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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,063 records · Page 59
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Factors underlying a latitudinal gradient in the S/G lignin monomer ratio in natural poplar variants

The chemical composition of wood plays a pivotal role in the adaptability and structural integrity of trees. However, few studies have investigated the environmental factors that determine lignin composition and its biological significance in plants. Here, we examined the lignin syringyl-to-guaiacyl (S/G) ratio in members of a Populus trichocarpa population sourced from their native habitat and conducted a genome wide association study to identify genes linked to lignin formation. Our results revealed many significant associations, suggesting that lignin biosynthesis is a complex polygenic trait. Additionally, we found an increase in the S/G ratio from northern to southern geographic origin of the trees sampled, along with a corresponding metabolic and transcriptional reprogramming of xylem cell wall biosynthesis. Further molecular analysis identified a mutation in a cell wall laccase genetically associated with higher S/G ratios that predominate in trees from warmer lower latitudes. Collectively, our findings suggest that lignin heterogeneity arises from an evolutionary process enabling poplar adaptation to different climatic challenges.

adaptation↗
DOE OSTI2025

Mixed warm dark matter constraints using Milky Way satellite galaxy counts

Warm dark matter has been strongly constrained in recent years as the sole component of dark matter. However, a less-explored alternative is that dark matter consists of a mixture of warm and cold dark matter (MWDM). In this work, we use observations of Milky Way satellite galaxies to constrain MWDM scenarios where the formation of small-scale structure is suppressed either by generic thermal relic warm dark matter or a sterile neutrino produced through the Shi-Fuller mechanism. To achieve this, we model satellite galaxies by combining numerical simulations with semianalytical models for the subhalo population, and use a galaxy-halo connection model to match galaxies onto dark matter subhalos. By comparing the number of satellites predicted by MWDM models to the observed satellite population from the Dark Energy Survey and Pan-STARRS1, we constrain the fraction of warm dark matter, f WDM , as a function of its mass, m WDM . We exclude dark matter being composed entirely of thermal relic warm dark matter with m WDM ≤ 6.6 keV at a posterior ratio of 10 ∶ 1 , consistent with previous works. However, we find that warm dark matter with smaller mass is allowed when mixed with cold dark matter, and that the f WDM constraints strengthen with decreasing m WDM until they plateau at f WDM ≲ 0.45 for m WDM ≲ 1.5 keV . Likewise, in the case of a sterile neutrino with mass of 7 keV produced through the Shi-Fuller mechanism, we exclude a fraction of f ν s ≲ 0.45 , independent of mixing angle. Our results extend constraints on MWDM to a region of parameter space that has been relatively unconstrained with previous analysis.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2024

Unveiling long-lived dual emission in a tetraphenylethylene-based metal–organic framework

Incorporating photoactive linkers into metal–organic frameworks (MOFs) has proved useful in improving photophysical properties of organic chromophores. This is achieved by controlling the local packing of linkers or defect engineering within the MOF. Using these ideas, we demonstrate that a tetraphenylethylene-based MOF exhibits long-lived linker-based emission out to 1 μs—substantially longer than previously reported. The emission contains two independent components whose dynamics branch from early timescales. Furthermore these findings suggest that charge recombination and distinct defect sites exist and contribute a weak yet detectable emission, and demonstrate how high-sensitivity transient photoluminescence spectroscopy can reveal unexpected populations in nominally crystalline materials.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Assessing electrogenetic activation via a network model of biological signal propagation

Introduction: Molecular communication is the transfer of information encoded by molecular structure and activity. We examine molecular communication within bacterial consortia as cells with diverse biosynthetic capabilities can be assembled for enhanced function. Their coordination, both in terms of engineered genetic circuits within individual cells as well as their population-scale functions, is needed to ensure robust performance. We have suggested that “electrogenetics,” the use of electronics to activate specific genetic circuits, is a means by which electronic devices can mediate molecular communication, ultimately enabling programmable control. Methods: Here, we have developed a graphical network model for dynamically assessing electronic and molecular signal propagation schemes wherein nodes represent individual cells, and their edges represent communication channels by which signaling molecules are transferred. We utilize graph properties such as edge dynamics and graph topology to interrogate the signaling dynamics of specific engineered bacterial consortia. Results: We were able to recapitulate previous experimental systems with our model. In addition, we found that networks with more distinct subpopulations (high network modularity) propagated signals more slowly than randomized networks, while strategic arrangement of subpopulations with respect to the inducer source (an electrode) can increase signal output and outperform otherwise homogeneous networks. Discussion: We developed this model to better understand our previous experimental results, but also to enable future designs wherein subpopulation composition, genetic circuits, and spatial configurations can be varied to tune performance. We suggest that this work may provide insight into the signaling which occurs in synthetically assembled systems as well as native microbial communities.

