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At least 1,063 records · Page 59

The SiH vibrational stretch as an indicator of the chemical state of interstellar grains

The infrared spectra of amorphous silicate grains and films formed in a variety of laboratory experiments have been measured. It is found that the frequency of the SiH fundamental stretch is extremely sensitive to the chemical environment of the grain in which the silicon is bound and varies from 2270/cm in oxidized grains to 2110/cm in a reducing environment. It is proposed that features previously observed in W33A could be due to -SiH groups in amorphous silica, partially reduced silica, silicon nitride or slightly oxidized silicon carbide. It is predicted that observations at 2270/cm will reveal a feature due to -SiH groups in highly oxidized interstelar and circumstellar grains. Such a feature might also appear in the spectra of comets.

Moore, Marla H.↗

Laboratory studies of the newly discovered infrared band at 4705.2/cm (2.1253 microns) in the spectrum of Io - The tentative identification of CO2

The present evaluation of results from over 120 laboratory experiments relevant to the Trafton et al. (1991) discovery of a 2.1253-micron line in the spectrum of Io demonstrates that this band is produced by neither overtones nor combinations of the fundamental bands of molecules already noted on Io. Since the band's frequency is close to the first overtone of the nu(3) asymmetric stretching mode of CO2, attention is given this molecule's behavior under Io conditions. While pure solid CO2, and CO2 intimately mixed in a matrix of solid SO2 and H2S, generate bands of similar widths, these fall at frequencies lower than the Io band. Attention is given to the possible identification of the Io band with CO2 multimers of 'clusters' on Io.

Sandford, Scott A.↗

Raman shifting of KrF laser radiation for tropospheric ozone measurements

The differential absorption lidar (DIAL) measurement of tropospheric ozone requires use of high average power UV lasers operating at two appropriate DIAL wavelengths. Laboratory experiments have demonstrated that a KrF excimer laser can be used to generate several wavelengths with good energy conversion efficiencies by stimulated Raman shifting using hydrogen (H2) and deuterium (D2). Computer simulations for an airborne lidar have shown that these laser emissions can be used for the less than 5 percent random error, high resolution measuremment of ozone across the troposphere using the DIAL technique. In the region of strong ozone absorption, laser wavelengths of 277.0 and 291.7 nm were generated using H2 and D2, respectively. In addition, a laser wavelength at 302.0 nm was generated using two cells in series, with the first containing D2 and the second containing H2. The energy conversion efficiency for each wavelength was between 14 and 27 percent.

Grant, William B.↗

Segmented Ge detector rejection of internal beta activity produced by neutron irradiation

Future Ge spectrometers flown in space to observe cosmic gamma-ray sources will incorporate segmented detectors to reduce the background from radioactivity produced by energetic particle reactions. To demonstrate the effectiveness of a segmented Ge detector in rejecting background events due to the beta decay of internal radioactivity, a laboratory experiment has been carried out in which radioactivity was produced in the detector by neutron irradiation. A Cf-252 source of neutrons was used to produce, by neutron capture on Ge-74 (36.5 percent of natural Ge) in the detector itself, Ge-75 (t sub 1/2 = 82.78 min), which decays by beta emission with a maximum electron kinetic energy of 1188 keV. By requiring that an ionizing event deposit energy in two or more of the five segments of the detector, each about 1-cm thick, the beta particles, which have a range of about 1-mm, are rejected, while most external gamma rays incident on the detector are counted. Analysis of this experiment indicates that over 85 percent of the beta events from the decay of Ge-75 are rejected, which is in good agreement with Monte Carlo calculations.

Varnell, L. S.↗

Segmented Ge detectors and mechanical coolers for future gamma-ray astronomy instruments

The effectiveness of a segmented Ge detector in rejecting background events due to the beta decay of internal radioactivity is demonstrated by a laboratory experiment in which radioactivity was produced in the detector by neutron irradiation. A Cf-252 source of neutrons was used to produce, by neutron capture on Ge-74 in the detector itself, Ge-75, which decays by beta emission with a maximum energy of 1188 keV. Simultaneous spectra are taken of the activity in the detector under two conditions: a free spectrum in which all events in the detector are accumulated, and a gated spectrum in which events are accumulated only if they deposit energy in two or more segments. A comparison of the spectra shows that over 85 percent of the beta events are rejected, which is in good agreement with predictions.

Varnell, Larry S.↗

Revived interest in the lunar atmosphere

The recent discoveries of Na and K in the lunar atmosphere are emphasized in a review of lunar atmospheric observations which identifies possible directions of research. Observations are briefly reviewed through the Apollo era which identified the atmosphere as a surface-boundary exosphere, and identified atmospheric constituents included He and Ar which rose and fell by a factor of 20 during the lunar diurnal cycle. Ar-36 and -40 were also identified as were the sources of ionospheric source and sink processes including the solar EUV flux. Na and K are discussed which were identified in a study of the spectroscopic ring effect, and the effects of elemental interaction with the lunar surface can be approximated in laboratory experiments. Observations and measurements of the lunar surface are important for the continued investigation of lunar and other planetary mechanisms.

