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At least 1,063 records · Page 59

Self-Lubricating, Wear-Resistant Diamond Films Developed for Use in Vacuum Environment

Diamond's outstanding properties--extreme hardness, chemical and thermal inertness, and high strength and rigidity--make it an ideal material for many tribological applications, such as the bearings, valves, and engine parts in the harsh environment found in internal-combustion engines, jet engines, and space propulsion systems. It has been demonstrated that chemical-vapor-deposited diamond films have low coefficients of friction (on the order of 0.01) and low wear rates (less than 10(sup -7) mm (sup 3/N-m)) both in humid air and dry nitrogen but that they have both high coefficients of friction (greater than 0.4) and high wear rates (on the order of 1(sup -4) mm sup 3/N-m)) in vacuum. It is clear that surface modifications that provide acceptable levels of friction and wear properties will be necessary before diamond films can be used for tribological applications in a space-like, vacuum environment. Previously, it was found that coatings of amorphous, non-diamond carbon can provide low friction in vacuum. Therefore, to reduce the friction and wear of diamond film in vacuum, carbon ions were implanted in an attempt to form a surface layer of amorphous carbon phases on the diamond films.

Source record↗

Critical velocity phenomena and the LTP

When the relative velocity between magnetized plasma and neutral gas exceeds a critical value, the gas-plasma interaction is dominated by collective phenomena which rapidly excite and ionize the neutrals. The interaction of the solar wind with a large cloud (between 10 to the 24th and 10 to the 28th power neutrals) vented from the moon should be of this type. Line radiation from such an interaction can yield an apparent lunar surface brightness rivaling reflected sunlight levels over small areas, if the kinetic-energy flow density of the gas is sufficiently high. The aberrated solar-wind flow past the moon would enhance the visibility of such interactions near the lunar sunrise terminator, supporting the statistical studies which indicate that the 'Lunar Transient Phenomena' (anomalous optical phenomena on the moon) are significantly correlated with the position of the terminator on the lunar surface.

Srnka, L. J.↗

Determination of Percent Area Coverage of Lunar Simulant on a Surface and Observations of Fairy Castle Structures

With NASA’s goal of returning humans to the Moon, it has become increasingly important to understand the impact of lunar regolith on spacecraft systems. The ability to measure the level of dust coverage on a surface is essential. Developing an accurate technique to determine percent area coverage is challenging due to the unique and complex layering of the dust particles on the surface, creating fairy castle structures that form complex towers, bridges, and buttresses using the smallest of dust particles as building blocks. For this study, these structures have been simulated using a unique dust distributor device and imaged with a scanning electron microscope. The results show the dusted surface’s complex topology, thus demonstrating the difficulty with determining the percent area of dust coverage. Implications for dust buildup on spacecraft, even at the microscopic level, can include degraded heat transfer and altered optical properties, making continuation of this research critical to support future human exploration of the Moon.

lunar dust↗

The mean sea surface height and geoid along the Geosat subtrack from Bermuda to Cape Cod

The mean sea-surface height and the gravitational geoid are presently estimated via near-surface velocity changes and concurrent sea-level changes along an ascending Geosat subtrack. The velocity measurements were made on three traverses, within ten days, of a Geosat subtrack, by means of an acoustic Doppler current profiler (ADCP). The mean sea-surface height was estimated as the difference between the instantaneous sea-surface height from ADCP and the Geosat residual sea level. In order to minimize mesoscale errors in the estimate, the along-track geoid estimate was computed as the difference between mean sea-level height from the Geosat Exact Repeat Mission and an estimate of the mean sea-surface height.

