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At least 1,063 records · Page 59

Computed barrier heights for H + CH2O yields CH3O yields CH2OH

The barrier heights (including zero-point effects) for H + CH2O yields CH3O and CH3O yields CH2OH have been computed using complete active space self consistent field (CASSCF)/gradient calculations to define the stationary point geometries and harmonic frequencies and internally contracted configuration-interaction (CCI) to refine the energetics. The computed barrier heights are 5.6 kcal/mol and 30.1 kcal/mol, respectively. The former barrier height compares favorably to an experimental activation energy of 5.2 kcal/mol.

Walch, Stephen P.↗

Temperature dependence of electronic energy transfer and quenching in copolymer films of styrene and 2-(2'-hydroxy-5'-vinylphenyl)-2H-benzotriazole

Quenching of the emission of both the polystyrene monomer and the excimer for a series of varying composition copolymer films of styrene and 2-(2'-hydroxy-5'-vinylphenyl)-2H-benzotriazole is reported. The preponderance of quenching for both the monomer and excimer emissions is due to interception of the migrating excitation at the quencher site, although additional quenching results via long-range dipole-dipole energy transfer from the monomer and excimer traps to the quencher trap. The quenching of the monomer fluorescence and phosphorescence and that of the excimer fluorescence were found to be temperature independent over the ranges 14-58 and 191-296 K, respectively. Most significantly, it is concluded that the energy migration process is temperature independent over the range 14-296 K.

O'Connor, Donald B.↗

A Hubble Space Telescope planetary camera view of giant H II regions - The Wolf-Rayet content of NGC 595 and NGC 604 in M33

We present images of NGC 595 and NGC 604, the most massive giant H II regions in M33, obtained with the Planetary Camera aboard the HST in order to study their WR population. Fourteen WR and/or Of candidates are detected in NGC 604, and eleven in NGC 595. All previously claimed 'superluminous' WR stars are found to be tight (diameter less than 3 pc) stellar aggregates containing one (or sometimes more) normal WR star. As suspected from ground-based data, the WR/O number ratio is significantly higher in NGC 595 (about 0.3) than in NGC 604 (about 0.1). The WR stars may be major contributors to the output of mechanical power and energy into the interstellar medium in both clusters. Over the observable initial mass range, the initial mass functions (IMFs) have similar slopes. These IMFs are somewhat flatter than those generally derived for massive stars in the Galaxy or the Magellanic Clouds.

Drissen, Laurent↗

Optical configurations of H I Lyman-alpha coronagraph/polarimeters

The Multi-Spectral Solar Telescope Array (MSSTA) has obtained numerous high-resolution soft X-ray/EUV/FUV solar images with multilayer telescopes; these show dramatic prominences, spicules, and threadlike limb structures. There is excellent correlation between faint Lyman-alpha coronal structures seen in the digitized MSSTA images and prominences seen in H-alpha images gathered by ground-based observatories. The MSSTA has established the feasibility of an all-reflecting, imaging Ly-alpha coronagraph/polarimeter.

Hoover, Richard B.↗

Magombedze - A new H-chondrite with light-dark structure

Magombedze is a light-dark structured H-chondrite breccia that fell in Zimbabwe on July 2, 1990 at 15:30 GMT. White clasts are moderately shocked and have equilibrated mafic silicates (pyroxene Fs(16-18), olivine Fa(18-19)) together with clear optically-recognizable plagioclase of variable composition (An(9-13) found); chondrules are distinct but contain no trace of preserved glass. The darker surrounding material contains a higher proportion of fine-grained metal and sulfide than the white clasts, and many of its constituent grains show little evidence of shock. Mafic silicates in the dark lithology are distinctly less-equilibrated (pyroxene Fs(5-21), olivine Fa(11-20)) than those in the white clasts, and many chondrules preserve brown devitrified glass; some metamorphic plagioclase of variable composition (An(11-22) found) is present. Some monoclinic pyroxene occurs in both fractions, but it is relatively common in the dark fraction. The white clasts are classified as H5, and the enclosing dark material is H3-5.

Macpherson, Glenn J.↗

Pressure broadening of the 2.5 THz H(Cl-35) rotational line by N2 and O2

The pressure broadening coefficients of the 2.5 THz rotation line of H(Cl-35) by N2 and O2, for application to the analysis of far infrared spectra obtained in the stratosphere, are reported. The broadening coefficients were measured in absorption at 296 and 201 L using a tunable far infrared spectrometer. Results show that at room temperature the N2 pressure broadening coefficient is 0.0669 +/-0.0021/cm/atm (2sigma), with a temperature coefficient B of 0.58 +/-0.02.

Park, K.↗

Simultaneous observations of H(+) and O(+) ions at two altitudes by the Akebono and Dynamics Explorer 1 satellites

Simultaneous observations of H(+) and O(+) ions from the suprathermal ion mass spectrometer on Akebono and the energetic ion composition spectrometer on Dynamics Explorer 1 are reported. These observations were performed simultaneously above and below regions of ion acceleration on auroral and polar cap magnetic field lines. The evening auroral zonal data directly confirm the existence of an ionospheric preenergization mechanism for oxygen ions. The preenergized oxygen ions have characteristic energies of the order of 10 eV and are transported to altitudes of several thousand kilometers where they acquire significant additional energy. The data indicate that the creation (energization) and transport of streams of upflowing ions in the polar cap is more complex than previously anticipated.

Peterson, W. K.↗

Fall and recovery of the Noblesville (Indiana, U.S.A.) H chondrite

We describe the circumstances of fall of a 0.5-kg meteorite that landed in Noblesville, Indiana, USA, 3.6 m in front of two witnesses on 1991 August 31. Provisional assessment of Noblesville as an H chondrite is confirmed by data reported elsewhere which demonstrate that it is a regolith breccia with unusual properties.

