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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,063 records · Page 59
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Electricity-driven recycling of ester plastics using one-electron electro-organocatalysis

Here, we report the catalytic use of electrochemically generated one-electron reducing agents to produce ester anion radicals that can decompose to acids and alcohols in the presence of oxygen. Through this approach, we demonstrate that molecular analogs of polyethylene terephthalate (PET) can be deconstructed into their molecular components. We additionally show efficient reductive scission of ester bonds in PET plastic using catalytically regenerated reducing agents based on benzimidazolium cations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Wind Turbine Materials Recycling Prize Phase 2 (Commercialization of Wind Turbine Blade Waste (WTBW)-Based, Lightweight, Cementitious Composite Materials): Cooperative Research and Development Final Report, CRADA Number CRD-24-31305

The National Laboratory of the Rockies (NLR) and AltiSora, LLC., will develop new lightweight cementitious composite material technologies that will utilize wind turbine blade waste as a raw material to; (1) allow a high value addition (2) at low cost, enabling (3) a significant waste consumption volume; while (4) consuming the entire wind turbine blade, without (5) creating any waste or emissions and to also (6) offer specific benefits to communities involved.

17 WIND ENERGY↗
DOE OSTI2016

Investigations for the Recycle of Pyroprocessed Uranium

Given the renewed interest in uranium from the pyroprocessing of used nuclear fuel in a molten salt system, the two biggest hurdles for marketing the uranium are radiation levels and transuranic content. A radiation level as low as possible is desired so that handling operations can be performed directly with the uranium. The transuranic content of the uranium will affect the subsequent waste streams generated and, thus also should be minimized. Although the pyroprocessing technology was originally developed without regard to radiation and transuranic levels, adaptations to the process have been considered to market the uranium. Process conditions have been varied during the distillation and casting cycles of the process with increasing temperature showing the largest effect on the reduction of radiation levels. Transuranic levels have been reduced significantly by incorporating a pre-step in the salt distillation operation to remove a majority of the salt prior to distillation.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2025

Polypropylene Composites Reinforced With Recycled Waste Cellulosic Fiber/Fine Mixture: The Impact of Cellulose Sieving on Performance

This study explores how a sieving step of waste cellulosic fiber and fine (WCFF) mixture affects the performance of WCFF‐loaded polypropylene (PP) composites and whether the separation of fines from fibers offers an added benefit. The WCFF samples were downsized, and four different filler size ranges were sieved using a series of mesh sizes from 4 to 0.85 mm. The WCFF/PP composites were then compounded at 20 wt.% loading of WCFF using a twin‐screw extruder. Incorporating WCFF increased the tensile strength to 41.28 MPa and the modulus to 3207 MPa, accounting for 28% and 38% enhancements, respectively. Interestingly, the greatest improvements were associated with the nonsieved WCFF case, and the sieved WCFF fibers provided only marginal enhancements over virgin PP. The outperformance of nonsieved WCFF was attributed to the synergistic reinforcement of hybrid fibers and fines as well as the maintenance of longer fibers in the system. However, the strain at break and impact strength of PP decreased after introducing WCFF. Moreover, the complex viscosity and storage modulus increased with an increase in the filler size, due to the formation of a more effective percolative network. The PP's crystallinity exhibited a relatively strong dependency on the sieving, where WCFF samples with short‐aspect‐ratio fillers promoted the crystallinity significantly. It was also found that the WCFF degradation onset temperature increased once it was incorporated into PP. This study suggests that waste cellulosic feedstocks can be utilized as a reinforcement without additional sieving to manufacture high‐performance and cost‐effective composites.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Effects of Natural and Artificial Weathering on the Physical Properties of Recycled Poly(ethylene terephthalate)

