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At least 1,063 records · Page 59
All sourcesNASA NTRSDOE OSTI
NASA NTRS2012

Simulations of Infrared Radiances Over a Deep Convective Cloud System Observed During TC4- Potential for Enhancing Nocturnal Ice Cloud Retrievals

Retrievals of ice cloud properties using infrared measurements at 3.7, 6.7, 7.3, 8.5, 10.8, and 12.0 microns can provide consistent results regardless of solar illumination, but are limited to cloud optical thicknesses tau < approx.6. This paper investigates the variations in radiances at these wavelengths over a deep convective cloud system for their potential to extend retrievals of tau and ice particle size D(sub e) to optically thick clouds. Measurements from the Moderate Resolution Imaging Spectroradiometer Airborne Simulator--ASTER, the Scanning High-resolution Interferometer Sounder, the Cloud Physics Lidar (CPL), and the Cloud Radar System (CRS) aboard the NASA ER-2 aircraft during the NASA TC4 (Tropical Composition, Cloud and Climate Coupling) experiment flight during 5 August 2007, are used to examine the retrieval capabilities of infrared radiances over optically thick ice clouds. Simulations based on coincident in-situ measurements and combined cloud tau from CRS and CPL measurements are comparable to the observations. They reveal that brightness temperatures at these bands and their differences (BTD) are sensitive to tau up to approx.20 and that for ice clouds having tau > 20, the 3.7 - 10.8 microns and 3.7 - 6.7 microns BTDs are the most sensitive to D(sub e). Satellite imagery appears consistent with these results. Keywords: clouds; optical depth; particle size; satellite; TC4; multispectral thermal infrared

CRS and CPL↗
NASA NTRS2012

Design and Status of the Balloon Experimental Twin Telescope for Infrared Interferometry (BETTII): An Interferometer at the Edge of Space

The Balloon Experimental Twin Telescope for Infrared Interferometry (BETTII) is an 8-meter baseline far-infraredinterferometer designed to fly on a high altitude balloon. BETTII uses a double-Fourier Michelson interferometer tosimultaneously obtain spatial and spectral information on science targets; the long baseline permits subarcsecond angular resolution, a capability unmatched by other far-infrared facilities. Here, we present key aspects of the overall design of the mission and provide an overview of the current status of the project. We also discuss briefly the implications of this experiment for future space-based far-infrared interferometers.

Balloon↗
NASA NTRS2016

Near-Infrared Spectroscopy of the Y0 WISEP J173835.52+273258.9 and the Y1 WISE J035000.32-565830.2: the Importance of Non-Equilibrium Chemistry

We present new near-infrared spectra, obtained at Gemini Observatory, for two Y dwarfs: WISE J035000.32−565830.2 (W0350) and WISEP J173835.52+273258.9 (W1738). A FLAMINGOS-2 R = 540 spectrum was obtained for W0350, covering 1.0 < λ micrometer < 1.7, and a cross-dispersed GNIRS R = 2800 spectrum was obtained for W1738, covering 0.993 - 1.087 micrometer, 1.191 - 1.305 micrometer, 1.589 - 1.631 micrometer, and 1.985 - 2.175 micrometer, in four orders. We also present revised Y JH photometry for W1738, using new NIRI Y and J imaging, and a re-analysis of the previously published NIRI H band images. We compare these data, together with previously published data for late-T and Y dwarfs, to cloud-free models of solar metallicity, calculated both in chemical equilibrium and with disequilibrium driven by vertical transport. We find that for the Y dwarfs the non-equilibrium models reproduce the near-infrared data better than the equilibrium models. The remaining discrepancies suggest that fine-tuning the CH4/CO and NH3/N2 balance is needed. Improved trigonometric parallaxes would improve the analysis. Despite the uncertainties and discrepancies, the models reproduce the observed near-infrared spectra well. We find that for the Y0, W1738, T(sub eff) = 425 +/- 25K and log g = 4.0 +/- 0.25, and for the Y1, W0350, T(sub eff) = 350 +/- 25K and log g = 4.0 +/- 0.25. W1738 may be metal-rich. Based on evolutionary models, these temperatures and gravities correspond to a mass range for both Y dwarfs of 3 - 9 Jupiter masses, with W0350 being a cooler, slightly older, version of W1738; the age of W0350 is 0.3 - 3 Gyr, and the age of W1738 is 0.15 - 1 Gyr.

