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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,063 records · Page 59
All sourcesNASA NTRSDOE OSTI
NASA NTRS1990

Heterogeneous reactions on nitric acid trihydrate

The first direct measurements are reported of the reaction probabilities at stratospheric temperatures for two important heterogeneous reactions on nitric acid trihydrate (NAT), the compound which makes up the predominant, type I form of polar stratospheric cloud (PSC). Sticking coefficients and solubilities of HCl and NAT, which are important in modeling physicochemical processes in the stratosphere, are also reported. The results show that the conversion of the chlorine reservoir species in the stratosphere to photochemically active forms can occur within a few days of the first appearance of type I PSCs during the polar winter.

Moore, S. B.↗
NASA NTRS1990

Carbon monoxide over the Amazon Basin during the wet season

Measurements of the distribution of carbon monoxide in the lower atmosphere (150-5000 m) over the Amazon region of Brazil during the wet season, taken in conjunction with the 1987 NASA Global Tropospheric Experiment/Amazon Boundary Layer Experiment (ABLE 2B), are analyzed. About 100 hr of airborne, in situ CO measurements were obtained using a tunable diode laser system, providing insights into factors influencing the basin-scale distribution of CO in the Amazonian troposphere during wet season conditions. Distribution of CO over the altitudes 0.15-4.5 km was influenced by such factors as surface emissions from biological sources and long-range transport of pollutants from Northern Hemisphere sources. It is noted that the disruption of mixed layer growth and decay processes has a particularly important influence on CO concentration in the daytime lower troposphere and that the correlation of CO with O3 was positive under conditions influenced by Northern Hemisphere air and negative under all other conditions observed.

Harriss, R. C.↗
NASA NTRS1990

NCTM of liquids at high temperatures using polarization techniques

Temperature measurement and control is extremely important in any materials processing application. However, conventional techniques for non-contact temperature measurement (mainly optical pyrometry) are very uncertain because of unknown or varying surface emittance. Optical properties like other properties change during processing. A dynamic, in-situ measurement of optical properties including the emittance is required. Intersonics is developing new technologies using polarized laser light scattering to determine surface emittance of freely radiating bodies concurrent with conventional optical pyrometry. These are sufficient to determine the true surface temperature of the target. Intersonics is currently developing a system called DAPP, the Division of Amplitude Polarimetric Pyrometer, that uses polarization information to measure the true thermodynamic temperature of freely radiating objects. This instrument has potential use in materials processing applications in ground and space based equipment. Results of thermophysical and thermodynamic measurements using laser reflection as a temperature measuring tool are presented. The impact of these techniques on thermophysical property measurements at high temperature is discussed.

Krishnan, Shankar↗
NASA NTRS1991

Production of oxygen from lunar ilmenite

The kinetics and the mechanism of reduction of synthetic ilmenite by hydrogen in the temperature range of 807 to 1014 C were investigated. At temperatures below 876 C, the temporal profiles of conversion have a sigmoidal shape and indicate the presence of three different stages (induction, acceleration, and deceleration) during the reduction reaction. The apparent activation energy for the reaction is 22.3 kcal/mole, whereas the intrinsic activation energy is 16.9 kcal/mole. Scanning electron microscopy and energy dispersive x-ray analyses show that the diffusion of Fe product away from the reaction front and through the TiO2 phase, followed by the nucleation and growth of a separate Fe phase is an important step affecting the process kinetics. X-ray diffraction and wavelength dispersive x-ray results indicate that the TiO2 can be reduced to lower oxides of titanium at temperatures higher than 876 C.

Shadman, F.↗
NASA NTRS1991

Refractory materials from lunar resources

Refractories - materials which are able to withstand extremely high temperatures - are sure to be an important part of any processing facility or human outpost which is built on Mars. Containers for processing lunar oxygen will need high temperature components. Fabrication of structural material from lunar resources need both containment vessels to hold high temperature melts and molds in which to form the final shapes. Certainly, it would be desirable to fabricate such vessels and molds on the Moon, rather than carrying them up from the Earth. At first glance, this might appear to be a trivial task, since the Moon's surface consists of a variety of refractory compositions. To turn the regolith into a useful fire brick or mold, however, will require water or other binders and additives which are likely to be in extremely short supply on the Moon. The steps needed to make fire bricks and molds for lunar-derived structural materials are examined, pointing out the critical steps and resources which will be needed. While these processes and applications may seem somewhat mundane, it is emphasized that it is precisely these rudimentary processes which must be mastered before discussing making aerobrakes, and other fancier refractories from lunar resources.

Fabes, B. D.↗
NASA NTRS1991

Production of solar photovoltaic cells on the Moon

Solar energy is directly available on the sunward lunar surface. Most, if not all, the materials are available on the Moon to make silicon based solar photovoltaic cells. A few additional types are possible. There is a small but growing literature on production of lunar derived solar cells. This literature is reviewed. Topics explored include trade-offs of local production versus import of key materials, processing options, the scale and nature of production equipment, implications of storage requirements, and the end-uses of the energy. Directions for future research and demonstrations are indicated.

