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At least 1,063 records · Page 59

Equilibrium carbon isotope fractionation factors of hydrocarbons: Semi-empirical force-field method

Here, we have calculated the reduced partition function ratios for carbon isotopes (β-factor) of 67 hydrocarbons (alkanes, alkenes, alkynes, cycloalkanes, and aromatics), including their 267 single-substituted isotopomers. The calculations were performed using the harmonic oscillator – rigid rotator model and the Urey / Bigeleisen-Mayer approach. Normal frequencies of molecular vibrations of the isotopologues were calculated from the molecular structures data and valence field force constants stored in the Light-handled Elucidation of Vibrations (LEV) database elaborated by Dr. Gribov and his colleagues in Russia. The LEV database is constructed from experimental spectroscopic and structural data by solving inverse problems of molecular vibrations. The LEV is internally consistent and the most comprehensive database available to date. The β-factor were calculated in the temperature range of 200–800 K with a 10 K step. Our calculations predict that the β-factors increase with an increasing number of C atoms within the same groups of hydrocarbons (e.g., alkanes). Our calculations also show a general descending order of 13 C enrichments among the different groups of hydrocarbons: cycloalkanes, aromatics, alkenes (double bonds) and isoalkanes, alkanes, alkynes (triple bonds). Position-specific, intramolecular isotope effects within hydrocarbons are determined by the β-factors of C in the different functional groups in the order: quaternary (C), tertiary (methine, CH), secondary (methylene, CH 2 ), primary (methyl, CH 3 ) and double bond (C=C), saturated bond (C - C), triple bond (HC≡). Our calculations on bulk and position-specific carbon isotope β-factors of the hydrocarbons, which are generally consistent with very limited ab initio calculations in the literature, are internally consistent and the most comprehensive to date for future applications to position-specific isotope geochemistry of hydrocarbons.

58 GEOSCIENCES↗

An Assessment of Persistent Acoustic Monitoring of a Nuclear Reactor during Full Power Generation

Persistent low-frequency (<180 Hz) acoustic detection took place within the boundaries of Oak Ridge National Laboratory to monitor full power operations of the High Flux Isotope Reactor. Three acoustic sensors were installed at distances of 69, 101, and 914 m from the northeast corner of the cooling towers to monitor and assess four reactor power generation cycles. Features were extracted from power spectral density calculations where data were collected during reactor on and off operations. Diverse spectral features were present during full reactor power, including a 21.4 Hz fundamental frequency and ascending harmonics. Using bandpass filters, these related frequencies were isolated and summed, and the root mean square energy was calculated. The method of isolating and summing characteristic features provided a significant improvement in identifying acoustic behavior related to reactor power when the raw signals were obscured by noise.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Development of a noncompact source theory with applications to helicopter rotors

A new formulation for determining the acoustic field of moving bodies, based on acoustic analogy, is derived. The acoustic pressure is given as the sum of two integrals, one of which has a derivative with respect to time. The integrands are functions of the normal velocity and surface pressure of the body. A computer program based on this formulation was used to calculate acoustic pressure signatures for several helicoptor rotors from experimental surface pressure data. Results are compared with those from compact source calculations. It is shown that noncompactness of steady sources on the rotor can account for the high harmonics of the pressure system. Thickness noise is shown to be a significant source of sound, especially for blunt airfoils in regions where noncompact source theory should be applied.

Farassat, F.↗

Gravity field of Jupiter and its satellite from Pioneer 10 and Pioneer 11 tracking data