Chun, Kayla↗
NASA NTRS1972

A comparison of reliability and conventional estimation of safe fatigue life and safe inspection intervals

Both the conventional and reliability analyses for determining safe fatigue life are predicted on a population having a specified (usually log normal) distribution of life to collapse under a fatigue test load. Under a random service load spectrum, random occurrences of load larger than the fatigue test load may confront and cause collapse of structures which are weakened, though not yet to the fatigue test load. These collapses are included in reliability but excluded in conventional analysis. The theory of risk determination by each method is given, and several reasonably typical examples have been worked out, in which it transpires that if one excludes collapse through exceedance of the uncracked strength, the reliability and conventional analyses gave virtually identical probabilities of failure or survival.

Hooke, F. H.↗
NASA NTRS1983

Si III line ratios in the sun

New atomic data for Si III have been used to predict level populations and emission-line intensity ratios for electron densities and temperatures appropriate to the solar transition region. The electron impact collision rates used here are substantially larger than those previously published owing to delineation of the complex resonance structures in the low-energy collision strengths. This together with small changes in the spontaneous radiative rates produces significant changes in the calculated intensity ratios. Generally good agreement is found with observations obtained using the Naval Research Laboratory slit spectrograph aboard Skylab, electron densities from three Si III ratios and from other methods normally agreeing to 0.2 dex or better for a wide variety of solar features. For a fourth ratio, incorporating lines with a wide wavelength separation, the agreement is less satisfactory, possibly owing to uncertainties in the observational data.

Dufton, P. L.↗
NASA NTRS1991

Structural reliability analysis of laminated CMC components

For laminated ceramic matrix composite (CMC) materials to realize their full potential in aerospace applications, design methods and protocols are a necessity. The time independent failure response of these materials is focussed on and a reliability analysis is presented associated with the initiation of matrix cracking. A public domain computer algorithm is highlighted that was coupled with the laminate analysis of a finite element code and which serves as a design aid to analyze structural components made from laminated CMC materials. Issues relevant to the effect of the size of the component are discussed, and a parameter estimation procedure is presented. The estimation procedure allows three parameters to be calculated from a failure population that has an underlying Weibull distribution.

Duffy, Stephen F.↗
NASA NTRS1991

Structural reliability analysis of laminated CMC components

For laminated ceramic matrix composite (CMC) materials to realize their full potential in aerospace applications, design methods and protocols are a necessity. The time independent failure response of these materials is focussed on and a reliability analysis is presented associated with the initiation of matrix cracking. A public domain computer algorithm is highlighted that was coupled with the laminate analysis of a finite element code and which serves as a design aid to analyze structural components made from laminated CMC materials. Issues relevant to the effect of the size of the component are discussed, and a parameter estimation procedure is presented. The estimation procedure allows three parameters to be calculated from a failure population that has an underlying Weibull distribution.

Duffy, Stephen F.↗
NASA NTRS1992

Utilization of on-site resources for Regenerative Life Support Systems at a lunar outpost

Regenerative life support systems (RLSS) will be required to regenerate air, water, and wastes, and to produce food for human consumption during long-duration stays on the moon. It may be possible to supplement some of the materials needed for RLSS from resources on the moon. Natural materials at the lunar surface may be used for a variety of lunar RLSS needs, including (i) soils or solid-support substrates for plant growth, (ii) sources for extraction of essential, plant-growth nutrients, (iii) substrates for microbial populations in the degradation of wastes, (iv) sources of O2 and H, which may be used to manufacture water, (v) feed stock materials for the synthesis of useful minerals (e.g., molecular sieves), and (vi) shielding materials surrounding the outpost structure to protect humans, plants, and microorganisms from harmful radiation.

