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At least 1,063 records · Page 59

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NASA NTRS1976

Rb, Sr and strontium isotopic composition, K/Ar age and large ion lithophile trace element abundances in rocks and glasses from the Wanapitei Lake impact structure

Shock metamorphosed rocks and shock-produced melt glasses from the Wanapitei Lake impact structure have been examined petrographically and by electron microprobe. Eleven clasts exhibiting varying degrees of shock metamorphism and eight impact-produced glasses have been analyzed for Rb, Sr and Sr isotopic composition. Five clasts and one glass have also been analyzed for large ion lithophile (LIL) trace element abundances including Li, Rb, Sr, and Ba and the REE's. The impact event forming the Wanapitei Lake structure occurred 37 m.y. ago based on K/Ar dating of glass and glassy whole-rock samples. Rb/Sr isotopic dating failed to provide a meaningful whole-rock or internal isochron. The isotopic composition of the glasses can be explained by impact-produced mixing and melting of metasediments.

Winzer, S. R.↗

NASA NTRS1976

Isotopic abundances of Hg in mercury stars inferred from the Hg II line at 3984 A

Wavelengths of the Hg II absorption feature at 3984 A in 30 Hg stars are distributed uniformly from the value for the terrestrial mix to a value that corresponds to nearly pure Hg-204. The wavelengths are correlated loosely with effective temperatures inferred from Q(UBV). Relative isotopic abundances derived from partially resolved profiles of the 3984-A line in iota CrB, chi Lup, and HR 4072 suggest that mass-dependent fractionation has occurred in all three stars. It is supposed that such fractionation occurs in all Hg stars, and a scheme whereby isotopic compositions can be inferred from a comparison of stellar wavelengths and equivalent widths with those calculated for a family of fractionated isotopic mixes. Theoretical profiles calculated for the derived isotopic composition agree well with high-resolution interferometric profiles obtained for three of the stars.

White, R. E.↗

NASA NTRS1976

The carbon monoxide abundance in interstellar clouds

The steady-state abundance of carbon monoxide in interstellar clouds is calculated as a function of optical depth, density, and temperature. The molecular reactions which lead to CO can be initiated by the following ion-molecule reactions: H(+) + O yields O(+) + H, C(+) + H2 yields CH2(+) + a photon, and H3(+) + C and O. As the ultraviolet radiation field is attenuated, C(+) is transformed primarily into CO and C I. There are characteristic column densities for the transition to CO corresponding to the optical depths for attenuating this field at different wavelengths. For thick, low-temperature clouds the attenuation of the fields which ionize carbon, sulfur, and heavy metals is important for CO production initiated by H3(+). Complete conversion to CO does not necessarily occur, and considerable neutral carbon may be expected even in optically thick clouds. Comparison of integrated column densities of CO with extinction are in reasonable agreement with observations.

Langer, W.↗

NASA NTRS1976

The abundances of H-3 and C-14 in the solar wind

Tritium is measured as a function of depth in a Surveyor 3 sample. The upper limit for solar-wind-implanted tritium gives a H-3/H-1 limit for the solar wind of 1 part in one hundred billion. The temperature release patterns of C-14 from lunar soils are measured. The C-14 release patterns from surface soils differ from a trench-bottom soil and give evidence for the presence of C-14 in the solar wind with a C-14/H-1 ratio of approximately 4 parts in one hundred billion. The implications of these radionuclide abundances in the solar wind are discussed.

Fireman, E. L.↗

NASA NTRS1977

Interpretation of high-resolution spectra of Mars. IV - New calculations of the CO abundance

Recent measurements of the half-widths of lines, pressure broadened by CO2 at a temperature of 200 K, in the 0-2 band of CO are used to reestimate the amount of CO in the atmosphere of Mars. Assuming an air-mass factor of 3.5, the amount of CO in a vertical path through the Martian atmosphere is estimated to be approximately 5.6 cm-atm. A comparison of CO and O2 abundances indicates that there is about 3.4 times as much molecular oxygen on Mars than expected. It is suggested that the extra oxygen may come from photodissociation of water.

