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At least 1,063 records · Page 59

Complex radiation-thermal history of Kaidun meteorite on data of track study of silicate minerals

The results of track study of approximately 80 individual silicate mineral crystals (ol, px, plag) picked out from Kaidun meteorite are presented. A wide range of observed rho(sub VH) value distributions indicate the complex irradiation history of Kaidun minerals. In one anortite crystal having two track groups with different parameters the pre-accretion irradiation traces were observed in all probability.

Kashkarov, L. L.↗

From minerals to rocks: Toward modeling lithologies with remote sensing

High spectral resolution imaging spectroscopy will play an important role in future planetary missions. Sophisticated approaches will be needed to unravel subtle, super-imposed spectral features typically of natural systems, and to maximize the science return of these instruments. Carefully controlled laboratory investigations using homogeneous mineral separates have demonstrated that variations due to solid solution, changes in modal abundances, and the effects of particle size are well understood from a physical basis. In many cases, these variations can be modeled quantitatively using photometric models, mixing approaches, and deconvolution procedures. However, relative to the spectra of individual mineral components, reflectance spectra of rocks and natural surfaces exhibit a reduced spectral contrast. In addition, soils or regolith, which are likely to dominate any natural planetary surface, exhibit spectral properties that have some similarities to the parent materials, but due to weathering and alteration, differences remain that cannot yet be fully recreated in the laboratory or through mixture modeling. A significant challenge is therefore to integrate modeling approaches to derive both lithologic determinations and include the effects of alteration. We are currently conducting laboratory investigations in lithologic modeling to expand upon the basic results of previous analyses with our initial goal to more closely match physical state of natural systems. The effects of alteration are to be considered separately.

Mustard, John F.↗

The Erevan howardite: Petrology of glassy clasts and mineral chemistry

The Erevan howardite is a polymict regolith breccia containing xenoliths of carbonaceous chondrites. In this work, we studied glassy clasts, which could be considered as primary quenched melts, and mineral chemistry of the breccia. The study reveals that the Erevan howardite consists of common rocks of the HED suite. However, unique glassy clasts, which are present in some eucritic melts, were identified. The mineral chemistry and the simulation of crystallization of the melts suggest that the compositions of the melts reflect those of some primary lithologies of EPB.

Nazarov, M. A.↗

Weathering features and secondary minerals in Antarctic Shergottites ALHA77005 and LEW88516

Previous work has shown that all three sub-groups of the shergottite, nakhlite, and chassignite (SNC) clan of meteorites contain aqueous precipitates of probable pre-terrestrial origin. In the context of secondary minerals, the most thoroughly studied shergottite has been Elephant Moraine, Antarctica A79001 (EETA79001). The recognition of LEW88516 as the latest SNC specimen, and its close similarity with ALHA77005, invite a comparative study of the latter two meteorites, and with EETA79001, from the perspective of aqueous alteration. The fusion crusts of the two meteorites are quite similar except that ALHA77005 is more vesicular (possibly indicating a higher indigenous volatile content). Secondary aluminosilicates (and salts on LEW88516) of definite Antarctic origin partially fill vesicles and fractures on both fusion crusts. Interior samples of the two meteorites are grossly similar in that traces of secondary minerals are present in both.

Wentworth, Susan J.↗

Bone geometry, structure and mineral distribution using Dual energy X ray Absorptiometry (DXA)

Dual energy x-ray absorptiometry (DXA) is currently the most widely used method of analyzing regional and whole body changes in bone mineral content (BMC) and areal (g/sq cm) bone mineral density (BMD). However, BMC and BMD do not provide direct measures of long bone geometry, structure, or strength nor do regional measurements detect localized changes in other regions of the same bone. The capabilities of DXA can be enhanced significantly by special processing of pixel BMC data which yields cross-sectional geometric and structural information. We have extended this method of analysis in order to develop non-uniform structural beam models of long bones.

