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All sourcesNASA NTRSDOE OSTI
NASA NTRS2012

JPL Innovation Foundry

Space science missions are increasingly challenged today: in ambition, by increasingly sophisticated hypotheses tested; in development, by the increasing complexity of advanced technologies; in budgeting, by the decline of flagship-class mission opportunities; in management, by expectations for breakthrough science despite a risk-averse programmatic climate; and in planning, by increasing competition for scarce resources. How are the space-science missions of tomorrow being formulated? The paper describes the JPL Innovation Foundry, created in 2011, to respond to this evolving context. The Foundry integrates methods, tools, and experts that span the mission concept lifecycle. Grounded in JPL's heritage of missions, flight instruments, mission proposals, and concept innovation, the Foundry seeks to provide continuity of support and cost-effective, on-call access to the right domain experts at the right time, as science definition teams and Principal Investigators mature mission ideas from "cocktail napkin" to PDR. The Foundry blends JPL capabilities in proposal development and concurrent engineering, including Team X, with new approaches for open-ended concept exploration in earlier, cost-constrained phases, and with ongoing research and technology projects. It applies complexity and cost models, projectformulation lessons learned, and strategy analyses appropriate to each level of concept maturity. The Foundry is organizationally integrated with JPL formulation program offices; staffed by JPL's line organizations for engineering, science, and costing; and overseen by senior Laboratory leaders to assure experienced coordination and review. Incubation of each concept is tailored depending on its maturity and proposal history, and its highest leverage modeling and analysis needs.

mission development↗
DOE OSTI2023

Experimentally simulated sea level rise destabilizes carbon-mineral associations in temperate tidal marsh soil

How sea level rise (SLR) alters carbon (C) dynamics in tidal salt marsh soils is unresolved. Changes in hydrodynamics could influence organo-mineral associations, influencing dissolved organic carbon (DOC) fluxes. As SLR increases the duration of inundation, we hypothesize that lateral DOC export will increase due to reductive dissolution of C-bearing iron (Fe) oxides, destabilizing soil C stocks and influencing greenhouse gas emissions. To test this, soil cores (0–8 cm depth) were collected from the high marsh of a temperate salt marsh that currently experiences changes in water level and soil redox oscillation due to spring-neap tides. Mesocosms experimentally simulated SLR by continuously inundating high marsh soils and were compared to mesocosms with Control conditions, where the water level oscillated on a spring-neap cycle. Porewater DOC, lateral DOC, and porewater reduced Fe (Fe 2+ ) concentrations were significantly higher in SLR treatments (1.7 ± 0.5 mM, 0.63 ± 0.14 mM, and 0.15 ± 0.11 mM, respectively) than Control treatments (1.2 ± 0.35 mM, 0.56 ± 0.15 mM, and 0.08 ± 01 mM, respectively Solid phase analysis with Fe extended X-ray absorption fine-structure spectroscopy further revealed that SLR led to > 3 times less Fe oxide-C coprecipitates than Control conditions In addition, the overall global warming potential (GWP) decreased under SLR due to suppressed CO 2 emissions. Our data suggest that SLR may increase lateral C export of current C stocks by dissolving C-bearing Fe oxides but decrease the overall GWP from emissions of soil trace gases. Finally, these findings have implications for understanding the fate of SOC dynamics under future SLR scenarios.

