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At least 1,063 records · Page 59
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NASA NTRS1994

A coronal mass ejection model for the 1992 July 15 flare on AU Microscopii observed by the extreme ultraviolet explorer

The dM1e flare star AU Microscopii (AU Mic) was observed by the EUVE Deep Survey Instrument on 1992 July 14-18. A large flare was detected in the Deep Survey Lexan/Boron (DS Lex/B)(65-190 A) band and the SW (70-190 A) and MW (140-380 A) spectrometers. The flare consisted of a sharp impulsive peak lasting approximately 2 hours followed by a decaying tail lasting about a day. We present a simple, single temperature, dynamic model for the flare decay which is consistent with the DS Lex/B light curve and reproduces the strongest, high-temperature spectral lines in the released EUVE spectra. In this model, we assume the long decay time is due to an ejected, magnetically confined, low beta plasmoid expanding self similarly in the ambient medium in a manner reminiscent of solar coronal mass ejections. We demonstrate that the long tail of the DS Lex/B light curve can be explained by rapid expansion, causing the plasma to become tenuous sufficiently quickly that it avoids catastrophic radiative cooling. From this model, we estimate the mass of the plasmoid to be approximately = 10(exp 20) g and the total energy of the event to be approximately = 10(exp 36) ergs. These values are approximately 10(exp 4) times as large as those seen during the largest solar coronal mass ejection (CME) events. We argue that the results of our model are consistent with other measurements of stellar flare parameters. We also estimate a mass-loss rate of a few times 10(exp -13) Solar mass/yr and discuss the role of mass loss from dMe stars in the mass balance of the interstellar medium. We estimate the rotational braking timescale from these events to be less than 500 million years and suggest that CME's may be an important source of angular momentum loss from late-type stars.

Cully, Scott L.↗
NASA NTRS1994

Interstellar gas and dust in the young cluster IC 348

We have completed a multiband absorption- and emission-line study of a star embedded in the young cluster IC 348, to determine the environmental effect of star formation on the interstellar medium (ISM) local to the region. The hottest and youngest star in IC 348 is BD +31 deg 643, a B5 V star which samples the inner bright nebular region. The nearby star omicron Per, which lies only 8 min to the north and is thought to lie beyond IC 348, samples the gas and dust which has not been processed by very recent star formation. We speculate that the ISM throughout the region was originally the same as that currently seen toward omicron Per, but now the constrasting environmental conditions due to the recent star formation have led to marked differences in the atomic, molecular, and dust characteristics of IC 348. These contrasts include what we have termed a 'composite' UV extinction curve for BD +31 deg 643, evidence for enhanced density and enhanced depletions within IC 348 and very different molecular abundances in the interstellar sightline to BD +31 deg 643. Toward BD +31 deg 643, we find a higher column density of CH, but lower CN and very much higher CH(+) than measured toward omicron Per. We conclude that the physical and chemical state of the gas and dust has been altered by local processes and conditions within IC 348. The characteristics of the ISM in IC 348, via our study of the star BD +31 deg 643, closely resembles those seen toward rho Oph, another sight line passing through a bright nebular region. However, the stars are not as hot in IC 348 as in Ophiuchus, so their effect on the local ISM is not as severe.

Snow, Theodore P.↗
DOE OSTI2017

Searching for Interstellar C{sub 60}{sup +} Using a New Method for High Signal-to-noise HST/STIS Spectroscopy

Due to recent advances in laboratory spectroscopy, the first optical detection of a very large molecule has been claimed in the diffuse interstellar medium (ISM): C{sub 60}{sup +} (ionized Buckminsterfullerene). Confirming the presence of this molecule would have significant implications regarding the carbon budget and chemical complexity of the ISM. Here we present results from a new method for ultra-high signal-to-noise ratio (S/N) spectroscopy of background stars in the near-infrared (at wavelengths of 0.9–1 μm), using the Hubble Space Telescope (HST) Imaging Spectrograph (STIS) in a previously untested “STIS scan” mode. The use of HST provides the crucial benefit of eliminating the need for error-prone telluric-correction methods in the part of the spectrum where the C{sub 60}{sup +} bands lie and where the terrestrial water vapor contamination is severe. Our STIS spectrum of the heavily reddened B0 supergiant star BD+63 1964 reaches an unprecedented S/N for this instrument (∼600–800), allowing the detection of the diffuse interstellar band (DIB) at 9577 Å attributed to C{sub 60}{sup +}, as well as new DIBs in the near-IR. Unfortunately, the presence of overlapping stellar lines, and the unexpected weakness of the C{sub 60}{sup +} bands in this sightline, prevents conclusive detection of the weaker C{sub 60}{sup +} bands. A probable correlation between the 9577 Å DIB strength and interstellar radiation field is identified, which suggests that more strongly irradiated interstellar sightlines will provide the optimal targets for future C{sub 60}{sup +} searches.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1995