Criswell, David R.↗
NASA NTRS1991

The composition of Phobos: Meteorite analogs based on KRFM and VSK spectral data from the Phobos 2 spacecraft

In 1989 the Phobos 2 spacecraft obtained 8-channel 0.3 to 0.6 mm KRFM spectra and two-channel wide-angel TV VSK images in bandpasses of 0.40 to 0.56 mm and 0.78 to 1.10 mm. The TV data were used to map four color ratio units on disk-resolved images of Phobos, and were combined with the KRFM spectra to analyze possible meteorite analogs for the mapped units. A total of 58 spectra of 39 meteorites were studied for similarities with Phobos data in spectral shape, absorption features, and visible near-IR color ratio. Analysis of the spectral data show that, among the meteorites studied, there are no unique spectral analogs for Phobos surface material. Currently, the closest spectral analogs are the optically altered black chondrite meteorites Gorlovka and Pervomaisky. The weak UV absorption bands in some KRFM spectra and the red slope in VSK color-ratio data indicate that carbonaceous chondrite-like material may also be a component of Phobos surface material. However, the lack of close carbonaceous chondrite spectral analogs and the existence of apparent absorption bands in KRFM spectra that are not seen in meteorite spectra suggest that there are processes and/or materials on the surface of Phobos that are not represented in the meteorite collections. The similarities between KRFM spectra of Phobos and the spectra of black chondrites suggest that optically altered mafic silicates may constitute a component of the surface material of Phobos, and that optical alteration and mixing by regolith processes may be an important factor in the evolution of Phobos surface material.

Britt, D. T.↗
NASA NTRS1991

Cloud albedo control by cloud-top entrainment

Marine stratus and stratocumulus clouds exert a considerable influence on the earth's heat budget, mainly due to their high albedos relative to the ocean surface. It is therefore important to understand the processes that control the radiative properties of these extensive cloud systems, particularly during daylight hours. Aircraft measurements of a stratocumulus cloud deck taken around local noon during the 1987 field phase of the First International Satellite Cloud Climatology Project Regional Experiment are the topic of this paper. A mixing line analysis of data from a series of flight tracks across a strong gradient in cloud albedo provides evidence that variations in the water vapor content of the air above the marine inversion can be responsible for the albedo change. The implications of this unexpected result for climate modeling are discussed.

Hanson, Howard P.↗
NASA NTRS1991

Coagulation of particles in Saturn's rings - Measurements of the cohesive force of water frost

Experimental data are presented on the sticking force of water ice particles which are indicative of the role that the cohesive properties of such particles could play in the dynamics of Saturn ring particles. Sticking forces are dependent on particle impact velocities; a 'Velcro' model is devised to describe the surface structure involved in sticking. The data indicate that below the critical impact velocity of about 0.03 cm/sec, particle cohesion always occurs. Due to the optical depth of micron-sized grains in the Saturn rings, particles are hypothesized to be coated with a layer of frost which will render cohesion an important ring-dynamics process.

Hatzes, A. P.↗
NASA NTRS1991

Negative ions in the coma of Comet Halley

The detection of negatively charged cometary ions in the inner coma of Comet Halley is reported. These ions are observed in three broad mass peaks at 7-19, 22-65, and 85-110 AMU, with densities reaching greater than about 1/cu cm, about 0.05/cu cm, and about 0.04/cu cm, respectively, at a distance of about 2300 km from the nucleus. The ion species thought to be present include O(-), OH(-), C(-), CH(-), CN(-) and heavier complex CHO molecular ions. As negative ions are easily destroyed by solar radiation at about 1 AU, an efficient production mechanism, so far unidentified, is required to account for the observed densities. The detection of negative ions in the coma near 1 AU implies that negative ions should also be present in similar neutral gas and dust environment farther away from the sun. If the negative-ion densities are large enough, they could play an important part in physical processes such as radiative transfer or charge exchange.

Chaizy, P.↗
NASA NTRS1990

Influence of the solar wind/interplanetary medium on Saturnian kilometric radiation

Previous studies on the periodicities of the Saturnian kilometric radiation (SKR) suggested a considerable solar wind influence on the occurrence of SKR, so it was obvious to investigate the relationship between parameters of the solar wind/interplanetary medium and this Saturnian radio component. Voyager 2 data from the Plasma Science experiment, the Magnetometer experiment and the Planetary Radio Astronomy experiment were used to analyze the external control of SKR. Out of the examined quantities known to be important in controlling magnetospheric processes this investigation yielded a dominance of the solar wind momentum, ram pressure and kinetic energy flux, in stimulating SKR and controlling its activity and emitted energy, and confirmed the results of the Voyager 1 analysis.

Rucker, Helmut O.↗
NASA NTRS1990

Flare physics at high energies

High-energy processes, involving a rich variety of accelerated particle phenomena, lie at the core of the solar flare problem. The most direct manifestation of these processes are high-energy radiations, gamma rays, hard X-rays and neutrons, as well as the accelerated particles themselves, which can be detected in interplanetary space. In the study of astrophysics from the moon, the understanding of these processes should have great importance. The inner solar system environment is strongly influenced by activity on the sun; the physics of solar flares is of great intrinsic interest; and much high-energy astrophysics can be learned from investigations of flare physics at high energies.