Whalen, Robert↗

Mapping minerals, amorphous materials, environmental materials, vegetation, water, ice and snow, and other materials: The USGS tricorder algorithm

One of the challenges of Imaging Spectroscopy is the identification, mapping and abundance determination of materials, whether mineral, vegetable, or liquid, given enough spectral range, spectral resolution, signal to noise, and spatial resolution. Many materials show diagnostic absorption features in the visual and near infrared region (0.4 to 2.5 micrometers) of the spectrum. This region is covered by the modern imaging spectrometers such as AVIRIS. The challenge is to identify the materials from absorption bands in their spectra, and determine what specific analyses must be done to derive particular parameters of interest, ranging from simply identifying its presence to deriving its abundance, or determining specific chemistry of the material. Recently, a new analysis algorithm was developed that uses a digital spectral library of known materials and a fast, modified-least-squares method of determining if a single spectral feature for a given material is present. Clark et al. made another advance in the mapping algorithm: simultaneously mapping multiple minerals using multiple spectral features. This was done by a modified-least-squares fit of spectral features, from data in a digital spectral library, to corresponding spectral features in the image data. This version has now been superseded by a more comprehensive spectral analysis system called Tricorder.

Clark, Roger N.↗

Iron alteration minerals in the visible and near-infrared spectra of low-albedo asteroids

Absorption features centered near 0.60-0.65 and 0.80-0.90 micrometers have been identified in the spectra of five low-albedo main-belt and outer-belt asteroids. These absorption features are attributed respectively to the (6)A(sub 1) goes to (4)T(sub 2)(G) and (6)A(sub 1) goes to (4)T(sub 1)(G) charge transfer transitions in minerals such as goethite, hematite, and jarosite that are products of the aqueous alteration of anhydrous silicates. A shoulder near 0.63 micrometers has also been identified in the absorption feature centered near 0.7 micrometers attributed to oxidized iron in phyllosilicates found predominantly in C- and G-class asteroids reflectance spectra. The coexistence of iron oxides with phyllosilicates in asteroids believed to have undergone aqueous alteration would be expected based upon analogy with terrestrial aqueous alteration and the observed mineralogy of carbonaceous chondrites. The number of low-albedo asteroids having only iron alteration absorption features compared to the number of low-albedo asteroids having spectral characteristics indicative of phyllosilicates is small. Either the conditions under which these asteroids formed are rare, or the iron alteration minerals could be formed in the interiors of objects where phyllosilicates dominate the surface mineralogy.

Vilas, Faith↗

The nanosphere iron mineral(s) in Mars soil

A series of surface-modified clays containing nanophase (np) iron/oxyhydroxides of extremely small particle sizes, with total iron contents as high as found in Mars soil, were prepared by iron deposition on the clay surface from ferrous chloride solution. Comprehensive studies of the iron mineralogy in these 'Mars-soil analogs' were conducted using chemical extractions, solubility analyses, pH and redox, x ray and electron diffractometry, electron microscopic imaging specific surface area and particle size determinations, differential thermal analyses, magnetic properties characterization, spectral reflectance, and Viking biology simulation experiments. The clay matrix and the procedure used for synthesis produced nanophase iron oxides containing a certain proportion of divalent iron, which slowly converts to more stable, fully oxidized iron minerals. The noncrystalline nature of the iron compounds precipitated on the surface of the clay was verified by their complete extractability in oxalate. Lepidocrocite (gamma-FeOOH) was detected by selected area electron diffraction. It is formed from a double iron Fe(II)/Fe(III) hydroxyl mineral such as 'green rust', or ferrosic hydroxide. Magnetic measurements suggested that lepidocrocite converted to the more stable meaghemite (gamma-Fe203) by mild heat treatment and then to nanophase hematite (aplha-Fe203) by extensive heat treatment. Their chemical reactivity offers a plausible mechanism for the somewhat puzzling observations of the Viking biology experiments. Their unique chemical reactivities are attributed to the combined catalytic effects of the iron oxide/oxyhydroxide and silicate phase surfaces. The mode of formation of these (nanophase) iron oxides on Mars is still unknown.

Banin, A.↗

Effect of excess dietary salt on calcium metabolism and bone mineral in a spaceflight rat model

High levels of salt promote urinary calcium (UCa) loss and have the potential to cause bone mineral deficits if intestinal Ca absorption does not compensate for these losses. To determine the effect of excess dietary salt on the osteopenia that follows skeletal unloading, we used a spaceflight model that unloads the hindlimbs of 200-g rats by tail suspension (S). Rats were studied for 2 wk on diets containing high salt (4 and 8%) and normal calcium (0.45%) and for 4 wk on diets containing 8% salt (HiNa) and 0.2% Ca (LoCa). Final body weights were 9-11% lower in S than in control rats (C) in both experiments, reflecting lower growth rates in S than in C during pair feeding. UCa represented 12% of dietary Ca on HiNA diets and was twofold higher in S than in C transiently during unloading. Net intestinal Ca absorption was consistently 11-18% lower in S than in C. Serum 1,25-dihydroxyvitamin D was unaffected by either LoCa or HiNa diets in S but was increased by LoCa and HiNa diets in C. Despite depressed intestinal Ca absoption in S and a sluggish response of the Ca endocrine system to HiNa diets, UCa loss did not appear to affect the osteopenia induced by unloading. Although any deficit in bone mineral content from HiNa diets may have been too small to detect or the duration of the study too short to manifest, there were clear differences in Ca metabolism from control levels in the response of the spaceflight model to HiNa diets, indicated by depression of intestinal Ca absorption and its regulatory hormone.