Chemical Evolution of Interstellar Dust into Planetary Materials

Comets are believed to retain some interstellar materials, stored in fairly pristine conditions since-their formation. The composition and properties of cometary dust grains should reflect those of grains in the outer part of the protosolar nebula which, at least in part, were inherited from the presolar molecular cloud. However, infrared emission features in comets differ from their interstellar counterparts. These differences imply processing of interstellar material on its way to incorporation in comets, but C and N appear to be retained. Overall dust evolution from the interstellar medium (ISM) to planetary materials is accompanied by an increase in proportion of complex organics and a decrease in pure carbon phases. The composition of cometary dust grains was measured in situ during fly-by missions to comet Halley in 1986. The mass spectra of about 5000 cometary dust grains with masses of 5 x 10(exp -17) - 5 x 10(exp -12) g provide data about the presence and relative abundances of the major elements H, C, N, O,Na, Mg, Al, Si, S, Cl, K, Ca, Ti, Cr, Fe, Ni. The bulk abundances of major rock-forming elements integrated over all spectra were found to be solar within a factor of 2, while the volatile elements H, C, N, O in dust are depleted in respect to their total cosmic abundances. The abundances of C and N in comet dust are much closer to interstellar than to meteoritic and are higher than those of dust in the diffuse ISM. In dense molecular clouds dust grains are covered by icy mantles, the average composition of which is estimated to be H:C:N:O = 96:14:1:34. Up to 40% of elemental C and O may be sequestered in mantles. If we use this upper limit to add H, C, N and O as icy mantle material to the abundances residing in dust in the diffuse ISM, then the resulting values for H. C, and N match cometary abundances. Thus, ice mantles undergoing chemical evolution on grains in the dense ISM appear to have been transformed into less volatile and more complex organic residues wherein the H, C and N are largely retained and ultimately accreted in cometary dust. The abundance of O is about the same for cometary dust, meteorites and interstellar dust. In all these samples, most of O in a solid phase is bonded to silicates. In dense molecular clouds, the abundance of O in dust+mantles is significantly higher then in cometary dust. This difference may reflect the greater lability of oxygenated species toward astrophysical processing. Laboratory studies show that O-bearing functional groups in organic compounds tend to be relatively easily removed by heating and/or UV and particle irradiation . In Halley's coma, O-containing organic grains, being unstable, were located closest to the nucleus. The decomposition of the organic grain component in the coma provided a significant extended source contribution to O-containing gaseous species such as CO and H2CO.

