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A study of the turbulence structures of wall-bounded shear flows

This project extends the study of the structure of wall-bounded flows using the topological properties of eddying motions as developed by Chong et al. (1990), Soria et al. (1992, 1994), and as recently extended by Blackburn et al. (1996) and Chacin et al. (1996). In these works, regions of flow which are focal in nature are identified by being enclosed by an isosurface of a positive small value of the discriminant of the velocity gradient tensor. These regions resemble the attached vortex loops suggested first by Theodorsen (1955). Such loops are incorporated in the attached eddy model versions of Perry & Chong (1982), Perry et al. (1986), and Perry & Marusic (1995), which are extensions of a model first formulated by Townsend (1976). The DNS data of wall bounded flows studied here are from the zero pressure gradient flow of Spalart (1988) and the boundary layer with separation and reattachment of Na & Moin (1996). The flow structures are examined from the viewpoint of the attached eddy hypothesis.

Chong, M. S.↗

NASA-UVA Light Aerospace Alloy and Structures Technology Program (LA2ST)

This report documents the progress achieved over the past 6 to 12 months on four graduate student projects conducted within the NASA-UVA Light Aerospace Alloy and Structures Technology Program. These studies were aimed specifically at light metallic alloy issues relevant to the High Speed Civil Transport. Research on Hydrogen-Enhanced Fracture of High-Strength Titanium Alloy Sheet refined successfully the high resolution R-curve method necessary to characterize initiation and growth fracture toughnesses. For solution treated and aged Low Cost Beta without hydrogen precharging, fracture is by ductile transgranular processes at 25 C, but standardized initiation toughnesses are somewhat low and crack extension is resolved at still lower K-levels. This fracture resistance is degraded substantially, by between 700 and 1000 wppm of dissolved hydrogen, and a fracture mode change is affected. The surface oxide on P-titanium alloys hinders hydrogen uptake and complicates the electrochemical introduction of low hydrogen concentrations that are critical to applications of these alloys. Ti-15-3 sheet was obtained for study during the next reporting period. Research on Mechanisms of deformation and Fracture in High-Strength Titanium Alloys is examining the microstructure and fatigue resistance of very thin sheet. Aging experiments on 0. 14 mm thick (0.0055 inch) foil show microstructural agility that may be used to enhance fatigue performance. Fatigue testing of Ti-15-3 sheet has begun. The effects of various thermo-mechanical processing regimens on mechanical properties will be examined and deformation modes identified. Research on the Effect of Texture and Precipitates on Mechanical Property Anisotropy of Al-Cu-Mg-X and Al-Cu alloys demonstrated that models predict a minor influence of stress-induced alignment of Phi, caused by the application of a tensile stress during aging, on the yield stress anisotropy of both modified AA2519 and a model Al-Cu binary alloy. This project is no longer included in the NASA-UVA LAST program. Research on the Creep Behavior and Microstructural stability of Al-Cu-Mg-Ag and Al-Cu-Li-Mg-Ag showed that the creep resistance of three candidate aluminum alloys (C415, C416 and ML377) was much superior compared to that of the current Concorde alloy, AA2618. Creep induced change in precipitates at grain boundaries was observed in the alloy which exhibits the highest creep strain of the three examined. The other two alloys developed no detectable microstructural changes at grain boundaries under the creep conditions tested.

