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At least 1,063 records · Page 59

Continuous Processing of Carbon Foam Products Made from Coal at Atmospheric Pressure

The main goal of the project was to create a continuous manufacturing process for carbon foam that operates at atmospheric pressure and can generate well-formed carbon foam panels and lightweight aggregates. This objective was accomplished and has enabled a platform where carbon foam products can be manufactured at significantly reduced cost and cycle time relative to the conventional high-pressure batch process, which in turn can enable the manufacture of much larger volumes of carbon foam. All these features should enable carbon foam to enter much larger markets and create meaningful demand for U.S. coal. Carbon foam panels and aggregate both consisted of at least 70 weight percent carbon per program requirements (typical was over 90-wt%), and at least 51 weight percent of the carbon was to be coal derived (typical was over 90-wt% carbon was from coal). Analyses regarding life cycle, technoeconomics, and final technological gaps have been documented in separate reports. This final report documents the methods used to attain the main goal and describes the technical results.

01 COAL, LIGNITE, AND PEAT↗

High-fidelity wind farm simulation methodology with experimental validation

The complexity and associated uncertainties involved with atmospheric-turbine-wake interactions produce challenges for accurate wind farm predictions of generator power and other important quantities of interest (QoIs), even with state-of-the-art high-fidelity atmospheric and turbine models. A comprehensive computational study was undertaken with consideration of simulation methodology, parameter selection, and mesh refinement on atmospheric, turbine, and wake QoIs to identify capability gaps in the validation process. For neutral atmospheric boundary layer conditions, the massively parallel large eddy simulation (LES) code Nalu-Wind was used to produce high-fidelity computations for experimental validation using high-quality meteorological, turbine, and wake measurement data collected at the Department of Energy/Sandia National Laboratories Scaled Wind Farm Technology (SWiFT) facility located at Texas Tech University’s National Wind Institute. The wake analysis showed the simulated lidar model implemented in Nalu-Wind was successful at capturing wake profile trends observed in the experimental lidar data.

17 WIND ENERGY↗

Classifying thermodynamic cloud phase using machine learning models

Vertically resolved thermodynamic cloud-phase classifications are essential for studies of atmospheric cloud and precipitation processes. The Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Thermodynamic Cloud Phase (THERMOCLDPHASE) value-added product (VAP) uses a multi-sensor approach to classify the thermodynamic cloud phase by combining lidar backscatter and depolarization, radar reflectivity, Doppler velocity, spectral width, microwave-radiometer-derived liquid water path, and radiosonde temperature measurements. The measured pixels are classified as ice, snow, mixed phase, liquid (cloud water), drizzle, rain, and liq_driz (liquid+drizzle). We use this product as the ground truth to train three machine learning (ML) models to predict the thermodynamic cloud phase from multi-sensor remote sensing measurements taken at the ARM North Slope of Alaska (NSA) observatory: a random forest (RF), a multi-layer perceptron (MLP), and a convolutional neural network (CNN) with a U-Net architecture. Evaluations against the outputs of the THERMOCLDPHASE VAP with 1 year of data show that the CNN outperforms the other two models, achieving the highest test accuracy, F1 score, and mean intersection over union (IOU). Analysis of ML confidence scores shows that ice, rain, and snow have higher confidence scores, followed by liquid, while mixed, drizzle, and liq_driz have lower scores. Feature importance analysis reveals that the mean Doppler velocity and vertically resolved temperature are the most influential data streams for ML thermodynamic cloud-phase predictions. Lidar measurements exhibit lower feature importance due to rapid signal attenuation caused by the frequent presence of persistent low-level clouds at the NSA site. The ML models' generalization capacity is further evaluated by applying them at another Arctic ARM site in Norway using data taken during the ARM Cold-Air Outbreaks in the Marine Boundary Layer Experiment (COMBLE) field campaign. The models demonstrated similar performance to that observed at the NSA site. Finally, we evaluate the ML models' response to simulated instrument outages and signal degradation and show that a CNN U-Net model trained with input channel dropouts performs better when input fields are missing.