Fomenkova, M. N.↗
NASA NTRS1998

The Local ISM and its Interaction with the Winds of Nearby Late-type Stars

We present new Goddard High-Resolution Spectrograph (GHRS) observations of the Ly-alpha and Mg II absorption lines seen toward the nearby stars 61 Cyg A and 40 Eri A. We use these data to measure interstellar properties along these lines of sight and to search for evidence of circumstellar hydrogen walls, which are produced by collisions between the stellar winds and the Local InterStellar Medium (LISM). We were able to model the Ly-alpha lines of both stars without hydrogen-wall absorption components, but for 61 Cyg A the fit required a stellar Ly-alpha, line profile with an improbably deep self-reversal, and for 40 Eri A the fit required a very low deuterium-to-hydrogen ratio that is inconsistent with previous GHRS measurements. Since these problems could be rectified simply by including stellar hydrogen-wall components with reasonable attributes, our preferred fits to the data include these components. We have explored several ways in which the hydrogen-wall properties measured here and in previous work can be used to study stellar winds and the LISM. We argue that the existence of a hydrogen wall around 40 Eri A and a low H I column density along that line of sight imply that either the interstellar density must decrease toward 40 Eri A or the hydrogen ionization fraction (chi) must increase. We find that hydrogen-wall temperatures are larger for stars with faster velocities through the LISM. The observed temperature-velocity relation is consistent with the predictions of hydromagnetic shock jump conditions. More precise comparison of the data and the jump conditions suggests crude upper limits for both chi and the ratio of magnetic to thermal pressure in the LISM (alpha): chi less than 0.6 and alpha less than 2. The latter upper limit corresponds to a limit on the LISM magnetic field of B less than 5 micro G. These results imply that the plasma Mach number of the interstellar wind flowing into the heliosphere is M(sub A) greater than 1.3, which indicates that the collision is supersonic and that there should therefore be a bow shock outside the heliopause in the upwind direction. Finally, we estimate stellar wind pressures (P sub wind) from the measured hydrogen-wall column densities. These estimates represent the first empirical measurements of wind properties for late-type main-sequence stars. The wind pressures appear to be correlated with stellar X-ray surface fluxes, F(x), in a manner consistent with the relation P(wind) varies as F(x)(exp -1/2), a relation that is also consistent with the variations of P(sub wind) and F(sub x) observed during the solar activity cycle. If this relation can in fact be generalized to solar-like stars, as is suggested by our data, then it is possible to estimate stellar wind properties simply by measuring stellar X-rays. One implication of this is that stellar wind pressures and mass-loss rates are then predicted to increase with time, since F(sub x) is known to decrease with stellar age.

Wood, Brian E.↗
DOE OSTI2017

A Test of the Interstellar Boundary EXplorer Ribbon Formation in the Outer Heliosheath

NASA’s Interstellar Boundary EXplorer ( IBEX ) mission is imaging energetic neutral atoms (ENAs) propagating to Earth from the outer heliosphere and local interstellar medium (LISM). A dominant feature in all ENA maps is a ribbon of enhanced fluxes that was not predicted before IBEX . While more than a dozen models of the ribbon formation have been proposed, consensus has gathered around the so-called secondary ENA model. Two classes of secondary ENA models have been proposed; the first class assumes weak scattering of the energetic pickup protons in the LISM, and the second class assumes strong but spatially localized scattering. Here we present a numerical test of the “weak scattering” version of the secondary ENA model using our gyro-averaged kinetic model for the evolution of the phase-space distribution of protons in the outer heliosheath. As input for our test, we use distributions of the primary ENAs from our MHD-plasma/kinetic-neutral model of the heliosphere-LISM interaction. The magnetic field spectrum for the large-scale interstellar turbulence and an upper limit for the amplitude of small-scale local turbulence (SSLT) generated by protons are taken from observations by Voyager 1 in the LISM. The hybrid simulations of energetic protons are also used to set the bounding wavenumbers for the spectrum of SSLT. Our test supports the “weak scattering” version. This makes an additional solid step on the way to understanding the origin and formation of the IBEX ribbon and thus to improving our understanding of the interaction between the heliosphere and the LISM.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2008

Prospects for Studying Interstellar Magnetic Fields with a Far-Infrared Polarimeter for SAFIR

Polarimetry at mid-infrared through millimeter wavelengths using airborne and ground-based telescopes has revealed magnetic structures in dense molecular clouds in the interstellar medium, primarily in regions of star formation. Furthermore, spectropolarimetry has offered clues about the composition of the dust grains and the mechanism by which they are aligned with respect to the local magnetic field. The sensitivity of the observations to date has been limited by the emission from the atmosphere and warm telescopes. A factor of 1000 in sensitivity can be gained by using instead a cold space telescope. With 5 arcminute resolution, Planck will make the first submillimeter polarization survey of the full Galaxy early in the next decade. We discuss the science case for and basic design of a far-infrared polarimeter on the SAFIR space telescope, which offers resolution in the few arcsecond range and wavelength selection of cold and warm dust components. Key science themes include the formation and evolution of molecular clouds in nearby spiral galaxies, the magnetic structure of the Galactic center, and interstellar turbulence.

