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At least 1,063 records · Page 59

Using the Charge-Discharge Cycling of Positive Electrode Symmetric Cells to Find Electrolyte/Electrode Combinations with Minimum Reactivity

The effects of solvents, salts, electrolyte additives and surface coatings on LiNi 0.4 Mn 0.4 Co 0.2 O 2 (NMC442) or LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC622) have been probed using positive electrode Li-ion symmetric cells coupled with dV/dQ analysis. A robust symmetric cell design is presented which prevents hardware corrosion for over at least 800 hours of testing to 4.5 V vs. Li/Li + at 40°C. Positive electrode symmetric cells using uncoated positive electrode materials and 1M LiPF 6 EC:EMC 3:7 or 1M LiPF 6 EMC electrolyte rapidly developed high impedance and showed poor capacity retention. However, if 1% pyridine boron trifluoride (PBF) was added to these electrolytes, cell performance was dramatically improved. Replacing LiPF 6 by LiBF 4 in the electrolytes above, with or without PBF, yielded positive electrode symmetric cells with good capacity retention. Two types of surface coatings were explored on NMC622 positive electrodes. Cells using surface-coated positive electrodes demonstrated better capacity retention for all electrolytes compared to cells without surface coatings. Finally, this work can be used as a guide by those attempting to find electrolyte/electrode pairs suitable for use in NMC/graphite cells that can operate with long lifetime to 4.5 V.

25 ENERGY STORAGE↗

Optimal shielding design for minimum materials cost or mass

The mathematical underpinnings of cost optimal radiation shielding designs based on an extension of optimal control theory are presented, a heuristic algorithm to iteratively solve the resulting optimal design equations is suggested, and computational results for a simple test case are discussed. A typical radiation shielding design problem can have infinitely many solutions, all satisfying the problem's specified set of radiation attenuation requirements. Each such design has its own total materials cost. For a design to be optimal, no admissible change in its deployment of shielding materials can result in a lower cost. This applies in particular to very small changes, which can be restated using the calculus of variations as the Euler-Lagrange equations. Furthermore, the associated Hamiltonian function and application of Pontryagin's theorem lead to conditions for a shield to be optimal.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Convolutional Neural Networks for Problems in Transport Phenomena: A Theoretical Minimum

Convolutional neural network (CNN), a deep learning algorithm, has gained popularity in technological applications that rely on interpreting images (typically, an image is a 2D field of pixels). Transport phenomena is the science of studying different fields representing mass, momentum, or heat transfer. Some of the common fields are species concentration, fluid velocity, pressure, and temperature. Each of these fields can be expressed as an image(s). Consequently, CNNs can be leveraged to solve specific scientific problems in transport phenomena. Herein, we show that such problems can be grouped into three basic categories: (a) mapping a field to a descriptor (b) mapping a field to another field, and (c) mapping a descriptor to a field. After reviewing the representative transport phenomena literature for each of these categories, we illustrate the necessary steps for constructing appropriate CNN solutions using sessile liquid drops as an exemplar problem. If sufficient training data is available, CNNs can considerably speed up the solution of the corresponding problems. Finally, the present discussion is meant to be minimalistic such that readers can easily identify the transport phenomena problems where CNNs can be useful as well as construct and/or assess such solutions.

97 MATHEMATICS AND COMPUTING↗

Summary and Analysis of Responses to Surveys on Experience with GHP Installations in Federal Facilities and Minimum Qualifications of GHP-related Professionals

To increase customer confidence in geothermal heat pump (GHP) technology, reduce the potential of improperly installed GHP systems, and ensure the quality and performance of GHP installations, the Geothermal Heat Pump Consortium (GHPC, now known as the Geothermal Exchange Organization or GEO) is leading an effort to develop the first national certification standard for all primary personnel involved in the implementation of GHP systems. This standard will be developed through a collaborative methodology that solicits information and input from consumers, industry stakeholders, and professional and trade organizations to identify the required qualifications of all the primary personnel and incorporate this information into the standard.

