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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,063 records · Page 59
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Inferring the scrape-off layer heat flux width in a divertor with a low degree of axisymmetry

Plasma facing components (PFCs) in the next generation of tokamak devices will operate in challenging environments, with heat loads predicted to exceed 10 MWm -2 . The magnitude of these heat loads is set by the width of the channel, the ‘scrape-off layer’ (SOL), into which heat is exhausted, and can be characterised by an e-folding length scale for the decay of heat flux across the channel. It is expected this channel will narrow as tokamaks move towards reactor relevant conditions. Understanding the processes involved in setting the SOL heat flux width is imperative to be able to predict the heat loads PFCs must handle in future devices. Measurements of the SOL width are performed on the high-field spherical tokamak, ST40, using a newly commissioned infrared thermography system. With its high on-axis toroidal magnetic field (≥1.5 T) ST40 is uniquely positioned to investigate the influence of toroidal field on the heat flux width in spherical tokamaks, whilst also extending measurements of the SOL width in spherical tokamaks to increased poloidal field (≥0.3 T). Due to the divertor on ST40 having a low degree of axisymmetry, it is necessary for a set of radial measurements of the heat flux to be taken across the divertor, made possible using an automated toolchain that fully incorporates its 3D geometry. These radial profiles are combined with the magnetic geometry of the plasma to infer the width of the SOL, with both Eich and double exponential profiles of heat flux observed. A reduction in the heat flux is observed toroidally across part of the divertor, along with increased heat loads observed locally around the edges of the tiles. Future work in characterising the impact of tile misalignment and uncertainties in the reconstructed divertor magnetic geometry is required in order to further understand the observed heat flux patterns, as are additional investigations into the role potentially being played by an inhomogeneous sheath electric field.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2021

Gamma and pulsed electron radiolysis studies of CyMe 4 BTBP and CyMe 4 BTPhen: Identification of radiolysis products and effects on the hydrometallurgical separation of trivalent actinides and lanthanides

The radiolytic stability of the highly selective ligands CyMe 4 BTBP and CyMe 4 BTPhen against ionizing gamma radiation was studied in 1-octanol solution. CyMe 4 BTBP and CyMe 4 BTPhen are important extractants for a potential treatment of used nuclear fuel. They were studied under identical experimental conditions to directly compare the effects of gamma and pulsed electron radiolysis on the ligands and systematically study the influence of structural changes in the ligand backbone. Distribution ratios of Am 3+ , Cm 3+ and Eu 3+ , the residual concentration of CyMe 4 BTBP and CyMe 4 BTPhen in solution, and the formation of radiolysis products were studied as a function of absorbed gamma dose and presence of an acidic aqueous phase during irradiation. Quantitative and semi-quantitative analyses were used to elucidate the radiolysis mechanism for both ligands. Addition products of alpha-hydroxyoctyl radicals formed through radiolysis of the 1-octanol diluent to the ligand molecules were identified as the predominant radiolysis products. These addition products also extract trivalent metal ions, as distribution ratios remained high although the parent molecule concentrations decreased. Therefore, the utilization time of a solvent using these extractants under the harsh conditions of used nuclear fuel treatment could be considerably longer than expected. Understanding the radiolysis mechanism is crucial for designing more radiation resistant extractants.

99 GENERAL AND MISCELLANEOUS↗
DOE OSTI2020

Predicting Excitation Energies of Twisted Intramolecular Charge-Transfer States with the Time-Dependent Density Functional Theory: Comparison with Experimental Measurements in the Gas Phase and Solvents Ranging from Hexanes to Acetonitrile

Electronically excited states characterized by intramolecular charge transfer play an essential role in many biological processes and optical devices. The ability to make quantitative ab initio predictions of the relative energetics involved is a challenging yet desirable goal, especially for large molecules in solution. In this work, we present a data set of 61 experimental measurements of absorption and emission processes, both in the gas phase and in solvents representing a broad range of polarities, which involve intramolecular charge transfer mediated by a nonzero, "twisted" dihedral angle between one or more donor and acceptor subunits. Among a variety of density functionals investigated within the framework of linear-response theory, the "optimally tuned" LRC-ωPBE functional, which utilizes a system-specific yet nonempirical procedure to specify the range-separation parameter, emerges as the preferred choice. For the entire set of excitation energies, involving changes in dipole moment ranging from 4 to >20 Debye, the mean signed and absolute errors are 0.02 and 0.18 eV, respectively (compared, e.g., to -0.30 and 0.30 for PBE0, 0.44 and 0.47 for LRC-ωPBEh, 0.83 and 0.83 for ωB97X-V). We analyze the performance of polarizable continuum solvation models available in Q-Chem that partition the solvent response into fast and slow time scales, and clear trends emerge when measurements corresponding to the four small 4-(dimethylamino)benzonitrile (DMABN)-like molecules and a charged species are excluded. We make the case that the large errors found only for small molecules in the gas phase and weak solvents cannot be expected to improve via the optimal tuning procedure, which enforces a condition that is exact only in the well-separated donor-acceptor limit, and present empirical evidence implicating the outsized importance for small donor-acceptor systems of relaxation effects that cannot be accounted for by the linear-response time-dependent density functional theory within the adiabatic approximation. Finally, we demonstrate the utility of the optimally tuned density functional approach by targeting the charge-transfer states of a large biomimetic model system for light-harvesting structures in Photosystem II.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Inviscid damping of an elliptical vortex subject to an external strain flow