Kelly, Kathryn A.↗

Setups for eliminating static charge of the ATLAS18 strip sensors

Abstract Construction of the new all-silicon Inner Tracker (ITk), developed by the ATLAS collaboration to beable to track charged particles produced at the High-Luminosity LHC, started in 2020 and is expected tocontinue till 2028. The ITk detector will include 18,000 highly segmented and radiation hard n+-in-psilicon strip sensors (ATLAS18), which are being manufactured by Hamamatsu Photonics. Mechanical and electrical characteristics of produced sensors are measured upon their delivery at several institutes participating in a complex Quality Control (QC) program. The QC tests performed on each individual sensor check the overall integrity and quality of the sensor.During the QC testing of ATLAS18 strip sensors, an increased number of sensors thatfailed the electrical tests was observed. In particular, IV measurements indicated an early breakdown,while large areas containing several tens or hundreds of neighbouring strips with low interstrip isolationwere identified by the Full strip tests, and leakage current instabilities were measured in a long-term leakage current stability setup. Moreover, a high surface electrostatic charge reaching a level of several hundreds of volts per inch was measured on a large number of sensors and on the plastic sheets, whichmechanically protect these sensors in their paper envelopes. Accumulated data indicates a clearcorrelation between observed electrical failures and the sensor charge-up.To mitigate the above-described issues, the QC testing sites significantly modified the sensor handlingprocedures and introduced sensor recovery techniques based on irradiation of the sensor surface with UVlight or application of intensive flows of ionized gas. In this presentation, we will describe the setupsimplemented by the QC testing sites to treat silicon strip sensors affected by static charge andevaluate the effectiveness of these setups in terms of improvement of the sensor performance.

Instruments & Instrumentation↗

The photochemical role of tropospheric nitrogen oxides

The role of nitrogen oxides in the tropospheric photochemical system is re-evaluated in the light of recent measurements of the rate constants for two key reactions. A model for nitrogen oxides is discussed which yields surface NO(x) (NO+NO2) levels approaching 1 ppb in NO(x) source regions but less than 0.1 ppb outside source regions. Applying the new rate coefficients implies increased radical concentrations and a more intense O3 and CO photochemistry. Even for densities of 0.1 ppb or less, NO(x) still leads to significant local O3 production and conversion of HO2 to OH. Unrealistic O3 profiles are obtained with the new rate coefficients for surface NO(x) densities of about 1 ppb, while reasonable agreement with observation is obtained with lower NO(x) densities. Feedback processes between CO, NO(x), OH, and CH4 are also discussed.

Chameides, W. L.↗

Inkjet-printed SnO x as an effective electron transport layer for planar perovskite solar cells and the effect of Cu doping

Inkjet printing is a more sustainable and scalable fabrication method than spin coating for producing perovskite solar cells (PSCs). Although spin-coated SnO 2 has been intensively studied as an effective electron transport layer (ETL) for PSCs, inkjet-printed SnO 2 ETLs have not been widely reported. Here, we fabricated inkjet-printed, solution-processed SnO x ETLs for planar PSCs. A champion efficiency of 17.55% was achieved for the cell using a low-temperature processed SnO x ETL. The low-temperature SnO x exhibited an amorphous structure and outperformed high-temperature crystalline SnO 2 . The improved performance was attributed to enhanced charge extraction and transport and suppressed charge recombination at ETL/perovskite interfaces, which originated from enhanced electrical and optical properties of SnO x , improved perovskite film quality, and well-matched energy level alignment between the SnO x ETL and the perovskite layer. Furthermore, SnO x was doped with Cu. Cu doping increased surface oxygen defects and upshifted energy levels of SnO x , leading to reduced device performance. A tunable hysteresis was observed for PSCs with Cu-doped SnO x ETLs, decreasing at first and turning into inverted hysteresis afterwards with increasing Cu doping level. This tunable hysteresis was related to the interplay between charge/ion accumulation and recombination at ETL/perovskite interfaces in the case of electron extraction barriers.

14 SOLAR ENERGY↗

An outgassing model of non-metallic materials for the ascent of a Titan 4 launch vehicle

Outgassing of nonmetallic materials and components inside Titan IV's 2A compartment during ascent may present a problem to the payload community in relation to molecular deposition and degradation of sensitive payload surfaces. The procedure currently being developed to model the amounts, transport, and deposition of outgassed molecular contaminants onto a payload's sensitive surface consists of three phases. The first phase involves the development of a thermogravimetric method that recreates the increasing temperature and decreasing pressure profiles expected in the 2A compartment of the TIV launch vehicle during ascent. The second phase involves the determination of deposition rates of outgassed materials onto a payload surface, and the subsequent evaporation rate as a function of temperature of deposited material. The third phase takes the temperature and pressure profiles from phase one, the deposition and evaporation rates and kinetic coefficients determined in phase two, and incorporates them into the SPACE II computer program to determine which payload surfaces are most susceptible to molecular deposition from TIV's outgassing sources, and the level of permanent deposition expected on those surfaces.

