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At least 1,063 records · Page 59

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NASA NTRS2010

The Search for Interstellar Sulfide Grains

The lifecycle of sulfur in the galaxy is poorly understood. Fe-sulfide grains are abundant in early solar system materials (e.g. meteorites and comets) and S is highly depleted from the gas phase in cold, dense molecular cloud environments. In stark contrast, sulfur is essentially undepleted from the gas phase in the diffuse interstellar medium, indicating that little sulfur is incorporated into solid grains in this environment. It is widely believed that sulfur is not a component of interstellar dust grains. This is a rather puzzling observation unless Fe-sulfides are not produced in significant quantities in stellar outflows, or their lifetime in the ISM is very short due to rapid destruction. Fe sulfide grains are ubiquitous in cometary samples where they are the dominant host of sulfur. The Fe-sulfides (primarily pyrrhotite; Fe(1-x)S) are common, both as discrete 0.5-10 micron-sized grains and as fine (5-10 nm) nanophase inclusions within amorphous silicate grains. Cometary dust particles contain high abundances of well-preserved presolar silicates and organic matter and we have suggested that they should contain presolar sulfides as well. This hypothesis is supported by the observation of abundant Fe-sulfides grains in dust around pre- and post-main sequence stars inferred from astronomical spectra showing a broad 23 micron IR feature due to FeS. Fe-sulfide grains also occur as inclusions in bona fide circumstellar amorphous silicate grains and as inclusions within deuterium-rich organic matter in cometary dust samples. Our irradiation experiments show that FeS is far more resistant to radiation damage than silicates. Consequently, we expect that Fe sulfide stardust should be as abundant as silicate stardust in solar system materials.

Keller, Lindsay P.↗

NASA NTRS1991

Laboratory and observational study of the interrelation of the carbonaceous component of interstellar dust and solar system materials

By studying the chemical and isotopic composition of interstellar ice and dust, one gains insight into the composition and chemical evolution of the solid bodies in the solar nebula and the nature of the material subsequently brought into the inner part of the solar system by comets and meteorites. It is now possible to spectroscopically probe the composition of interstellar ice and dust in the mid-infrared, the spectral range which is most diagnostic of fundamental molecular vibrations. We can compare these spectra of various astronomical objects (including the diffuse and dense interstellar medium, comets, and the icy outer planets and their satellites) with the spectra of analogs we produce in the laboratory under conditions which mimic those in these different objects. In this way one can determine the composition and abundances of the major constituents of the various ices and place general constraints on the types of organics coating the grains in the diffuse interstellar medium. In particular we have shown the ices in the dense clouds contain H2O, CH3OH, CO, perhaps some NH3 and H2CO, we well as nitriles and ketones or esters. Furthermore, by studying the photochemistry of these ice analogs in the laboratory, one gains insight into the chemistry which takes place in interstellar/precometary ices. Chemical and spectroscopic studies of photolyzed analogs (including deuterated species) are now underway. The results of some of these studies will be presented and implications for the evolution of the biogenic elements in interstellar dust and comets will be discussed.

Allamandola, L. J.↗

NASA NTRS1997

Reduction of EUVE Guest Observer Data

We report on the observation of the HI filament LVC 88+36-2 with the Deep Survey/Spectrometers of EUVE. Detecting the shadow of this cloud in absorption might have proven the existence of a diffuse EUV background behind the cloud, and constrain the emission geometries of the hot plasma in the Local Interstellar Medium (LISM). By detecting diffuse emission in the EUVE spectrometers, it would also be possible to constrain the temperature and pressure of the emitting regions as well as determine whether or not the hot phase of the LISM is in equilibrium with cosmic elemental abundances. Unfortunately, we did not detect a cloud shadow with this set of observations. This is due to a combination of circumstances, but mostly due to the fact that EUV diffuse emission is weak compared to the background levels of EUVE. If a shadow exists in the EUVE, then it is less than 1% of the EUVE detector background of 1e-3 cts arcmin(exp -2) in the Deep Survey detector.

