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At least 1,063 records · Page 59

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NASA NTRS1975

Large modular graphite radiant heaters for testing space shuttle thermal protection systems

A graphite radiant heating array, capable of heating a 5-ft span of shuttle wing leading edge or a 4 x 8 ft flat panel through an entry thermal profile up to 3200 G, has been designed and built by McDonnell Douglas Corporation for NASA-Johnson Space Center. The unique, interchangeable, self-contained heather modules and their versatile support structure/coolant manifold are discussed along with the extensive thermal analysis that accompanied the design effort. A complete description of the geometric capabilities of the array, as well as the design details of the individual modules, is presented. The complete performance envelope of the array is discussed, including maximum temperature and gradients, heating uniformity, and the required utilities and support equipment.

Cox, B. G.↗

NASA NTRS1975

The effect of thermal exposure on the mechanical properties of aluminum-graphite composites

The mechanical properties of aluminum-graphite composites were measured at room temperature in the as-received condition, after elevated temperature exposure and after thermal cycling. The composites were fabricated by solid-state diffusion bonding of liquid-phase Al-infiltrated Thornel 50 fibers. The results showed that the maximum longitudinal tensile strength of the as-received material was 80,000 psi, which corresponds well with the rule of mixture value. The composite strength was observed to vary widely, depending on the extent of wetting of the fibers by the aluminum. The strength of the composites in the transverse direction was generally very low, due to poor interfacial bonding. Aluminum carbide (Al4C3) formed at the surface of the fibers at temperatures greater than 500 C. Development of the carbide was shown to be diffusion-controlled and was dependent on the time and temperature used. It was shown that the tensile strength was virtually unaffected by heat-treatment up to 500 C; beyond that temperature a drastic degradation of tensile strength occurred. Thermal cycling of the composites below 500 C resulted in an observable degradation of the composite strength.

Khan, I. H.↗

NASA NTRS1975

Graphite fiber reinforced thermoplastic resins

Mechanical properties of neat resin samples and graphite fiber reinforced samples of thermoplastic resins were characterized with particular emphasis directed to the effects of environmental exposure (humidity, temperature and ultraviolet radiation). Tensile, flexural, interlaminar shear, creep and impact strengths were measured for polysulfone, polyarylsulfone and a state-of-the-art epoxy resin samples. In general, the thermoplastic resins exhibited environmental degradation resistance equal to or superior to the reference epoxy resin. Demonstration of the utility and quality of a graphite/thermoplastic resin system was accomplished by successfully thermoforming a simulated compressor blade and a fan exit guide vane.

Novak, R. C.↗

NASA NTRS1975

Enhanced crystallinity of low temperature deposited silicon films on graphite subtrates

The previously developed technique of a sandwich coating for silicon crystallinity enhancement in silicon films deposited at low temperature is applied to graphite substrates. The measured increase in silicon crystallinity is comparable to that observed earlier using a quartz substrate. The distribution of aluminum in the silicon films is determined using Auger spectroscopic depth profiling. Carbon diffusion from the substrate into the silicon film is shown to be negligible at a substrate temperature of 600 C.

Chang, C. A.↗

NASA NTRS1976

Further development of high temperature-resistant graphite fiber coupling agents

Potential coupling agents for graphite fibers were screened by their effect on the weight losses of Thornel 300, HMS, and HTS fibers at 588K for 200 and 400 hours. Unidirectional laminates were made from HMS and HTS fibers, untreated, and treated with each of the seven coupling agents. The matrix of all laminates was PMR polyimide (PMR-PR). On the basis of the best overall retention of elevated temperature interlaminar shear strength after 200 hours at 588K, composite weight after 200 hours at 588K, and fiber weight after 400 hours at 588K, ventromer T-1 applied from aqueous solution and pyrolyzed PPQ were selected for further evaluation as coupling agents for HTS fiber while ventromer T-2 and pyrolyzed PPQ were selected as coupling agents for HMS fiber. It was shown that pyrolyzed PPQ as a coupling agent improves the oxidative stability of HTS/PMR-PI composites.