Ramaty, R.↗
NASA NTRS1992

Pressure regimes and core formation in the accreting earth

Recent work suggests that a large degree of melting is required to segregate metal from silicates, suggesting a connection with the formation of magma oceans. At low pressures metallic liquids do not wet silicate minerals, preventing the metal from aggregating into large masses that can sink. At high pressures, above 25 GPa, the dihedral angles of grains in contact with oxygen-rich metallic liquids may be reduced enough to allow percolation of metal, but this has not been confirmed. Physical models of core formation and accretion may therefore involve the formation of magma oceans and the segregation of metal at both high and low pressures. Models of core formation involving different pressure regimes are discussed as well as chemical evidence bearing on the models. Available geophysical data is ambiguous. The nature of the 670 km boundary (chemical difference or strictly phase change) between the upper and lower mantle is in doubt. There is some evidence that plumes are derived from the lower mantle, and seismic tomography strongly indicates that penetration of subducting oceanic crust into the lower mantle, but the tomography data also indicates that the 670 km discontinuity is a significant barrier to general mantle convection. The presence of the D' layer at the base of the lower mantle could be a reaction zone between the mantle and core indicating core-mantle disequilibrium, or D' layer could be subducted material. The abundance of the siderophile elements in the mantle could provide clues to the importance of high pressure processes in Earth, but partition coefficients at high pressures are only beginning to be measured.

Newsom, H. E.↗
NASA NTRS1990

Predicting cloud water variations in the GISS GCM

A cloud water parameterization under development for the NASA Goddard Institute for Space Studies (GISS) global climate model (GCM) is described. The scheme is based on the studies of Sundqvist (1978) and Sundqvist et al. (1989), with a number of additional features designed to mimic the effects of important microphysical and dynamic processes in clouds. Preliminary results on geographical and seasonal variations from simulations of the current climate are presented.

Del Genio, Anthony D.↗
NASA NTRS1989

Physics of the central engine

Physical processes which may be important in the central engines of AGNs are discussed. Black hole accretion models have been elaborated during the past few years, and provide a plausible framework for jet and spectrum formation. However, the specific mechanisms responsible for producing the observed continuum radiation remain uncertain. Consideration is given to nonthermal models for the IR continuum, constraints on thermal plasma, and the production of relativistic electrons.

Begelman, Mitchell C.↗
NASA NTRS1993

Some aspects of the interaction between chemical and dynamic processes relating to the Antarctic ozone hole

Observational and modeling studies have been conducted to examine the interaction between the chemical and dynamical processes that occur during springtime in the lower stratosphere of the Southern Hemisphere. The temporal evolution of the ozone distribution and the circulation during 1987 is contrasted with that for 1988 as an illustrative example of how dynamical processes and the resulting meteorological conditions modulate the ozone depletion. Concurrently with the observational analysis, an effort was initiated to simulate the ozone depletion during austral spring using a 3D chemical/transport model. The model includes a parameterized representation of the heterogeneous processes thought to be important in this region. The simulation indicates that the inclusion of this additional chemistry, which results in the release of free chlorine and the redistribution of odd nitrogen into reservoir species, reproduces many aspects of the observations.

Eckman, R. S.↗
NASA NTRS1991

South African TOPEX/Poseidon altimeter experiment

The area surrounding the southern tip of Africa contains a juxtaposition of a variety of interesting and climatically relevant features. On the Indian Ocean side, the Agulhas Current with its tributaries form a conduit through which much of the southern Indian Ocean surface flow is focused. South of the continent, this flow is fragmented and partially injected into the Atlantic Ocean and across the Subtropical Convergence into the Southern Ocean. To the west of the subcontinent, the circulation of the South Atlantic subtropical gyre in the Cape Basin interacts with the vigorous Benguela upwelling regime. The creation, transformation, and transport of water masses and the intra-annual and climatic importance of all these processes have been specifically recognized by the World Ocean Circulation Experiment (WOCE). The South African TOPEX/POSEIDON Altimeter Experiment addresses many of these issues through four mutually complementary and interrelated subprojects.

Gruendlingh, Marten L.↗
NASA NTRS1992

Lunar Resource Assessment: Strategies for Surface Exploration

Use of the indigenous resources of space to support long-term human presence is an essential element of the settlement of other planetary bodies. We are in a very early stage of understanding exactly how and under what circumstances space resources will become important. The materials and processes to recover them that we now think are critical may not ultimately be the raison d'etre for a resource utilization program. However, the need for strategic thinking proceeds in parallel with efforts to implement such plans and it is not too soon to begin thinking how we could and should use the abundant resources of materials and energy available from the Moon. The following commodities from the Moon are discussed: (1) bulk regolith, for shielding and construction on the lunar surface (ultimately for export to human-tended stations in Earth-Moon space), and (2) oxygen and hydrogen, for propellant and life support.

Spudis, Paul D.↗