Inviscid spatial Landau damping is studied experimentally for the case of oscillatory motion of a two-dimensional vortex about its elliptical equilibrium in the presence of an applied strain flow. Here, the experiments are performed using electron plasmas in a Penning–Malmberg trap. They exploit the isomorphism between the two-dimensional Euler equations for an ideal fluid and the drift-Poisson equations for the plasma, where plasma density is the analog of vorticity. Perturbed elliptical vortex states are created using E x B strain flows, which are generated by applying voltages to electrodes surrounding the plasma. Measurements of spatial Landau damping (also called critical-layer damping) are in agreement with previous studies in the absence of an applied strain, where the damping is due to a resonance between the local fluid motion and the vortex oscillations. Interestingly, the damping rate does not change significantly over a wide range of applied strain rates. This can be accurately predicted from the initial vorticity profile, even though the resonant frequency is reduced substantially due to the applied strain. For higher amplitude perturbations, nonlinear trapping oscillations also exhibit behavior similar to the strain-free case. In principle, higher-order effects of the applied strain, such as separatrix crossing of peripheral vorticity and interactions with harmonics of the fundamental resonance, are expected to change the damping rate. However, this occurs only for conditions that are not realized in the experiments described here. Vortex-in-cell simulations are used to investigate the possible roles of these effects.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

Results of the KRUSTY Nuclear System Test

The Kilowatt Reactor Using Stirling TechnologY (KRUSTY) was a prototypic nuclear-powered test of a 5-kW(thermal) Kilopower space reactor. This paper presents results from the KRUSTY nuclear system test, which operated the power system at various temperatures and power levels for 28 consecutive hours. The testing showed that the system operated as expected and that the reactor is highly tolerant of possible failure conditions and transients. The key feature demonstrated was the ability of the reactor to load-follow the demand of the power conversion system. The thermal power of the test ranged from 1.5 to 5.0 kW(thermal), with a fuel temperature up to 880°C. Each 80-W(electric)–rated Stirling converter produced ~90 W(electric) at a component efficiency of ~35% and an overall system efficiency of ~25%.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2025

Subspace-Driven Learning for Anomaly Detection in Process Transients

Nuclear power plant (NPP) monitoring and diagnostic centers are actively investigating and implementing automated anomaly detection algorithms to help plants catch anomalies sooner, thereby preventing or reducing the duration of unexpected shutdowns. Current machine learning-based anomaly detection methods are expected to be highly effective during stable, full-power operations because NPPs typically operate as baseload power generators, meaning there are extensive operating data available from plant equipment. However, it is expected that anomaly detection methods will face significant challenges during transient conditions (i.e., when power output falls below full power) because plants only occasionally operate at these lower power levels, generating sparse transient operational data, and resulting in false alarms or missed detections. Here, to address this issue, transfer learning is used, which for this problem leverages knowledge (in the form of learned features) from stable, full-power operations to improve detection accuracy during transient conditions, even with limited data. In this effort, a novel subspace approach is developed to transfer a subset of the data features from full power operation to transients. This approach is validated through experiments using synthetic data and was found to outperform two baseline transfer learning approaches in anomaly detection performance across a range of amounts of transient data used in the training process.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗
DOE OSTI2024