Griffin, R. N.↗

NASA NTRS1976

Development of polyphenylquinoxaline graphite composites

Six polyphenylquinoxalines (PPQ) containing pendant cyano (CN) groups were synthesized. The polymers were characterized in terms of inherent viscosity, glass transition temperature, softening temperature and weight loss due to aging in air at 316 C (600 F). The potential for crosslinking PPQs by trimerization of pendant CN groups was investigated. A polymer derived from 1 mole 3,3,4,4 -tetraaminobenzophenone, .2 mole p-bis(p -cyanophenoxyphenylglyoxalyl)benzene and .8 mole p-bis(phenylglyoxalyl)benzene was selected for more extensive characterization in HM-S graphite fiber-reinforced composites. Mechanical properties were determined using composites made from HM-S fiber and polymer and composites made from HM-S fiber, polymer and a potential CN group trimerization catalyst. Composite mechanical properties, inter-laminar shear strength and flexure properties, were determined over the temperature range of +21 C to 316 C.

Shdo, J. D.↗

NASA NTRS1976

Quinoxaline polymers and copolymers derived from 1,4-bis(1'-naphthalenyloxalyl)benzene and their graphite composites

Experimental studies were performed with new polyquinoxalines and their graphite composites. Four polymers were synthesized, and then were characterized with respect to their inherent viscosity, elemental chemical analysis, mechanical, and thermodynamic properties. Structural formulas of the polymers and their precursors are given; methods of synthesis are described; and specifically examined was the preparation of polymers from 3,3' diamino-benzidine from 1,4- and 1,3- bis ((1'-napthalenyl) oxalyl) benzene respectively. Also considered was the preparation of polyquinoxalines from poly (p-benzil), and 1,2- aryldiamines.

Port, W. S.↗

NASA NTRS1975

Review of electrical and thermal properties of carbon and graphite

Some of the electrical and thermal properties of ordered and partially ordered carbons are reviewed. Earlier and current research areas are discussed relative to electrical properties of pyrolytic and polycrystalline graphite; thermal, electrical, and magnetic properties of graphitizable and glassy carbon with heat treatment temperatures in the range 600-2500 C; Josephson junction-like and switching behavior in carbon films; and some high-conductivity and superconducting compounds made from carbon. Due to the newness and complexity of many of the areas examined, the results are not always completely understood, nor have these areas been completely investigated experimentally. Suggestions for future research are made.

Woollam, J. A.↗

NASA NTRS1977

Ultrasonic evaluation of the strength of unidirectional graphite-polyimide composites

An acoustic-ultrasonic method is described that was successful in ranking unidirectional graphite-polyimide composite specimens according to variations in interlaminar shear strength. Using this method, a quantity termed the stress wave factor was determined. It was found that this factor increases directly with interlaminar shear strength. The key variables in this investigation were composite density, fiber weight fraction, and void content. The stress wave factor and other ultrasonic factors that were studied were found to provide a powerful means for nondestructive evaluation of mechanical strength properties.

Vary, A.↗

NASA NTRS1977

Results of graphite-polyimide isogrid panel testing

A procedure was developed for fabricating short-fiber HTS graphite and NR150B2 polyimide resin into an isogrid configuration. After fabrication, the panels were subjected to structural analysis and testing. The testing program is described.

Hyer, M. W.↗

NASA NTRS1977

Electrochemical behavior of 0.2 to 3 molar ferrous chloride-ferric chloride mixtures on edge-on pyrolytic graphite rotated disk electrodes

Potentiostatic determinations in various mixtures of FeCl2-FeCl3 with excess HCl show rest potentials that are 0.1 V less electropositive than the theoretical values from the formulated ratios of FeII to FeIII (probably as a result of complexing). The standard rate constant sub s. ranges between 0.0001 and 0.000 cm/sec. Tafel slopes b of roughly 0.12V per decade indicate single-electron exchange kinetics. No significant trend in either b or sub s was attributed to mixture composition. The higher sub s. values occurred with and edge-on pyrolytic graphite that had undergone a permanent surface change.

