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At least 1,063 records · Page 59

To investigate the reciprocal interactions between dielectric barrier discharges and different biological targets in cell culture medium

The objective of this project was to investigate the dynamic interactions between non-thermal plasma (NTP) and biological targets suspended in a physiological liquid medium. The experiments under this collaborative study were designed to combine theoretical and experimental approaches to test the hypothesis that when living cells (and the growth medium surrounding them) encounter plasma, they reciprocally and dynamically modify each other.

59 BASIC BIOLOGICAL SCIENCES↗

Utilizing NASA Earth Observations to Evaluate Urban Tree Canopy and Land Surface Temperature for Green Infrastructure Development and Urban Heat Mitigation in Huntsville, AL

Huntsville, Alabama’s population has grown by 10.8% since 2010, due in part to the city’s advancing engineering industry. Rapid urban growth negatively impacts the environment by decreasing tree canopy cover and increasing impervious surface cover, which can intensify the urban heat island effect. To examine the impacts of this urban growth on the environment, the team partnered with the City of Huntsville to utilize Landsat 5 Thematic Mapper (TM), Landsat 8 Operational Land Imager (OLI), Landsat 8 Thermal Infrared Sensor (TIRS), Terra Moderate Resolution Imaging Spectroradiometer (MODIS) and the International Space Station’s Global Ecosystems Dynamic Investigation (GEDI) and ECOsystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS). The team utilized these Earth observations in combination with ancillary datasets to create a suite of end products to assist in mitigating the effects of extreme heat due to urban expansion and tree canopy loss. Rasters of annual land surface temperature (LST) was calculated in Google Earth Engine from 2010 to 2019. The team derived land cover classes through supervised and threshold classification methods to distinguish trees, other vegetation types, impervious surfaces, and water. From 2010 to 2019, LST increased approximately 4 °F for all census tracts within the city and the total amount of tree cover increases less than 3%. The findings will aid the city in future decision-making processes by indicating areas that would benefit from increased green infrastructure.

Greta Paris↗

Huntsville Urban Development: Utilizing NASA Earth Observations to Evaluate Urban Tree Canopy and Land Surface Temperature for Green Infrastructure Development and Urban Heat Mitigation in Huntsville, AL

Huntsville, Alabama’s population has grown by approximately 11% since 2010, due in part to the city’s advancing engineering industry. Rapid urban growth negatively impacts the environment by decreasing tree canopy cover and increasing impervious surface cover, which can intensify the urban heat island effect. To examine the impacts of this urban growth on the environment, the team partnered with the City of Huntsville to utilize Landsat 5 Thematic Mapper (TM), Landsat 8 Operational Land Imager (OLI) and Thermal Infrared Sensor (TIRS), Terra Moderate Resolution Imaging Spectroradiometer (MODIS) and the International Space Station’s Global Ecosystems Dynamic Investigation (GEDI) and ECOsystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS). The team utilized these Earth observations in combination with ancillary datasets to create a suite of end products to assist in mitigating the effects of extreme heat due to urban expansion and tree canopy loss. Annual land surface temperature (LST) was calculated and land cover classes were derived through supervised and threshold classification methods to distinguish trees, other vegetation types, impervious surfaces, and water. From 2010 to 2019, LST increased approximately 4 °F for all census tracts within the city and the total amount of tree cover increased by approximately 3%. The findings will aid the city in future decision-making processes by indicating areas that would benefit from increased green infrastructure.

Greta Paris↗

Huntsville Urban Development: Utilizing NASA Earth Observations to Evaluate Urban Tree Canopy and Land Surface Temperature for Green Infrastructure Development and Urban Heat Mitigation in Huntsville, Alabama

Huntsville, Alabama’s population has grown by approximately 11% since 2010, due in part to the city’s advancing engineering industry. Rapid urban growth negatively impacts the environment by decreasing tree canopy cover and increasing impervious surface cover, which can intensify the urban heat island effect. To examine the impacts of this urban growth on the environment, the team partnered with the City of Huntsville to utilize Landsat 5 Thematic Mapper (TM), Landsat 8 Operational Land Imager (OLI) and Thermal Infrared Sensor (TIRS), Terra Moderate Resolution Imaging Spectroradiometer (MODIS) and the International Space Station’s Global Ecosystems Dynamic Investigation (GEDI) and ECOsystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS). The team utilized these Earth observations in combination with ancillary datasets to create a suite of end products to assist in mitigating the effects of extreme heat due to urban expansion and tree canopy loss. Annual land surface temperature (LST) was calculated and land cover classes were derived through supervised and threshold classification methods to distinguish trees, other vegetation types, impervious surfaces, and water. From 2010 to 2019, LST increased approximately 4 °F for all census tracts within the city and the total amount of tree cover increased by approximately 3%. The findings will aid the city in future decision-making processes by indicating areas that would benefit from increased green infrastructure.