Dowell, C. Darren↗
DOE OSTI2018

Interstellar Mapping and Acceleration Probe (IMAP): A New NASA Mission

The Interstellar Mapping and Acceleration Probe (IMAP) is a revolutionary mission that simultaneously investigates two of the most important overarching issues in Heliophysics today: the acceleration of energetic particles and interaction of the solar wind with the local interstellar medium. While seemingly disparate, these are intimately coupled because particles accelerated in the inner heliosphere play critical roles in the outer heliospheric interaction. Selected by NASA in 2018, IMAP is planned to launch in 2024. The IMAP spacecraft is a simple sun-pointed spinner in orbit about the Sun-Earth L1 point. IMAP’s ten instruments provide a complete and synergistic set of observations to simultaneously dissect the particle injection and acceleration processes at 1 AU while remotely probing the global heliospheric interaction and its response to particle populations generated by these processes. In situ at 1 AU, IMAP provides detailed observations of solar wind electrons and ions; suprathermal, pickup, and energetic ions; and the interplanetary magnetic field. For the outer heliosphere interaction, IMAP provides advanced global observations of the remote plasma and energetic ions over a broad energy range via energetic neutral atom imaging, and precise observations of interstellar neutral atoms penetrating the heliosphere. Complementary observations of interstellar dust and the ultraviolet glow of interstellar neutrals further deepen the physical understanding from IMAP. IMAP also continuously broadcasts vital real-time space weather observations. Finally, IMAP engages the broader Heliophysics community through a variety of innovative opportunities. This paper summarizes the IMAP mission at the start of Phase A development.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2018

Interstellar Mapping and Acceleration Probe (IMAP): A New NASA Mission

The Interstellar Mapping and Acceleration Probe (IMAP) is a revolutionary mission that simultaneously investigates two of the most important overarching issues in Heliophysics today: the acceleration of energetic particles and interaction of the solar wind with the local interstellar medium. While seemingly disparate, these are intimately coupled because particles accelerated in the inner heliosphere play critical roles in the outer heliospheric interaction. Selected by NASA in 2018, IMAP is planned to launch in 2024. The IMAP spacecraft is a simple sun-pointed spinner in orbit about the Sun-Earth L1 point. IMAP's ten instruments provide a complete and synergistic set of observations to simultaneously dissect the particle injection and acceleration processes at 1 AU while remotely probing the global heliospheric interaction and its response to particle populations generated by these processes. In situ at 1 AU, IMAP provides detailed observations of solar wind electrons and ions; suprathermal, pickup, and energetic ions; and the interplanetary magnetic field. For the outer heliosphere interaction, IMAP provides advanced global observations of the remote plasma and energetic ions over a broad energy range via energetic neutral atom imaging, and precise observations of interstellar neutral atoms penetrating the heliosphere. Complementary observations of interstellar dust and the ultraviolet glow of interstellar neutrals further deepen the physical understanding from IMAP. IMAP also continuously broadcasts vital real-time space weather observations. Finally, IMAP engages the broader Heliophysics community through a variety of innovative opportunities. This papersummarizes the IMAP mission at the start of Phase A development.

McComas, D. J.↗
DOE OSTI2017

Parsec-scale Variations in the {sup 7}Li i/{sup 6}Li i Isotope Ratio Toward IC 348 and the Perseus OB 2 Association

Measurements of the lithium isotopic ratio in the diffuse interstellar medium from high-resolution spectra of the Li i λ 6708 resonance doublet have now been reported for a number of lines of sight. The majority of the results for the {sup 7}Li/{sup 6}Li ratio are similar to the solar system ratio of 12.2, but the line of sight toward o Per, a star near the star-forming region IC 348, gave a ratio of about two, the expected value for gas exposed to spallation and fusion reactions driven by cosmic rays. To examine the association of IC 348 with cosmic rays more closely, we measured the lithium isotopic ratio for lines of sight to three stars within a few parsecs of o Per. One star, HD 281159, has {sup 7}Li/{sup 6}Li ≃ 2 confirming production by cosmic rays. The lithium isotopic ratio toward o Per and HD 281159 together with published analyses of the chemistry of interstellar diatomic molecules suggest that the superbubble surrounding IC 348 is the source of the cosmic rays.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1995

Extreme ultraviolet spectroscopy and photometry of VV Puppis during a high accretion state