ARM Aerial Facility↗

Thermodynamic Cloud Phase Classifications Using Machine Learning at NSA and ANX

Vertically resolved thermodynamic cloud phase classifications are essential for studies of atmospheric cloud and precipitation processes. The Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) THERMOCLDPHASE Value-Added Product (VAP) uses a multi-sensor approach to classify thermodynamic cloud phase by combining lidar backscatter and depolarization, radar reflectivity, Doppler velocity, spectral width, microwave radiometer-derived liquid water path, and radiosonde temperature measurements. The measured voxels are classified as ice, snow, mixed-phase, liquid (cloud water), drizzle, rain, and liq_driz (liquid+drizzle). We use this product as the ground truth to train three machine learning (ML) models to predict the thermodynamic cloud phase from multi-sensor remote sensing measurements taken at the ARM North Slope of Alaska (NSA) observatory: a random forest (RF), a multilayer perceptron (MLP), and a convolutional neural network (CNN) with a U-Net architecture. Evaluations against the outputs of the THERMOCLDPHASE VAP with one year of data show that the CNN outperforms the other two models, achieving the highest test accuracy, F1-score, and mean Intersection over Union (IOU). Analysis of ML confidence scores shows ice, rain, and snow have higher confidence scores, followed by liquid, while mixed, drizzle, and liq_driz have lower scores. Feature importance analysis reveals that the mean Doppler velocity and vertically resolved temperature are the most influential datastreams for ML thermodynamic cloud phase predictions. The ML models’ generalization capacity is further evaluated by applying them at another Arctic ARM site in Norway using data taken during the ARM Cold-Air Outbreaks in the Marine Boundary Layer Experiment (COMBLE) field campaign. Finally, we evaluate the ML models’ response to simulated instrument outages and signal degradation.

54 ENVIRONMENTAL SCIENCES↗

Extraterrestrial platinum group nuggets in deep-sea sediments

A previously unrecognized property of iron cosmic spheres is reported. The most common spheres larger than 300 microns do not, in fact, contain FeNi metal cores, but instead contain a micrometer-sized nugget composed almost entirely of platinum group elements. These elements appear to have been concentrated by the oxidation of molten meteoritic metal during atmospheric entry. This process is critically dependent on the relative abundance of oxygen in the atmosphere, and the first appearance of the nuggets in the geological record may provide a marker indicating when the oxygen abundance attained half of its present level.

Brownlee, D. E.↗

Vertical transport in the atmosphere: Measurement capabilities and requirements of VHF radars, part 1.6A

Mass exchange, mixing on transport in the atmosphere involves reversible processes, i.e., any kind of organized motions such as wave and large scale flows, and nonreversible processes, i.e., molecular and turbulent diffusion. Without evaluating in detail the relative efficiency of these processes, an attempt is made to summarize those phenomena which can be qualitatively (and eventually also quantitatively) observed with VHF radars. Only mixing in the vertical direction is considered, since this appears to be the essential part of transport processes to which VHF radars can contribute better understanding. Mixing processes in the troposphere are discussed. Possible contributions of VHF radars to the study the mass exchange processes between the troposphere and stratosphere are studied. Transport in the middle atmosphere is briefly summarized, since it is in principle similar to transport in the lower atmosphere.

Rottger, J.↗

The deceleration of infalling plasma in magnetized neutron star atmospheres - Nonisothermal atmospheres

This paper examines the deceleration of accreting material in the strongly magnetized plasma atmosphere of an X-ray pulsar, for accretion rates less than 0.1 times the Eddington flux. The previous work on accretion, flow deceleration is extended to nonisothermal atmospheres. A rough model of radiative processes in neutron star atmospheres bombarded by accreting material is used to calculate the atmosphere's temperature and density profiles. The atmospheric structure and the accretion flow stopping depth are computed iteratively. For cases where the infall velocity is close to the free-fall velocity, a simple prescription for an equivalent single temperature, T(iso), is given. It is found that the plasma deceleration is close to stopping in a homogeneous, isothermal atmosphere at T(iso). Exceptions to this result occur for small infall velocities.