Quantification of locked mode instability triggered by a change in confinement

Abstract This work presents the first analysis of the disruptive locked mode (LM) triggered by the dynamics of a confinement change. It shows that, under certain conditions, the LM threshold during the transient is significantly lower than expected from steady states. We investigate the sensitivity to a controlled n = 1 error field (EF) activated prior to the L-H transition in the COMPASS tokamak, at q 95 ∼ 3, β N ∼ 1, and using EF coils on the high-field side of the vessel. A threshold for EF penetration subsequent to the L-H transition is identified, which shows no significant trend with density or applied torque, and is an apparent consequence of the reduced intrinsic rotation of the 2/1 mode during this transient phase. This finding challenges the assumption made in theoretical and empirical works that natural mode rotation can be predicted by global plasma parameters and urges against using any parametric EF penetration scaling derived from steady-state experiments to define the EF correction strategy in the entire discharge. Furthermore, even at EFs below the identified penetration threshold, disruptive locking of sawtooth-seeded 2/1 tearing modes is observed after about 30% of L-H transitions without external torque.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Three-dimensional structure of hybrid magnetic skyrmions determined by neutron scattering

Magnetic skyrmions are topologically protected chiral spin textures which present opportunities for next-generation magnetic data storage and logic information technologies. The topology of these structures originates in the geometric configuration of the magnetic spins, more generally described as the structure. While the skyrmion structure is most often depicted using a two-dimensional projection of the three-dimensional (3D) structure, recent works have emphasized the role of all three dimensions in determining the topology and their response to external stimuli. Here, grazing-incidence small-angle neutron scattering and polarized neutron reflectometry are used to determine the 3D structure of hybrid skyrmions. The structure of the hybrid skyrmions, which includes a combination of Néel-like and Bloch-like components along their length, is expected to significantly contribute to their notable stability, which includes ambient conditions. To interpret the neutron scattering data, micromagnetic simulations of the hybrid skyrmions were performed, and the corresponding diffraction patterns were determined using a Born approximation transformation. The converged magnetic profile reveals the magnetic structure along with the skyrmion depth profile, including the thickness of the Bloch and Néel segments and the diameter of the core.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Learning Forecasts of Rare Stratospheric Transitions from Short Simulations

Abstract Rare events arising in nonlinear atmospheric dynamics remain hard to predict and attribute. We address the problem of forecasting rare events in a prototypical example, sudden stratospheric warmings (SSWs). Approximately once every other winter, the boreal stratospheric polar vortex rapidly breaks down, shifting midlatitude surface weather patterns for months. We focus on two key quantities of interest: the probability of an SSW occurring, and the expected lead time if it does occur, as functions of initial condition. These optimal forecasts concretely measure the event’s progress. Direct numerical simulation can estimate them in principle but is prohibitively expensive in practice: each rare event requires a long integration to observe, and the cost of each integration grows with model complexity. We describe an alternative approach using integrations that are short compared to the time scale of the warming event. We compute the probability and lead time efficiently by solving equations involving the transition operator, which encodes all information about the dynamics. We relate these optimal forecasts to a small number of interpretable physical variables, suggesting optimal measurements for forecasting. We illustrate the methodology on a prototype SSW model developed by Holton and Mass and modified by stochastic forcing. While highly idealized, this model captures the essential nonlinear dynamics of SSWs and exhibits the key forecasting challenge: the dramatic separation in time scales between a single event and the return time between successive events. Our methodology is designed to fully exploit high-dimensional data from models and observations, and has the potential to identify detailed predictors of many complex rare events in meteorology.

Finkel, Justin↗
DOE OSTI2023

Validation Simulations for Multi-Component Mixture Model [Slides]

Set up and ran a large, 3D, 3 component Rayleigh-Taylor Mixing Simulation: Match initial conditions from; Run with multiple mesh sizes to demonstrate convergence to expected mixing layer growth rate. Wrote and tested new FLAG capability to enforce a specified temporal temperature profile.

42 ENGINEERING↗
DOE OSTI2022

Longleaf Pine Seedlings Are Extremely Resilient to the Combined Effects of Experimental Fire and Drought

The longleaf pine ecosystem is dependent on frequent fire. Climate change is expected to influence moisture availability and it is unclear how drought conditions may interact with prescribed fire to influence management objectives associated with maintaining longleaf pine ecosystems. This study aimed to understand the impacts of drought, fire intensity and their interaction on P. palustris grass-stage seedlings. We used droughted and well-watered P. palustris seedlings burned at two different fire intensity levels at an indoor combustion facility. Needle fuel moisture content of burned seedlings was not different between droughted and well-watered groups. Mortality and resprouting only occurred at fire intensity levels exceeding 3.5 MJ m−2 in combination with drought that resulted in predawn water potentials more negative than −1.7 MPa. Our observations of minimal mortality after exposing P. palustris seedlings to a range of fire intensities in a burn lab contrast the higher mortality observed in field studies for the species. Compared to seedlings and saplings of Western US Pinus species, this study demonstrates that P. palustris is considerably more resistant to the combined effects of high surface fire intensity and drought.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1974