Accurate two-way Doppler tracking data obtained from Pioneers 10 and 11 during their Jupiter encounters are analyzed to yield significantly improved values for the masses of the Galilean satellites, the harmonic coefficients of Jupiter, and the mass of the planet. The spacecraft trajectories relative to Jupiter are discussed, and nongravitational spacecraft accelerations are taken into account. Gravity results are derived from a simultaneous iterative weighted least-squares solution for the orbital elements of seven bodies, the masses of Jupiter and the Galilean satellites, the right ascension and declination of Jupiter's instantaneous pole relative to the 1950.0 mean earth equator and equinox, the Jovian gravity harmonic coefficients, the mass of a hypothetical mascon at the Great Red Spot, and the nongravitational-acceleration parameters. Four separate solutions are determined, and the best numerical values are given for the ratios of the masses of the four Galilean satellites to the mass of Jupiter; the ratio of the sun's mass to that of the Jupiter system; the second, third, fourth, fifth, and sixth zonal harmonic coefficients of Jupiter; the sectoral harmonics; and the ratio of the hypothetical mascon's mass to that of Jupiter.

Null, G. W.↗

Geomagnetism of earth's core

Instrumentation, analytical methods, and research goals for understanding the behavior and source of geophysical magnetism are reviewed. Magsat, launched in 1979, collected global magnetometer data and identified the main terrestrial magnetic fields. The data has been treated by representing the curl-free field in terms of a scalar potential which is decomposed into a truncated series of spherical harmonics. Solutions to the Laplace equation then extend the field upward or downward from the measurement level through intervening spaces with no source. Further research is necessary on the interaction between harmonics of various spatial scales. Attempts are also being made to analytically model the main field and its secular variation at the core-mantle boundary. Work is also being done on characterizing the core structure, composition, thermodynamics, energetics, and formation, as well as designing a new Magsat or a tethered satellite to be flown on the Shuttle.

Benton, E. R.↗

Cruise noise of counterrotation propeller at angle of attack in wind tunnel

The noise of a counterrotation propeller at angle of attack was measured in the NASA Lewis 8- by 6-Foot Supersonic Wind Tunnel at cruise conditions. Noise increases of as much as 4 dB were measured at positive angles of attack on the tunnel side wall, which represented an airplane fuselage. These noise increases could be minimized or eliminated by operating the counterrotation propeller with the front propeller turning up-inboard. This would require oppositely rotating propellers on opposite sides of the airplane. Noise analyses at different bandwidths enabled the separate front- and rear-propeller tones, as well as the total noise, at each harmonic to be determined. A simplified noise model was explored to show how the observed circumferential noise patterns of the separate propeller tones might have occurred. The total noise pattern, which represented the sum of the front- and rear-propeller tones at a particular harmonic, showed trends that would be hard to interpret without the separate-tone results. Therefore it is important that counterrotation angle-of-attack noise data be taken in such a manner that the front- and rear-propeller tones can be separated.

Dittmar, J. H.↗

Integrated CFD modeling of gas turbine combustors

3D, curvilinear, multi-domain CFD analysis is becoming a valuable tool in gas turbine combustor design. Used as a supplement to experimental testing. CFD analysis can provide improved understanding of combustor aerodynamics and used to qualitatively assess new combustor designs. This paper discusses recent advancements in CFD combustor methodology, including the timely integration of the design (i.e. CAD) and analysis (i.e. CFD) processes. Allied Signal's F124 combustor was analyzed at maximum power conditions. The assumption of turbulence levels at the nozzle/swirler inlet was shown to be very important in the prediction of combustor exit temperatures. Predicted exit temperatures were compared to experimental rake data, and good overall agreement was seen. Exit radial temperature profiles were well predicted, while the predicted pattern factor was 25 percent higher than the harmonic-averaged experimental pattern factor.

Fuller, E. J.↗

On the unique structure of the magnetic fields of Uranus and Neptune

The magnetic fields of Uranus and Neptune, which have comparable dipole, quadrupole, and octupole harmonics, are unique in the present-day solar system, but they resemble the geomagnetic field at the epochs of excursions and reversals known from paleomagnetic data. The precession dynamo model, in which the dominant role in the generation of the planetary magnetic fields is played by external gravitational forces, allows us to propose two scenarios for the formation of the unique topology of the magnetic fields of Uranus and Neptune. In the first case, tidal flows in the 'oceans' of these two planets extend down to the depths where the matter has a noticeable electric conductivity and velocity. A hydromagnetic interaction of the moving conducting fluid with the planetary magnetic field outside the generation region results in the deformation of the field and the deceleration of the motion under the action of the radial magnetic field. In the second case, the deformation of the field facilitates drastic changes in cyclonic cells within the generation region causing instabilities that result in a multi-polar field structure, excursions, and inversions. This paper considers this problem in greater detail by using the Neptune-Triton system as an example.