Ming, D. W.↗
NASA NTRS2005

The Space Infrared Interferometric Telescope (SPIRIT)

SPIRIT, a candidate NASA "Origins Probe," is a spatial and spectral interferometer with an operating wavelength range 25 - 400 microns. SPIRIT will provide sub-arcsecond resolution images and spectra with resolution R = 3000 in a 1 arcmin field of view to accomplish three primary scientific objectives: (1) Learn how planetary systems form from protostellar disks, and how they acquire their chemical organization; (2) Characterize the family of extrasolar planetary systems by imaging the structure in debris disks to understand how and where planets form, and why some planets are ice giants and others are rocky; and (3) Learn how high-redshift galaxies formed and merged to form the present-day population of galaxies. Observations with the space-based SPIRIT will be complementary to those of ground-based submillimeter and millimeter arrays and to JWST. We report results of a recently-completed pre-Phase A mission study.

Leisawitz, David↗
NASA NTRS2007

Molecules and Dust in the Humunculus: Ejecta of Eta Carinae

In the 18401s, Eta Carinae ejected massive amounts of nitrogen-rich, carbon- and oxygen-poor material which we see as the hourglass-shaped Homunculus. With the Hubble Space Telescope Imaging Spectrograph, we detected multiple shells in line of sight, the most massive and intriguing being at -513 km/s. Numerous lines of Fe I, Fe II, Ni II, Cr II, Sc II, Sr II, Ti II, V II, etc are identified as well as nearly a thousand H2 lines. The metals have energy level populations consistent with 760K and excited by photons < 8.5eV. We have now identified CH, CH+, OH, and NH at the same velocity, but at 60K, suggesting stratification in the outer ejecta. Analysis of the interior, photoionized emission hourglass structure, known as the Little Homunculus, indicates He, N overabundances and C, 0 underabundances (approximately 1/80 solar). A skirt of neutral and partially ionized gas lies between the lobes of the hourglasses. A portion is seen as the Strontium Filament, a metal- ionized, neutral hydrogen structure. Relative abundances of TiNi are 1/80 solar, CrNi are 1/20 solar. This complex of ejecta appears to have been ejected by a massive star(s) at the end of the hydrogen-burning phase when convection led to overproduction of nitrogen at the expense of carbon and oxygen. Given the underabundances of carbon and oxygen, the chemistry of this system is quite different to the normal ISM, leading to a nitrogen- dominated chemistry. What little C and 0 that is formed is immediately taken up by SiO and Al0 molecules leading to a very different gas/dust ratio than the normal ISM. Dust in this ejecta is abundance, but known to be very grey in character. Observations with HST/STIS and VLT/UVES will be presented along with simple physical models and CLOUD modeling. Insight by the participants will be solicited.

Gull, T.↗
NASA NTRS2019

Multimessenger Science Opportunities with mHz Gravitational Waves

LISA will open the mHz band of gravitational waves (GWs) to the astronomy community. Thestrong gravity which powers the variety of GW sources in this band is also crucial in a numberof important astrophysical processes at the current frontiers of astronomy. These range fromthe beginning of structure formation in the early universe, through the origin and cosmic evolutionof massive black holes in concert with their galactic environments, to the evolution ofstellar remnant binaries in the Milky Way and in nearby galaxies. These processes and theirassociated populations also drive current and future observations across the electromagnetic(EM) spectrum. We review opportunities for science breakthroughs, involving either direct coincidentEM+GW observations, or indirect multimessenger studies. We argue that for the UScommunity to fully capitalize on the opportunities from the LISA mission, the US efforts shouldbe accompanied by a coordinated and sustained program of multi-disciplinary science investment,following the GW data through to its impact on broad areas of astrophysics. Supportfor LISA-related multimessenger observers and theorists should be sized appropriately for aflagship observatory and may be coordinated through a dedicated mHz GW research center.