two Y dwarfs↗
NASA NTRS2015

Modulation Transfer Function of Infrared Focal Plane Arrays

Modulation transfer function (MTF) is the ability of an imaging system to faithfully image a given object. The MTF of an imaging system quantifies the ability of the system to resolve or transfer spatial frequencies. In this presentation we will discuss the detail MTF measurements of 1024x1024 pixels mid -wavelength and long- wavelength quantum well infrared photodetector, and 320x256 pixels long- wavelength InAs/GaSb superlattice infrared focal plane arrays (FPAs). Long wavelength Complementary Barrier Infrared Detector (CBIRD) based on InAs/GaSb superlattice material is hybridized to recently designed and fabricated 320x256 pixel format ROIC. The n-type CBIRD was characterized in terms of performance and thermal stability. The experimentally measured NE delta T of the 8.8 micron cutoff n-CBIRD FPA was 18.6 mK with 300 K background and f/2 cold stop at 78K FPA operating temperature. The horizontal and vertical MTFs of this pixel fully delineated CBIRD FPA at Nyquist frequency are 49% and 52%, respectively.

long-wave infrared↗
NASA NTRS1995

Some Recent Advances and Applications of Infrared Detector Technology at the Jet Propulsion Laboratory

The Jet Propulsion Laboratory has a long history in the development and application of infrared detector technology for the exploration of our planetary system. We will describe some recent applications of IR detector technology at JPL for ground based astronomy, the Earth Observing System, the Cassini Mission to Saturn, and the other proposed planetary missions. The infrared detector technologies to be discussed include single element, multiplexed linear and staring arrays, using a wide variety of infrared sensing materials including InSb, InGaAs, HgCdTe (PV and PC) and SiAs.

IR↗
NASA NTRS2023

Thermal Infrared Dust Optical Depth and Coarse-Mode Effective Diameter Over Oceans Retrieved From Collocated MODIS and CALIOP Observations

In this study, we developed a novel algorithm based on the collocated Moderate Resolution Imaging Spectroradiometer (MODIS) thermal infrared (TIR) observations and dust vertical profiles from the Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) to simultaneously retrieve dust aerosol optical depth at 10 µm (DAOD10μm) and the coarse-mode dust effective diameter (Deff) over global oceans. The accuracy of the Deff retrieval is assessed by comparing the dust lognormal volume particle size distribution (PSD) corresponding to retrieved Deff with the in-situ measured dust PSDs from the AER-D, SAMUM-2 and SALTRACE field campaigns through case studies. The new DAOD10μm retrievals were evaluated first through comparisons with the collocated DAOD10.6μm retrieved from the combined Imaging Infrared Radiometer (IIR) and CALIOP observations from our previous study (Zheng et al. 2022). The pixel-to-pixel comparison of the two DAOD retrievals indicates a good agreement (R~0.7) and a significant reduction of (~50%) retrieval uncertainties largely thanks to the better constraint on dust size. In a climatological comparison, the seasonal and regional (5°×2°) mean DAOD10um retrievals based on our combined MODIS and CALIOP method are in good agreement with the two independent Infrared Atmospheric Sounding Interferometer (IASI) products over three dust transport regions (i.e., North Atlantic (NA; R = 0.9), Indian Ocean (IO; R = 0.8) and North Pacific (NP; R = 0.7)). Using the new retrievals from 2013 to 2017, we performed a climatological analysis of coarse mode dust Deff over global oceans. We found that dust Deff over IO and NP are up to 20% smaller than that over NA. Over NA in summer, we found a ~50% reduction of the number of retrievals with Deff > 5 μm from 15°W to 35°W and a stable trend of Deff average at 4.4 μm from 35°W throughout the Caribbean Sea (90°W). Over NP in spring, only ~5% of retrieved pixels with Deff > 5 μm are found from 150°E to 180°, while the mean Deff remains stable at 4.0 μm throughout eastern NP. To our best knowledge, this study is the first to retrieve both DAOD and coarse-mode dust particle size over global oceans for multiple years. This retrieval dataset provides insightful information for evaluating dust long-wave radiative effects and coarse mode dust particle size in models.