Barrows, R. D.↗

Mars dust storm simulations: Analysis of surface stress

The primary mechanism by which dust is inserted into the Martian atmosphere is the interaction of low-level atmospheric motions with the planet's surface. Near-surface winds exert a shear stress upon dust particles resting on the Martian surface, and at some lower threshold limit of stress magnitude, approximately 0.04 N-m(exp -2), particles are set into motion. Wind tunnel studies indicate that the first particles are too large to remain in suspension in the Martian atmosphere, but their impact back upon the surface can set smaller suspendable particles into motion. This process is termed saltation. Numerical simulations of Martian dust storms were carried out via the interactive coupling of the NASA Ames Mars general circulation Model with an aerosol transport/microphysical model.

Murphy, J. R.↗

Characterizing Mediterranean Land Surfaces as Component of the Regional Climate System by Remote Sensing

Extensive areas in the Mediterranean region are subject to land degradation and desertification. The high variability of the coupling between the surface and the atmosphere affects the regional climate. Relevant surface characteristics, such as spectral reflectance, surface emissivity in the thermal-infrared region, and vegetation indices, serve as "primary" level indicators for the state of the surface. Their spatial, seasonal and interannual variability can be monitored from satellites. Using relationships between these primary data and combining them with prior information about the land surfaces (such as topography, dominant soil type, land use, collateral ground measurements and models), a second layer of information is built up which specifies the land surfaces as a component of the regional climate system. To this category of parameters which are directly involved in the exchange of energy, momentum and mass between the surface and the atmosphere, belong broadband albedo, thermodynamic surface temperature, vegetation types, vegetation cover density, soil top moisture, and soil heat flux. Information about these parameters finally leads to the computation of sensible and latent heat fluxes. The methodology was tested with pilot data sets. Full resolution, properly calibrated and normalized NOAA-AVHRR multi-annual primary data sets are presently compiled for the whole Mediterranean area, to study interannual variability and longer term trends.

Bolle, H.-J.↗

Demonstrations of System-Level Autonomy for Spacecraft

System-level autonomy refers to autonomously meeting the crosscutting needs of a system through awareness and coordinated control spanning the system's breadth of capabilities. In contrast to function-level autonomy, which focuses on capabilities required to achieve a specific function such as surface navigation or image recognition, system-level autonomy addresses the needs to coordinate and manage activities and resources, and estimate the state, across subsystems. This paper describes demonstrations that were conducted on a spacecraft workstation testbed. The autonomy was provided by system-level planning and execution integrated with system-level estimators of orbit knowledge and spacecraft hardware health. These components are embedded in a system-level framework defining how goals are formed and executed, which elements exist, and how control authority is distributed among components. The planning and execution system at the heart of the framework has the capability to schedule, execute and monitor completion of tasks, as well as plan around unexpected events including new science opportunities and anomalies. The planning and scheduling system is the Multi-mission EXECutive (MEXEC), supported by the system-level health state estimator Model-Based Off-Nominal State Identification and Detection (MONSID), and Autonomous Navigation (AutoNav) algorithms, which determine the orbital system state based on optical observation of other targets. These components are applicable to many kinds of missions on different platforms. These demonstrations were elaborations of earlier experiments conducted on the ASTERIA (Arcsecond Space Telescope Enabling Research In Astrophysics) CubeSat, described in a companion submission [1]. The spacecraft’s extended mission served as an in-flight test platform, during which some individual autonomous capabilities were flown successfully. The autonomy experiments described here were performed on the ASTERIA workstation testbed.

Prather, Maurice↗

Correlations Between Topex Altimeter and Temperature Profile Data in the Equatorial Pacific

Observations of sea-surface heights from satellite altimeters have been a major contributor to monitoring the evolution of the recent major El Nino event. Assimilating altimeter data directly into numerical models only takes advantage of the surface signature provided by the data. However, that surface signature is usually indicative of processes occurring at depth, especially in the equatorial Pacific. In order for assimilation schemes to make maximum use of surface data, it is helpful to have knowledge of how to best extend that data in the vertical to account for that variability. Toward that end, the vertical correlation structure between satellite-observed sea-surface heights and in situ temperature measurements is examined using TOPEX altimeter and TOGA TAO profile data for the period 1993-1998. This time period includes several states of the tropical Pacific, including a perturbed state from 1993-1994, a quiescent state encompassing 1995-1996, and the major ENSO event of 1997-1998. Analyses for each of these periods, as well as the total period will be presented. In addition to analyses at specific depth levels, analyses for particular density surfaces will also be presented.

