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At least 1,063 records · Page 59

Polyatomic molecule vibrations

Polyatomic molecule vibrations are analyzed as harmonic vibrations along normal coordinates. The energy eigenvalues are found for linear and nonlinear symmetric triatomic molecules for valence bond models of the potential function with arbitrary coupling coefficients; such models can usually be fitted to observed energy levels with reasonably good accuracy. Approximate normal coordinates for the H2O molecule are discussed. Degenerate vibrational modes such as occur in CO2 are analyzed and expressions for Fermi resonance between close-lying states of the same symmetry are developed. The bending modes of linear triatomic molecules are expressed in terms of Laguerre polynomials in cylindrical coordinates as well as in terms of Hermite polynomials in Cartesian coordinates. The effects of large-amplitude bending such as occur in the C3 molecule are analyzed, along with anharmonic effects, which split the usually degenerate bending mode energy levels. Finally, the vibrational frequencies, degeneracies, and symmetry properties of XY3, X2Y2, and XY4 type molecules are discussed.

Source record↗

The study of the physics of cometary nuclei

A semiannual progress report describing the work completed during the period 1 September 1975 to 29 February 1976 on the physics of cometary nuclei was given. The following items were discussed: (1) a paper entitled ""A speculation about comets and the earth'', (2) a chapter entitled"" The physics of comets'' for ""Reviews of Astronomy and Astrophysics'', (3) continuing work on split comets, and (4) results dealing with a new application of nongravitational solar-radial forces as a measure of comet nucleus dimensions and activity.

Whipple, F. L.↗

Fundamental analysis of the failure of polymer-based fiber reinforced composites

A mathematical model is described which will permit predictions of the strength of fiber reinforced composites containing known flaws to be made from the basic properties of their constituents. The approach was to embed a local heterogeneous region (LHR) surrounding the crack tip into an anisotropic elastic continuum. The model should (1) permit an explicit analysis of the micromechanical processes involved in the fracture process, and (2) remain simple enough to be useful in practical computations. Computations for arbitrary flaw size and orientation under arbitrary applied load combinations were performed from unidirectional composites with linear elastic-brittle constituent behavior. The mechanical properties were nominally those of graphite epoxy. With the rupture properties arbitrarily varied to test the capability of the model to reflect real fracture modes in fiber composites, it was shown that fiber breakage, matrix crazing, crack bridging, matrix-fiber debonding, and axial splitting can all occur during a period of (gradually) increasing load prior to catastrophic fracture. The computations reveal qualitatively the sequential nature of the stable crack process that precedes fracture.

Kanninen, M. F.↗

Aerodynamic performance of 0.4066-scale model to JT8D refan stage

The aerodynamic performance of a scale model of the split flow JT8D rafan stage is presented over a range of flows at speeds from 40 to 100 percent design. The bypass stage peak efficiency of 0.800 occurred at a total weight flow of 35.82 kilograms per second and a pressure ratio of 1.697. The stall margin was 15 percent based on pressure ratio and weight flow at stall and peak efficiency conditions. The data indicated that the hub region of the core stators was choked at design speed over the entire flow range tested.

Moore, R. D.↗

Evaluation of TILS for use as the orbiter landing NAVAID

An evaluation of the tactical instrument landing systems (TILS) for use in the orbiter autoland system was made. It was found that with certain modifications, the TILS can satisfy orbiter autoland requirements. These modifications, include (1) addition of DME equipment, (2) expansion of elevation coverage from 0-10 deg to 0-30 deg, and (3) expansion to redundant systems with associated ground monitors. Additional modifications that are not necessary to meet the orbiter requirements, but that can enhance performance margin are (1) tightening of elevation antenna beam width from 1.3 deg to 0.5 deg and (2) split site configuration to provide azimuth and range coverage through rollout.

Tate, J. M.↗

The 1.06 micrometer wideband laser modulator: Fabrication and life testing

The design, fabrication, testing and delivery of an optical modulator which will operate with a mode-locked Nd:YAG laser at 1.06 micrometers were performed. The system transfers data at a nominal rate of 400 Mbps. This wideband laser modulator can transmit either Pulse Gated Binary Modulation (PGBM) or Pulse Polarization Binary Modulation (PPBM) formats. The laser beam enters the modulator and passes through both crystals; approximately 1% of the transmitted beam is split from the main beam and analyzed for the AEC signal; the remaining part of the beam exits the modulator. The delivered modulator when initially aligned and integrated with laser and electronics performed very well. The optical transmission was 69.5%. The static extinction ratio was 69:1. A 1000 hour life test was conducted with the delivered modulator. A 63 bit pseudorandom code signal was used as a driver input. At the conclusion of the life test the modulator optical transmission was 71.5% and the static extinction ratio 65:1.

