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At least 1,063 records · Page 59
All sourcesNASA NTRSDOE OSTI
NASA NTRS2017

High-Resolution IR Absorption Spectroscopy of Polycyclic Aromatic Hydrocarbons in the 3-micrometers Region: Role of Periphery

In this work we report on high-resolution IR absorption studies that provide a detailed view on how the peripheral structure of irregular polycyclic aromatic hydrocarbons (PAHs) affects the shape and position of their 3-micrometers absorption band. To this purpose we present mass-selected, high-resolution absorption spectra of cold and isolated phenanthrene, pyrene, benz[a]antracene, chrysene, triphenylene, and perylene molecules in the 2950-3150 per cm range. The experimental spectra are compared with standard harmonic calculations, and anharmonic calculations using a modified version of the SPECTRO program that incorporates a Fermi resonance treatment utilizing intensity redistribution. We show that the 3-micrometers region is dominated by the effects of anharmonicity, resulting in many more bands than would have been expected in a purely harmonic approximation. Importantly, we find that anharmonic spectra as calculated by SPECTRO are in good agreement with the experimental spectra. Together with previously reported high-resolution spectra of linear acenes, the present spectra provide us with an extensive dataset of spectra of PAHs with a varying number of aromatic rings, with geometries that range from open to highly-condensed structures, and featuring CH groups in all possible edge configurations. We discuss the astrophysical implications of the comparison of these spectra on the interpretation of the appearance of the aromatic infrared 3-micrometers band, and on features such as the two-component emission character of this band and the 3-micrometers emission plateau.

techniques: spectroscopic↗
NASA NTRS2016

Connecting the Interstellar Gas and Dust Properties in Distant Galaxies Using Quasar Absorption Systems

Gas and dust grains are fundamental components of the interstellar medium and significantly impact many of the physical processes driving galaxy evolution, such as star-formation, and the heating, cooling, and ionization of the interstellar material. Quasar absorption systems (QASs), which trace intervening galaxies along the sightlines to luminous quasars, provide a valuable tool to directly study the properties of the interstellar gas and dust in distant, normal galaxies. We have established the presence of silicate dust grains in at least some gas-rich QASs, and find that they exist at higher optical depths than expected for diffuse gas in the Milky Way. Differences in the absorption feature shapes additionally suggest variations in the silicate dust grain properties, such as in the level of grain crystallinity, from system-to-system. We present results from a study of the gas and dust properties of QASs with adequate archival IR data to probe the silicate dust grain properties. We discuss our measurements of the strengths of the 10 and 18 micron silicate dust absorption features in the QASs, and constraints on the grain properties (e.g., composition, shape, crystallinity) based on fitted silicate profile templates. We investigate correlations between silicate dust abundance, reddening, and gas metallicity, which will yield valuable insights into the history of star formation and chemical enrichment in galaxies.

Aller, Monique C.↗
NASA NTRS2017

Composite Reflective Absorptive IR-Blocking Filters Embedded in Metamaterial Antireflection Coated Silicon

Infrared (IR)-blocking filters are crucial for controlling the radiative loading on cryogenic systems and for optimizing the sensitivity of bolometric detectors in the far-IR. We present a new IR filter approach based on a combination of patterned frequency-selective structures on silicon and a thin (2575 micron thick) absorptive composite based on powdered reststrahlen absorbing materials. For a 300 K blackbody, this combination reflects approximately 50% of the incoming light and blocks greater than.99.8% of the total power with negligible thermal gradients and excellent low-frequency transmission. This allows a reduction in the IR thermal loading to negligible levels in a single cold filter. These composite filters are fabricated on silicon substrates, which provide excellent thermal transport laterally through the filter and ensure that the entire area of the absorptive filter stays near the bath temperature. A metamaterial antireflection coating cut into these substrates reduces in-band reflections to below 1%, and the in-band absorption of the powder mix is below 1% for signal bands below 750 GHz. This type of filter can be directly incorporated into silicon refractive optical elements.