Greta Paris↗

The thermal balance of the atmosphere of Venus

Current knowledge of the temperature structure of the atmosphere of Venus is briefly summarized. The principal features to be explained are the high surface temperature, the small horizontal temperature contrasts near the cloud tops in the presence of strong apparent motions, and the low value of the exospheric temperature. In order to understand the role of radiative and dynamical processes in maintaining the thermal balance of the atmosphere, a great deal of additional data on the global temperature structure, solar and thermal radiation fields, structure and optical properties of the clouds, and circulation of the atmosphere are needed. The ability of the Pioneer Venus Orbiter and Multiprobe Missions to provide these data is indicated.

Tomasko, M. G.↗

Online Dynamic Mode Decomposition Based System Identification of Multi-Zone Building HVAC Systems

Many works have recently been conducted to reduce the electricity consumption of smart buildings and allow them to support various grid services. Most of these works require accurate system models for the various appliances in the building including heating, ventilation, and air conditioning (HVAC) units. In this paper, we investigate a recursive data-driven system identification strategy to construct the thermal model for a time-varying building with a multi-zone HVAC unit. The online dynamic mode decomposition (DMD)-based strategy is employed to identify the multi-zone thermal building dynamics, where a simple information update (rank-1) is selected to avoid computational complexity. The DMD-based identification strategy is validated using a real gymnasium building equipped with a 4-zone HVAC unit, and its performance is compared with that of the traditional nuclear-norm subspace identification (N2SID) strategy.

Wu, Tumin [University of Tennessee, Knoxville (UTK↗

Characterization of MOCVD fluid dynamics by laser velocimetry

Three-component laser velocimetry techniques are applied to characterize the fluid dynamics of an MOCVD reactor. These methods provide three-dimensional quantitative measurements of the gas velocities inside the reactor at typical growth temperatures. The effects of buoyancy-induced convection are examined by comparing data from the hot reactor with cold reactor results. It was found that thermal convection dominated the fluid dynamics of the reactor at growth temperatures. Cold reactor tests showed unstable flow patterns that were subject to fluidic switching effects.

Johnson, E. J.↗

Tuning the spin dynamics and magnetic phase transitions of the Cantor alloy via composition and sample processing protocols: A muon spin relaxation study

CrMnFeCoNi, also called the Cantor alloy, is a well-known high-entropy alloy whose magnetic properties have recently become a focus of attention. Here, we present a detailed muon spin relaxation study of the influence of chemical composition and sample processing protocols on the magnetic phase transitions and spin dynamics of several different Cantor alloy samples. Specific samples studied include a pristine equiatomic sample, samples with deficient and excess Mn content, and equiatomic samples magnetized in a field of 9 T or plastically deformed in pressures up to 0.5 GPa. The results confirm the sensitive dependence of the transition temperature on composition and demonstrate that post-synthesis pressure treatments cause the transition to become significantly less homogeneous throughout the sample volume. In addition, we observe critical spin dynamics in the vicinity of the transition in all samples, reminiscent of canonical spin glasses and magnetic materials with ideal continuous phase transitions. Application of an external magnetic field suppresses the critical dynamics in the Mn-deficient sample, while the equiatomic and Mn-rich samples show more robust critical dynamics. The spin-flip thermal activation energy in the paramagnetic phase increases with Mn content, ranging from 3.1⁢(3) × 10 -21 J for 0% Mn to 1.2⁢(2) × 10 -20 J for 30% Mn content. These results shed light on critical magnetic behavior in environments of extreme chemical disorder and demonstrate the tunability of spin dynamics in the Cantor alloy via chemical composition and sample processing.