Baker, John↗
DOE OSTI2020

A method for mapping submicron-scale crystallographic order/disorder applied to human tooth enamel

Tooth enamel, the outermost layer of human teeth, is a complex, hierarchically structured biocomposite. The details of this structure are important in multiple human health contexts, from understanding the progression of dental caries (tooth decay) to understanding the process of amelogenesis and related developmental defects. Enamel is composed primarily of long, nanoscale crystallites of hydroxyapatite that are bundled by the thousands to form micron-scale rods. Studies with transmission electron microscopy show the relationships between small groups of crystallites and X-ray diffraction characterize averages over many rods, but the direct measurement of variations in local crystallographic structure across and between enamel rods has been missing. Here, we describe a synchrotron X-ray-based experimental approach and a novel analysis method developed to address this gap in knowledge. A ~500-nm-wide beam of monochromatic X-rays in conjunction with a sample section only 1 μm in thickness enables 2D diffraction patterns to be collected from small well-separated volumes within the enamel microstructure but still probes enough crystallites (~300 per pattern) to extract population-level statistics on crystallographic features like lattice parameter, crystallite size, and orientation distributions. Furthermore, the development of a quantitative metric to characterize relative order and disorder based on the azimuthal autocorrelation of diffracted intensity enables these crystallographic measurements to be correlated with their location within the enamel microstructure (e.g., between rod and interrod regions). These methods represent a step forward in the characterization of human enamel and will elucidate the variation of the crystallographic structure across and between enamel rods for the first time.

crystallographic order/disorder↗
DOE OSTI2024

Mathematical Modeling of Multi-Phenomena Anisotropic Systems: Ejection of Primary Aerosols during the Fast Pyrolysis of Biomass

This study introduces a novel particle model for biomass fast pyrolysis, incorporating an anisotropic cylindrical particle to address mass and energy transport coupled with aerosol ejection, which previous models have overlooked. The main contribution lies in developing a model that considers aerosol generation in anisotropic cylindrical particles for the first time, addressing bubbling dynamics and bursting within the liquid phase. The population balance equation describes bubble dynamics and aerosol formation, capturing phenomena like nucleation, growth, coalescence, and bursting. The model employs the method of moments with bubble volume as an internal variable, substantially reducing computational costs by eliminating dependence on this variable. Results highlight the significant impact of anisotropy and particle size on aerosol ejection: smaller, less elongated particles experience faster heating, quicker conversion, and the increased accumulation of the liquid intermediate phase. Specifically, 1 mm diameter particles yield higher concentrations of metaplast and bio-oil aerosols, exceeding 15%, compared to concentrations below 11% for 3 mm particles. This model provides insights into aerosol structure (volume, surface area), aiding in understanding aerosol reactivity at the reactor scale.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

Lifetime measurements in the even-even Cd 102 – 108 isotopes

The heaviest T z = 0 doubly-magic nucleus, Sn 100 , and the neighboring nuclei offer unique opportunities to investigate the properties of nuclear interaction. For instance, the structure of light-Sn nuclei has been shown to be affected by the delicate balance between nuclear-interaction components, such as pairing and quadrupole correlations. From Cd to Te, many common features and phenomena have been observed experimentally along the isotopic chains, leading to theoretical studies devoted to a more general and comprehensive study of the region. In this context, having only two proton holes in the Z = 50 shell, the Cd isotopes are expected to present properties similar to those found in the Sn isotopic chain. The aim of this work was to measure lifetimes of excited states in neutron-deficient nuclei in the vicinity of Sn 100 . Here, the neutron-deficient nuclei in the N ≈ Z ≈ 50 region were populated using a multinucleon transfer reaction with a Cd 106 beam and a Mo 92 target. The beamlike products were identified by the VAMOS + + spectrometer, while the γ rays were detected using the AGATA array. Lifetimes of excited states were determined using the recoil distance Doppler-shift method, employing the Cologne differential plunger. Lifetimes of low-lying states were measured in the even-mass Cd 102 – 108 isotopes. In particular, multiple states with excitation energy up to ≈ 3 MeV, belonging to various bands, were populated in Cd 106 via inelastic scattering. The transition strengths corresponding to the measured lifetimes were compared with those resulting from state-of-the-art beyond-mean-field calculations using the symmetry-conserving configuration-mixing approach. Conclusions: Despite the similarities in the electromagnetic properties of the low-lying states, there is a fundamental structural difference between the ground-state bands in the Z = 48 and Z = 50 isotopes. The comparison between experimental and theoretical results revealed a rotational character of the Cd nuclei, which have prolate-deformed ground states with β 2 ≈ 0.2 . At this deformation Z = 48 becomes a closed-shell configuration, which is favored with respect to the spherical one.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRSDate not supplied