We determine the physical properties of the accretion region of the AM Her-type binary VV Puppis using extreme ultraviolet (EUV) medium-resolution spectroscopy and photometry obtained with the Extreme Ultraviolet Explorer (EUVE) observatory. The EUV continuum from VV Pup was detected in the wavelength range from 75 to 135 A and was simultaneously recorded with the Deep Survey/Spectrometer (DS/S) imaging telescope, allowing for the extraction of an accurate light curve. VV Pup appeared to have entered a high-accretion state just prior to the pointed EUVE observations. We use the EUV light curve to infer the diameter of the accretion region (d = 220 km) assuming a hemispherical geometry and a radius of 9000 km for the white dwarf. We perform a model atmosphere analysis and, based on the light curve properties and assuming a distance of 145 pc, we derive an effective temperature of the accretion region in the range 270,000 is less than T(sub eff) is less than 360,000 K and a neutral hydrogen column density in the local interstellar medium of n(sub H) = 1.9 - 3.7 x 10(exp 19)/sq cm. The total EUV/soft X-ray energy radiated by the accretion region is approximately 3.5 x 10(exp 32) ergs/s. Our results provide a first verification of past suggestions that deep heating of the white dwarf surface produces the soft X-ray flux from the polars. We present a possible detection of O VI absortion features, and we suggest that extensive EUVE observations targeting high-accretion events may result in oxygen and heavier element abundance determination in the accretion region.

Vennes, Stephane↗
NASA NTRS2022

Deuterium Isotope Fractionation of Polycyclic Aromatic Hydrocarbons in Meteorites as an Indicator of Interstellar/Protosolar Processing History

The stable isotope composition of soluble and insoluble organic compounds in carbonaceous chondrites can be used to determine the provenance of organic molecules in space. Deuterium enrichment in meteoritic organics could be a residual signal of synthetic reactions occurring in the cold interstellar medium or an indicator of hydrothermal parent-body reactions. δD values have been measured in grains and bulk samples for a wide range of meteorites; however, these reservoirs are highly variable and may have experienced fractionation during thermal and/or aqueous alteration. Among the plethora of organic compounds in meteorites are polycyclic aromatic hydrocarbons (PAHs), which are stable and abundant in carbonaceous chondrites, and their δD ratio may preserve evidence about their formation environment as well as the influence of parent-body processes. This study tests hypotheses about the potential links between PAHs-deuteration concentrations and their formation conditions by examining the δD ratio of PAHs in three CM carbonaceous chondrites representing an aqueous alteration gradient. We use deuterium enrichments in soluble 2–5-ring PAHs as an indicator of either photon-driven deuteration due to unimolecular photodissociation in warm regions of space, gas-phase ion–molecule reactions in cold interstellar regions of space, or UV photolysis in ices. We also test hypothesized reaction pathways during parent-body processing that differ between partially and fully aromatized PAHs. New methodological approaches were developed to extract small, volatile PAHs without fractionation. Our results suggest that meteoritic PAHs could have formed through reactions in cold regions, with possible overprinting of deuterium enrichment during aqueous parent-body alteration, but the data could not rule out PAH alteration in icy mantles as well.

H V Graham↗
DOE OSTI2019

Calibrating Interstellar Abundances Using Supernova Remnant Radiative Shocks

Using integral field data we extract the optical spectra of shocked interstellar clouds in Kepler’s supernova remnant located in the inner regions of our Galaxy, as well as in the Large Magellanic Cloud, the Small Magellanic Cloud, NGC 6822, and IC 1613. Using self-consistent shock modeling, we make a new determination of the chemical composition of the interstellar medium in N, O, Ne, S, Cl, and Ar in these galaxies and obtain accurate estimates of the fraction of refractory grains destroyed in the shock. By comparing our derived abundances with those obtained in recent works using observations of B-stars, F supergiant stars, and H ii regions, we provide a new calibration for abundance scaling in the range of 7.9≲12+log O/H≲9.1.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2012

Hydrocarbons on Saturns Satellites: Relationship to Interstellar Dust and the Solar Nebula