Dolginov, Sh. SH.↗

Chromospheric evaporation and decimetric radio emission in solar flares

We have discovered decimetric signatures of the chromospheric evaporation process. Evidence for the radio detection of chromospheric evaporation is based on the radio-inferred values of (1) the electron density, (2) the propagation speed, and (3) the timing, which are found to be in good agreement with statistical values inferred from the blueshifted Ca XIX soft X-ray line. The physical basis of our model is that free-free absorption of plasma emission is strongly modified by the steep density gradient and the large temperature increase in the upflowing flare plasma. The steplike density increase at the chromospheric evaporation front causes a local discontinuity in the plasma frequency, manifested as almost infinite drift rate in decimetric type III bursts. The large temperature increase of the upflowing plasma considerably reduces the local free-free opacity (due to the T(exp -3/2) dependence) and thus enhances the brightness of radio bursts emitted at the local plasma frequency near the chromospheric evaporation front, while a high-frequency cutoff is expected in the high-density regions behind the front, which can be used to infer the velocity of the upflowing plasma. From model calculations we find strong evidence that decimetric bursts with a slowly drifting high-frequency cutoff are produced by fundamental plasma emission, contrary to the widespread belief that decimetric bursts are preferentially emitted at the harmonic plasma level. We analyze 21 flare episodes from 1991-1993 for which broadband (100-3000 MHz) radio dynamic spectra from Pheonix, hard X-ray data from (BATSE/CGRO) and soft X-ray data from Burst and Transient Source Experiment/Compton Gamma Ray Observatory (GOES) were available.

Aschwanden, Markus J.↗

Chromospheric Evaporation and Decimetric Radio Emission in Solar Flares

We have discovered decimetric signatures of the chromospheric evaporation process. Evidence for the radio detection of chromospheric evaporation is based on the radio-inferred values of (1) the electron density, (2) the propagation speed, and (3) the timing, which are found to be in good agreement with statistical values inferred from the blueshifted Ca xix soft X-ray line. The physical basis of our model is that free-free absorption of plasma emission is strongly modified by the steep density gradient and the large temperature increase in the upflowing flare plasma. The steplike density increase at the chromospheric evaporation front causes a local discontinuity in the plasma frequency, manifested as almost infinite drift rate in decimetric type III bursts. The large temperature increase of the upflowing plasma considerably reduces the local free-free opacity (due to the T-(exp -3/2) dependence) and thus enhances the brightness of radio bursts emitted at the local plasma frequency near the chromospheric evaporation front, while a high-frequency cutoff is expected in the high-density regions behind the front, which can be used to infer the velocity of the upflowing plasma. From model calculations we find strong evidence that decimetric bursts with a slowly drifting high-frequency cutoff are produced by fundamental plasma emission, contrary to the widespread belief that decimetric bursts are preferentially emitted at the harmonic plasma level. We analyzed 21 flare episodes from 1991-1993 for which broadband (100-3000 MHz) radio dynamic spectra from Phoenix, hard X-ray data from BATSE/CGRO, and soft X-ray data from GOES were available. We detected slowly drifting high-frequency cutoffs between 1.1 and 3.0 GHz, with drift rates of -41 +/- 32 MHz/s, extending over time intervals of 24 +/- 23 s. Developing a density model for type III-emitting flare loops based on the statistically observed drift rate of type III bursts by Alvarez & Haddock, we infer velocities of up to 360 km/s for the upflowing plasma, with an average of v(sub CE) = 236 +/- 130 km /s for episodes with 5-15 s duration. The mean electron density of the upflowing plasma is n(sub e) = 5.2(+/-3.1) x 10(exp 10) /cu cm when it is first detected in radio, at coronal altitudes of h(sub 0) = 9.2 +/- 2.3 Mm.