Munson, C. D.↗
NASA NTRS2015

Qualification of a Multi-Channel Infrared Laser Absorption Spectrometer for Monitoring CO, HCl, HCN, HF, and CO2 Aboard Manned Spacecraft

Monitoring of specific combustion products can provide early-warning detection of accidental fires aboard manned spacecraft and also identify the source and severity of combustion events. Furthermore, quantitative in situ measurements are important for gauging levels of exposure to hazardous gases, particularly on long-duration missions where analysis of returned samples becomes impractical. Absorption spectroscopy using tunable laser sources in the 2 to 5 micrometer wavelength range enables accurate, unambiguous detection of CO, HCl, HCN, HF, and CO2, which are produced in varying amounts through the heating of electrical components and packaging materials commonly used aboard spacecraft. Here, we report on calibration and testing of a five-channel laser absorption spectrometer designed to accurately monitor ambient gas-phase concentrations of these five compounds, with low-level detection limits based on the Spacecraft Maximum Allowable Concentrations. The instrument employs a two-pass absorption cell with a total optical pathlength of 50 cm and a dedicated infrared semiconductor laser source for each target gas. We present results from testing the five-channel sensor in the presence of trace concentrations of the target compounds that were introduced using both gas sources and oxidative pyrolysis (non-flaming combustion) of solid material mixtures.

environmental monitoring↗
NASA NTRS2013

Algorithm Development for Predicting Biodiversity Based on Phytoplankton Absorption

Ocean color remote sensing has provided the scientific community with unprecedented global coverage of chlorophyll a, an indicator of phytoplankton biomass. Together, satellite-derived chlorophyll a and knowledge of Phytoplankton Functional Types (PFTs) will improve our limited understanding of marine ecosystem responses to physiochemical climate drivers involved in carbon cycle dynamics and linkages. Using cruise data from the Gulf of Maine and the Middle Atlantic Bight (N 269 pairs of HPLC and phytoplankton absorption samples), two modeling approaches were utilized to predict phytoplankton absorption and pigments. Algorithm I predicts the chlorophyll-specific absorption coefficient (a*(sub ph) (m(exp 2) mg chl a(exp - 1)) using inputs of temperature, light, and chlorophyll a. Modeled r(exp 2) values (400700 nm) ranged from 0.79 to 0.99 when compared to in situ observations with approximately 25 percent lower r(exp 2) values in the UV region. Algorithm II-a utilizes matrix inversion analysis to predict a(sub ph)(m(exp -1), 400700 nm) and r(exp 2) values ranged from 0.89 to 0.99. The prediction of phytoplankton pigments with Algorithm II-b produced r(exp 2) values that ranged from 0.40 to 0.93. When used in combination, Algorithm I, and Algorithm II-a are able to use satellite products of SST, PAR, and chlorophyll a (Algorithm I) to predict pigment concentrations and ratios to describe the phytoplankton community. The results of this study demonstrate that the spatial variation in modeled pigment ratios differ significantly from the 10-year SeaWiFS average chlorophyll a data set. Contiguous observations of chlorophyll a and phytoplankton biodiversity will elucidate ecosystem responses with unprecedented complexity.

phytoplankton↗
NASA NTRS2016

Compact Multi-Channel Infrared Laser Absorption Spectrometer for Spacecraft Fire Safety Monitoring

We report on the design of a six-channel tunable laser absorption spectroscopy instrument for measuring ambient gas-phase concentrations of CO, HCl, HCN, HF, CO2, and O2 in spacecraft environments. Monitoring of these compounds can provide early warning detection of fire events while also indicating what materials have been exposed to heating. Continued post-fire monitoring of these hazardous gases can also facilitate safe and effective cleanup. The sensor is a miniaturized version of a five-channel prototype that was previously validated in ground-based oxidative pyrolysis tests. Here, we describe absorption line selection and theoretical detection limits for a sensor with reduced absorption pathlengths for each detection channel, which allows for a substantial reduction in overall instrument footprint. Ultimately, the new instrument is designed to be used in fire safety tests conducted by NASA, where various materials will undergo oxidative pyrolysis in an unmanned spacecraft returning from low Earth orbit.

Briggs, Ryan M.↗
NASA NTRS2019

The Broad Absorption Line Tidal Disruption Event iPTF15af: Optical and Ultraviolet Evolution

We present multiwavelength observations of the tidal disruption event (TDE) iPTF15af, discovered by the intermediate Palomar Transient Factory survey at redshift z = 0.07897. The optical and ultraviolet (UV) light curves of the transient show a slow decay over 5 months, in agreement with previous optically discovered TDEs. It also has a comparable blackbody peak luminosity of L(sub peak) approx. = 1.5 x 10(exp 44) erg s(exp -1). The inferred temperature from the optical and UV data shows a value of (3–5) × 10(exp 4) K. The transient is not detected in X-rays up to L(sub X) < 3 x 10(exp 42) erg s(exp -1) within the first 5 months after discovery. The optical spectra exhibit two distinct broad emission lines in the He ii region, and at later times also Hα emission. Additionally, emission from [N iii] and [O iii] is detected, likely produced by the Bowen fluorescence effect. UV spectra reveal broad emission and absorption lines associated with high-ionization states of N v, C iv, Si iv, and possibly P v. These features, analogous to those of broad absorption line quasars (BAL QSOs), require an absorber with column densities N(sub H) > 10(exp 23) cm(exp -2). This optically thick gas would also explain the nondetection in soft X-rays. The profile of the absorption lines with the highest column density material at the largest velocity is opposite that of BAL QSOs. We suggest that radiation pressure generated by the TDE flare at early times could have provided the initial acceleration mechanism for this gas. Spectral UV line monitoring of future TDEs could test this proposal.