Vallerga, John↗

NASA NTRS1997

Reduction of EUVE Guest Observer Data

This report documents the observations of the HI filament LVC 88+36-2 with the Deep Survey/Spectrometers of EUVE. Detecting the shadow of this cloud in absorption might have proven the existence of a diffuse EUV background behind the cloud, and constrain the emission geometries of the hot plasma in the Local Interstellar Medium (LISM). By detecting diffuse emission in the EUVE spectrometers, it would also be possible to constrain the temperature and pressure of the emitting regions as well as determine whether or not the hot phase of the LISM is in equilibrium with cosmic elemental abundances. Unfortunately, we did not detect a cloud shadow with this set of observations. This is due to a combination of circumstances, but mostly due to the fact that EUV diffuse emission is weak compared to the background levels of EUVE. If a shadow exists in the EUVE, then it is less than 1% of the EUVE detector background of 1e-3 cts arcmin(sup -2) in the Deep Survey detector.

Vallerga, John↗

NASA NTRS1993

Boundary conditions for the paleoenvironment: Chemical and physical processes in the pre-solar nebula

In observations with the NRAO 12m telescope at Kitt Peak, Arizona, Irvine, a new interstellar radical, CH2N, has been detected. This identification is important for the study of hydrogenation processes in the interstellar medium. In particular, although the abundance of hydrogen is some four orders of magnitude higher than that of other reactive elements in this environment, many organic molecules in quiescent clouds are very unsaturated. This is a consequence of activation barriers which cannot be overcome at the temperatures of cold clouds, even when such reactions are energetically allowed. The hydrogenation series based on the cyanide radical (HnCN) has had four members previously detected in the interstellar medium: CN (n equals O), HCN (n equals l), CH2CN (n equals 3), and CH3NH2 (n equals 5). The recent determination of the rotational spectrum of the CH2N radical through microwave spectroscopy in Japan has made possible a search for this species. In addition to its potential importance for interstellar chemistry, the CH2N radical has been proposed as a reaction intermediate for HCN production in the atmosphere of Jupiter, and as a possible species in the expanding envelopes of oxygen--rich evolved stars. We detected CH2N in the cold cloud TMC--1 where the abundance seems to be some three orders of magnitude lower than that of HCN. A tentative detection was made in the Galactic Center molecular cloud Sgr B2. To our knowledge, there are no predicted abundances of CH2N from models of interstellar chemistry.

Irvine, William M.↗

NASA NTRS2003

Radioastronomical Searches for Instellar Biomolecules

Impacts of comets and asteroids could have delivered large amounts of organic matter to the early Earth. to retain a significant interstellar signature; observations of recent bright comets indicate that they have a molecular inventory consistent with their ices being largely unmodified interstellar material. Many simple organic molecules with biochemical significance observed in circumstellar envelopes and in molecular clouds, similar to that from which the Solar System formed, may have acted as the precursors of the more complex organics found in meteorites. Therefore, there is potentially a strong link between interstellar organics and prebiotic chemical evolution. Radioastronomical observations, particularly at millimeter wavelengths, allow us to determine the chemical composition and characteristics of the molecular inventory in interstellar space. Here we report some of our recent results from extensive astronomical searches for astrobiologically-important interstellar organics.

Kuan, Y.-J.↗

NASA NTRS1995

Discovery of a candidate old, isolated neutron star in the field of a galactic cirrus cloud

New x-ray optical, and radio observations of the bright, unidentified x-ray source MS 0317.7-6647 are presented suggesting that this source is a likely compact stellar remnant. As part of the Einstein Extended Medium Sensivity Survey, this source was discovered serendipitously in the Einstein Imaging Proportional Counter pointing towards the nearby (4.5 Mpc) spiral galaxy NGC 1313. The very high x-ray to optical flux ratio, pointlike ROSAT HRI detection, and extremely soft component in the x-ray spectrum of MS 0317.7-6647 eliminate all the usual classes of optical counterparts to faint x-ray sources except for a very massive x-ray binary (and black hole candidate) in NGC 1313, a nearby, companionless pulsar similar to Geminga, or a very nearby ( approximately 100 pc) isolated, old neutron star slowly accreting interstellar matter onto its magnetic poles. The presence of an IR cirrus cloud which shadows the approximately 0.25 keV x-ray background in this direction supports the latter possibilty.

Stocke, John T.↗

NASA NTRS2010

Isotopic Fractionation in Primitive Material: Quantifying the Contribution of Interstellar Chemistry

Anomalously fractionated isotopic material is found in many primitive Solar System objects, such as meteorites and comets. It is thought, in some cases, to trace interstellar matter that was incorporated into the Solar Nebula without undergoing significant processing. We will present the results of models of the nitrogen, oxygen, and carbon fractionation chemistry in dense molecular clouds, particularly in cores where substantial freeze-out of molecules on to dust has occurred. The range of fractionation ratios expected in different interstellar molecules will be discussed and compared to the ratios measured in molecular clouds, comets and meteoritic material. These models make several predictions that can be tested in the near future by molecular line observations, particularly with ALMA.