Miller, Guy↗

Radiative-Convective Processes in Regulating Tropical Ocean-Atmosphere

Relationship between sea surface temperature (SST) and cloud/water vapor reveals important information about radiative-climate feedbacks. Many previous studies have found that cloud amount and SST are positively correlated for SST between 28-29.5 C, for SST greater than 29.5 C, cloud amount actually decreases with increasing SST. The breakdown of SST-cloud correlation at 29.5 C was suggested to be related to the formation of localized hot spots with very high SST due to increased solar radiation in regions of strong subsidence forced by convection elsewhere. In this study, the breakdown is related to the radiative cooling in the subsidence regime over the cold pool surrounding the warm pool. We show model and observational evidence that radiative cooling over the cold pool limits the strength of SST-induced tropical circulation. As a result, occurrence of convection is also limited when SST contrast between the warm pool and cold pool is large.

Sui, C.-H.↗

Flammability: A Review and Analysis

With its founding in 1975, Committee G-4 of the American Society for Testing and Materials (ASTM) embarked on the process of defining the flammability of metallic materials in oxygen-enriched atmospheres. In this process, they are joined by the National Aeronautics and Space Administration (NASA), the National Fire Protection Association (NFPA), and the Compressed Gas Association (CGA). Although none of these organizations has explicitly defined flammability, the following definitions and statements provide a composite understanding of the concept: 1. "This Standard Guide (ASTM G94-92) is concerned primarily with the properties of a material associated with its relative susceptibility to ignition and propagation of combustion." 2. "A material is considered flammable at the maximum use pressure if at least one sample burns more than 6 in. (15.2 cm). At least, five samples must be tested." NASA 3. "Flammable: Capable, when ignited of maintaining combustion under the specified environmental conditions." NFPA 53. 4. "Combustion: A complex sequence of chemical reactions between a fuel and an oxidant accompanied by the evolution of heat, and usually, the emission of light." NFPA 53. and 5. "A safe oxygen-piping transmission or distribution system is one that is designed and installed in accordance with all applicable codes and regulations for the service conditions and locations involved and further meets the special requirements for oxygen services." CGA-G4 Flammability thus equates, after ignition, to propagation of combustion, synonymous with steady state burning, under specified environmental conditions. Properties for which quantitative values are given in ASTM G94-92 and which are used to describe metals flammability consistent with the concept of steady state burning are either system independent properties, such as, enthalpies of reaction, burn ratios, flame temperatures, thermal conductivity, and heat release; or system dependent properties, such as, oxygen index, promoted combustion, threshold pressure and burn rates. Each property is reviewed and analyzed as to whether it provides an absolute or relative measure for flammability. It is shown that burn ratio, as applied to the actual steady state combustion condition, approaches the desired absolute measure of flammability.

Wilson, D. Bruce↗

Evaluation of the Sensor Data Record from the Nadir Instruments of the Ozone Mapping Profiler Suite (OMPS)

This paper evaluates the first 15 months of the Ozone Mapping and Profiler Suite (OMPS) Sensor Data Record (SDR) acquired by the nadir sensors and processed by the National Oceanic and Atmospheric Administration Interface Data Processing Segment. The evaluation consists of an inter-comparison with a similar satellite instrument, an analysis using a radiative transfer model, and an assessment of product stability. This is in addition to the evaluation of sensor calibration and the Environment Data Record product that are also reported in this Special Issue. All these are parts of synergetic effort to provide comprehensive assessment at every level of the products to ensure its quality. It is found that the OMPS nadir SDR quality is satisfactory for the current Provisional maturity. Methods used in the evaluation are being further refined, developed, and expanded, in collaboration with international community through the Global Space-based Inter-Calibration System, to support the upcoming long-term monitoring.

validation↗

Climate-change effects on soils: Accelerated weathering, soil carbon and elemental cycling