Aschwanden, Markus J.↗

Analytic Theory of Titans Schumann Resonance: Constraints on Ionospheric Conductivity and Buried Water Ocean

This study presents an approximate model for the atypical Schumann resonance in Titan's atmosphere that accounts for the observations of electromagnetic waves and the measurements of atmospheric conductivity performed with the Huygens Atmospheric Structure and Permittivity, Wave and Altimetry (HASI-PWA) instrumentation during the descent of the Huygens Probe through Titan's atmosphere in January 2005. After many years of thorough analyses of the collected data, several arguments enable us to claim that the Extremely Low Frequency (ELF) wave observed at around 36 Hz displays all the characteristics of the second harmonic of a Schumann resonance. On Earth, this phenomenon is well known to be triggered by lightning activity. Given the lack of evidence of any thunderstorm activity on Titan, we proposed in early works a model based on an alternative powering mechanism involving the electric current sheets induced in Titan's ionosphere by the Saturn's magnetospheric plasma flow. The present study is a further step in improving the initial model and corroborating our preliminary assessments. We first develop an analytic theory of the guided modes that appear to be the most suitable for sustaining Schumann resonances in Titan's atmosphere. We then introduce the characteristics of the Huygens electric field measurements in the equations, in order to constrain the physical parameters of the resonating cavity. The latter is assumed to be made of different structures distributed between an upper boundary, presumably made of a succession of thin ionized layers of stratospheric aerosols spread up to 150 km and a lower quasi-perfect conductive surface hidden beneath the non-conductive ground. The inner reflecting boundary is proposed to be a buried water-ammonia ocean lying at a likely depth of 55-80 km below a dielectric icy crust. Such estimate is found to comply with models suggesting that the internal heat could be transferred upwards by thermal conduction of the crust, while convective processes cannot be ruled out.

TITAN↗

Extended quantitative rescattering model for simulating high-order harmonic streaking spectra by synchronization of an intense IR laser and a time-delayed attosecond XUV pulse

In this work, we theoretically investigate the modulated high-harmonic generation (HHG) driven by an intense few-cycle infrared (IR) laser field and a weak extreme-ultraviolet (XUV) pulse at a delayed time. We establish an extended quantitative rescattering (EQRS) model to simulate the HHG streaking spectra, with the ideas of correcting the IR ionization and the transition from the ground to continuum states in the strong-field approximation. The EQRS model has an accuracy comparable to that from “exactly” solving the time-dependent Schrödinger equation (TDSE). We reveal that the fringes in the streaking spectra are caused by the interference between the attosecond XUV pulse and harmonics resulting from different recombination pathways under the intense IR laser. We then demonstrate that the XUV pulse can be accurately retrieved by treating the single-atom TDSE results or macroscopic propagation results as the “input” data. This work provides with a tool for efficiently simulating and thoroughly analyzing the XUV-assisted HHG, which could also enhance its capability for tracing the electron dynamics involved in the strong-field phenomena.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Effects of Resonance in Quasi-Periodic Oscillators of Neutron Star Binaries

Using a large quantity of Rossi X-Ray Timing Explorer data presented in the literature, I offer a detailed investigation into the accuracy of the quasi-periodic oscillation (QPO) frequency determination. The QPO phenomenon seen in X-ray binaries is possibly a result of the resonance of the intrinsic (eigen) oscillations and harmonic driving forces of the system. I show that the resonances, in the presence of the damping of oscillations, occur at frequencies that are systematically and randomly shifted with respect to the eigenfrequencies of the system. The shift value strongly depends on the damping rate that is measured by the half-width of the QPO feature. Taking into account this effect, I analyze the QPO data for four Z sources, Scorpius X-I, GX 340+0, GX 5-1, and GX 17+2, and two atoll sources, 4U 1728-34 and 4U 0614+09. The transition-layer model (TLM) predicts the existence of the invariant quantity delta, an inclination angle of the magnetospheric axis with respect to the normal to the disk. I calculate delta and the error bars of delta using the resonance shift, and I find that the inferred delta-values are consistent with constants for these four Z sources, in which horizontal-branch oscillation and kilohertz frequencies have been detected and correctly identified. It is shown that the inferred delta are in the range between 5.5 deg and 6.5 deg. I conclude that the TLM seems to be compatible with the data.