Lipschutz, Michael E.↗

Are crystalline C-(H-O-N) carbons the elusive meteoritic carbynes?

I present an internally consistent reinterpretation of carbyne diffraction data making a few plausible assumptions. The results support that carbynes could be crystalline, randomly interstratified (or mixed-layered) carbons with variable C/(C+H+O+N) ratios rather than thermodynamically stable carbon allotropes. The metastable carbynes are likely the result of incomplete, kinetically-inhibited, low-temperature pyrolysis of precursor material. A renewed interest in meteoritic carbynes should seek to combine light-element chemistry and crystallography of these elusive carbons.

Rietmeijer, Frans J. M.↗

Order/disorder and phase diagram of H on Pd(100)

A phase boundary for H-Pd(100) was calculated using the Metropolis (1953) algorithm and the embedded atom method (EAM) described by Daw and Foiles (1987). The calculated phase boundary agreed with an experimentally determined phase boundary in its curvature and the coverage at which maximum Tc appeared, but was about 125 K lower than the experimental phase boundary.

Tibbits, P.↗

The H + OCS hot atom reaction - CO state distributions and translational energy from time-resolved infrared absorption spectroscopy

Time-resolved infrared diode laser spectroscopy has been used to probe CO internal and translational excitation from the reaction of hot H atoms with OCS. Product distributions should be strongly biased toward the maximum 1.4 eV collision energy obtained from 278 nm pulsed photolysis of HI. Rotations and vibrations are both colder than predicted by statistical density of states theory, as evidenced by large positive surprisal parameters. The bias against rotation is stronger than that against vibration, with measurable population as high as v = 4. The average CO internal excitation is 1920/cm, accounting for only 13 percent of the available energy. Of the energy balance, time-resolved sub-Doppler line shape measurements show that more than 38 percent appears as relative translation of the separating CO and SH fragments. Studies of the relaxation kinetics indicate that some rotational energy transfer occurs on the time scale of our measurements, but the distributions do not relax sufficiently to alter our conclusions. Vibrational distributions are nascent, though vibrational relaxation of excited CO is unusually fast in the OCS bath, with rates approaching 3 percent of gas kinetic for v = 1.

Nickolaisen, Scott L.↗

Rapid oscillations in cataclysmic variables. X - TW Pictoris (=H 0534-581)

Photometry of the X-ray-selected cataclysmic variable TW Pictoris (=H 0534-581) reveals a periodic signal at P = 6.1 hr, which is approximately the orbital period of the binary. In addition, a highly probable signal is found at P = 119.76 +/- 0.09 min. Coupled with the high excitation, the high L(x)/L(opt) ratio, and the probable detection of a similar spectroscopic period, this makes it likely that the star belongs to the 'DQ Herculis' class of cataclysmic variable in which the stable short period is the spin period of an accreting magnetic white dwarf. Theory suggests that TW Pic is a particularly attractive candidate for showing circular polarization at visual or near-infrared wavelengths.

Patterson, Joseph↗

Hidden supernova remnants in the Large Magellanic Cloud H II complex N44

We have obtained ROSAT PSPC observations of N44, one of the largest H II complexes in the Large Magellanic Cloud. The X-ray emission mostly fails within the ionized shell structures in N44. We find that one faint shell is a classical supernova remnant overlooked by previous surveys. If we model the two largest shells as pressure-driven superbubbles, the predicted X-ray luminosity falls far below the observed value. Instead, we show that off-center supernova remnants hitting superbubble shells can explain the excess X-ray emission.

Chu, You-Hua↗

The Hubble diagram in V for supernovae of Type Ia and the value of H(0) therefrom

The Hubble diagram for Type I supernovae is derived in V and is summarized from the literature in B and in m(pg). The ridge line equation of the diagram in V and the calibration of the absolute magnitudes at maximum are presented. The intrinsic (B - V) color at B maximum light is 0.09 +/- 0.04 mag. The Virgo Cluster distance is derived and found to be 23.9 +/- 2.4 Mpc. This Virgo distance gives the cosmic value of the Hubble constant to be H(0) = 47 +/- 5 km/sec per Mpc.

Sandage, Allan↗

Pressure distribution over a Clark Y-H airfoil section with a split flap

An investigation was made in the N.A.C.A. 7 by 10 foot wind tunnel of the distribution of air pressure over one chord section of a Clark Y-H airfoil with a split flap. The results obtained are given in the form of diagrams showing the chordwise distribution of pressure on both airfoil and flap as plots of calculated aerodynamic coefficients for both airfoil and flap.

Wenzinger, Carl J↗

The Column Strength of Two Extruded Aluminum-Alloy H-Sections

Extruded aluminum-alloy members of various cross sections are used in aircraft as compression members either singly or as stiffeners for aluminum-alloy sheet. In order to design such members, it is necessary to know their column strength or, in the case of stiffeners, the value of the double modulus, which is best obtained for practical purposes from column tests. Column tests made on two extruded h-sections are described, and column formulas and formulas for the ratio of the double modulus to Young's modulus, based on the tests, are given.

Osgood, William R↗

Regolith breccia consisting of H and LL chondrite mixture

Antarctic meteorite Yamato-8424 (Y-8424) is a regolith breccia that is homogenized mixture of H and LL chondrite components. The breccia consists mainly of a fine-grained material with mineral fragments of olivine, pyroxene, and Fe-Ni metal with traces of plagioclase.

Yanai, Keizo↗