To understand the origin and evolution of our Solar System, and the basic components that led to life on Earth, we study interstellar and planetary spectroscopic signatures. The possible relationship of organic material detected in carbonaceous meteorites, interplanetary dust particles (IDPs), comets and the interstellar medium have been the source of speculation over the years as the composition and processes that governed the early solar nebula have been explored to understand the extent to which primitive material survived or became processed. The Cassini VIMS has provided new data relevant to this problem. Three of Saturn's satellites, Phoebe, Iapetus, and Hyperion, are found to have aromatic and aliphatic hydrocarbons on their surfaces. The aromatic hydrocarbon signature (C-H stretching mode at 3.28 micrometers) is proportionally significantly stronger (relative to the aliphatic bands) than that seen in other Solar System bodies (e.g., comets) and materials (Stardust samples, IDPs, meteorites) and the distinctive sub-features of the 3.4 micrometer aliphatic band (CH2 and CH3 groups) are reminiscent of those widely detected throughout the diffuse ISM. Phoebe may be a captured object that originated in the region beyond the present orbit of Neptune, where the solar nebula contained a large fraction of original interstellar ice and dust that was less processed than material closer to the Sun. Debris from Phoebe now resident on Iapetus and Hyperion, as well as o Phoebe itself, thus presents a unique blend of hydrocarbons, amenable to comparisons with interstellar hydrocarbons and other Solar System materials. The dust ring surrounding Saturn, in which Phoebe is embedded, probably originated from a collision with Phoebe. Dust ring particles are the likely source of the organic-bearing materials, and perhaps the recently identified small particles of Fe detected on Saturn's satellites. Lab measurements of the absolute band strengths of representative aliphatic and aromatic molecules, together with measurements from the VIMS data, allow us to calculate the number of C atoms to find the relative abundances of C atoms in the two kinds of organic molecules. The strength of the prominent aromatic C-H stretch band relative to the aliphatic band complex in Phoebe and Iapetus indicates that the relative abundance of aromatic to aliphatic carbon is very large (greater than 200). In contract, the aromatic band is nearly imperceptible in spectra of interplanetary dust particles (IDP), returned samples from comet 91P/Wild 2, insoluable carbonaceous material in most meteorites, and the diffuse interstellar dust (DISM) (although aromatics are known in all these materials-here we consider only the spectroscopic signature)

Cruikshank, D. P.↗
NASA NTRS1990

Physical conditions in photodissociation regions - Application to galactic nuclei

A procedure is outlined which determines the physical characteristics of the neutral interstellar medium in the nuclei of luminous galaxies. The method uses millimeter and IR observations to find the mass and density of the molecular and atomic gas components as well as the UV flux incident on clouds. The area and volume filling factors and approximate number of clouds and cloud radii are also found. For the Galactic center, about 100 clouds of radius about 0.4 pc and density about 100,000/cu cm are found within about 5 pc. The atomic gas temperature is about 700 K and the FUV field on clouds is about 100,000 times the local Galactic FUV field. The flux is consistent with a central source of luminosity of 2-3 x 10 to the 7th solar. Roughly 100,000 clouds of radius roughly 0.4 pc are found within the roughly 330 pc nuclear region of M82. The large number of clouds produces a projected area filling factor approaching unity. Cloud heating may be dominated by an intense interstellar UV flux.

Wolfire, Mark G.↗
NASA NTRS2017

Deep K-Band Observations of TMC-1 with the Green Bank Telescope: Detection of HC7O, Nondetection of HC11N, and a Search for New Organic Molecules

The 100-meter Robert C. Byrd Green Bank Telescope K-band (KFPA) receiver was used to perform a high-sensitivity search for rotational emission lines from complex organic molecules in the cold interstellar medium toward TMC-1 (Taurus Molecular Cloud - cyanopolyyne peak), focussing on the identification of new carbon-chain-bearing species as well as molecules of possible prebiotic relevance. We report a detection of the carbon-chain oxide species HC7O and derive a column density of (7.8 plus or minus 0.9) times 10 (sup 11) per square centimeter. This species is theorized to form as a result of associative electron detachment reactions between oxygen atoms and C7H minus, and/or reaction of C6H2 plus with CO (followed by dissociative electron recombination). Upper limits are given for the related HC6O, C6O, and C7O molecules. In addition, we obtained the first detections of emission from individual (sup 13) C isotopologues of HC7N, and derive abundance ratios HC7N/HCCCC (sup 13) CCCN equal to 110 plus or minus 16 and HC7N/HCCCC (sup 13) CCCN equal to 96 plus or minus 11, indicative of significant (sup 13) C depletion in this species relative to the local interstellar elemental (sup 12) C divided by (sup 13) C ratio of 60-70. The observed spectral region covered two transitions of HC11N, but emission from this species was not detected, and the corresponding column density upper limit is 7.4 times 10 (sup 10) per square centimeter (at 95 percent confidence). This is significantly lower than the value of 2.8 times 10 (sup 11) per square centimeter previously claimed by Bell et al. and confirms the recent nondetection of HC11N in TMC-1 by Loomis et al. Upper limits were also obtained for the column densities of malononitrile and the nitrogen heterocycles quinoline, isoquinoline, and pyrimidine.