Teague, J. R.↗

A subvortex technique for the close approach to a discretized vortex sheet

The close-approach problem associated with vortex-lattice methods was examined numerically with the objective of calculating velocities at arbitrary points, not just at midpoints, between the vortices. The objective was achieved using a subvortex technique in which a vortex splits into an increasing number of subvortices as it is approached. The technique, incorporated in a two-dimensional potential flow method using "submerged" vortices and sources, was evaluated for a cambered Joukowski airfoil. The method could be extended to three dimensions, and should improve non-linear methods, which calculate interference effects between multiple wings and vortex wakes, and which include procedures for force-free wakes.

Maskew, B.↗

Mossbauer effect in the ion-implanted iron-carbon alloys

The concentration dependence of Mossbauer effect in four carbon ion-implanted iron absorbers, which contain carbon as the solute atoms, has been investigated over the range of concentration 0.05 through 1 atomic percent. The specimens were prepared by implanting carbon atoms on each reference iron foil with four different bombarding energies of 250 keV, 160 keV, 140 keV and 80 keV, respectively. Thus, the specimen contains a uniform dosage of carbon atoms which penetrated up to 3,000 A depth of the reference iron. In the measurement of Mossbauer spectra, the backscattering conversion electron counting geometry was used. Typical results of Mossbauer parameters of iron-carbon alloys show that the isomer shift, quadrupole shift, the effective hyperfine splitting of Fe-57, and the intensity ratio exhibit a large variation with the increase of carbon concentration in the environment of iron atoms.

Han, K. S.↗

Exciton coupling in molecular crystals

The implications of perfect exciton coupling and molecular vibrations were investigated, as well as the effect they have on the lifetime of singlet and triplet excitons coupled in a limiting geometry. Crystalline bibenzyl, Cl4Hl4, provided a situation in which these mechanisms involving exciton coupling can be studied in the limit of perfect coupling between units due to the crystal's geometry. This geometry leads to a coupling between the two halves of the molecule resulting in a splitting of the molecular excited states. The study reported involves an experimental spectroscopic approach and begins with the purification of the bibenzyl. The principal experimental apparatus was an emission spectrometer. A closed cycle cryogenic system was used to vary the temperature of the sample between 20 K and 300 K. The desired results are the temperature-dependent emission spectra of the bibenzyl; in addition, the lifetimes and quantum yields measured at each temperature reveal the effect of competing radiationless processes.

Ake, R. L.↗

Petrographic and petrological study of lunar rock materials

Samples returned from Apollo 14 (14171, 14305, 14319), Apollo 15 (15255), Apollo 16 (61175, 67455), and Apollo 17 (77215) were studied optically and selected polished sections by SEM/Microprobe. Splits and separates from 77215, 67455, 61175 and 15255 were prepared; 77215 and 67455 were analyzed for major, minor and LIL trace elements. The data indicate that 77215, a noritic breccia clast found in the Station7 boulder, is a norite cumulate similar to and probably derived from the same body as 78235. The Apollo 17 boulders are found to be part of the same melt sheet, which was formed by a major impact event, possibly Serenitatis, about 4 B. Y. ago. The Apollo 14 and 16 breccias are polymict, their clast populations indicating quite different provenance. The Apollo 14 breccias are possibly the result of multiple impacts, while the other breccias studied appear to have been formed by single impacts. ANT suite clasts included in 61175 are, for the most part, granulites resulting from subsolidus recrystallization of norites, anorthosites or gabbros. This metamorphism appears to have occurred prior to the impact event forming 61175.

Winzer, S. R.↗

NASA advanced control technology: An overview

NASA's current and projected advanced control technology programs for future transport aircraft include the design and verification of full flight envelope autopilots, the development and flight test of all-digital fly by wire systems, the evolution of low cost innovative avionics concepts such as split surface stability augmentation systems, the evaluation of integrated propulsion control and cooperative autopilot/propulsion control systems, the application of active control systems to short haul and long haul transports, and the demonstration of reconfigured active control aircraft. Key technical features and anticipated contributions of these technologies are outlined.