Blagorodnova, N.↗
NASA NTRS2018

On the Discrepancy Between the X-Ray and UV Absorption Measurements of O VI in the Local ISM

The total amount of Ovi present in the interstellar medium (ISM) obtained via absorption measurements in UV and X-ray spectra is currently in disagreement, with the latter being significantly larger (by a factor of 10 or more) than the former. Previous works have proposed that the blend of the Ovi K line (22.032 Ã) with the Oii K-L12 line (22.04 Ã) could account for the stronger absorption observed in the X-ray spectra. Here, we present a detailed study of the oxygen absorption in the local ISM, implementing our new model IGMabs which includes photoabsorption cross-sections of highly ionized species of abundant elements as well as turbulence broadening. By analysing high-resolution Chandra spectra of 13 low-mass X-ray binaries (LMXBs) and 29 extragalactic sources, we have estimated the column densities of Oi - Oiii and from Ovi - Oviii along multiple line-of-sights. We find that in most cases the Oii K-L12 line accounts for <30 per cent of the total Ovi K a + Oii K b. We conclude that the amount of Oii predicted by our model is still insufficient to explain the discrepancy between X-ray and UV measurements of Ovi column densities.

Gatuzz, Efrain↗
NASA NTRS2019

An upgraded G-band differential absorption radar system for future airborne studies

A proof-of-concept, 170 GHz frequency-modulated, continuous-wave (FMCW) radar has been developed for measuring water vapor profiles within the cloudy boundary layer from an airborne platform. The measurement concept exploits the differential absorption accrued by two or more transmitted frequencies in the vicinity of the 183 GHz water absorption line to retrieve range-resolved humidity profiles, so-called differential absorption radar (DAR). The upgraded system design includes important considerations for monostatic radar operation with an open fuselage viewport (i.e. no radome). The radar features an all-solid-state tansmitter with > 0:4 W continuous transmit power, a 60 cm primary aperture and corresponding 58 dB antenna gain, and more than 80 dB transmit/receive isolation, enabling near thermal-noise-limited sensitivity with a 8 dB noise figure receiver. Ice-cloud radar returns are detected beyond 8 km in height from the ground, demonstrating the high sensitivity of the system. In addition to in-cloud humidity profiling capabilities, deployment of a water vapor DAR from an airborne platform enables measurements of total column water vapor (TCWV) for all weather and surface scenarios. Precision estimates and potential biases for future TCWV measurements are discussed.

Monje, Raquel↗
NASA NTRSDate not supplied

Measurements of Temperature and Enthalpy in NASA Ames 60-MW Arcjet using Atomic Oxygen and Atomic Nitrogen Absorption

We report on measurements of temperature and enthalpy in the 60-MW Interaction Heating Facility (IHF) Arcjet at the NASA Ames Research Center. These quantities were measured at sub-second temporal resolution using tunable diode laser absorption spectroscopy, employing four Distributed Feedback (DFB) lasers to simultaneously probe the arcjet flow. Optical access was achieved through a specially-designed optical disk mounted in series with the modules of the arc heater in the add-air plenum of the column, which is positioned between the downstream electrodes and the nozzle. Gas at this measurement location serves as the reservoir condition for the ensuing supersonic expansion. Conditions in the reservoir are extreme, with temperatures between 5000-8000 K and pressures between 1-9 atm. Absorption from the 5S state of atomic oxygen at 777.2 nm and the 4P state of atomic nitrogen at 868.0 nm, two electronically-excited quantum states, formed the basis of the flow characterization measurements. Fiber-coupled laser light was pitched through the IHF via 1/8" ports in the optical disks, permitting optical access with minimal intrusion to the flow. Data was collected at 3 nominal conditions, a Low condition (1600 A, 2000 V, 0.13 kg/s), a Medium condition (3500 A, 5700 V, 0.61 kg/s), and a High condition (5900 A, 6800 V, 0.84 kg/s). Measurements suggest agreement within 1-2% between excited oxygen and excited nitrogen thermometry, indicating approximate thermal and chemical equilibration of the arcjet reservoir state, a result in keeping with long-standing assumptions of CFD modelling. Spatial gradients are found in the flow due to enthalpy loss to the facility walls, but the measured spatial non-uniformities are consistent with axi-symmetry. Measurements of specific enthalpy in the reservoir are also made utilizing excited oxygen and excited nitrogen absorption under the assumption of chemical equilibration.