Morgan, Thomas H.↗

Passive range estimation for rotorcraft low-altitude flight

The automation of rotorcraft low-altitude flight presents challenging problems in control, computer vision and image understanding. A critical element in this problem is the ability to detect and locate obstacles, using on-board sensors, and modify the nominal trajectory. This requirement is also necessary for the safe landing of an autonomous lander on Mars. This paper examines some of the issues in the location of objects using a sequence of images from a passive sensor, and describes a Kalman filter approach to estimate the range to obstacles. The Kalman filter is also used to track features in the images leading to a significant reduction of search effort in the feature extraction step of the algorithm. The method can compute range for both straight line and curvilinear motion of the sensor. A laboratory experiment was designed to acquire a sequence of images along with sensor motion parameters under conditions similar to helicopter flight. Range estimation results using this imagery are presented.

Sridhar, B.↗

Styles of ejecta emplacement under atmospheric conditions

Laboratory experiments provide essential first-order constraints on processes affecting ballistic ejecta and styles of ejecta emplacement under different atmospheric environments at planetary scales. The NASA-Ames Vertical Gun allows impacting different fine-grained particulate targets under varying atmospheric pressure and density, thereby helping to isolate controlling variables. Further analysis now permits characterizing distinct modes of emplacement that reflect the degree of ejecta entrainment within a turbidity flow created by ejecta curtain movement through the atmosphere.

Schultz, P. H.↗

Annoyance caused by advanced turboprop aircraft flyover noise: Comparison of different propeller configurations

A laboratory experiment was conducted to compare the annoyance of flyover noise from advanced turboprop aircraft having different propeller configurations with the annoyance of conventional turboprop and turbofan aircraft flyover noise. A computer synthesis system was used to generate 40 realistic, time varying simulations of advanced turboprop takeoff noise. Of the 40 noises, single-rotating propeller configurations (8) and counter-rotating propeller configurations with an equal (12) and unequal (20) number of blades on each rotor were represented. Analyses found that advanced turboprops with single-rotating propellers were, on average, slightly less annoying than the other aircraft. Fundamental frequency and tone-to-broadband noise ratio affected annoyance response to advanced turboprops, but the effects varied with propeller configuration and noise metric. The addition of duration corrections and corrections for tones above 500 Hz to the noise measurement procedures improved annoyance prediction ability.

Mccurdy, David A.↗

Quantification of UV stimulated ice chemistry: CO and CO2

Recent laboratory experiments are presented that show that during photolysis of the pure ices there is evidence of the interconversion of CO to CO2 and CO2 to CO using Lyman alpha (1216A) radiation. In addition, there is a substantial amount of another substance being produced. This substance is evident by its infrared absorption peak at 2235 cm(-1). It is believed that this new peak is due to carbon suboxide, C3O2. CO and CO2 have already been detected in comets, and C3O2 has been suggested as a cometary from radiation of CO. Comparisons are made between our results at 1215A and proton radiation experiments and radiation at other wavelengths. The suggestion is that the processing of ices is energy dependent, i.e., dependent on the type of radiation. Several difficult problems have to be solved before these radiation conversions can be quantified. The steps that we are taking to quantify the kinetics are discussed.

Anicich, V. G.↗

Kinetic conversion of CO to CH4 in the Solar System

Some of the most interesting chemistry in the Solar System involves changes in the oxidation state of the simple carbon species. The chemical pathways for the conversion of CH4 to CO and CO2 are for the most part known. The reverse process, the reduction of CO to CH4, is, however, poorly understood. This is surprising in view of the importance of the reduction process in the chemistry of the Solar System. Recently we investigated the chemical kinetics of a hitherto unsuspected reaction. It is argued that the formation of the methoxy radical (CH3O) from H+H2CO may play an essential role in the reduction of CO to CH4. The rate coefficient for this reaction has been estimated using the approximate theory of J. Troe and transition state theory. We will discuss the implications of this reaction for the chemistry of CO on Jupiter, in the solar nebula, for interpreting the laboratory experiments of A. Bar-Nun and A. Shaviv and A. Bar-Nun and S. Chang, and for organic synthesis in the prebiotic terrestrial atmosphere. The possible relation of CO reduction in the solar nebula and polyoxymethylene observed in comet Halley will be discussed.