dissolved organic carbon↗
DOE OSTI2012

Effect of Component Failures on Economics of Distributed Photovoltaic Systems

This report describes an applied research program to assess the realistic costs of grid connected photovoltaic (PV) installations. A Board of Advisors was assembled that included management from the regional electric power utilities, as well as other participants from companies that work in the electric power industry. Although the program started with the intention of addressing effective load carrying capacity (ELCC) for utility-owned photovoltaic installations, results from the literature study and recommendations from the Board of Advisors led investigators to the conclusion that obtaining effective data for this analysis would be difficult, if not impossible. The effort was then re-focused on assessing the realistic costs and economic valuations of grid-connected PV installations. The 17 kW PV installation on the University of Hartford's Lincoln Theater was used as one source of actual data. The change in objective required a more technically oriented group. The re-organized working group (changes made due to the need for more technically oriented participants) made site visits to medium-sized PV installations in Connecticut with the objective of developing sources of operating histories. An extensive literature review helped to focus efforts in several technical and economic subjects. The objective of determining the consequences of component failures on both generation and economic returns required three analyses. The first was a Monte-Carlo-based simulation model for failure occurrences and the resulting downtime. Published failure data, though limited, was used to verify the results. A second model was developed to predict the reduction in or loss of electrical generation related to the downtime due to these failures. Finally, a comprehensive economic analysis, including these failures, was developed to determine realistic net present values of installed PV arrays. Two types of societal benefits were explored, with quantitative valuations developed for both. Some societal benefits associated with financial benefits to the utility of having a distributed generation capacity that is not fossil-fuel based have been included into the economic models. Also included and quantified in the models are several benefits to society more generally: job creation and some estimates of benefits from avoiding greenhouse emissions. PV system failures result in a lowering of the economic values of a grid-connected system, but this turned out to be a surprisingly small effect on the overall economics. The most significant benefit noted resulted from including the societal benefits accrued to the utility. This provided a marked increase in the valuations of the array and made the overall value proposition a financially attractive one, in that net present values exceeded installation costs. These results indicate that the Department of Energy and state regulatory bodies should consider focusing on societal benefits that create economic value for the utility, confirm these quantitative values, and work to have them accepted by the utilities and reflected in the rate structures for power obtained from grid-connected arrays. Understanding and applying the economic benefits evident in this work can significantly improve the business case for grid-connected PV installations. This work also indicates that the societal benefits to the population are real and defensible, but not nearly as easy to justify in a business case as are the benefits that accrue directly to the utility.

14 SOLAR ENERGY↗
DOE OSTI2012

Playas Grid Reliability and Distributed Energy Research

The future looks bright for solar and renewable energies in the United States. Recent studies claim that by 2050, solar power could supply a third of all electricity demand in the country’s western states. Technology advances, soft policy changes, and increased energy consciousness will all have to happen to achieve this goal. The New Mexico Institute of Mining and Technology (NMT) and the Department of Homeland Security (DHS) perform various training and research activities at this site. Given its unique nature, Playas was chosen to test Micro-Grids and other examples of renewable distributed energy resources (DER). Several proposed distributed energy sources (DERs) were not implemented as planned including the Micro-Grid. However, Micro-Grid design and computer modeling were completed and these results are included in this report. As part of this research, four PV (solar) generating systems were installed with remote Internet based communication and control capabilities. These systems have been integrated into and can interact with the local grid So that (for example) excess power produced by the solar arrays can be exported to the utility grid. Energy efficient LED lighting was installed in several buildings to further reduce consumption of utility-supplied power. By combining reduced lighting costs; lowering HVAC loads; and installing smart PV generating equipment with energy storage (battery banks) these systems can greatly reduce electrical usage drawn from an older rural electrical cooperative (Co-Op) while providing clean dependable power. Several additional tasks under this project involved conducting research to develop methods of producing electricity from organic materials (i.e. biofuels, biomass. etc.), the most successful being the biodiesel reactor. Improvements with Proton Exchange Membranes (PEM) for fuels cells were demonstrated and advances in Dye Sensitized Solar Cells (DSSC) were also shown. The specific goals of the project include: 1) Instrumentation of the power distribution system with distributed energy resources, demand-side control and intelligent homes within the town of Playas, NM, 2) Creation of models (power flow and dynamic) of the Playas power distribution system, 3) Validation of the models through comparison of predicted behavior to data collected from instrumentation, and 4) Utilization of the models and test grid to characterize the impact of new devices and approaches (e.g., distributed generation and load management) on the local distribution system as well as the grid at large. In addition to the above stated objectives, the research also focused on three critical challenges facing renewable distributed energy platforms: 1) hydrogen from biomass, 2) improved catalyst support systems for electrolysis membranes and fuel cell systems, and 3) improved manufacturing methodologies of low cost photovoltaics. The following sections describe activities performed during this project. The various tasks were focused on establishing Playas as a “…theoretical and experimental test bed…” through which components of a modern/smart grid could be characterized. On a broader scale, project efforts were aimed at development of tools and gathering of experience/expertise that would accelerate progress toward implementation of a modern grid.