Peter M. Finch↗
DOE OSTI2017

Quantification of sauter mean diameter in diesel sprays using scattering-absorption extinction measurements

Quantitative measurements of the primary breakup process in diesel sprays are lacking due to a range of experimental and diagnostic challenges, including: high droplet number density environments, very small characteristic drop size scales (~1-10 μm), and high characteristic velocities in the primary breakup region (~600 m/s). Due to these challenges, existing measurement techniques have failed to resolve a sufficient range of the temporal and spatial scales involved and much remains unknown about the primary atomization process in practical diesel sprays. To gain a better insight into this process, we have developed a joint visible and x-ray extinction measurement technique to quantify axial and radial distributions of the path-integrated Sauter Mean Diameter (SMD) and Liquid Volume Fraction (LVF) for diesel-like sprays. This technique enables measurement of the SMD in regions of moderate droplet number density, enabling construction of the temporal history of drop size development within practical diesel sprays. The experimental campaign was conducted jointly at the Georgia Institute of Technology and Argonne National Laboratory using the Engine Combustion Network “Spray D” injector. X-ray radiography liquid absorption measurements, conducted at the Advanced Photon Source at Argonne, quantify the liquid-fuel mass and volume distribution in the spray. Diffused back-illumination liquid scattering measurements were conducted at Georgia Tech to quantify the optical thickness throughout the spray. By application of Mie-scatter equations, the ratio of the absorption and scattering extinction measurements is demonstrated to yield solutions for the SMD. This work introduces the newly developed scattering-absorption measurement technique and highlights the important considerations that must be taken into account when jointly processing these measurements to extract the SMD. These considerations include co-alignment of measurements taken at different institutions, identification of viable regions where the measurement ratio can be accurately interpreted, and uncertainty analysis in the measurement ratio and resulting SMD. Because the measurement technique provides the spatial history of the SMD development, it is expected to be especially informative to the diesel spray modeling community. Results from this work will aid in understanding the effect of ambient densities and injection pressures on primary breakup and help assess the appropriateness of spray submodels for engine computational fluid dynamics codes.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2017

Device and method for luminescence enhancement by resonant energy transfer from an absorptive thin film

Disclosed are a device and a method for the design and fabrication of the device for enhancing the brightness of luminescent molecules, nanostructures, and thin films. The device includes a mirror, a dielectric medium or spacer, an absorptive layer, and a luminescent layer. The absorptive layer is a continuous thin film of a strongly absorbing organic or inorganic material. The luminescent layer may be a continuous luminescent thin film or an arrangement of isolated luminescent species, e.g., organic or metal-organic dye molecules, semiconductor quantum dots, or other semiconductor nanostructures, supported on top of the absorptive layer.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Architecture for Absorption Based Heaters

An absorption based heater is constructed on a fluid barrier heat exchanging plate such that it requires little space in a structure. The absorption based heater has a desorber, heat exchanger, and absorber sequentially placed on the fluid barrier heat exchanging plate. The vapor exchange faces of the desorber and the absorber are covered by a vapor permeable membrane that is permeable to a refrigerant vapor but impermeable to an absorbent. A process fluid flows on the side of the fluid barrier heat exchanging plate opposite the vapor exchange face through the absorber and subsequently through the heat exchanger. The absorption based heater can include a second plate with a condenser situated parallel to the fluid barrier heat exchanging plate and opposing the desorber for condensation of the refrigerant for additional heating of the process fluid.