A Structurally-Adaptive Framework for Distributed Airborne Sensing over Real-time Collaborative Information Sharing Networks

The emergence and maturation of wireless communication technologies continue to transform the aviation industry and are enabling new solutions to challenges faced by NASA’s Advanced Air Mobility (AAM) initiative. AAM is leading towards high-density autonomous aircraft operations in areas underserved by traditional aviation, such as over densely populated urban centers. In this paper, we build on concepts from Smart Spaces - where sensing, processing, and communication are embedded in an environment, and agents are operating within the space can exploit these capabilities in real-time through collaborative information sharing networks. Building from these concepts, we propose a framework to enable a dynamic, topologically-adaptive, and distributed estimation system for man-rated aviation to address challenges faced by autonomous AAM operations. This paper presents the initial concept of operations and system design for this framework, presents a mathematical formulation for abstraction of the problem, identifies requirements and constraints for operation, and presents algorithmic constructs and mathematical formalisms to demonstrate operation. The proposed framework will be evaluated on a regional AAM flight scenario and will focus on two initial applications: (1) GPS-free navigation supporting precision approach and landing (PAL), and (2) surveillance and conformance monitoring of aircraft in vertiport airspaces. Such approaches show promise in addressing gaps in current technologies needed to enable future AAM concepts, while promising greater capabilities, performance, robustness, and safety over current aviation systems and operations.

Structurally-Adaptive↗
DOE OSTI2020

A Cross-correlation Study of High-energy Neutrinos and Tracers of Large-scale Structure

The origin of the bulk of the astrophysical neutrinos detected by the IceCube Observatory remains a mystery. Previous source-finding analyses compared the directions of IceCube events and individual sources in astrophysical catalogs. The source association method is technically challenging when the number of source candidates is much larger than the number of the observed astrophysical neutrinos. In this paper, we show that in this large source number regime, a two-point cross-correlation analysis of neutrino data and source catalog can instead be used to constrain potential source populations for the high-energy astrophysical neutrinos, and provide spatial evidence for the existence of astrophysical neutrinos. We present an analysis of the cross-correlation of the IceCube 2010–2012 point-source data and a WISE–2MASS galaxy sample. While we find no significant detection of cross-correlation with the publicly available neutrino data set, we show that, when applied to the full IceCube data, which has a longer observation time and higher astrophysical neutrino purity, our method has sufficient statistical power to detect a cross-correlation signal if the neutrino sources trace the large-scale structure of the universe.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

The structure of CaO–MgO–Al 2 O 3 –SiO 2 melts and glasses doped with FeO X –NiO

Neutron and x-ray diffraction measurements have been performed on CaO–MgO–Al 2 O 3 –SiO 2 (CMAS) glasses doped with NiO–Fe X O at room temperature, along with x-ray measurements on aerodynamically levitated liquids at ≥2000 K. The disordered structures have been modeled using empirical potential structure refinement to investigate the relation between the aluminosilicate network and the modifying cations. The SiO 4 and AlO 4 tetrahedra are found to have wider Si–O and Al–O bond distance distributions in the glass, and the first Ca–O n coordination shell is highly distorted, redistributing different populations of long and short bonds between the liquid and the glass. The addition of Fe and Ni at low aluminosilicate content increases the number of free oxygens not bonded to AlO 4 or SiO 4 . Mg–O and Fe–O are both found to be predominantly fourfold and fivefold in the liquid and glassy states. Despite these low coordination numbers, their bond angle distributions indicate that they are predominantly in nontetrahedral-type geometries, with ferrous and ferric iron possessing similar coordination environments. The Ca–O and Mg–O average coordination numbers and enthalpies of solution are consistent with their higher reactivity within relatively acidic aluminosilicate melts.

36 MATERIALS SCIENCE↗