36 MATERIALS SCIENCE↗

Size Effects in the Thermal Conductivity of Amorphous Polymers

Manipulating thermal conductivity through nanoengineering is of critical importance to advance technologies, such as soft robotics, artificial skin, wearable electronics, batteries, thermal insulation, and thermoelectrics. Here, by examining amorphous polymers, including polystyrene, polypropylene, polyethylene, and ethylene vinyl alcohol, using molecular dynamics simulations, we find that the thermal conductivities of amorphous polymers can be reduced below their amorphous limit by size effects. Size-dependent thermal transport in amorphous materials is decomposed into crystalline, crystalline-to-amorphous, and amorphous regimes. In the amorphous regime, the mean free path of propagating heat carriers can range from tens of nanometers to more than 100 nm, contributing 16%–36% of the total thermal conductivity. A two-channel model that combines no size effect (i.e., difusons and locons) and size effect (i.e., propagons) is proposed to account for size-dependent thermal conductivity. We also find that the presence of charged molecules in polymers can significantly affect the thermal conductivity and its size effects due to electrostatic interactions. Overall, this work provides insights into the thermal conductivity of amorphous polymers that will have a broad impact on the nano- and chemical engineering of polymers for various energy-related applications.

36 MATERIALS SCIENCE↗

Thermal Analysis of an In-Space Heat Shield Exposed to a Rocket Plume During Stage Separation

Thermal analyses were conducted to evaluate the thermal response of various individual materials and multi-layer configurations for an in-space heat shield exposed to a rocket plume during stage separation. Frequently used, readily available thermal protection materials consisting of cork, carbon cloth phenolic (CCP), and silica cloth phenolic (SCP) were selected for an initial screening analysis. SCP was chosen as the primary material for further evaluation using an updated thermal environment calculated using computational fluid dynamics (CFD) results. A multi-layer configuration consisting of SCP providing erosion resistance and a Nomex honeycomb providing thermal protection was then evaluated as a solution for more mass-efficient performance. Pyrolysis depth, bondline temperature, back-side temperature, and a thermal factor of safety were used to define the necessary material thickness profile. Adhesives were included in the analyses with considerations for maximum temperature and application method. One dimensional thermal analyses at several stations along the heat shield surface were performed for the initial screening and follow-on analyses. The methodology used standard processes and computer programs applicable to solid rocket motor internal insulation and nozzle thermal analysis such as Chemical Equilibrium and Applications (CEA), Aerotherm Chemical Equilibrium (ACE), Momentum/Energy Integral Technique (MEIT), and Insulation Thermal Response and Ablation Code (ITRAC). The baseline SCP/Nomex honeycomb multi-layer configuration thermal performance predictions satisfied the objectives with an acceptable mass estimate for the design maturity. The EA9673 film adhesive and SCP resin were the best performing bonding agents considered for the SCP/Nomex honeycomb and Nomex honeycomb/structural substrate interfaces. The baseline mass estimate was lowest when the resin was the bonding agent due to the higher maximum service temperature. These thermal analyses evaluated typical internal and external nozzle materials using a calculated thermal environment and heat loads that were lower than a typical rocket motor internal environment but greater than standard external aeroheating.

Andrew T Hiatt↗

Atomic dynamics in fluids: Normal mode analysis revisited

Developing microscopic understanding of the thermal properties of liquids is challenging due to their strong dynamic disorder, which prevents characterization of the atomic degrees of freedom. There have been significant research interests in the past few decades to extend the normal mode analysis for solids to instantaneous structures of liquids. However, the nature of normal modes that arise from these unstable structures is still elusive. Here, in this paper, we explore the instantaneous eigenmodes of dynamical matrices of various Lennard-Jones argon liquid and gas systems at high temperatures and show that the normal modes can be interpreted as an interpolation of T →∞ (gas) and T=0 (solid) mode descriptions. We find that normal modes become increasingly collisional and translational, recovering atomistic gaslike behavior rather than vibrational with increase in temperature, suggesting that normal modes in liquids may be described by both solidlike and gaslike modes.

74 ATOMIC AND MOLECULAR PHYSICS↗

Energy efficient engine, high pressure turbine thermal barrier coating. Support technology report

This report describes the work performed on a thermal barrier coating support technology task of the Energy Efficient Engine Component Development Program. A thermal barrier coating (TBC) system consisting of a Ni-Cr-Al-Y bond cost layer and ZrO2-Y2O3 ceramic layer was selected from eight candidate coating systems on the basis of laboratory tests. The selection was based on coating microstructure, crystallographic phase composition, tensile bond and bend test results, erosion and impact test results, furnace exposure, thermal cycle, and high velocity dynamic oxidation test results. Procedures were developed for applying the selected TBC to CF6-50, high pressure turbine blades and vanes. Coated HPT components were tested in three kinds of tests. Stage 1 blades were tested in a cascade cyclic test rig, Stage 2 blades were component high cycle fatigue tested to qualify thermal barrier coated blades for engine testing, and Stage 2 blades and Stage 1 and 2 vanes were run in factory engine tests. After completion of the 1000 cycle engine test, the TBC on the blades was in excellent condition over all of the platform and airfoil except at the leading edge above midspan on the suction side of the airfoil. The coating damage appeared to be caused by particle impingement; adjacent blades without TBC also showed evidence of particle impingement.