Climate change [i.e., high atmospheric carbon dioxide (CO2) concentrations (≥400 ppm); increasing air temperatures (2-4°C or greater); significant and/or abrupt changes in daily, seasonal, and inter-annual temperature; changes in the wet/dry cycles; intensive rainfall and/or heavy storms; extended periods of drought; extreme frost; heat waves and increased fire frequency] is and will significantly affect soil properties and fertility, water resources, food quantity and quality, and environmental quality. Biotic processes that consume atmospheric CO2, and create organic carbon (C) that is either reprocessed to CO2 or stored in soils are the subject of active current investigations, with great concern over the influence of climate change. In addition, abiotic C cycling and its influence on the inorganic C pool in soils is a fundamental global process in which acidic atmospheric CO2 participates in the weathering of carbonate and silicate minerals, ultimately delivering bicarbonate and Ca2+ or other cations that precipitate in the form of carbonates in soils or are transported to the rivers, lakes, and oceans. Soil responses to climate change will be complex, and there are many uncertainties and unresolved issues. The objective of the review is to initiate and further stimulate a discussion about some important and challenging aspects of climate-change effects on soils, such as accelerated weathering of soil minerals and resulting C and elemental fluxes in and out of soils, soil/geo-engineering methods used to increase C sequestration in soils, soil organic matter (SOM) protection, transformation and mineralization, and SOM temperature sensitivity. This review reports recent discoveries, identifies key research needs, and highlights opportunities offered by the climate-change effects on soils.

accelerated weathering↗

Overview of different aspects of climate change effects on soils

Climate change [i.e., high atmospheric carbon dioxide (CO 2 ) concentrations (≥400 ppm); increasing air temperatures (2-4°C or greater); significant and/or abrupt changes in daily, seasonal, and inter-annual temperature; changes in the wet/dry cycles; intensive rainfall and/or heavy storms; extended periods of drought; extreme frost; heat waves and increased fire frequency] is and will significantly affect soil properties and fertility, water resources, food quantity and quality, and environmental quality. Biotic processes that consume atmospheric CO 2 and create organic carbon (C) that is either reprocessed to CO 2 or stored in soils, are the subject of active current investigations with great concern over the influence of climate change. In addition, abiotic C cycling and its influence on the inorganic C pool in soils is a fundamental global process in which acidic atmospheric CO 2 participates in the weathering of carbonate and silicate minerals, ultimately delivering bicarbonate and Ca 2 + or other cations that precipitate in the form of carbonates in soils or are transported to the rivers, lakes, and oceans. Soil responses to climate change will be complex, and there are many uncertainties and unresolved issues. The objective of the review is to initiate and further stimulate a discussion about some important and challenging aspects of climate-change effects on soils, such as accelerated weathering of soil minerals and resulting C and elemental fluxes in and out of soils, soil/geo-engineering methods used to increase C sequestration in soils, soil organic matter (SOM) protection, transformation and mineralization, and SOM temperature sensitivity. This review reports recent discoveries and identifies key research needs required to understand the effects of climate change on soils.

54 ENVIRONMENTAL SCIENCES↗

Upper tropospheric water vapor: A field campaign of two Raman lidars, Airborne hygrometers, and Radiosondes

Water vapor in the atmosphere plays an important role in radiative transfer and the process of radiative balance so critical for understanding global change. It is the principal ingredient in cloud formation, one of the most difficult atmospheric processes to model, and the most variable component of the Earth-atmosphere albedo. And as a free molecule, it is the most active infrared absorber and emitter, thus, the most important greenhouse gas. The radiative impact of water vapor is important at all levels of the atmosphere. Even though moisture decreases by several orders-of-magnitude from the Earth's surface to the tropopause, recent research has shown that, from a radiative standpoint, a small percentage change in water vapor at any level is nearly equivalent. Therefore accurate and precise measurements of this important atmospheric constituent are needed at all levels to evaluate the full radiative impact. The need for improved measurements in the upper troposphere is particularly important because of the generally hostile (very dry and cold) conditions encountered. Because of the importance of water vapor to the understanding of radiative transfer, the Department of Energy's Atmospheric Radiation Measurements (ARM) program initiated a series of measurement campaigns at the Cloud And Radiation Testbed (CART) site in Oklahoma, especially focused on atmospheric water vapor. Three water vapor intensive observation period (water vapor IOP) campaigns were planned. Two of the water vapor IOP campaigns have been completed: the first IOP was held during the fall of 1996 with a focus on boundary layer water vapor measurements, and the second was conducted during the fall of 1997 with a focus on both boundary layer moisture e and moisture in the upper troposphere. This paper presents a review of the intercomparisons of water vapor measurements in the upper troposphere aquired during the second water vapor IOP. Data to be presented include water vapor measurements ements from: two Raman Lidars, the NASA Goddard Scanning Raman Lidar (SRL) and the CART Raman Lidar (CARL), a number of Vaisala radiosondes launched during the IOP campaign, and a dew point hygrometer flown on the University of North Dakota Cessna Citation Aircraft.