09 BIOMASS FUELS↗
DOE OSTI2015

Nuclear Data Needs and Capabilities for Applications

In July 2014, DOE NP carried out a review of the US Nuclear Data Program. This led to several recommendations, including that the USNDP should “devise effective and transparent mechanisms to solicit input and feedback from all stakeholders on nuclear data needs and priorities.” The review also recommended that USNDP pursue experimental activities of relevance to nuclear data; the revised 2014 Mission Statement accordingly states that the USNDP uses “targeted experimental studies” to address gaps in nuclear data. In support of these recommendations, DOE NP requested that USNDP personnel organize a Workshop on Nuclear Data Needs and Capabilities for Applications (NDNCA). This Workshop was held at Lawrence Berkeley National Laboratory (LBNL) on 27-29 May 2015. The goal of the NDNCA Workshop was to compile nuclear data needs across a wide spectrum of applied nuclear science, and to provide a summary of associated capabilities (accelerators, reactors, spectrometers, etc.) available for the required measurements. The first two days of the workshop consisted of 25 plenary talks by speakers from 16 different institutions, on nuclear energy (NE), national security (NS), isotope production (IP), and industrial applications (IA). There were also shorter “capabilities” talks that described the experimental facilities and instrumentation available for the measurement of nuclear data. This was followed by a third day of topic-specific “breakout” sessions and a final closeout session. The agenda and copies of these talks are available online at http://bang.berkeley.edu/events/NDNCA/agenda. The importance of nuclear data to both basic and applied nuclear science was reflected in the fact that while the impetus for the workshop arose from the 2014 USNDP review, joint sponsorship for the workshop was provided by the Nuclear Science and Security Consortium, a UC-Berkeley based organization funded by the National Nuclear Security Administration (NNSA).

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2021

Controlled Pyrolysis: A Robust Scalable Composite Recycling Technology

The reinforced composites industry is facing significant challenges in handling the scrap composite material from automobile manufacturing, the wind turbine industry, and others. The fibers in the material, whether they be carbon, glass, or other materials have commercial value if they can be recovered successfully. Successfully means the fibers are clean with no sizing or other binders and have adequate strength and physical properties that would allow them to be economically reprocessed into valuable product. The composites recycling project was an industry-collaborative effort to develop a composite recycling technology using controlled pyrolysis. Through the recycling of scrap and end-of-life (EOL) cured composite materials, this pilot study was intended to create a business case by realizing a cost-effective means for recycling EOL and production scrap composite materials, ultimately reducing the volume of composite materials destined for landfill. The project was led by the Institute for Advanced Composites Manufacturing Innovation (IACMI), the American Composites Manufacturers Association (ACMA), Oak Ridge National Laboratory (ORNL), Continental Structural Plastics (CSP) a Teijin Group Company, CHZ Technologies, and A. Schulman with support from Owens Corning, John Deere, General Electric (GE), Ashland LLC, and Plastics Europe (CEFIC). The team studied and tested CHZ Technologies’ controlled pyrolysis system, known as the Thermolyzer TM , which operates on a scalable basis to convert organic polymer materials into a clean synthesis gas and char containing the recoverable carbon and glass fiber reinforcement. The recoverable energy contained in the input polymers creates the synthesis gas that can be used to provide heat to the Thermolyzer TM primary reactor in a sustainable manner. That is, once the Thermolyzer TM is started with a small amount of external natural gas, the synthesis gas that is created from the polymers will continue to operate the burners so long as feedstock is supplied. The reinforcing fiber materials remaining in the solid phase char were separated and cleaned for re-use in other polymer systems based on the retained properties of the fibers. The study created reports (attached in the appendix) on the Mass and Energy Balances, syngas analytics, VOC assessment, yield analysis and other analytics necessary for a Techno-Economic Analysis (TEA) to quantify the economic impact of the recovery and sustainable re-use of the carbon and glass fibers. The process consisted of 4 steps: Selection of 4 samples of cured composite waste materials from project partners interested in materials recycling and recovering the reinforcing fibers for best case re-use. The materials included glass fiber (GF) polyester/vinyl ester automotive SMC from CSP, GF epoxy balsa/PVC foam wind blades from GE, carbon fiber (CF) epoxy wind blade laminated spar caps from GE, and GF/CF epoxy hybrid assembly from John Deere. Processing the waste composite samples into 1-2” shreds. Packaging the shredded composites into bulk sacks on international shipping pallets for shipment to KUG in Forst (Lausitz), Germany. Pyrolysis of the shredded composites under controlled conditions designed for each polymer system. Collecting samples of the gas and char for analysis. Shipping the char containing the CF/GF back to the US for the next steps of testing the fibers and developing protocols for sustainable re-use of the fibers in composite applications.