Young, L. D. G.↗

NASA NTRS1976

Chemical abundances in the atmospheres of the giant planets and their satellites

Recent results on the composition and structure of the atmospheres of Jupiter, Saturn, Uranus, Neptune, Pluto, and their satellites are summarized with an orientation toward topics of particular interest to the subject of exobiology. The need for an accurate Jovian temperature profile is noted, and current values are given for the known H2, NH3, and CH4 abundances of each planet as well as Titan and Triton. Trace constituents and chromophores in the Jovian atmosphere are discussed, the role of comets as a link between chemical evolution in the solar system and the chemistry of the interstellar medium is examined, and some features in the IR spectrum of Titan are interpreted. The hope is expressed that Titan will remain a useful proving ground for theories of low-temperature abiogenic organic-compound production

Owen, T.↗

NASA NTRS1977

A reexamination of solar upper photosphere models, the calcium abundance, and empirical damping parameters

A general iterative method is described for constructing thermal models of the solar photosphere consistent with observed strong and weak lines of Ca I and Ca II. Calibrations of the solar calcium abundance and the van der Waals parameter for important Ca I and Ca II lines are obtained using plane-parallel largely LTE model atmospheres, and these thermal models are modified for better fits to the measured Ca II H and K inner wing shapes. Possible sources of error in this semiempirical approach are evaluated. The derived hydrogen van der Waals broadening is compared with theoretical estimates of that broadening as well as with experimental measurements of the helium broadening

Ayres, T. R.↗

NASA NTRS1977

The abundance of boron in Vega and Sirius

High-resolution (0.05 A) Copernicus observations of the 1362.46-A B II resonance line in Sirius and Vega are analyzed. In Vega, this line is found to be strong, broad, asymmetric, and blended with another line; it is not observed in Sirius. Angular velocities of 18-20 km/s for Vega and 10 km/s for Sirius are determined. A search for subordinate lines of B II reveals no such features in the Sirius spectrum and the possible weak presence of two unblended lines in that of Vega. The cause of the asymmetry of the B II blend in Vega is investigated, line-profile calculations are performed for Sirius, and the B content of Vega is obtained by means of an LTE synthesis of the B II blend as well as a non-LTE computation of the B II line alone. It is concluded that Sirius is deficient in B relative to Vega by a factor of at least 20. The Be abundances of both stars are also examined in relation to the galactic-cosmic-ray spallation theory for the origin of light elements.

Praderie, F.↗

NASA NTRS1977

Correlation between nickel and sulfur abundances in Orgueil phyllosilicates

Sympathetic variations in nickel and sulfur abundances, on a scale of micrometers, in Orgueil phyllosilicates apparently reproduce similar correlations among matrices of different carbonaceous chondrites. In Orgueil this effect probably results from aqueous alteration of a Ni-Si-bearing phase on the parent body.

Kerridge, J. F.↗

NASA NTRS1977

Studies of chemical abundances in the outer solar system

Ground-based observations and the Pioneer 10 mission have led to new discoveries and revisions of previous ideas about the outer solar system. Among these are the discovery of atmospheres on lo and Ganymede, emission from sodium and hydrogen in a cloud around lo, and the presence of acetylene, ethane, and phosphine in the atmosphere of Jupiter. Titan, the largest satellite of Saturn, continues to be an extremely interesting and baffling object, clearly very different in composition from the bodies we are familiar with in the inner solar system; this is also true of Ganymede and Callisto. New data on the abundances of methane and hydrogen in the atmospheres of Uranus and Neptune suggest that the values of C/H in these atmospheres may be much lower than had been previously thought. This result reinforces the apparent compositional differences between these two planets and Jupiter and Saturn, whose atmospheres exhibit a near-solar value for this ratio.

Owen, T.↗

NASA NTRS1977

Mars and earth - Origin and abundance of volatiles

An investigation is conducted concerning the factors which are responsible for the tenuous nature of the Martian atmosphere in comparison to the terrestrial atmosphere, taking into account new data obtained in connection with the Viking missions. It is found that Mars was poor in volatiles from the start and fell further behind earth by less complete outgassing, by extensive retrapping, and by the partial loss of lighter gases. Attention is given to noble gases on earth and Mars, the condensation of noble gases and other volatiles, the sources of earth's volatiles, the bulk composition of earth, the release of volatiles from earth, clues to the volatile endowment of Mars, an abundance table for Mars, a comparison of terrestrial and Martian conditions, isotopic data on noble gases, xenon-129 on Mars and earth, possibilities concerning the loss of an early Martian atmosphere, the evolution of the atmosphere of Mars, conditions in the case of planet Venus, and the reasons for the poorness of small planets in volatiles.

Anders, E.↗

NASA NTRS1977

The abundances of ammonia in the atmospheres of Jupiter, Saturn, and Titan

An investigation of low-resolution ratio spectra of Jupiter, Saturn, and Titan in the region 5400-6500 A has permitted new evaluations of ammonia absorption bands. The distribution of ammonia over the disk of Jupiter is very inhomogeneous. The carbon-to-nitrogen ratio is distinctly different from the solar value, but this is probably a result of uneven mixing of methane and ammonia, as suggested previously by Kuiper (1952), rather than a compositional anomaly. The abundancy of ammonia on Saturn also shows spatial variations, but appears constant in time over a 3-yr period. Two weak, unidentified absorptions were discovered in the red region of Titan's spectrum, in the absence of any detectable ammonia.

