe Ia in disc galaxies.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Multiple monoenergetic gamma radiography (MMGR) with a compact superconducting cyclotron

Smuggling of special nuclear materials and nuclear devices through borders and ports of entry constitutes a major risk to global security. Technologies are needed to reliably screen the flow of commerce for the presence of high-Z materials such as uranium and plutonium. Here, we present an experimental proof-of-concept of a technique that uses inelastic (p,p') nuclear reactions to generate monoenergetic photons, which provide means to measure the areal density and the effective-Z (Z eff ) of an object with an accuracy surpassing that achieved by current methods. We use an ION-12 SC superconducting 12 MeV proton cyclotron to produce 4.4, 6.1, 6.9, and 7.1 MeV photons from a variety of nuclear reactions. Using these photons in a transmission mode, we show that we are able to accurately reconstruct the areal densities and Zeff of a test object. This methodology could enable mobile applications to screen commercial cargoes with high material specificity, providing a means of distinguishing common cargo materials from high-Z materials that include uranium and plutonium.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2023

Machine learning-aided line intensity ratio technique applied to deuterium plasmas

It has been demonstrated that the electron density, n e , and temperature, T e , are successfully evaluated from He I line intensity ratios coupled with machine learning (ML). In this paper, the ML-aided line intensity ratio technique is applied to deuterium (D) plasmas with 0.031 < n e (10 18 m –3 ) < 0.67 and 2.3 < T e (eV) < 5.1 in the PISCES-A linear plasma device. Two line intensity ratios, D α /D γ and D α /D β , are used to develop a predictive model for n e and T e separately. Reasonable agreement of both ne and Te with those from single Langmuir probe measurements is obtained at n e > 0.1 × 10 18 m –3 . Addition of the D 2 /D α intensity ratio, where the D 2 band emission intensity is integrated in a wavelength range of λ ~ 557.4–643.0 nm, is found to improve the prediction of, in particular, n e , and T e . It is also confirmed that the technique works for D plasmas with 0.067 < n e (10 18 m –3 ) < 6.1 and 0.8 < T e (eV) < 15 in another linear plasma device, PISCES-RF. The two training datasets from PISCES-A and PISCES-RF are combined, and unified predictive models for n e and T e give reasonable agreement with probe measurements in both devices.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Growth and characterization of high-quality Zr doped AlN epilayers

AlN stands out for its remarkable figures of merit for electronic and photonic devices, attributed to its ultrawide bandgap of ∼6.1 eV and an exceptionally high critical field of ∼15 MV/cm. More recently, zirconium (Zr) doped AlN (AlN:Zr) has also been identified as a promising material platform for the exploration of solid-state qubits for quantum information and technology, high performance piezoelectric acoustic wave resonators, and optically triggered ultrafast power switching devices facilitated by optically activating Zr related impurities. Despite the significant potential, the ability for producing AlN:Zr epitaxial structures has yet to be established. In this study, we have achieved AlN:Zr epilayers with a high Zr doping level [NZr] of up to 1020 cm−3 using industrial standard metal-organic chemical vapor deposition growth technique. High crystalline quality of AlN:Zr was confirmed by x-ray diffraction, revealing a narrow full width at half maximum of the (002) rocking curve at 216 arcsec for 1.8 μm thick epilayers deposited on sapphire at [NZr]=1020 cm−3. Zr doping was observed to slightly increase the c-lattice constant to 4.992 Å for AlN:Zr (at [NZr]=1020 cm−3) compared to 4.980 Å for undoped AlN. X-ray photoelectron spectroscopy measurement results verified the substitution of Zr at the Al site (ZrAl). The formation of (ZrAl–VN) complexes, which are predicted to possess all the desired properties required by quantum qubits, was confirmed through optical absorption studies. The realization of high-quality AlN:Zr epilayers significantly broadens the scope of technologically significant device applications for AlN.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Urban warming advances spring phenology but reduces the response of phenology to temperature in the conterminous United States

Urbanization has caused environmental changes, such as urban heat islands (UHIs), that affect terrestrial ecosystems. However, how and to what extent urbanization affects plant phenology remains relatively unexplored. Here, we investigated the changes in the satellite-derived start of season (SOS) and the covariation between SOS and temperature (R T ) in 85 large cities across the conterminous United States for the period 2001–2014. We found that 1) the SOS came significantly earlier (6.1 ± 6.3 d) in 74 cities and R T was significantly weaker (0.03 ± 0.07) in 43 cities when compared with their surrounding rural areas (P < 0.05); 2) the decreased magnitude in R T mainly occurred in cities in relatively cold regions with an annual mean temperature <17.3 °C (e.g., Minnesota, Michigan, and Pennsylvania); and 3) the magnitude of urban–rural difference in both SOS and R T was primarily correlated with the intensity of UHI. Simulations of two phenology models further suggested that more and faster heat accumulation contributed to the earlier SOS, while a decrease in required chilling led to a decline in R T magnitude in urban areas. Furthermore, these findings provide observational evidence of a reduced covariation between temperature and SOS in major US cities, implying the response of spring phenology to warming conditions in nonurban environments may decline in the warming future.

54 ENVIRONMENTAL SCIENCES↗