36 MATERIALS SCIENCE↗
DOE OSTI2012

Phosphorus Cycling in the Red Tide Incubator Region of Monterey Bay in Response to Upwelling

This study explores the cycling of phosphorus (P) in the euphotic zone following upwelling in northeastern Monterey Bay (the Red Tide Incubator region) of coastal California, with particular emphasis on how bacteria and phytoplankton that form harmful algal blooms mediate and respond to changes in P availability. In situ measurements of nutrient concentrations, phytoplankton community composition, and cell-specific alkaline phosphatase (AP) activity (determined via enzyme-labeled fluorescence assay) were measured during three cruises. Upwelling led to a 10-fold increase in dissolved inorganic (DIP) in surface waters, reaching ~0.5μmol L -1 . This DIP was drawn down rapidly as upwelling relaxed over a period of 1 week. Ratios of nitrate to DIP drawdown (~5:1, calculated as the change in nitrate divided by the change in DIP) were lower than the Redfield ratio of 16:1, suggesting that luxury P uptake was occurring as phytoplankton bloomed. Dissolved organic (DOP) remained relatively constant (~0.3μmol L -1 ) before and immediately following upwelling, but doubled as upwelling relaxed, likely due to phytoplankton excretion and release during grazing. This transition from a relatively high DIP:DOP ratio to lower DIP:DOP ratio was accompanied by a decline in the abundance of diatoms, which had low AP activity, toward localized, spatially heterogeneous blooms of dinoflagellates in the genera Prorocentrum, Ceratium, Dinophysis, Alexandrium, and Scrippsiella that showed high AP activity regardless of ambient DIP levels. A nutrient addition incubation experiment showed that phytoplankton growth was primarily limited by nitrate, followed by DIP and DOP, suggesting that P regulates phytoplankton physiology and competition, but is not a limiting nutrient in this region. AP activity was observed in bacteria associated with lysed cell debris and aggregates of particulate organic material, where it may serve to facilitate P regeneration, as well as affixed to the surfaces of intact phytoplankton cells, possibly indicative of close, beneficial phytoplankton–bacteria interactions.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS2007

Duration Limits for Orbital Flight: Current Considerations for the International Space Station

According to ISS documentation, long-duration missions are defined as missions exceeding 30 days. The ISS medical organization has set a 180-day limit for ISS missions from a medical perspective, with a possibility of planning missions of up to 220days with additional consideration. The ISS medical community does not currently consider changes to the existing duration constraints for ISS mission planning. However, longer stays on orbit may be highly desirable or even necessary in certain foreseeable operational circumstances. To develop a methodology for contingency planning, the ISS medical community, led by NASA, has identified medically relevant risks associated with extended stays of crewmembers aboard the ISS.