GSHP National Survey↗

Energy Efficiency and Minimum Standards: a Market Analysis of Recent Changes in Appliance Eenergy Efficiency Standards in the United States

The objective of this paper is to examine the effect of energy efficiency standards on prices and market shares of major household appliances in the United States. The household appliance market is analyzed using point-of-sale (POS) retail data of clothes washers and dryers from NPD Group. Energy efficiency information for each clothes washer model was obtained from the Federal Trade Commission (FTC) appliance energy database. Using these data, we conclude that energy efficiency standards had an overall negative impact on clothes washer price, and products with a mid-low efficiency rating experienced the greatest short run price drop following the January 2004 and 2007 new standard effective dates. In neither instance is there any evidence of an increase in prices of affected appliances. In both cases we analyse the price effects of the standard both relative to dryers as a counterfactual group. Additionally, we show that market shares for clothes washers shifted towards greater efficiency over the course of the period between 2002 and 2011.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Neutronics Analyses of the Minimum Original HEU TREAT Core

This work was performed to support the feasibility study on the potential conversion of the Transient Reactor Test Facility (TREAT) at Idaho National Laboratory from the use of high-enriched uranium (HEU) fuel to the use of low-enriched uranium (LEU) fuel. The analyses were performed by the GTRI Reactor Conversion staff at the Argonne National Laboratory (ANL). The objective of this study was to validate the MCNP model of the TREAT reactor with the well-documented measurements which were taken during the start-up and early operation of TREAT. Furthermore, the effect of carbon graphitization was also addressed. The graphitization level was assumed to be 100% (ANL/GTRI/TM-13/4). For this purpose, a set of experiments was chosen to validate the TREAT MCNP model, involving the approach to criticality procedure, in-core neutron flux measurements with foils, and isothermal temperature coefficient and temperature distribution measurements. The results of this study extended the knowledge base for the TREAT MCNP calculations and established the credibility of the MCNP model to be used in the core conversion feasibility analysis.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

County-Level Climate Uncertainty for Risk Assessments: Volume 6 Appendix E - Historical Minimum Near-Surface Air Temperature.

This report uses the CMIP5 series of climate model simulations to produce country- level uncertainty distributions for use in socioeconomic risk assessments of climate change impacts. It provides appropriate probability distributions, by month, for 169 countries and autonomous-areas on temperature, precipitation, maximum temperature, maximum wind speed, humidity, runoff, soil moisture and evaporation for the historical period (1976-2005), and for decadal time periods to 2100. It also provides historical and future distributions for the Arctic region on ice concentration, ice thickness, age of ice, and ice ridging in 15-degree longitude arc segments from the Arctic Circle to 80 degrees latitude, plus two polar semicircular regions from 80 to 90 degrees latitude. The uncertainty is meant to describe the lack of knowledge rather than imprecision in the physical simulation because the emphasis is on unfalsified risk and its use to determine potential socioeconomic impacts. The full report is contained in 27 volumes.

54 ENVIRONMENTAL SCIENCES↗

Minimum Resolution Requirements for Gamma Identification Algorithms

Each year there are millions of dollars spent on the research and production of high-resolution detectors. This research indicates that the pursuit of higher resolution detectors is not always necessary. The terminal resolution of a NaI detector, or highest detector resolution, at which identification algorithms fail to identify highly enriched uranium (HEU) was evaluated using GADRAS, Genie, and GammaVision. GADRAS employs a template matching algorithm, while Genie and GammaVision utilize a mathematical approach for peak search and identification. The NaI spectra utilized for evaluation were generated using the GADRAS Inject tab and source modeling functions. Each spectrum included terrestrial and cosmic background from Dallas, TX. The resolutions for each spectrum were increased from a default 8.92% to a point where each algorithm would fail to identify 235 U from a HEU source. Six different source configurations were used in this research: bare HEU, 50% shielded HEU, 90% shielded HEU, bare HEU with an interference source of 99 mTc, bare HEU with 99 mTc both shielded 50%, and bare HEU with 99 mTc both shielded 90%. T

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

County-Level Climate Uncertainty for Risk Assessments: Volume 7 Appendix F - Forecast Minimum Near-Surface Air Temperature

This report uses the CMIP5 series of climate model simulations to produce country- level uncertainty distributions for use in socioeconomic risk assessments of climate change impacts. It provides appropriate probability distributions, by month, for 169 countries and autonomous-areas on temperature, precipitation, maximum temperature, maximum wind speed, humidity, runoff, soil moisture and evaporation for the historical period (1976-2005), and for decadal time periods to 2100. It also provides historical and future distributions for the Arctic region on ice concentration, ice thickness, age of ice, and ice ridging in 15-degree longitude arc segments from the Arctic Circle to 80 degrees latitude, plus two polar semicircular regions from 80 to 90 degrees latitude. The uncertainty is meant to describe the lack of knowledge rather than imprecision in the physical simulation because the emphasis is on unfalsified risk and its use to determine potential socioeconomic impacts. The full report is contained in 27 volumes.

54 ENVIRONMENTAL SCIENCES↗