dust optical depth↗
DOE OSTI2018

Results of Absolute Cavity Pyrgeometer and Infrared Integrating Sphere Comparisons

Accurate and traceable atmospheric longwave irradiance measurements are required for understanding radiative impacts on the Earth's energy budget. The standard to which pyrgeometers are traceable is the interim World Infrared Standard Group (WISG), maintained in the Physikalisch-Meteorologisches Observatorium Davos (PMOD). The WISG consists of four pyrgeometers that were calibrated using Rolf Philipona's Absolute Sky-scanning Radiometer [1]. The Atmospheric Radiation Measurement (ARM) facility has recently adopted the WISG to maintain the traceability of the calibrations of all Eppley precision infrared radiometer (PIR) pyrgeometers. Subsequently, Julian Grobner [2] developed the infrared interferometer spectrometer and radiometer (IRIS) radiometer, and Ibrahim Reda [3] developed the absolute cavity pyrgeometer (ACP). The ACP and IRIS were developed to establish a world reference for calibrating pyrgeometers with traceability to the International System of Units (SI). The two radiometers are unwindowed with negligible spectral dependence, and they are traceable to SI units through the temperature scale (ITS-90). The two instruments were compared directly to the WISG three times at PMOD and twice at the Southern Great Plains (SGP) facility to WISG-traceable pyrgeometers. The ACP and IRIS agreed within +/- 1 W/m2 to +/- 3 W/m2 in all comparisons, whereas the WISG references exhibit a 2-5 Wm2 low bias compared to the ACP/IRIS average, depending on the water vapor column, as noted in Grobner et al. [4]. Consequently, a case for changing the current WISG has been made by Grobner and Reda. However, during the five comparisons the column water vapor exceeded 8 mm. Therefore, it is recommended that more ACP and IRIS comparisons should be held under different environmental conditions and water vapor column content to better establish the traceability of these instruments to SI with established uncertainty.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2020

Infrared absorption spectroscopy of dynamically compressed water

Streaked visible spectroscopy is well established in dynamic compression research. Infrared measurements remain problematic, however, due to the diminishing sensitivity of streak camera photocathodes beyond 800 nm. Time-stretch techniques offer an alternative method for probing infrared features during single-event experiments. This paper discusses the development of a time-stretch spectroscopy diagnostic using dispersed supercontinuum laser pulses. The technique is applied to near-infrared measurements of liquid water during multiple shock compression.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2024

ASMS 2024 Investigation of Uranyl Perchlorate Anion Complexes in the Gas Phase via Infrared Multiphoton Dissociation and Collision Induced Dissociation