Duderstadt, E. C.↗

Thermal-fluctuation effects on small-scale statistics in turbulent gas flow

Kolmogorov's theory of turbulence assumes that the small-scale turbulent structures in the energy cascade are universal and are determined by the energy dissipation rate and the kinematic viscosity alone. However, thermal fluctuations, absent from the continuum description, terminate the energy cascade near the Kolmogorov length scale. Here, we propose a simple superposition model to account for the effects of thermal fluctuations on small-scale turbulence statistics. Furthermore, for compressible Taylor–Green vortex flow, we demonstrate that the superposition model in conjunction with data from direct numerical simulation of the Navier–Stokes equations yields spectra and structure functions that agree with the corresponding quantities computed from the direct simulation Monte Carlo method of molecular gas dynamics, verifying the importance of thermal fluctuations in the dissipation range.

42 ENGINEERING↗

An Investigation of the Influence of Urban Areas on Rainfall Using a Cloud-Mesoscale Model and the TRMM Satellite

A recent paper by Shepherd and Pierce (conditionally accepted to Journal of Applied Meteorology) used rainfall data from the Precipitation Radar on NASA's Tropical Rainfall Measuring Mission's (TRMM) satellite to identify warm season rainfall anomalies downwind of major urban areas. A convective-mesoscale model with extensive land-surface processes is employed to (a) determine if an urban heat island (UHI) thermal perturbation can induce a dynamic response to affect rainfall processes and (b) quantify the impact of the following three factors on the evolution of rainfall: (1) urban surface roughness, (2) magnitude of the UHI temperature anomaly, and (3) physical size of the UHI temperature anomaly. The sensitivity experiments are achieved by inserting a slab of land with urban properties (e.g. roughness length, albedo, thermal character) within a rural surface environment and varying the appropriate lower boundary condition parameters. Early analysis suggests that urban surface roughness (through turbulence and low-level convergence) may control timing and initial location of UHI-induced convection. The magnitude of the heat island appears to be closely linked to the total rainfall amount with minor impact on timing and location. The physical size of the city may predominantly impact on the location of UHI-induced rainfall anomaly. The UHI factor parameter space will be thoroughly investigated with respect to their effects on rainfall amount, location, and timing. This study extends prior numerical investigations of the impact of urban surfaces on meteorological processes, particularly rainfall development. The work also contains several novel aspects, including the application of a high-resolution (less than I km) cloud-mesoscale model to investigate urban-induce rainfall process; investigation of thermal magnitude of the UHI on rainfall process; and investigation of UHI physical size on rainfall processes.

Shepherd, J. Marshall↗

An Investigation of the Influence of Urban Areas on Rainfall Using the TRMM Satellite and a Cloud-Mesoscale Model

A recent paper by Shepherd and Pierce (in press at Journal of Applied Meteorology) used rainfall data from the Precipitation Radar on NASA's Tropical Rainfall Measuring Mission's (TRMM) satellite to identify warm season rainfall anomalies downwind of major urban areas. Data (PR) were employed to identify warm season rainfall (1998-2000) patterns around Atlanta, Montgomery, Nashville, San Antonio, Waco, and Dallas. Results reveal an average increase of approx. 28% in monthly rainfall rates within 30-60 kilometers downwind of the metropolis with a modest increase of 5.6% over the metropolis. Portions of the downwind area exhibit increases as high as 51%. The percentage changes are relative to an upwind control area. It was also found that maximum rainfall rates in the downwind impact area exceeded the mean value in the upwind control area by 48%-116%. The maximum value was generally found at an average distance of 39 km from the edge of the urban center or 64 km from the center of the city. Results are consistent with METROMEX studies of St. Louis almost two decades ago and with more recent studies near Atlanta. A convective-mesoscale model with extensive land-surface processes is currently being employed to (a) determine if an urban heat island (UHI) thermal perturbation can induce a dynamic response to affect rainfall processes and (b) quantify the impact of the following three factors on the evolution of rainfall: (1) urban surface roughness, (2) magnitude of the UHI temperature anomaly, and (3) physical size of the UHI temperature anomaly. The sensitivity experiments are achieved by inserting a slab of land with urban properties (e.g. roughness length, albedo, thermal character) within a rural surface environment and varying the appropriate lower boundary condition parameters. The study will discuss the feasibility of utilizing satellite-based rainfall estimates for examining rainfall modification by urban areas on global scales and over longer time periods. The talk also introduces very preliminary results from the modeling component of the study. Such research has implications for weather forecasting, urban planning, water resource management, and understanding human impact on the environment and climate.