Deep flaws in weldments of aluminum and titanium

Surface flawed specimens of 2219-T87 and 6Al-4V STA titanium weldments were tested to determine static failure modes, failure strength, and fatigue flaw growth characteristics. Thicknesses selected for this study were purposely set at values where, for most test conditions, abrupt instability of the flaw at fracture would not be expected. Static tests for the aluminum weldments were performed at room, LN2 and LH2 temperatures. Titanium static tests for tests were performed at room and LH2 temperatures. Results of the static tests were used to plot curves relating initial flaw size to leakage- or failure-stresses (i.e. "failure" locus curves). Cyclic tests, for both materials, were then performed at room temperature, using initial flaws only slightly below the previously established failure locus for typical proof stress levels. Cyclic testing was performed on pairs of specimens, one with and one without a simulated proof test cycle. Comparisons were made then to determine the value and effect of proof testing as affected by the various variables of proof and operating stress, flaw shape, material thickness, and alloy.

Masters, J. N.↗
NASA NTRS1980

Increased capability gas generator for Space Shuttle APU. Development/hot restart test report

The design, fabrication, and testing of an increased capability gas generator for use in space shuttles are described. Results show an unlimited hot restart capability in the range of feed pressures from 400 psi to 80 psi. Effects of vacuum on hot restart were not addressed, and only beginning-of-life bed conditions were tested. No starts with bubbles were performed. A minimum expected life of 35 hours or more is projected, and the design will maintain a surface temperature of 350 F or more.

Source record↗
NASA NTRS1981

Operational LANDSAT remote sensing system development

The reduction of $121.6 million dollars from NOAA's LANDSAT development program for FY 1982, and the shortened time period for transferring remote sensing technology to the private sector resulted in changes in the Agency's plans for managing the operational system. Proposed legislation for congressional consideration or enactment to establish conditions under which this private sector transfer will occur, and the expected gradual rise in the price of data products are discussed. No money exists for capital investment and none is projected for investing in an operational data handling system for the LANDSAT D satellite. Candidates knowledgeable of various aspects of the needs and uses of remote sensing are urged to consider participation in NOAA's advisory committee.

Cotter, D. J.↗
NASA NTRS1982

Water as a probe of star-forming regions

Preliminary calculations employing statistical equilibrium techniques were carried out to determine brightness temperatures of water transitions occurring in the submillimeter band. The interesting candidates appear to be the 325 GHz, 380 GHz, and 448 GHz transitions, they are compared with the 183 GHz and 380 GHz transitions observed in the Orion Kleinmann-Low nebula and the combined results seem to be consistent with H2 densities of 100,000 -1 million cm-3 and a water column density of approximately 10 to 18th power. This implies a relative abundance of approximately 0.00001 which means that water may be about one twentieth of CO. In addition, it was found that for the conditions of the Orion plateau source, the 448 GHz line is expected to be a mild maser.

Rodriguez-Kuiper, E. N.↗
NASA NTRS1987

The lambda point experiment in microgravity

An experiment for performing high-resolution measurements of the heat capacity singularity at the lambda point of helium in microgravity conditions is described. By obtaining such measurements in space, it is expected that the intrinsic distortion of the transition would be reduced by at least two orders of magnitude, allowing the theory of cooperative phase transitions to be more effectively tested. Technology developments for the lambda point experiment include a new high-resolution thermometer, an advanced thermal control system, and a reusable flight-qualified superfluid helium dewar.

Lipa, J. A.↗
NASA NTRS1988

Leakage predictions for Rayleigh-step, helium-purge seals

Rayleigh-step, helium purge, annular shaft seals, studied for use in liquid oxygen turbopumps, generate a hydrodynamic force that enables the seal to follow shaft perturbations. Hence, smaller clearances can be used to reduce seal leakage. FLOWCAL, a computer code developed by Mechanical Technology Incorporated, predicts gas flow rate through an annular seal with an axial pressure gradient. Analysis of a 50-mm Rayleigh-step, helium-purge, annular seal showed the flow rate increased axial pressure gradient, downstream pressure, and eccentricity ratio. Increased inlet temperature reduced leakage. Predictions made at maximum and minimum clearances (due to centrifugal and thermal growths, machining tolerances and + or - 2 percent uncertainty in the clearance measurement) placed wide boundaries on expected flow rates. The widest boundaries were set by thermal growth conditions. Predicted flow rates for a 50-mm Rayleigh-step, helium-purge, annular seal underestimated measured flow rates by three to seven times. However, the analysis did accurately predict flow rates for choked gas flow through annular seals when compared to flow rates measured in two other independent studies.

Proctor, Margaret P.↗