Navidi, Meena↗

Experiment 305: Pathophysiology of Mineral Loss During Space Flight

The objective of this SLS-2 experiment was to determine the pathophysiology of mineral loss during space flight. This was to be accomplished by (1) determining the concentrations of blood minerals and of calciotropic hormones (parathyroid hormone-PTH, vitamin D metabolites) before, during, and after a 14 day shuttle flight, and (2) determining, by calcium kinetic analysis (using stable calcium isotopes), the influence of space flight on intestinal calcium absorption .

Arnaud, Claude D.↗

Mechanisms of Bone Mineralization and Effects of Mechanical Loading

The data suggest that PTH and PKC inhibit nodule formation, and that alternative energy sources are utilized by osteoblasts in the process of mineralization. The conditions and techniques to grow, fix, photograph, and measure bone mineralization in vitro were defined. The results are presently in preliminary form and require further assessment as follows; quantitate the surface area of nodules + treatments via computer-aided image analysis; use PTH + inhibitors of signaling pathways to determine the mechanism of nodule formation; determine how protein kinase C is involved as a promotor of nodule formation; cell proliferation vs. cell death affected by modulation of signal transduction (i.e., PTH, enzyme inhibitors and activators); identify mRNA induced or decreased in response to PTH and signaling modulators that encode proteins that regulate cell morphology, proliferation, and nodule formation. Therefore, several follow-up studies between the laboratories at NASA-Ames Research Center and my laboratory at the University of Illinois have been initiated.

Babich, Michael↗

Bulk and Stable Isotopic Compositions of Carbonate Minerals in Martian Meteorite Allan Hills 84001: No Proof of High Formation Temperature

Understanding the origin of carbonate minerals in the Martian meteorite Allan Hills (ALH) 84001 is crucial to evaluating the hypothesis that they contain traces of ancient Martian life. Using arguments based on chemical equilibria among carbonates and fluids, an origin at greater than 650 C (inimical to life) has been proposed. However, the bulk and stable isotopic compositions of the carbonate minerals are open to multiple interpretations and so lend no particular support to a high-temperature origin. Other methods (possibly less direct) will have to be used to determine the formation temperature of the carbonates in ALH 84001.

Treiman, Allan H.↗

Alteration Products and Secondary Minerals in Martian Meteorite Allan Hills 84001

The martian meteorites contain alteration products and secondary minerals that are a critical part of understanding their near-surface histories on both Mars and Earth. In some martian meteorites, suspected martian preterrestrial alteration products can be distinguished from terrestrial weathering effects Using scanning electron microscopy (SEM), field emission SEM (FE-SEM), transmission electron microscopy (TEM), and energy-dispersive X-ray analysis (EDS), we are studying natural fracture surfaces of ALH 84001 chips, including samples from both the interior and the exterior of the meteorite. Exterior samples include fusion crust surfaces, which are important in determining the extent of terrestrial weathering of meteorites. The focus of this study is weathering features and secondary minerals other than the distinctive carbonate globules that continue to be studied by many researchers.

Wentworth, S. J.↗

Terrestrial Biomarkers for Early Life on Earth as Analogs for Possible Martian Life Forms: Examples of Minerally Replaced Bacteria and Biofilms From the 3.5 - 3.3-Ga Barberton Greenstone Belt, South Africa