Peter R Kurzhals↗

Results of tests CS4 and CS5 to investigate dynamic loads and pressures on 0.03-scale models (Ax1319-3/4 and 45-0) of mated 747 cam and space shuttle orbiter in the Boeing transonic wind tunnel

A 0.03-scale model of the 747 CAM/Orbiter was tested in an 8 x 12 foot transonic wind tunnel. Dynamic loads, pressure, and empennage flow field data were obtained using pressure transducers, strain gages, and a split film anemometer. The test variables included Mach number, angle of attack, sideslip angle, orbiter tailcone on and off, orbiter partial tailcone, orbiter nozzle air scoops, orbiter body flap angle, and orbiter elevon angle.

Source record↗

A measurement of perpendicular current density in an aurora

A Nike Tomahawk sounding rocket was launched into a 400-gamma auroral substorm from Esrange, Kiruna, Sweden. The rocket instrumentation included a split Langmuir-probe plasma-velocity detector and a double-probe electric-field detector. Above 140-km altitude, the electric field deduced from the ion-flow velocity measurement and the electric field measured by the double probe agree to an accuracy within the uncertainties of the two measurements. The difference between the two measurements at altitudes below 140 km provides an in situ measurement of current density and conductivity. Alternatively, if values for the conductivity are assumed, the neutral-wind velocity can be deduced. The height-integrated current was 0.11 A/m flowing at an azimuth angle of 276 deg. The neutral winds were strong, exhibited substantial altitude variation in the east-west component, and were predominantly southward.

Bering, E. A.↗

Diagonalization and simultaneous symmetrization of the gas-dynamic matrices

The hyperbolic nature of the unsteady, inviscid, gas-dynamic equations implies the existence of a similarity transformation for diagonalizing an arbitrary linear combination of coefficient matrices. It is shown that the individual matrices are simultaneously symmetrized by the similarity transformation. The transformations and their norms can be applied to the well-posedness of the Cauchy problem, linear stability theory for finite-difference approximations, and simplification of block-tridiagonal systems that arise in implicit time-split algorithms.

Warming, R. F.↗

The lithium-like 2s 2S-2p 2P transition in solar flares

Accurate wavelengths of the Fe XXIV lithium-like doublet at 192 and 255 A are derived from measurements made in a sample of four solar flares observed with a spectroheliograph aboard Skylab and selected to minimize systematic effects. The mean value of the Fe XXIV doublet interval is determined, and new members of the lithium isoelectronic sequence are identified, including Cr XXII, Mn XXIII, and Ni XXVI. Doublet splitting along the lithium sequence is analyzed in terms of the experimental screening factor, it is found that the doublet separations increase smoothly with charge number along the sequence, and the doublet interval in Ni XXVI is accurately extrapolated. The experimental screening factors are compared with the values predicted by Snyder's (1971) relativistic screening theory, and excellent agreement is found.

Widing, K. G.↗

Field-aligned fluxes in the geomagnetic equator

During 12 electron injection events observed by Explorer 45 during the December, 1971, and February, 1972, in magnetic storms it was found that the lowest observable pitch angle particles (down to 7 degrees in one case) arrived first. Pitch angle dispersion and shell-splitting effects are shown to be inadequate explanations for most of these pitch angle distributions. It is suggested that parallel electric fields may be supplying 1- to 5-keV electrons to the magnetosphere from the ionosphere. Various models of parallel electric fields are discussed.

Semar, C. L.↗

Hydrogen as an energy vector

The feasibility of utilizing hydrogen as an energy vector is considered, with special attention given to means of hydrogen production. The state-of-the-art in thermochemical processes is reviewed, and criteria for the technical and economic feasibility of large-scale thermochemical water splitting processes are presented. The production of hydrogen from coal and from photolysis of water is discussed.

Powers, W. D.↗

Effect of velocity gradients on measurements of turbulent shear stress

Experiments were carried out to evaluate the effects of normal velocity gradients on hot wire measurements in a subsonic boundary layer of the same size as the flow investigated by Johnson and Rose (1975). Both hot wire and film anemometers were used to measure the turbulent properties of the boundary layer. A special X-wire probe with one wire vertical and the other at an angle of about 40 deg to the flow was used to demonstrate the gradient effects. The results indicate that major errors are encountered when mean and turbulent velocity gradients exist along the length of hot wire sensors, the problem being more pronounced at high speeds. Although the split film sensor results show a significant improvement over the X-wire sensor, further reduction in the space resolution of sensors by roughly an order of magnitude would appear to be necessary to reduce the error to acceptable values near the wall.

Sandborn, V. A.↗