Miller, R. O.↗

NASA NTRS1977

Design and fabrication of graphite-epoxy bolted wing skin splice specimens

Graphite-epoxy bolted joint specimens were designed and fabricated. These specimens were to be representative of a side-of-body wing skin splice with a 20-year life expectancy in a commercial transport environment. Preliminary tests were performed to determine design values of bearing and net tension stresses. Based upon the information developed, a three-fastener-wide representative wing skin splice was designed for a load of 2627 KN/m (15,000 lbf/in.). One joint specimen was fabricated and tested at NASA. The wing skin splice failed at 106 percent of design ultimate load. This joint design achieved all static load objectives. Fabrication of six specimens, together with their loading fixtures, was completed, and the specimens were delivered to NASA-LRC.

Johnson, R. W.↗

NASA NTRS1977

Effect of bow-type initial imperfection on the buckling load and mass of graphite-epoxy blade-stiffened panels

A structural synthesis computer code which accounts for first order effects of an initial bow and which can be used for sizing stiffened composite panels having an arbitrary cross section is used to study graphite blade-stiffened panels. The effect of a small initial bow on both the load carrying ability of panels and on the mass of panels designed to carry a specified load is examined. Large reductions in the buckling load caused by a small initial bow emphasize the need for considering a bow when a panel is designed.

Stroud, W. J.↗

NASA NTRS1976

The graphite crystal X-ray spectrometer on OSO-8

The large-area graphite crystal X-ray spectrometer aboard the OSO-8 satellite is described. The instrument can be used to measure continuum profiles over the energy band from 2 to 8 keV with a resolution of several tens of electron volts and to detect narrow line emission from strong X-ray sources with a limiting sensitivity (3 sigmas) of the order of 10-eV, equivalent width for a three-day observing period.

Kestenbaum, H. L.↗

NASA NTRS1977

Impact behavior of graphite-epoxy simulated fan blades

The response of a graphite-epoxy material, Modmor II/PR-286, to foreign object impact was investigated by impacting spherical projectiles of three different materials - gelatin, ice, and steel - on simulated blade specimens. Visual and metallographic inspection revealed three damage mechanisms: penetration, leading edge bending failure, and stress wave delamination and cracking. The steel projectiles caused penetration damage regardless of the impact location and angle. For the ice and gelatin particles impacting the leading edge, failure was due to large local bending strains, resulting in significant material removal and delamination damage.

Cook, T. S.↗

NASA NTRS1977

Graphite grain surface reactions in interstellar and protostellar environments

Surface reactions on warm (at least 60 K) graphite grains between lattice C atoms and impinging H and O atoms within or in the vicinity of H II regions can provide a prolific source of H2CO and other interstellar molecules. It is proposed that similar reactions in the primitive solar nebula led to the formation of the organic molecules found in carbonaceous chondrites. From this and related evidence, it is argued that most of the solid material in the solar system may have originated as interstellar grains.

Barlow, M. J.↗

NASA NTRS1977

Use of the short-beam shear test for quality control of graphite-polyimide laminates

The properties of laminated composite materials are strongly affected by many fabrication variables including temperature, time, and molding pressure. It is therefore necessary to have reliable quality control tests to check the properties of manufactured materials. The short-beam shear test is used widely by both manufacturers and researchers as a quality control test in the production of materials and development of new material systems. There are, however, several limitations to the standard test method. This paper presents the results of short-beam shear tests on graphite-polyimide laminates and reports on stiffness-strength relationships and nondestructive evaluation methods which aid in the interpretation of the test data.

Stinchcomb, W. W.↗

NASA NTRS1977

Experimental studies of graphite-epoxy and boron-epoxy angle ply laminates in shear

The nonlinear/inelastic response under inplane shear of a large variety of graphite-epoxy and boron-epoxy angle-ply laminates was tested. Their strength allowables were obtained and the mechanisms which govern their mode of failure were determined. Two types of specimens for the program were chosen, tested, and evaluated: shear panels stabilized by an aluminum honeycomb core and shear tubes. A modified biaxially compression/tension loaded picture frame was designed and utilized in the test program with the shear panels. The results obtained with this test technique categorically prefer the shear panels, rather than the tubes, for adequate and satisfactory experimental definition of the objectives. Test results indicate the existence of a so-called core-effect which ought to be considered when reducing experimental data for weak in shear laminates.

Weller, T.↗