Adamec, David↗

Evaluating Ultraviolet Radiation Exposures Determined from TOMS Satellite Data at Sites of Amphibian Declines in Central and South America

Many amphibian species have experienced substantial population declines, or have disappeared altogether, during the last several decades at a number of amphibian census sites in Central and South America. This study addresses the use of satellite-derived trends in solar ultraviolet-B (UV-B; 280-320 nm) radiation exposures at these sites over the last two decades, and is intended to demonstrate a role for satellite observations in determining whether UV-B radiation is a contributing factor in amphibian declines. UV-B radiation levels at the Earth's surface were derived from the Total Ozone Mapping Spectrometer (TOMS) satellite data, typically acquired daily since 1979. These data were used to calculate the daily erythemal (sunburning) UV-B, or UV-B(sub ery), exposures at the latitude, longitude, and elevation of each of 20 census sites. The annually averaged UV-B(sub ery) dose, as well as the maximum values, have been increasing in both Central and South America, with higher levels received at the Central American sites. The annually averaged UV-B(sub ery) exposures increased significantly from 1979-1998 at all 11 Central American sites examined (r(exp 2) = 0.60 - 0.79; P<=0.015), with smaller but significant increases at five of the nine South American sites (r(exp 2) = 0.24-0.42; P<=0.05). The contribution of the highest UV-B(sub ery) exposure levels (>= 6750 J/sq m*d) to the annual UV-B(sub ery) total has increased from approx. 5% to approx. 15% in Central America over the 19 year period, but actual daily exposures for each species are unknown. Synergy among UV-B radiation and other factors, especially those associated with alterations of water chemistry (e.g., acidification) in aqueous habitats is discussed. These findings justify further research concerning whether UV-B(sub ery) radiation plays a role in amphibian population declines and extinctions.

Middleton, Elizabeth M.↗

Fluorination‐Enhanced Surface Stability of Disordered Rocksalt Cathodes

Abstract Cation‐disordered rocksalt (DRX) oxides are a promising new class of high‐energy‐density cathode materials for next‐generation Li‐ion batteries. However, their capacity fade presents a major challenge. Partial fluorine (F) substitution into the oxygen (O) lattice appears to be an effective strategy for improving the cycling stability, but the underlying atomistic mechanism remains elusive. Here, using a combination of advanced transmission electron microscopy based imaging and spectroscopy techniques, the structural and chemical evolution upon cycling of Mn‐based DRX cathodes with an increasing F content (Li–Mn–Nb–O–F x , x = 0, 0.05, 0.2) are probed. The atomic origin behind the beneficial effect of high‐level fluorination for enhancing the surface stability of the DRX is revealed. It is discovered that, due to the reduced O redox activity while with increasing F concentration, F in the DRX lattice mitigates the formation of an O‐deficient surface layer upon cycling. For low F‐substituted DRX, the O loss near the surface results in the formation of an amorphous cathode–electrolyte interphase layer and nanoscale voids after extended cycling. Increased F concentration in the DRX lattice minimizes both O loss and the interfacial reactions between DRX and the liquid electrolyte, enhancing the surface stability of DRX. These results provide guidance on the development of next‐generation cathode materials through anion substitution.

Li, Linze↗

Nitrogen and phosphorus cycling in an ombrotrophic peatland: a benchmark for assessing change

Aims Slow decomposition and isolation from groundwater mean that ombrotrophic peatlands store a large amount of soil carbon (C) but have low availability of nitrogen (N) and phosphorus (P). To better understand the role these limiting nutrients play in determining the C balance of peatland ecosystems, we compile comprehensive N and P budgets for a forested bog in northern Minnesota, USA. Methods N and P within plants, soils, and water are quantified based on field measurements. The resulting empirical dataset are then compared to modern-day, site-level simulations from the peatland land surface version of the Energy Exascale Earth System Model (ELM-SPRUCE).