The search for extraterrestrial life and especially martian life hinges on a variety of methods used to identify vestiges of what we could recognize as life, including chemical signatures, morphological fossils, and biogenic precipitates. Although the possibility of extant life on Mars (subsurface) is being considered, most exploration efforts may be directed toward the search for fossil life. Geomorphological evidence points to a warmer and wetter Mars early on in its history, a scenario that encourages comparison with the early Earth. For this reason, study of the early terrestrial life forms and environment in which they lived may provide clues as to how to search for extinct martian life. As a contribution to the early Archean database of terrestrial microfossils, we present new data on morphological fossils from the 3.5-3.3-Ga Barberton greenstone belt (BGB), South Africa. This study underlines the variety of fossil types already present in some of the oldest, best-preserved terrestrial sediments, ranging from minerally replaced bacteria and bacteria molds of vaRious morphologies (coccoid, coccobacillus, bacillus) to minerally replaced biofilm. Biofilm or extracellular polymeric substance (EPS) is produced by bacteria and appears to be more readily fossilisable than bacteria themselves. The BGB fossils occur in shallow water to subaerial sediments interbedded with volcanic lavas, the whole being deposited on oceanic crust. Penecontemporaneous silicification of sediments and volcanics resulted in the chertification of the rocks, which were later subjected to low-grade metamorphism (lower greenschist).

Westall, F.↗

High Salt Diets, Bone Strength and Mineral Content of Mature Femur After Skeletal Unloading

It is known that high salt diets increase urinary calcium (Ca) loss, but it is not known whether this effect weakens bone during space flight. The Bone Hormone Lab has studied the effect of high salt diets on Ca balance and whole body Ca in a space flight model (2,8). Neither the strength nor mineral content of the femurs from these studies has been evaluated. The purpose of this study was to determine the effect of high salt diets (HiNa) and skeletal unloading on femoral bone strength and bone mineral content (BMC) in mature rats.

Liang, Michael T. C.↗

Comparison of Radiative Forcing Calculations Due to Mineral Dust from a Transport Model, Satellite Measurements and an Assimilation System

This study uses information on mineral aerosol from a transport model to calculate global radiative forcing values. The transport model is driven by assimilated meteorology and outputs three-dimensional dust spatial information for various size ranges. The dust fields are input to an off-line radiative transfer calculation to obtain the direct radiative forcing due to the dust fields. During June, July and August of 1988 presence of dust 1) reduces the global net incoming radiation at the top of atmosphere (TOA) by 0.3 to 0.7 W/sq m and 2) reduces net incoming radiation at the earth's surface by 1.3 to 2.0 W/sq m. Over Africa our estimates of the reduction of radiation at the top of atmosphere compare well with TOA reductions derived from ERBE and TOMS satellite data. However, our heating rates are not consistent with analysis temperature increments produced by the assimilation system over regions of high aerosol loading. These increments are based on differences between temperature observations and temperatures from the assimilation general circulation model. One explanation is that the lower tropospheric temperatures retrieved by TOVS are being contaminated by mineral aerosol.

Weaver, Clark J.↗

Mineral Mapping Using AVIRIS Data at Ray Mine, AZ

Imaging Spectroscopy enables the identification and mapping of surface mineralogy over large areas. This study focused on assessing the utility of Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data for environmental impact analysis over the Environmental Protection Agency's (EPA) high priority Superfund site Ray Mine, AZ. Using the Spectral Angle Mapper (SAM) algorithm to analyze AVIRIS data makes it possible to map surface materials that are indicative of acid generating minerals. The improved performance of the AVIRIS sensor since 1996 provides data with sufficient signal to noise ratio to characterize up to 8 image endmembers. Specifically we employed SAM to map minerals associated with mine generated acid waste, namely jarositc, goethite, and hematite, in the presence of a complex mineralogical background.

McCubbin, Ian↗

Thermal and Evolved Gas Analyses at Reduced Pressures: A Mineral Database for the Thermal Evolved Gas Analyzer (TEGA)

Volatile-bearing minerals (e.g., Fe-oxyhydroxides, phyllosilicates, carbonates, and sulfates) may be important phases on the surface of Mars. The Thermal Evolved Gas Analyzer (TEGA), which was part of the Mars Polar Lander payload, was to detect and identify volatile-bearing phases in the Martian regolith. The TEGA instrument is composed of a differential scanning calorimetry (DSC) interfaced with an evolved gas analyzer (EGA). The EGA consists of a Herriott cell of a tunable-diode laser (TDL) spectrometer that determines CO, and H2O abundances. The sample chamber in TEGA operates at about 100 mbar (-76 torr) with a N2 carrier gas flow of 0.4 sccm. Essentially no information exists on the effects of reduced pressure on the thermal properties of volatile-bearing minerals. Here we present a database for the thermal behavior of volatile-bearing phases under reduced pressure conditions.

Lauer, H. V., Jr.↗