Smith, Gwen↗
NASA NTRS1999

Development of Fuzzy Logic and Soft Computing Methodologies

Our earlier research on computing with words (CW) has led to a new direction in fuzzy logic which points to a major enlargement of the role of natural languages in information processing, decision analysis and control. This direction is based on the methodology of computing with words and embodies a new theory which is referred to as the computational theory of perceptions (CTP). An important feature of this theory is that it can be added to any existing theory - especially to probability theory, decision analysis, and control - and enhance the ability of the theory to deal with real-world problems in which the decision-relevant information is a mixture of measurements and perceptions. The new direction is centered on an old concept - the concept of a perception - a concept which plays a central role in human cognition. The ability to reason with perceptions perceptions of time, distance, force, direction, shape, intent, likelihood, truth and other attributes of physical and mental objects - underlies the remarkable human capability to perform a wide variety of physical and mental tasks without any measurements and any computations. Everyday examples of such tasks are parking a car, driving in city traffic, cooking a meal, playing golf and summarizing a story. Perceptions are intrinsically imprecise. Imprecision of perceptions reflects the finite ability of sensory organs and ultimately, the brain, to resolve detail and store information. More concretely, perceptions are both fuzzy and granular, or, for short, f-granular. Perceptions are f-granular in the sense that: (a) the boundaries of perceived classes are not sharply defined; and (b) the elements of classes are grouped into granules, with a granule being a clump of elements drawn together by indistinguishability, similarity. proximity or functionality. F-granularity of perceptions may be viewed as a human way of achieving data compression. In large measure, scientific progress has been, and continues to be, driven by a quest to progress from perceptions to measurements. Pursuit of this aim has led to brilliant successes. But alongside the successes stand problems whose solutions are not in sight. Representative of such problems is the problem of automation of driving in city traffic. In this case, as in many others, what can be done with ease by humans - without any measurements and a computations - is an intractable task for machines.

Zadeh, L. A.↗
DOE OSTI2016

Studies on the magnetic ground state of a spin Mobius strip

In this paper, we report the synthesis, structure and detailed characterisation of three n-membered oxovanadium rings, Na n [(V=O) n Na n (H 2 O) n (α, β, or γ-CD) 2 ]•m H 2 O (n=6, 7, or 8), prepared by the reactions of (V=O)SO 4 •x H 2 O with α, β, or γ-cyclodextrins (CDs) and NaOH in water. Their alternating heterometallic vanadium/sodium cyclic core structures were sandwiched between two CD moieties such that O-Na-O groups separated the neighbouring vanadyl ions. Antiferromagnetic interactions between the S=1/2 vanadyl ions led to S=0 ground states for the even-membered rings, but to two quasi-degenerate S=1/2 states for the spin-frustrated heptanuclear cluster.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Photocatalytic fuel production

The conversion of carbon dioxide and water to fuel in artificial systems requires efficient coupling of light absorbers and catalysts, and assembly of the components into hierarchical structures to close the photocatalytic cycle. Recent breakthroughs in the embodiment of molecular photoactive components in ultrathin oxide layers, and the introduction of new materials approaches for interfacial charge transfer have led to substantially improved coupling of chromophores and catalysts. Finally, these advances are accelerating the exploration of novel architectures for reducing CO 2 by H 2 O in scalable, single integrated photosystems to reach the high power efficiencies recently demonstrated with photovoltaic-assisted approaches.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