Charnley, Steven↗

NASA NTRS2010

Isotopic Fractionation in Comets: Quantifying the Contribution of Interstellar Chemistry

Anomalously fractionated isotopic material is found in many primitive Solar System objects, such as meteorites and comets. It is thought, in some cases, to trace interstellar matter that was incorporated into the Solar Nebula without undergoing significant processing. We will present the results of models of the nitrogen, oxygen, and carbon fractionation chemistry in dense molecular clouds, particularly in cares where substantial freeze-taut of molecules on to dust has occurred. The range of fractionation ratios expected in different interstellar molecules will be discussed and compared to the ratios measured in molecular clouds, comets and meteoritic material. These models make several predictions that can be tested in the near future by molecular line observations, particularly with the GBT.

Charnley, Steven↗

NASA NTRS2011

Models of Isotopic Fractionation in Prestellar Cores

Anomalously fractionated isotopic material is found in many primitive Solar System objects, such as meteorites and comets. It is thought, in some cases, to trace interstellar matter that was incorporated into the Solar Nebula without undergoing significant processing. We will present the results of models of the nitrogen, oxygen, and carbon fractionation chemistry in dense molecular clouds, particularly in cores where substantial freeze-out of molecules on to dust has occurred. The range of fractionation ratios expected in different interstellar molecules will be discussed and compared to the ratios measured in molecular clouds, comets and meteoritic material. These studies make several predictions that can be tested in the near future by high-resolution molecular line observations with ALMA.

Charnley, Steven B.↗

NASA NTRS2011

Isotope Fractionation in the Interstellar Medium

Charnley, Steven↗

NASA NTRS2012

Models of Isotopic Fractionation in Prestellar Cores

Anomalously fractionated isotopic material is found in many primitive Solar System objects, such as meteorites and comets. It is thought, in some cases, to trace interstellar matter that was incorporated into the Solar Nebula without undergoing significant processing. We will present the results of models of the nitrogen, oxygen, and carbon fractionation chemistry in dense molecular clouds, particularly in cores where substantial freeze-out of molecules on to dust has occurred. The range of fractionation ratios expected in different interstellar molecules will be discussed and compared to the ratios measured in molecular clouds, comets and meteoritic material. These studies make several predictions that can be tested in the near future by high-resolution molecular line observations with ALMA.

Charnley, Steven B.↗

DOE OSTI2022

Gas and Cosmic-Ray Properties in the MBM 53, 54, and 55 Molecular Clouds and the Pegasus Loops Revealed by H i Line Profiles, Dust, and Gamma-Ray Data

In studying the interstellar medium (ISM) and Galactic cosmic rays (CRs), uncertainty of the interstellar gas density has always been an issue. To overcome this difficulty, we used a component decomposition of the 21 cm H i emission line and used the resulting gas maps in an analysis of γ-ray data obtained by the Fermi Large Area Telescope (LAT) for the MBM 53, 54, and 55 molecular clouds and the Pegasus loop. We decomposed the ISM gas into intermediate-velocity clouds, narrow-line and optically thick H i, broad-line and optically thin H i, CO-bright H 2 , and CO-dark H 2 using detailed correlations with the H i line profiles from the HI4PI survey, the Planck dust-emission model, and the Fermi-LAT γ-ray data. We found the fractions of the optical depth correction to the H i column density and CO-dark H 2 to be nearly equal. We fitted the CR spectra directly measured at/near the Earth and the measured γ-ray emissivity spectrum simultaneously. We obtained a spectral break in the interstellar proton spectrum at ~7 GeV, and found that the γ-ray emissivity normalization agrees with the AMS-02 proton spectrum within 10%, relaxing the tension with the CR spectra previously claimed.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS1983

A note on compressibility and energy cascade in turbulent molecular clouds

Observed velocity-size correlations are reexamined in the light of an improved theory of turbulent energy cascade that is developed. It is shown that observed velocity-size correlations cannot be compared with the Kolmogorov law, which is based on incompressible turbulent flow. The fact that the log v-log(l/rho) scaling law (v the turbulent velocity, l the associated region size, and rho the fluid density) predicted for compressible energy cascade is always steeper than that observed in molecular clouds indicates the injection rather than the dissipation of mechanical energy at smaller scales of motion. It is also shown that the concept of strict energy cascade may not be generally applicable in the interstellar medium. The agreement between theory and observation turns out to be best for small cool clouds and cloud cores, suggesting that, for these regions at least, the dominant process in establishing the observed v-l-rho correlation is a turbulent energy cascade.