Yung, Y. L.↗

Annoyance caused by aircraft en route noise

A laboratory experiment was conducted to quantify the annoyance response of people on the ground to enroute noise generated by aircraft at cruise conditions. The en route noises were ground level recordings of eight advanced turboprop aircraft flyovers and six conventional turbofan flyovers. The eight advanced turboprop enroute noises represented the NASA Propfan Test Assessment aircraft operating at different combinations of altitude, aircraft Mach number, and propeller tip speed. The conventional turbofan en route noises represented six different commercial airliners. The overall durations of the en route noises varied from approximately 40 to 160 sec. In the experiment, 32 subjects judged the annoyance of the en route noises as well as recordings of the takeoff and landing noises of each of 5 conventional turboprop and 5 conventional turbofan aircraft. Each of the noises was presented at three sound pressure levels to the subjects in an anechoic listening room. Analysis of the judgments found small differences in annoyance between three combinations of aircraft type and operation. Current tone and corrections did not significantly improve en route annoyance prediction. The optimum duration-correction magnitude for en route noise was approximately 1 dB per doubling of effective duration.

Mccurdy, David A.↗

Planetary geosciences, 1989-1990

NASA's Planetary Geosciences Programs (the Planetary Geology and Geophysics and the Planetary Material and Geochemistry Programs) provide support and an organizational framework for scientific research on solid bodies of the solar system. These research and analysis programs support scientific research aimed at increasing our understanding of the physical, chemical, and dynamic nature of the solid bodies of the solar system: the Moon, the terrestrial planets, the satellites of the outer planets, the rings, the asteroids, and the comets. This research is conducted using a variety of methods: laboratory experiments, theoretical approaches, data analysis, and Earth analog techniques. Through research supported by these programs, we are expanding our understanding of the origin and evolution of the solar system. This document is intended to provide an overview of the more significant scientific findings and discoveries made this year by scientists supported by the Planetary Geosciences Program. To a large degree, these results and discoveries are the measure of success of the programs.

Zuber, Maria T.↗

Laboratory Velocimeter Measurements Using the Edge Technique

We have developed a simple but powerful measurement methodology using the edge technique to measure the Doppler shift of backscatter laser radiation. With this method, instantaneous velocity information, including wind measurements, can be obtained with sub-meter-per-second accuracy and with high range resolution using a pulsed lidar system. This paper describes laboratory experiments that demonstrate the basic principles of the edge technique. These experiments demonstrate the sensitivity of the technique and the high velocity accuracy which can be obtained. In addition, many of the characteristics which make the edge technique a powerful method for use in lidar wind application were verified. These include the insensitivity of the measurement to laser and/or edge filter frequency jitter and drift, and the ability to make Doppler shift measurements which are of the order of 100 times better than the spectral bandwidth of the measurement (the combined spectral width of the laser and edge filter).

Gentry, Bruce M.↗

Tempered glass and thermal shock of ceramic materials

A laboratory experiment is described that shows students the different strengths and fracture toughnesses between tempered and untempered glass. This paper also describes how glass is tempered and the materials science aspects of the process.

Bunnell, L. Roy↗

Computer vision in microstructural analysis

The following is a laboratory experiment designed to be performed by advanced-high school and beginning-college students. It is hoped that this experiment will create an interest in and further understanding of materials science. The objective of this experiment is to demonstrate that the microstructure of engineered materials is affected by the processing conditions in manufacture, and that it is possible to characterize the microstructure using image analysis with a computer. The principle of computer vision will first be introduced followed by the description of the system developed at Texas A&M University. This in turn will be followed by the description of the experiment to obtain differences in microstructure and the characterization of the microstructure using computer vision.

Srinivasan, Malur N.↗

Determining significant material properties: A discovery approach

The following is a laboratory experiment designed to further understanding of materials science. The experiment itself can be informative for persons of any age past elementary school, and even for some in elementary school. The preparation of the plastic samples is readily accomplished by persons with resonable dexterity in the cutting of paper designs. The completion of the statistical Design of Experiments, which uses Yates' Method, requires basic math (addition and subtraction). Interpretive work requires plotting of data and making observations. Knowledge of statistical methods would be helpful. The purpose of this experiment is to acquaint students with the seven classes of recyclable plastics, and provide hands-on learning about the response of these plastics to mechanical tensile loading.

Karplus, Alan K.↗

Investigations on atomic-vapor-filter high-spectral-resolution lidar for temperature measurements

The temperature measurement by the analysis of Rayleigh scattered laser radiation with atomic vapor filters is investigated in both theory and laboratory experiments. Synthetic air is irradiated with a cw dye laser at 283 nano-meters, and the backscattered spectrum is analyzed with two lead vapor cells in one oven. Temperature measurements are carried out, and the effect of different parameters on the accuracy is investigated. Important aspects for the realization of a lidar are given.

Voss, E.↗