Investigation of Uranyl Perchlorate Anion Complexes in the Gas Phase via Infrared Multiphoton Dissociation and Collision Induced Dissociation Brittany D. M. Hodges, Christopher A. Zarzana, JungSoo Kim, Jonathan Martens, and W. C. M. Berden Introduction (120 words max) Effects of electronic structure on chemical bonding and reactivity play critical roles shaping the chemical bonding and reactivity behaviors of heavy elements. Understanding the role of f electrons in bond formation between the actinide-series elements like uranium with other ligands is critical for solving technical challenges associated with these heavy elements, important to nuclear fuel cycles, efficient separations of rare earth metals, and understanding the chemistry of stored nuclear fuels and related environmental management sites. In this study, we further examine the interactions between uranyl and the perchlorate ion in order to understand the structures of these ions through the use of IRMPD. Here we report the IRMPD spectra of [UO2(ClO4)3]-, [UO3(ClO4)2]-, and a proposed transition state. Methods (120 word max) IRMPD spectra and CID spectra were acquired using a Bruker amaZon QIT/MS instrument at the Free-Electron Lasers for Infrared eXperiments (FELIX) laboratory at Radboud University. The FELIX QIT/MS is modified to allow for the high-intensity tunable IR beam from FELIX to be directed into the ion packet, resulting in multiphoton dissociation that is measured only when the IR frequency is in resonance with an adequately high absorption vibrational mode of the mass-selected complex. DFT geometry optimizations and frequency calculations using the Gaussian suite of programs were performed using B3LYP, TPSSh, and PBE0 level of theory with 6-31+G(d) basis for the O, C, H, and N atoms and the SDD basis set for U. The SDD basis set employs the Stuttgart/Dresden effective core potential. Preliminary Data or Plenary Speakers Abstract (300 words max) Metal ion clusters of uranyl perchlorate were formed via direct electrospray ionization. For each metal ligand complex of interest, the parent ion was isolated and collision induced dissociation fragmentation and Infrared Multiphoton Dissociation (IRMPD) fragmentation spectra were acquired. Results presented here are the first look at the IRMPD spectra of [UO3(ClO4)2]-, [UO2(ClO4)3]-. Structures were examined using Gaussian at different levels of theory B3LYP level of theory, TPPSh and PBE0 levels, to reflect the behaviors of uranium metal ligand complexes most accurately. In these structures, we identified an overlap between each of these uranyl stretches resulting in their largely being obscured by a perchlorate mode. The CID product spectra agree with similar structures reported by Groenewold for uranyl nitrate in 2006 (10.1021/ja058106n).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2013

STAR FORMATION RATES IN RESOLVED GALAXIES: CALIBRATIONS WITH NEAR- AND FAR-INFRARED DATA FOR NGC 5055 AND NGC 6946

We use the near-infrared Br{gamma} hydrogen recombination line as a reference star formation rate (SFR) indicator to test the validity and establish the calibration of the Herschel/PACS 70 {mu}m emission as a SFR tracer for sub-galactic regions in external galaxies. Br{gamma} offers the double advantage of directly tracing ionizing photons and of being relatively insensitive to the effects of dust attenuation. For our first experiment, we use archival Canada-France-Hawaii Telescope Br{gamma} and Ks images of two nearby galaxies: NGC 5055 and NGC 6946, which are also part of the Herschel program KINGFISH (Key Insights on Nearby Galaxies: a Far-Infrared Survey with Herschel). We use the extinction corrected Br{gamma} emission to derive the SFR(70) calibration for H II regions in these two galaxies. A comparison of the SFR(70) calibrations at different spatial scales, from 200 pc to the size of the whole galaxy, reveals that about 50% of the total 70 {mu}m emission is due to dust heated by stellar populations that are unrelated to the current star formation. We use a simple model to qualitatively relate the increase of the SFR(70) calibration coefficient with decreasing region size to the star formation timescale. We provide a calibration for an unbiased SFR indicator that combines the observed H{alpha} with the 70 {mu}m emission, also for use in H II regions. We briefly analyze the PACS 100 and 160 {mu}m maps and find that longer wavelengths are not as good SFR indicators as 70 {mu}m, in agreement with previous results. We find that the calibrations show about 50% difference between the two galaxies, possibly due to effects of inclination.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

SPECTROSCOPIC INFRARED EXTINCTION MAPPING AS A PROBE OF GRAIN GROWTH IN IRDCs

We present spectroscopic tests of MIR to FIR extinction laws in IRDC G028.36+00.07, a potential site of massive star and star cluster formation. Lim and Tan developed methods of FIR extinction mapping of this source using Spitzer-MIPS 24 μm and Herschel-PACS 70 μm images, and by comparing to MIR Spitzer-IRAC 3–8 μm extinction maps, found tentative evidence for grain growth in the highest mass surface density regions. Here we present results of spectroscopic infrared extinction mapping using Spitzer-IRS (14–38 μm) data of the same Infrared dark cloud (IRDC). These methods allow us to first measure the SED of the diffuse Galactic interstellar medium that is in the foreground of the IRDC. We then carry out our primary investigation of measuring the MIR to FIR opacity law and searching for potential variations as a function of mass surface density within the IRDC. We find relatively flat, featureless MIR–FIR opacity laws that lack the ∼12 and ∼35 μm features associated with the thick water ice mantle models of Ossenkopf and Henning. Their thin ice mantle models and the coagulating aggregate dust models of Ormel et al. are a generally better match to the observed opacity laws. We also find evidence for generally flatter MIR to FIR extinction laws as mass surface density increases, strengthening the evidence for grain and ice mantle growth in higher density regions.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