Titarchuk, Lev↗

The Arctic Plant Aboveground Biomass Synthesis Dataset

Plant biomass is a fundamental ecosystem attribute that is sensitive to rapid climatic changes occurring in the Arctic. Nevertheless, measuring plant biomass in the Arctic is logistically challenging and resource intensive. Lack of accessible field data hinders efforts to understand the amount, composition, distribution, and changes in plant biomass in these northern ecosystems. Here, we present The Arctic plant aboveground biomass synthesis dataset, which includes field measurements of lichen, bryophyte, herb, shrub, and/or tree aboveground biomass (g m -2 ) on 2,327 sample plots from 636 field sites in seven countries. We created the synthesis dataset by assembling and harmonizing 32 individual datasets. Aboveground biomass was primarily quantified by harvesting sample plots during mid- to late-summer, though tree and often tall shrub biomass were quantified using surveys and allometric models. Each biomass measurement is associated with metadata including sample date, location, method, data source, and other information. This unique dataset can be leveraged to monitor, map, and model plant biomass across the rapidly warming Arctic.

54 ENVIRONMENTAL SCIENCES↗

A spherical harmonics method for asteroid pole determination

A new and general method is presented for determining pole orientations of unresolved solar system bodies that exhibit brightness variation with rotation. The accuracy of the method is limited only by the number of available apparitions, which imposes the degree where the Legendre expansion must be truncated. It is shown that power spectra of lightcurves provide enough information to extract pole coordinates from the data, independent of body shape and albedo variegation. The method has been tested using several computer-generated synthetic light-curves, and the accuracy is found to be about 5 deg in both the longitude and latitude of the pole, which is considerably better than that obtained from the standard triaxial ellipsoid model. Finally, the new spherical harmonics method has been applied to six well-observed asteroids: 16 Psyche, 22 Kalliope, 39 Laetitia, 44 Nysa, 45 Eugenia, and 349 Dembowska.

Lumme, K.↗

The NASA Spacecraft Transponding Modem

A new deep space transponder is being developed by the Jet Propulsion Laboratory for NASA. The Spacecraft Transponding Modem (STM) implements the standard transponder functions and the channel service functions that have previously resided in spacecraft Command/Data Subsystems. The STM uses custom ASICs, MMICs, and MCMs to reduce the active device parts count to 70, mass to I kg, and volume to 524 cc. The first STMs will be flown on missions launching in the 2003 time frame. The STM tracks an X-band uplink signal and provides both X-band and Ka-band downlinks, either coherent or non-coherent with the uplink. A NASA standard Command Detector Unit is integrated into the STM, along with a codeblock processor and a hardware command decoder. The decoded command codeblocks are output to the spacecraft command/data subsystem. Virtual Channel 0 (VC-0) (hardware) commands are processed and output as critical controller (CRC) commands. Downlink telemetry is received from the spacecraft data subsystem as telemetry frames. The STM provides the following downlink coding options: the standard CCSDS (7-1/2) convolutional coding, ReedSolomon coding with interleave depths one and five, (15-1/6) convolutional coding, and Turbo coding with rates 1/3 and 1/6. The downlink symbol rates can be linearly ramped to match the G/T curve of the receiving station, providing up to a 1 dB increase in data return. Data rates range from 5 bits per second (bps) to 24 Mbps, with three modulation modes provided: modulated subcarrier (3 different frequencies provided), biphase-L modulated direct on carrier, and Offset QPSK. Also, the capability to generate one of four non-harmonically related telemetry beacon tones is provided, to allow for a simple spacecraft status monitoring scheme for cruise phases of missions. Three ranging modes are provided: standard turn around ranging, regenerative pseudo-noise (PN) ranging, and Differential One-way Ranging (DOR) tones. The regenerative ranging provides the capability of increasing the ground received ranging SNR by up to 30 dB. Two different avionics interfaces to the command/data subsystem's data bus are provided: a MIL STD 1553B bus or an industry standard PCI interface. Digital interfaces provide the capability to control antenna selection (e.g., switching between high gain and low gain antennas) and antenna pointing (for future steered Ka-band antennas).