42 ENGINEERING↗
DOE OSTI2022

A New Search for Low-mass Dark Matter and an Examination and Reduction of the Uncertainty due to the Photoelectric Absorption Cross Section using a Cryogenic Silicon Detector with Single-charge Sensitivity

Many astrophysical observations point to the abundant existence of dark matter (DM) in the universe composed of particles beyond the Standard Model. However despite numerous experiments using different techniques, DM particles have yet to be directly observed. The Super Cryogenic Dark Matter Search (SuperCDMS) SNOLAB experiment will employ silicon and germanium crystal detectors operated at temperatures as low as 15~mK to probe DM interactions using phonon and ionization signals. Recently, R\&D; facilities have developed gram-sized high-voltage eV-scale (HVeV) silicon detectors that achieve single-electron-hole-pair resolution. By probing effective DM-electron interactions, these devices can be used for searches of low-mass DM candidates.This dissertation presents a DM search experiment known as HVeV Run~2 that employs a second-generation HVeV detector operated in an above-ground laboratory at Northwestern University (IL, USA). Energy spectra are obtained from a blind analysis with 0.39 and 1.2\,g-days of exposure with the detector biased at 60 and 100\,V, respectively. The 0.93~gram detector achieves a 3\,eV phonon energy resolution, corresponding to a world-leading charge resolution of 3\,\% of a single electron-hole pair for a detector bias of 100\,V. With charge carrier trapping and impact ionization effects incorporated into the DM signal models, the resulting exclusion limits are reported for inelastic DM-electron scattering for DM masses from 0.5--$10^{4}$\,MeV$/c^{2}$; in the mass range from 1.2--50\,eV$/c^{2}$ the limits for dark photon and axion-like particle absorption are reported.Several DM search experiments, including HVeV Run~2, are sensitive to low-mass DM candidates that rely on the temperature-dependent photoelectric absorption cross section of silicon. However discrepancies in the underlying literature data result in dominating systematic uncertainties on the DM exclusion limits. In order to reduce these systematic uncertainties, this dissertation presents a novel method of making a direct, low-temperature measurement of the photoelectric absorption cross section of silicon at energies near the band gap (1.2--2.8\,eV).

Wilson, Matthew James↗
DOE OSTI2023

ICRF wave propagation and absorption modelling via machine learning

A surrogate model of the wave absorption in the ion cyclotron range of frequencies is presented. The model is trained to capture the physics of 1D electron and ion power absorption profiles for both the high harmonic fast wave scheme in NSTX, and the minority heating scheme in WEST. The surrogate models, based on both the random forest regressor and the multilayer perceptron algorithms, reduce inference time of 1D power absorption profiles from 1-5 minutes required by TORIC to ∼50 µs with high accuracy (i.e. R2 = 0.71−0.96).

Sánchez-Villar↗
DOE OSTI2024

Laser absorptivity measurement device

A laser absorptivity measurement device uses a linearly polarized incident beam, an optical configuration comprising an internal polarizing beamsplitter that transmits the linearly polarized incident beam and a quarter-wave plate that converts linearly polarized incident beam into a circularly polarized incident beam that is reflected off a processing substrate. The quarter-wave plate and polarizing beamsplitter can then direct the reflected light back into an integrating volume, where the power of the reflected light can be measured by a photodetector. The laser absorptivity measurement device is capable of making real-time absorption efficiency measurements of a variety of laser-based processes, including laser welding and brazing, additive manufacturing, and laser marking.

Tung, Daniel↗
DOE OSTI2018

Role of Ti Content on the Occurrence of the 3309-cm{sup –1} Peak in FTIR Absorption Spectra of Ruby Samples

The study is based on the determination of trace elements in ruby samples, Ti in particular, using laser ablation inductively coupled plasma mass spectrometry (LA–ICP–MS). The samples were then divided into three groups: high (≥ 200 ppma), moderate (100–200 ppma), and low (≤ 50 ppma) Ti content. In addition, X-ray absorption spectroscopy (XAS) was employed to confirm that the Ti oxidation state was Ti{sup 4+}. The heat experiment conditions were set at 800, 1200, and 1650°C to investigate the transformation of the –OH vibration in the FTIR spectra of ruby samples. The FTIR spectra showed that samples containing a low Ti concentration did not show the 3309-cm{sup –1} absorption peak either before or after heating at any of the designed temperatures. An obvious 3309-cm{sup –1} peak appeared only in samples with a moderate to high Ti content after heating at ≥ 1200°C. The results also suggest that, in addition of Ti{sup 4+}, the occurrence of the 3309-cm{sup –1} peak in the FTIR spectra is strongly affected by the charge compensation of –OH in Al sites, i.e., the structural –OH; thus, the structural –Ti–OH stretching in the ruby samples. Hence, for gemological identification, the 3309-cm{sup –1} peak can be applied to indicate whether a ruby has undergone heat treatment if those samples contain enough Ti ions in their structure, i.e., Ti ≥ 100 ppma. This condition is usually found in ruby samples from major deposits such as Mong Hsu and Mogok, Myanmar; Luc Yen, Vietnam; and Montopuez, Mozambique.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