In accelerated weathering tests, specimens are exposed to higher radiation intensity, temperature and humidity than is likely under natural weathering in order to achieve rapid degradation of the polymer in a convenient short time. In the current work, a correlation between the two environments is attempted so that a prediction of lifetimes in the natural environment can be achieved. During aging, surface flaws are created due to the chain scission process. This is initiated by the absorption of ultra-violet light and directly affects visual appearance and impact strength. After natural weathering, the material shows only plastic deformation in an impact test. However, after artificial weathering to 5000 h of UV exposure, there is a decrease of 85% in impact strength. Colour change occurs at a high rate in the early stages of UV exposure. Beyond 2000 h of exposure, the colour change approaches a steady state and a correlation between the changes under natural and artificial weathering becomes apparent for a potential prediction of lifetimes. From the analysis including the specular component (SCI), taking surface roughening into account, 1 year under natural weathering was found to be equivalent to 25 days under accelerated weathering.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Biological Recycling of Polyethylene Terephthalate: A Mini-Review

Plastics have become an inseparable part of our life in the society due to their merits such as low cost, light weight, good mechanical and thermal properties along with easy process ability. Since the last few decades, the unrestrained use of plastics in various fields like agriculture, packaging, transportation has raised a serious issue about its disposal and pollution. An efficient decomposition of plastics takes about 1000 years. Not only there is an increase in the problem of waste disposal of plastics but also they release CO{sub 2} and dioxins on burning which contributes to cause pollution. There is a growing concern for use of efficient microorganisms meant for biodegradation of non-degradable synthetic polymer because conventionally used methods for plastic disposal are ineffective for plastic waste management. This review paper focuses on one such type of plastic-polyethylene terephthalate (PET) which is widely used in a flexible packaging application, its manufacturing process and the various effects of waste generated by it on the surrounding environment. This review discusses an overview of various existing plastic disposal methods along with their limitations and mechanism of biodegradation of PET and factors affecting biodegradation.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Structure-property relationships and recyclability of natural fiber insulation

Thermal insulation can significantly decrease the energy required to maintain internal temperatures within buildings, saving money and decreasing environmental impacts. Many industrially available insulation options utilize petroleum-derived materials, such as polyurethane, fiberglass, and polystyrene, which can be detrimental to the environment by emitting greenhouse gases during production. A sustainable alternative to these synthetic insulations is the use of renewable feedstocks to produce comparable insulation products. In this work, natural fibers such as flax and banana were bound with an epoxy system to produce natural-fiber insulation. Key experimental parameters for this study included evaluating the fiber lengths and processing methods while varying the viscosity of the epoxy binder solvent dissolution. Insulation performance was determined by comparing density, thermal conductivity, resilience, and compressive strength; these parameters were tested to further understand and investigate the structure- property relationships within the system and to understand how these composites compare to current commercial materials. Furthermore, from this characterization and optimization, a natural fiber sample with an R/in. >5 was achieved, making these materials competitive with commercial alternatives.

Compressive strength↗
DOE OSTI2018

Dose-response relationships between urinary phthalate metabolites and serum thyroid hormones among waste plastic recycling workers in China

Highlights: • Maximum urinary phthalate levels of the workers are higher than those of controls. • A non-linear association of urinary MMP with total T3 was found among the workers. • The workers showed a non-linear association of urinary MMP with the T3/T4 ratio. • The workers exhibited a non-linear association of urinary MEP with the T3/T4 ratio. Exposure to phthalates may affect thyroid hormone status. However, there were inconsistent observations for the associations of phthalates exposure with altered thyroid hormones.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Synthesis, characterization, and recycling of bio-derivable polyester covalently adaptable networks for industrial composite applications

Fiber-reinforced polymers (FRPs) are critical for energy-relevant applications such as wind turbine blades. Despite this, the end-of-life options for FRPs are limited as they are permanently cross-linked thermosets. To enable the circularity of FRPs, we formulated a bio-derivable polyester covalently adaptable network (PECAN), sometimes referred to as a polyester vitrimer, to manufacture FRPs at >1 kg scale, which is accomplished as the resin is infusible (175-425 cP at 25 °C viscosity), can be cured at 80 °C within 5 h and is depolymerizable via methanolysis yielding high-quality fibers and recoverable hardener. The FRPs exhibit a transverse tensile modulus comparable with today's wind relevant FRPs (10.4-11.9 GPa). Modeling estimates a resin minimum selling price of $2.28/kg and, relative to an epoxy-amine resin, PECAN manufacture requires 19%-21% less supply chain energy and emits 33%-35% less greenhouse gas emissions. Overall, this study suggests that redesigned thermosets can yield beneficial circularity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