Berner, Jeff B.↗

Assessing within-Field Corn and Soybean Yield Variability from WorldView-3, Planet, Sentinel-2, and Landsat 8 Satellite Imagery

Crop yield monitoring is an important component in agricultural assessment. Multispectral remote sensing instruments onboard space-borne platforms such as Advanced Very High Resolution Radiometer (AVHRR), Moderate Resolution Imaging Spectroradiometer (MODIS), and Visible Infrared Imaging Radiometer Suite (VIIRS) have shown to be useful for efficiently generating timely and synoptic information on the yield status of crops across regional levels. However, the coarse spatial resolution data inherent to these sensors provides little utility at the management level. Recent satellite imagery collection advances toward finer spatial resolution (down to 1 m) alongside increased observational cadence (near daily) implies information on crops obtainable at field and within-field scales to support farming needs is now possible. To test this premise, we focus on assessing the efficiency of multiple satellite sensors, namely WorldView-3, Planet/Dove-Classic, Sentinel-2, and Landsat 8 (through Harmonized Landsat Sentinel-2 (HLS)), and investigate their spatial, spectral (surface reflectance (SR) and vegetation indices (VIs)), and temporal characteristics to estimate corn and soybean yields at sub-field scales within study sites in the US state of Iowa. Precision yield data as referenced to combine harvesters’ GPS systems were used for validation. We show that imagery spatial resolution of 3 m is critical to explaining 100% of the within-field yield variability for corn and soybean. Our simulation results show that moving to coarser resolution data of 10 m, 20 m, and 30 m reduced the explained variability to 86%, 72%, and 59%, respectively. We show that the most important spectral bands explaining yield variability were green (0.560 µm), red-edge (0.726 µm), and near-infrared (NIR - 0.865 µm). Furthermore, the high temporal frequency of Planet and a combination of Sentinel-2/Landsat 8 (HLS) data allowed for optimal date selection for yield map generation. Overall, we observed mixed performance of satellite-derived models with the coefficient of determination (R^2) varying from 0.21 to 0.88 (averaging 0.56) for the 30 m HLS and from 0.09 to 0.77 (averaging 0.30) for 3 m Planet. R^2 was lower for fields with higher yields, suggesting saturation of the satellite-collected reflectance features in those cases. Therefore, other biophysical variables, such as soil moisture and evapotranspiration, at similar fine spatial resolutions are likely needed alongside the optical imagery to fully explain the yields.

agriculture; yield; within-field; corn; soybean; r↗

Applications of higher harmonic control to hingeless rotor systems

A comprehensive analytical formulation was developed to predict the vibratory hub loads of a helicopter rotor system in forward flight. This analysis is used to calculate the optimal higher harmonic control inputs and associated actuator power required to minimize these hub loads. The present formulation is based on a finite element method in space and time. A nonlinear time domain, unsteady aerodynamic model is used to obtain the airloads, and the rotor induced inflow is calculated using a nonuniform inflow model. Predicted vibratory hub loads are correlated with experimental data from a scale model rotor. Results of a parametric study on a hindgeless rotor show that blade flap, lag and torsion vibration characteristics, offset of blade center of mass from elastic axis, offset of elastic axis from quarter-chord axis, and blade thrust greatly affect the higher harmonic control actuator power requirement.

Nguyen, Khanh↗