Fleck, R. C., Jr.↗

NASA NTRS1975

Interstellar absorption lines in the spectrum of zeta Ophiuchi

Extensive high-resolution scans with the Copernicus UV spectrometer are combined with available ground-based data on interstellar lines to obtain temperatures, densities, and abundances in H I clouds and H II regions in the direction of zeta Oph. Column densities are obtained for 21 elements in various ionization stages, and upper limits are reported for 5 elements and 11 molecules. Analysis of radial velocities and growth curves indicates that H2, HD, and most neutral atoms are concentrated in one cloud with a heliocentric velocity of -14.4 km/s and that H II regions exist in addition to the Stroemgren sphere. The electron and proton densities are calculated for the -14.4 km/s cloud, and the temperatures required for the populations of the fine-structure levels in the C I ground state and the excited rotational levels of H2 are computed and indicate that the dense cloud must have some associated hotter regions. Relative to hydrogen, most of the elements in the H I clouds are found to be depleted by factors of 3 to 4000 as compared with solar system abundances, and several elements appear to be depleted in the H II regions as well.

Morton, D. C.↗

NASA NTRS1977

The origin of comets

Empirical data related to questions regarding the origin of comets are examined, taking into account the primitive temperature and its evolution, the cometary C-12/C-13 isotope ratio, the chemistry of comets, and the solar-system related orbits of the comets. The theories of cometary origin considered are related to a condensation of comets from the solar nebula and a later ejection into Oort's cloud, a recent condensation of comets in situ, a capture of interstellar comets, and a reversal of the arrow of time in the traditional evolution of comets. The only hypothesis which seems to survive an evaluation of the theories on the basis of the existing data is that the comets were condensed some five billion years ago in the vicinity of the giant planets or beyond, at the outer edge of the solar nebula.

Delsemme, A. H.↗

NASA NTRS1984

Interstellar Grain Mantles

Techniques for determining the composition of small dust grains in interstellar matter are discussed. The best way to study the composition of interstellar grain mantles is by infrared spectroscopy. The absorption features in a complete infrared spectrum from 2 to 15 microns can be used as fingerprints to identify the absorbing molecule. Ground-based observations around 3 microns confirmed the presence of H2O ice in interstellar grain mantles, through the detection of the 3.08 micron OH stretching vibration. The detection of other molecules, in particular the carbon bearing molecules, is however hampered by atmospheric absorption in the 5-8 micron region and the presence of the strong ice and silicate bands, which dominate the 3 and 10 micron region respectively. Kuiper Airborne Observatory observations of the 5-8 micron region of the spectrum are therefore extremely important to determine the composition of interstellar grain mantles. The 5 to 8 micron spectra of molecular cloud sources was obtained using a 24 detector grating spectrometer. An important characteristic of this spectrometer is that the whole spectrum is obtained simultaneously. It is therefore relatively easy to correct for atmospheric transmission.

Witteborn, F.↗

NASA NTRS1985

The extent of the local hi halo

Forty-five high-latitude, OB stars have been observed in the Ly alpha and 21 cm lines of HI in an effort to map out the vertical distribution and extent of the local HI halo. The 25 stars for which a reliable HI colum density can be obtained from Ly alpha lie between 60 and 3100 pc from the plane. The principal result is that the total column density of HI at z 1 kpc is, on the average, 5 + or - 3 x 10 the 19th power/sq cm, or 15% of the total sub HI. At relatively low z the data toward some stars suggest a low effective scale height and fairly high average foreground density, while toward others the effective scale height is large and the average density is low. This can be understood as the result of irregularities in the interstellar medium. A model with half of the HI mass in clouds having radii of a few pc and a Gaussian vertical distribution with sigma sub 2 = 135 pc, and half of the mass in an exponential component with a scale height of 500 pc, gives a satisfactory fit to the data. The technique of comparing Ly alpha and 21 cm column densities is also used to discuss the problem of estimating the distance to several possibly subluminous stars.

Lockman, F. J.↗