Thermal stability of hexagonal OsB{sub 2}

The synthesis of novel hexagonal ReB{sub 2}-type OsB{sub 2} ceramic powder was performed by high energy ball milling of elemental Os and B powders. Two different sources of B powder have been used for this mechanochemical synthesis. One B powder consisted of a mixture of amorphous and crystalline phases and a mixture of {sup 10}B and {sup 11}B isotopes with a fine particle size, while another B powder was a purely crystalline (rhombohedral) material consisting of enriched {sup 11}B isotope with coarse particle size. The same Os powder was used for the synthesis in both cases. It was established that, in the first case, the hexagonal OsB{sub 2} phase was the main product of synthesis with a small quantity of Os{sub 2}B{sub 3} phase present after synthesis as an intermediate product. In the second case, where coarse crystalline {sup 11}B powder was used as a raw material, only Os{sub 2}B{sub 3} boride was synthesized mechanochemically. The thermal stability of hexagonal OsB{sub 2} powder was studied by heating under argon up to 876 °C and cooling in vacuo down to −225 °C. During the heating, the sacrificial reaction 2OsB{sub 2}+3O{sub 2}→2Os+2B{sub 2}O{sub 3} took place due to presence of O{sub 2}/water vapor molecules in the heating chamber, resulting in the oxidation of B atoms and formation of B{sub 2}O{sub 3} and precipitation of Os metal out of the OsB{sub 2} lattice. As a result of such phase changes during heating, the lattice parameters of hexagonal OsB{sub 2} changed significantly. The shrinkage of the a lattice parameter was recorded in 276–426 °C temperature range upon heating, which was attributed to the removal of B atoms from the OsB{sub 2} lattice due to oxidation followed by the precipitation of Os atoms and formation of Os metal. While significant structural changes occurred upon heating due to presence of O{sub 2}, the hexagonal OsB{sub 2} ceramic demonstrated good phase stability upon cooling in vacuo with linear shrinkage of the lattice parameters and no phase changes detected during cooling. - Graphical abstract: The in situ high temperature XRD contour plot (A) and XRD patterns (B) of h-OsB{sub 2} upon heating and cooling under an argon atmosphere. - Highlights: • Different boron sources were compared for the synthesis of h-OsB{sub 2}. • The phase stability and thermal behavior of h-OsB{sub 2} were studied by in situ XRD. • Shrinkage of the a lattice parameter was observed from 276 °C to 426 °C upon heating. • Oxidation of OsB{sub 2} produced B vacancies led to the shrinkage of a lattice parameter.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Selective Methane Oxidation by Heterogenized Iridium Catalysts

Oxidative methane (CH 4 ) carbonylation promises a direct route to the synthesis of value-added oxygenates such as acetic acid (CH 3 COOH). Here, in this paper, we report a strategy to realize oxidative CH 4 carbonylation through immobilized Ir complexes on an oxide support. Our immobilization approach not only enables direct CH 4 activation but also allows for easy separation and reutilization of the catalyst. Furthermore, we show that a key step, methyl migration, that forms a C–C bond, is sensitive to the electrophilicity of carbonyl, which can be tuned by a gentle reduction to the Ir centers. While the as-prepared catalyst that mainly featured Ir(IV) preferred CH 3 COOH production, a reduced catalyst featuring predominantly Ir(III) led to a significant increase of CH 3 OH production at the expense of the reduced yield of CH 3 COOH.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Near Quantitative Removal of Selenate and Sulfate Anions from Wastewaters by Cocrystallization with Chelating Hydrogen-Bonding Guanidinium Ligands

Selenium (Se) has become an environmental contaminant of aquatic ecosystems as a result of human activities, particularly mining, fossil fuel combustion, and agricultural activities. By leveraging the high sulfate concentrations relative to Se oxyanions (i.e., SeO n 2– , n = 3, 4) present in some wastewaters, we have developed an efficient approach to Se-oxyanion removal by cocrystallization with bisiminoguanidinium (BIG) ligands that form crystalline sulfate/selenate solid solutions. The crystallization of the sulfate, selenate and selenite, oxyanions and of sulfate/selenate mixtures with five candidate BIG ligands are reported along with the thermodynamics of crystallization and aqueous solubilities. Oxyanion removal experiments with the top two performing candidate ligands show a near quantitative removal (>99%) of sulfate or selenate from solution. When both sulfate and selenate are present, there is near quantitative removal (>99%) of selenate, down to sub-ppb Se levels, with no discrimination between the two oxyanions during cocrystallization. Reducing the selenate concentrations by 3 orders of magnitude or more relative to sulfate, as found in many wastewaters, led to no measurable loss in Se removal efficiencies. This work offers a simple and effective alternative to selective separation of trace amounts of highly toxic selenate oxyanions from wastewaters, to meet stringent regulatory discharge limits.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Nanocluster and single-atom catalysts for thermocatalytic conversion of CO and CO 2