Salmon, Verity G.↗

Hydrous carbonates on Mars? Evidence from Mariner 6/7 infrared spectrometer and ground-based telescopic spectra

Absorption features at 2.28 and 5.4 micrometers identified in Mariner 6/7 infrared spectrometer and terrestrial telescopic spectra are consistent with the spectra of hydrous magnesium carbonates such as hydromagnesite and artinite. Spectral characteristics of these hydrous carbonates are different from those of the anhydrous carbonates, as the former do not have the strong spectral features typically associated with anhydrous carbonates such as calcite and siderite. Theoretical mixing indicates that, depending on the type of hydrous carbonate, 10-20 wt % can be incorporated into the regolith without contradicting the spectral observations or the Viking x ray fluorescence chemical analysis. Hydrous carbonates form as weathering products of mafic minerals in the presence of H2O and CO2, even in the Antarctic. Their formation as evaporite minerals from either original magmas or hydrothermally altered rocks is consistent with the Martian environment, provided liquid water is or has been at least transiently present. On Earth, formation of hydrous Mg carbonates is associated with the production of amorphous iron oxides, which is consistent with both the environment and the inferred surface mineralogy of Mars. These minerals are about 60 wt % H2O, CO3, and OH; if they are abundant everywhere at the 10% level, then about 6% of the surface weight could be volatiles bound in this type of mineral. Although the spectroscopic evidence for anhydrous carbonates is scant, the possible presence of hydrous carbonates provides an appealing mechanism for the existence of carbonates on Mars.

Calvin, Wendy M.↗

Theoretical constraints on oxygen and carbon dioxide concentrations in the Precambrian atmosphere

Simple (one-dimensional) climate models suggest that carbon dioxide concentrations during the Archean must have been at least 100-1000 times the present level to keep the Earth's surface temperature above freezing in the face of decreased solar luminosity. Such models provide only lower bounds on CO2, so it is possible that CO2 levels were substantially higher than this and that the Archean climate was much warmer than today. Periods of extensive glaciation during the early and late Proterozoic, on the other hand, indicate that the climate at these times was relatively cool. To be consistent with climate models CO2 partial pressures must have declined from approximately 0.03 to 0.3 bar around 2.5 Ga ago to between 10(-3) and 10(-2) bar at 0.8 Ga ago. This steep decrease in carbon dioxide concentrations may be inconsistent with paleosol data, which implies that pCO2 did not change appreciably during that time. Oxygen was essentially absent from the Earth's atmosphere and oceans prior to the emergence of a photosynthetic source, probably during the late Archean. During the early Proterozoic the atmosphere and surface ocean were apparently oxidizing, while the deep ocean remained reducing. An upper limit of 6 x 10(-3) bar for pO2 at this time can be derived by balancing the burial rate of organic carbon with the rate of oxidation of ferrous iron in the deep ocean. The establishment of oxidizing conditions in the deep ocean, marked by the disappearance of banded iron formations approximately 1.7 Ga ago, permitted atmospheric oxygen to climb to its present level. O2 concentrations may have remained substantially lower than today, however, until well into the Phanerozoic.

Review, Tutorial↗

3-D Surface Depression Profiling Using High Frequency Focused Air-Coupled Ultrasonic Pulses

Surface topography is an important variable in the performance of many industrial components and is normally measured with diamond-tip profilometry over a small area or using optical scattering methods for larger area measurement. This article shows quantitative surface topography profiles as obtained using only high-frequency focused air-coupled ultrasonic pulses. The profiles were obtained using a profiling system developed by NASA Glenn Research Center and Sonix, Inc (via a formal cooperative agreement). (The air transducers are available as off-the-shelf items from several companies.) The method is simple and reproducible because it relies mainly on knowledge and constancy of the sound velocity through the air. The air transducer is scanned across the surface and sends pulses to the sample surface where they are reflected back from the surface along the same path as the incident wave. Time-of-flight images of the sample surface are acquired and converted to depth/surface profile images using the simple relation (d = V*t/2) between distance (d), time-of-flight (t), and the velocity of sound in air (V). The system has the ability to resolve surface depression variations as small as 25 microns, is useable over a 1.4 mm vertical depth range, and can profile large areas only limited by the scan limits of the particular ultrasonic system. (Best-case depth resolution is 0.25 microns which may be achievable with improved isolation from vibration and air currents.) The method using an optimized configuration is reasonably rapid and has all quantitative analysis facilities on-line including 2-D and 3-D visualization capability, extreme value filtering (for faulty data), and leveling capability. Air-coupled surface profilometry is applicable to plate-like and curved samples. In this article, results are shown for several proof-of-concept samples, plastic samples burned in microgravity on the STS-54 space shuttle mission, and a partially-coated cylindrical ceramic composite sample. Impressive results were obtained for all samples when compared with diamond-tip profiles and measurements from micrometers. The method is completely nondestructive, noninvasive, non-contact and does not require light-reflective surfaces.

Roth, Don J.↗