Shepherd, J. Marshall↗

Maturation of Dynamic Power Convertors for Radioisotope Power Systems

Dynamic Radioisotope Power Systems (DRPS) are being developed by NASA’s Radioisotope Power Systems (RPS) Program in collaboration with the U.S. Department of Energy (DOE) for space science and exploration missions. A development effort is currently underway to mature dynamic power convertors for infusion into a potential future flight generator. This convertor maturation effort was formulated by the RPS Program at NASA Headquarters based on successful maturation models and utilizes expertise from agency’s technology and mission centers to support requirements development and technology assessments. The effort is being executed by Glenn Research Center’s (GRC) DRPS Project and the Thermal Energy Conversion Branch. The Dynamic Power Convertor (DPC) contracts consist of three phases to enable design, fabrication, and independent assessment of prototypes after delivery to the government. The contracts are intended to gather data on candidate dynamic conversion technologies to fill knowledge gaps, support assessments of dynamic conversion technologies, and elicit generator requirements. The 110-watt Stirling Radioisotope Generator (SRG-110) and Advanced Stirling Radioisotope Generator (ASRG) flight development projects provided Stirling convertor demonstration units and engineering models to verify and validate convertors against performance specifications and mission requirements. These units utilize temperature resistant materials and non-contacting bearings to demonstrate wear-free, long-life operation. This maturation effort builds on past lessons-learned and new requirements focused on demonstrating convertor robustness to critical environments meant to stress key aspects of each convertor within the margins of the design. This effort seeks to realize the full potential of dynamic power conversion technologies for NASA’s space science and exploration missions.

Wilson, Scott↗

Modeling of Thermal Decomposition of TATB-Based Explosive for Safety Analysis

We investigate and model the cook-off behavior of LX-17 to understand the response of explosive systems in abnormal thermal environments. Decomposition has been explored via conventional ODTX (One-Dimensional Time-to-eXplosion), PODTX (ODTX with pressure-measurement), TGA (Thermo-Gravimetric Analysis), and DSC (Differential Scanning Calorimetry) experiments under isothermal and ramped temperature profiles. The data were used to fit reaction rate parameters for proposed schemes in an ALE3D computational model. This model includes chemical reactions, thermo- and hydro-dynamics, and material properties, including thermal expansion, compressibility, and strength. These parameterizations were carried out utilizing a Python evolutionary optimization method on LLNL’s high-performance computing clusters. Additional experiments are being developed to further characterize and monitor decomposition intermediates to improve the model. Once experimentally validated, this model will be scalable to several applications involving LX-17. Furthermore, the optimization methodology developed herein should be applicable to other high explosive materials.

Chemistry - Chemical explosives↗

Enhancing the efficiency of time-dependent density functional theory calculations of dynamic response properties

X-ray Thomson scattering (XRTS) constitutes an essential technique for diagnosing material properties under extreme conditions, such as high pressures and intense laser heating. Time-dependent density functional theory (TDDFT) is one of the most accurate available ab initio methods for modeling XRTS spectra, as well as a host of other dynamic material properties. However, strong thermal excitations, along with the need to account for variations in temperature and density as well as the finite size of the detector significantly increase the computational cost of TDDFT simulations compared to ambient conditions. In this work, we present a broadly applicable method for optimizing and enhancing the efficiency of TDDFT calculations. Our approach is based on a one-to-one mapping between the dynamic structure factor and the imaginary time density–density correlation function, which naturally emerges in Feynman’s path integral formulation of quantum many-body theory. Specifically, we combine rigorous convergence tests in the imaginary time domain with a constraints-based attenuation of narrow-band fluctuations to improve the efficiency of TDDFT modeling without the introduction of any significant bias. As a result, we can report a speed-up by up to an order of magnitude, thus substantially reducing the burden of computational cost required for XRTS analysis.

Moldabekov, Zhandos A. [Helmholtz-Zentrum Dresden-↗