Excitation of Molecular Hydrogen in the Orion Bar PhotodissociationRegion from a Deep Near-infrared IGRINS Spectrum

We present a deep near-infrared spectrum of the Orion Bar Photodissociation Region (PDR) taken with the Immersion Grating INfrared Spectrometer (IGRINS) on the 2.7 m telescope at the McDonald Observatory. IGRINS has high spectral resolution (R∼45,000) and instantaneous broad wavelength coverage (1.45–2.45 μm), enabling us to detect 87 emission lines from rovibrationally excited molecular hydrogen (H{sub 2}) that arise from transitions out of 69 upper rovibration levels of the electronic ground state. These levels cover a large range of rotational and vibrational quantum numbers and excitation energies, making them excellent probes of the excitation mechanisms of H{sub 2} and physical conditions within the PDR. The Orion Bar PDR is thought to consist of cooler high density clumps or filaments (T=50--250 K, n{sub H}=10{sup 5}--10{sup 7} cm{sup −3}) embedded in a warmer lower density medium (T=250--1000 K, n{sub H}=10{sup 4}--10{sup 5} cm{sup −3}). We fit a grid of constant temperature and density Cloudy models, which recreate the observed H{sub 2} level populations well, to constrain the temperature to a range of 600–650 K and the density to n{sub H}=2.5×10{sup 3}--10{sup 4} cm{sup −3}. The best-fit model gives T = 625 K and n{sub H}=5×10{sup 3} cm{sup −3}. This well-constrained warm temperature is consistent with kinetic temperatures found by other studies for the Orion Bar’s lower density medium. However, the range of densities well fit by the model grid is marginally lower than those reported by other studies. We could be observing lower density gas than the surrounding medium, or perhaps a density-sensitive parameter in our models is not properly estimated.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS2016

Radiation Tolerance Studies of Long Wavelength Infrared InAs/GaSb Detectors

In this work we investigated the effect of proton irradiation on the performance of long wavelength infrared (LWIR) InAs/GaSb photodiodes (λ(sub c) = 10.2µm) based on the complementary barrier infrared detector (CBIRD) design. We found that irradiation with 68MeV protons up to the total ionizing dose TID = 200 kRad results in only small (about 15%) decrease of the Quantum Efficiency and does not increase the operational bias of the photodiodes. However, the irradiation causes a significant increase of the dark current from j(sub d) = 5x10(exp -5) A/sq cm at V(sub b) = 0.1V and T = 80K to j(sub d) = 6x10(exp -3) A/sq cm at TID = 200 kRad. This change in the dark current mechanism can be attributed to the onset of surface leakage current, generated by the trap assisted tunneling processes in the proton displacement damage areas near the device sidewalls.

InAs/GaSb photodiodes↗
DOE OSTI2024

Detection and Signal Processing for Near-Field Nanoscale Fourier Transform Infrared Spectroscopy

Researchers from a broad spectrum of scientific and engineering disciplines are increasingly using scattering-type near-field infrared spectroscopic techniques to characterize materials non-destructively with nanoscale spatial resolution. However, a sub-optimal understanding of a technique's implementation can complicate data interpretation and act as a barrier to entering the field. Here the key detection and processing steps involved in producing scattering-type near-field nanoscale Fourier transform infrared spectra (nano-FTIR) are outlined. The self-contained mathematical and experimental work derives and explains: i) how normalized complex-valued nano-FTIR spectra are generated, ii) why the real and imaginary components of spectra qualitatively relate to dispersion and absorption respectively, iii) a new and generally valid equation for spectra which can be used as a springboard for additional modeling of the scattering processes, and iv) an algebraic expression that can be used to extract an approximation to the sample's local extinction coefficient from nano-FTIR. The algebraic model for weak oscillators is validated with nano-FTIR and attenuated total reflectance Fourier transform infrared (ATR-FTIR) spectra on samples of polystyrene and Kapton and further provides a pedagogical pathway to cementing some of the technique's key qualitative attributes.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Low‐Loss Far‐Infrared Surface Phonon Polaritons in Suspended SrTiO 3 Nanomembranes