In this Minireview, we discuss recent advances in understanding nanocluster and single-atom catalysts for CO and CO 2 emissions control applications. Through analyzing thermocatalytic CO oxidation and CO 2 reduction, two fundamentally and industrially important reactions, we compare representative nanocluster and single-atom catalytic systems from perspectives of intrinsic chemistry and reaction engineering. Generally, nanoclusters and single atoms display different catalytic performances (i.e., activity, selectivity, and stability) for these reactions depending on the synthesis methods, support materials, and reaction conditions. Key observations of activity and selectivity tradeoffs between nanoclusters and single-atom catalysts are highlighted. Here, the dynamic structural responses of these catalytic species under CO oxidation or CO 2 reduction reaction conditions are also discussed. Synthetic control and detailed experimental and computational characterization of single-atom and nanocluster catalysts for CO and CO 2 conversion have led to exciting progress over the past decade. Still, more efforts are needed to understand and develop catalysts that meet the environmental, energy, and technical requirements to power a sustainable global economy.

03 NATURAL GAS↗
DOE OSTI2017

Solution-Grown Rubrene Crystals as Radiation Detecting Devices

There has been increased interest in organic semiconductors over the last decade because of their unique properties. Of these, 5, 6, 11, 12-tetraphenylnaphthacene (rubrene) has generated the most interest because of its high charge carrier mobility. In this paper, large single crystals with a volume of ~1 cm 3 were grown from solution by a temperature reduction technique. The faceted crystals had flat surfaces and cm-scale, visually defect-free areas suitable for physical characterization. X-ray diffraction analysis indicates that solvent does not incorporate into the crystals and photoluminescence spectra are consistent with pristine, high-crystallinity rubrene. Furthermore, the response curve to pulsed optical illumination indicates that the solution grown crystals are of similar quality to those grown by physical vapor transport, albeit larger. The good quality of these crystals in combination with the improvement of electrical contacts by application of conductive polymer on the graphite electrodes have led to the clear observation of alpha particles with these rubrene detectors. Finally, preliminary results with a 252 Cf source generate a small signal with the rubrene detector and may demonstrate that rubrene can also be used for detecting high-energy neutrons.

36 MATERIALS SCIENCE↗
DOE OSTI2015

A bioinformatics prediction approach towards analyzing the glycosylation, co-expression and interaction patterns of epithelial membrane antigen (EMA/MUC1)

Epithelial membrane antigen (EMA or MUC1) is a heavily glycosylated, type I transmembrane glycoprotein commonly expressed by epithelial cells of duct organs. It has been shown to be aberrantly glycosylated in several diseases including cancer. Protein sequence based annotation and analysis of glycosylation profile of glycoproteins by robust computational and comprehensive algorithms provides possible insights to the mechanism(s) of anomalous glycosylation. In present report, by using a number of bioinformatics applications we studied EMA/MUC1 and explored its trans-membrane structural domain sequence that is widely subjected to glycosylation. Exploration of different extracellular motifs led to prediction of N and O-linked glycosylation target sites. Based on the putative O-linked target sites, glycosylated moieties and pathways were envisaged. Furthermore, Protein network analysis demonstrated physical interaction of EMA with a number of proteins and confirmed its functional involvement in cell growth and proliferation pathways. Gene Ontology analysis suggested an involvement of EMA in a number of functions including signal transduction, protein binding, processing and transport along with glycosylation. Thus, present study explored potential of bioinformatics prediction approach in analyzing glycosylation, co-expression and interaction patterns of EMA/MUC1 glycoprotein.

60 APPLIED LIFE SCIENCES↗