ISM: abundances, ISM: lines and bands, ISM: molecu↗
NASA NTRS2001

Chemical and Isotopic Analysis of Trace Organic Matter on Meteorites and Interstellar Dust Using a Laser Microprobe Instrument

Polycyclic Aromatic Hydrocarbons (PAHs) are of considerable interest today because they are ubiquitous on Earth and in the interstellar medium (ISM). In fact, about 20% of cosmic carbon in the galaxy is estimated to be in the form of PAHs. Investigation of these species has obvious uses for determining the cosmochemistry of the solar system. Work in this laboratory has focused on four main areas: 1) Mapping the spatial distribution of PAHs in a variety of meteoritic samples and comparing this distribution with mineralogical features of the meteorite to determine whether a correlation exists between the two. 2) Developing a method for detection of fullerenes in extraterrestrial samples using microprobe Laser Desorption Ionization Mass Spectroscopy and utilizing this technique to investigate fullerene presence, while exploring the possibility of spatially mapping the fullerene distribution in these samples through in situ detection. 3) Investigating a possible formation pathway for meteoritic and ancient terrestrial kerogen involving the photochemical reactions of PAHs with alkanes under prebiotic and astrophysically relevant conditions. 4) Studying reaction pathways and identifying the photoproducts generated during the photochemical evolution of PAH-containing interstellar ice analogs as part of an ongoing collaboration with researchers at the Astrochemistry Lab at NASA Ames. All areas involve elucidation of the solar system formation and chemistry using microprobe Laser Desorption Laser Ionization Mass Spectrometry. A brief description of microprobe Laser Desorption Ionization Mass Spectroscopy, which allows selective investigation of subattomole levels of organic species on the surface of a sample at 10-40 micrometer spatial resolution, is given.

Zare, Richard N.↗
DOE OSTI2016

The galactic census of high- and medium-mass protostars. III. {sup 12}Co maps and physical properties of dense clump envelopes and their embedding gmcs

We report the second complete molecular line data release from the Census of High- and Medium-mass Protostars (CHaMP), a large-scale, unbiased, uniform mapping survey at sub-parsec resolution, of millimeter-wave line emission from 303 massive, dense molecular clumps in the Milky Way. This release is for all {sup 12}CO J = 1 → 0 emission associated with the dense gas, the first from Phase II of the survey, which includes {sup 12}CO, {sup 13}CO, and C{sup 18}O. The observed clump emission traced by both {sup 12}CO and HCO{sup +} (from Phase I) shows very similar morphology, indicating that, for dense molecular clouds and complexes of all sizes, parsec-scale clumps contain Ξ ∼ 75% of the mass, while only 25% of the mass lies in extended (≳10 pc) or “low density” components in these same areas. The mass fraction of all gas above a density of 10{sup 9} m{sup −3} is ξ{sub 9} ≳ 50%. This suggests that parsec-scale clumps may be the basic building blocks of the molecular interstellar medium, rather than the standard GMC concept. Using {sup 12}CO emission, we derive physical properties of these clumps in their entirety, and compare them to properties from HCO{sup +}, tracing their denser interiors. We compare the standard X-factor converting I{sub {sup 1}{sup 2}CO} to N{sub H{sub 2}} with alternative conversions, and show that only the latter give whole-clump properties that are physically consistent with those of their interiors. We infer that the clump population is systematically closer to virial equilibrium than when considering only their interiors, with perhaps half being long-lived (10s of Myr), pressure-confined entities that only terminally engage in vigorous massive star formation, supporting other evidence along these lines that was previously published.

79 ASTRONOMY AND ASTROPHYSICS↗