Phonon polaritons (PhPs), excitations arising from the coupling of light with lattice vibrations, enable light confinement and local field enhancement, which is essential for various photonic and thermal applications. To date, PhPs with high confinement and low loss are mainly observed in the mid-infrared regime and mostly in manually exfoliated flakes of van der Waals (vdW) materials. In this work, the existence of low-loss, thickness-tunable phonon polaritons in the far-infrared regime within transferable freestanding SrTiO 3 membranes synthesized through a scalable approach, achieving high figures of merit is demonstrated, which are comparable to the previous record values from the vdW materials. Leveraging atomic precision in thickness control, large dimensions, and compatibility with mature oxide electronics, functional oxide membranes present a promising large-scale 2D platform alternative to vdW materials for on-chip polaritonic technologies in the infrared regime.

functional oxide membranes↗
DOE OSTI2022

Electrical Switching of Nematic Plasmonic Nanocolloids for Infrared Solar Gain Control

Controlling solar gain is essential to reduce the energy consumption by residential and commercial buildings, which are responsible for ≈40% of all energy generated globally. However, the dynamic control of solar gain in the near-infrared that corresponds to ≈50% of the overall Sun's energy at the Earth's surface, separately from the visible spectral range has been a challenge, albeit commercial coatings provide passive control while retaining highly visible transmission. To address this problem, in this paper switchable silver colloids (SSCs) are demonstrated, colloidal analogs of the common silver coatings used for solar gain control. When dispersed in a nematic liquid crystal, orientations of such plasmonic silver nanoplates are controlled by ≈1 V low-voltage electric fields, allowing for sub-second switching of the near-infrared-based solar gain. Installed and retrofit products made from thin films of such nanoplate dispersions confined between glass and plastic substrates, respectively, exhibit electrically controlled infrared-based solar gain while retaining high visible-range transparency, low haze, and high color rendering index. Furthermore, this study's findings reveal a great potential of soft-matter systems in addressing energy-related problems.

36 MATERIALS SCIENCE↗
DOE OSTI2013

Resonant infrared pulsed laser deposition of cyclic olefin copolymer films

Barrier materials on thin-film organic optoelectronic devices inhibit the uptake of water, oxygen, or environmental contaminants, and fabricating them is a major challenge. By definition, these barrier layers must be insoluble, so the usual routes to polymer- or organic-film deposition by spin coating are not problematic. In this paper, we report comparative studies of pulsed laser deposition of cyclic olefin copolymer (COC), an excellent moisture barrier and a model system for a larger class of protective materials that are potentially useful in organic electronic devices, such as organic light-emitting diodes (OLEDs). Thin films of COC were deposited by resonant and nonresonant infrared pulsed laser ablation of solid COC targets, using a free-electron laser tuned to the 3.43 μm C–H stretch of the COC, and a high-intensity nanosecond Q-switched laser operated at 1064 nm. The ablation craters and deposited films were characterized by scanning-electron microscopy, Fourier-transform infrared spectrometry, atomic-force microscopy, high-resolution optical microscopy, and surface profilometry. Thermal-diffusion calculations were performed to determine the temperature rise induced in the film at the C–H resonant wavelength. The results show that resonant infrared pulsed laser deposition (RIR-PLD) is an effective, low-temperature thin-film deposition technique that leads to evaporation and deposition of intact molecules in homogeneous, smooth films. Nonresonant PLD, on the other hand, leads to photothermal damage, degradation of the COC polymers, and to the deposition only of particulates.

36 MATERIALS SCIENCE↗