Melfi, S. Harvey↗

Regime dependence of cloud condensate variability observed at the Atmospheric Radiation Measurement Sites

Microphysical processes and cloud–radiation interaction occur on spatial scales of variability smaller than those represented explicitly in global weather forecasting and climate models. It is therefore necessary to parametrize the unresolved heterogeneity of humidity and cloud condensate in order to predict process rates accurately. Ground‐based observations from the Atmospheric Radiation Measurement sites located in various climatic regions of the world provide a source of high‐temporal‐resolution observations of cloud condensate. A number of different retrieval products for cloud condensate are assessed for the different geographical regions, years and seasons. The retrieval reliability varies with cloud type, but for cloud categories largely unaffected by precipitation a comparison across sites and longer time periods is possible. These observations confirm previously documented variability behaviour as a function of cloud fraction, but also reveal a systematic regime dependence that is not captured by existing parametrizations. Condensate variability measured as a fractional standard deviation (FSD) in warm boundary‐layer clouds is greater in the Tropics than in mid and high latitudes for scenes with comparable cloud type and fraction, with the observed FSD varying from 1.2 in the Tropics to 0.4 in the Arctic. A parametrization of the FSD of cloud liquid condensate based on the grid‐box mean total water amount and cloud fraction is formulated and shown to capture the observed range of FSD values better across different geographical sites and different seasons. The regime dependence of FSD for cirrus cloud is less pronounced than that for liquid clouds and is found largely to agree with FSD values previously derived from satellite observations.

Ahlgrimm, Maike↗

Processing AIRS Scientific Data Through Level 2

The Atmospheric Infrared Spectrometer (AIRS) Science Processing System (SPS) is a collection of computer programs, denoted product generation executives (PGEs), for processing the readings of the AIRS suite of infrared and microwave instruments orbiting the Earth aboard NASA s Aqua spacecraft. AIRS SPS at an earlier stage of development was described in "Initial Processing of Infrared Spectral Data' (NPO-35243), NASA Tech Briefs, Vol. 28, No. 11 (November 2004), page 39. To recapitulate: Starting from level 0 (representing raw AIRS data), the PGEs and their data products are denoted by alphanumeric labels (1A, 1B, and 2) that signify the successive stages of processing. The cited prior article described processing through level 1B (the level-2 PGEs were not yet operational). The level-2 PGEs, which are now operational, receive packages of level-1B geolocated radiance data products and produce such geolocated geophysical atmospheric data products such as temperature and humidity profiles. The process of computing these geophysical data products is denoted "retrieval" and is quite complex. The main steps of the process are denoted microwave-only retrieval, cloud detection and cloud clearing, regression, full retrieval, and rapid transmittance algorithm.

Oliphant, Robert↗

Oxidation–reduction processes upon interaction of aluminum oxide melt with molybdenum and tungsten in a hydrogen-containing atmosphere

A thermodynamic analysis of the processes occurring in the Мо–W–Al{sub 2}O{sub 3} system at T = 2400 K and a total pressure of 1 bar, set by controlled reducing Ar + H{sub 2} atmosphere, has been performed. It is found that the basic components of the system do not interact directly, although may be actively involved in chemical reactions with participation of other components to undergo numerous cyclic oxidation–reduction processes. Particular attention is paid to the processes involving such chemically active reagents as Н{sub 2}O{sub 2}, HO{sub 2}, H{sub 2} (H), gaseous Al, and its hydrides (AlH, AlH{sub 2}, AlH{sub 3}).

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