Woodman, J. H.↗

NASA NTRS1977

Ozone abundances in the lower mesosphere deduced from backscattered solar radiances

Backscatter ultraviolet data obtained by the Explorer E satellite imply very large ozone column abundances above 56 km in the tropics during mid-day. The number of molecules in a vertical column decays by a factor of 2-3 after the solar zenith angle exceeds 75 deg in the evening. An increase of similar magnitude occurs after sunrise. Such behavior implies the presence of a greater source of odd oxygen than is included in current photochemical theories. Ozone profiles deduced between altitudes of 50 and 62 km when the solar zenith angle exceeds 80 deg are in reasonable agreement with past rocket results.

Frederick, J. E.↗

NASA NTRS1978

Nitrogen abundances and isotopic compositions in stony meteorites

Nitrogen contents range from a few parts per million in ordinary chondrites and achondrites to several hundred parts per million in enstatite chondrites and carbonaceous chondrites. Four major isotopic groups are recognized: (1) C1 and C2 carbonaceous chondrites, (2) enstatite chondrites, (3) C3 chondrites, and (4) ordinary chondrites. The major variations are primary, representing isotopic abundances established at the time of condensation and accretion. Secondary processes, such as spallation reactions, solar wind implantation and metamorphic loss may cause small but observable isotopic variations in particular cases. The large isotopic difference between enstatite chondrites and carbonaceous chondrites cannot be accounted for by equilibrium condensation from a homogeneous nebular gas, and requires either unusually large kinetic effects, or a temporal or spatial variation of isotopic composition of the nebula. Nitrogen isotopic heterogeneity in the nebula due to nuclear processes has not been firmly established, but may be required to account for the large variations found within the Allende and Leoville meteorites. The unique carbonaceous chondrite, Renazzo, also requires a special source. It is not yet possible, from the meteoritic data, to establish the mode of accretion of nitrogen onto the primitive earth.

Kung, C.-C.↗

NASA NTRS1978

The abundance of carbon monoxide in Jupiter

Spectra of Jupiter in the 5-micron window region have been acquired. From these it is deduced that (1) the presence of CO in Jupiter is verified; (2) the column abundance is approximately 0.016 cm amagat (identical to 4.3 by 10 to the 17th power mol/sq cm); and (3) the CO is probably nonuniformly mixed in the atmosphere, being concentrated into the stratosphere.

Beer, R.↗

NASA NTRS1978

Implications of abundant hygroscopic minerals in the Martian regolith

Converging lines of evidence suggest that a significant portion of the Martian surface fines may consist of salts and smectite clays. Salts can form stoichiometric hydrates as well as eutectic solutions with depressed freezing points; clays contain bound water of constitution and adsorb significant quantities of water from the vapor phase. The formation of ice may be suppressed by these minerals in some regions on Mars, and their presence in abundance would imply important consequences for atmospheric and geologic processes and the prospects for exobiology.

Clark, B. C.↗

NASA NTRS1978

The mean mass of the abundant cosmic-ray nuclei from boron to silicon at 1.2 GeV per atomic mass unit

Results are presented for an investigation of cosmic-ray isotopic composition in which a balloon-borne instrument was used to perform an isotopic analysis of the abundant elements from B through Si in the energy range from 1.0 to 1.6 GeV/amu. The technique employed, which depends on the effect of earth's magnetic field on incoming cosmic rays, and reduction of the observational data are described in detail. Mean masses of the elements B, C, N, O, Ne, Mg, and Si are extracted from normalized Cerenkov spectra and evaluated in terms of the 'leaky box' model of galactic propagation and confinement. The implications of the results for cosmic-ray sources are shown to be consistent with the nucleosynthesis of certain isotopes in the cosmic rays in explosive carbon burning under the conditions of peak temperature, density, and neutronization expected in an explosion of a massive highly evolved star. The possibility of alternate interpretations is noted.

Dwyer, R.↗

NASA NTRS1978

The EUV flux inferred from AE-C He/+/ abundances

The ionization rate of helium in the thermosphere is inferred from He(+) abundances determined by instrumentation on the Atmosphere Explorer-C satellite. The inferred ionization rate is independent of the particular geophysical parameters of the thermosphere for solar zenith angles less than 80 deg and altitudes between 280 and 360 km. The ionization rate is consistent with a value calculated from the EUV flux of Hinteregger (1976) below 504 A.

Oppenheimer, M.↗