Gangloff, Richard P.↗

Impact Cratering Calculations

Understanding the physical processes of impact cratering on planetary surfaces and atmospheres as well as collisions of finite-size self-gravitating objects is vitally important to planetary science. The observation has often been made that craters are the most ubiquitous landform on the solid planets and the satellites. The density of craters is used to date surfaces on planets and satellites. For large ringed basin craters (e.g. Chicxulub), the issue of identification of exactly what 'diameter' transient crater is associated with this structure is exemplified by the arguments of Sharpton et al. (1993) versus those of Hildebrand et al. (1995). The size of a transient crater, such as the K/T extinction crater at Yucatan, Mexico, which is thought to be the source of SO,-induced sulfuric acid aerosol that globally acidified surface waters as the result of massive vaporization of CASO, in the target rock, is addressed by our present project. The impact process excavates samples of planetary interiors. The degree to which this occurs (e.g. how deeply does excavation occur for a given crater diameter) has been of interest, both with regard to exposing mantle rocks in crater floors, as well as launching samples into space which become part of the terrestrial meteorite collection (e.g. lunar meteorites, SNC's from Mars). Only in the case of the Earth can we test calculations in the laboratory and field. Previous calculations predict, independent of diameter, that the depth of excavation, normalized by crater diameter, is d(sub ex)/D = 0.085 (O'Keefe and Ahrens, 1993). For Comet Shoemaker-Levy 9 (SL9) fragments impacting Jupiter, predicted excavation depths of different gas-rich layers in the atmosphere, were much larger. The trajectory and fate of highly shocked material from a large impact on the Earth, such as the K/T bolide is of interest. Melosh et al. (1990) proposed that the condensed material from the impact upon reentering the Earth's atmosphere induced. radiative heating, and producing global firestorms. The observed reentry splash of the SL-9 impact-induced plumes that reimpact Jupiter (Boslough et al., 1994) supported Melosh's K/T model. The fate of early primitive planetary atmospheres during the latter stages of planetary accretion, resulting from impactors in the 100 to 103 km diameter require modeling, e.g. Newman et al. (1997). Ahrens (1990; 1993) and Chen and Ahrens (1997) found that upon delivery of most of the impact energy to the solid planet, very large ground motions arise, which couple sufficient kinetic energy to the atmosphere to cause substantial atmospheric escape. The trade-off of this model with that of Cameron (1997) who suggests that atmospheric blow-off occurs as a result of the massive impact-induced heating of the atmosphere and Pepin (1997) who uses this heating event to model differential hydrodynamic loss of lighter atmospheric gases, requires further research.

Ahrens, Thomas J.↗

Torsional Eye Movements Evoked by Unilateral Labyrinthine Galvanic Polarizations in the Squirrel Monkey

Electrical stimulation of vestibular-nerve afferents innervating the semicircular canals has been used to identify the extraocular muscles receiving activation or inhibition by individual ampullary nerves. This technique was originally developed by Szentagothai (1950) and led to the description of three neuron reflex arcs that connect each semicircular canal through an interneuron traversing in the region of the medial longitudinal fasciculus to one ipsilateral and one contralateral eye muscle. Selective ampullary nerve stimulation was subsequently used by Cohen and colleagues (Cohen and Suzuki, 1963; Cohen et al., 1964; Suzuki et al., 1964; Cohen et al., 1966) to study movements of the eyes and activation of individual extraocular muscles in response to stimulation of combinations of ampullary nerves. This work led to a description of the now familiar relationships between activation of a semicircular canal ampullary nerves and the anticipated movement in each eye. Disconjugacy of eye movements induced by individual vertical canal stimulation and dependence of the pulling direction of vertical recti and oblique muscles on eye position were also defined in these experiments. Subsequent studies have defined the mechanisms by which externally applied galvanic currents result in a change in vestibular-nerve afferent discharge. The currents appear to act at the spike trigger site. Perilymphatic cathodal currents depolarize the trigger site and lead to excitation whereas anodal currents hyperpolarize and result in inhibition. Afferents innervating all five vestibular endorgans appear to be affected equally by the currents (Goldberg et al., 1984). Irregularly discharging afferents are about 5-10 times more sensitive than regularly discharging ones because of the steeper slope of the former's faster postspike recovery of excitability in encoder sensitivity (Smith and Goldberg, 1986). Response adaptation similar to that noted during acceleration steps is apparent for longer periods of current administration. This adaptation is manifested as a perstimulus return toward resting discharge and poststimulus after-response in the opposite direction (Goldberg et al., 1984; Minor and Goldberg, l991). Cathodal currents (with respect to the perilymphatic space of the vestibule) are excitatory whereas anodal currents are inhibitory. Horizontal eye movements evoked by unilateral galvanic polarizations administered through chronically implanted labyrinthine stimulating electrodes have been studied in alert squirrel monkeys (Minor and Goldberg, 1991). We sought to extend this analysis by recording three-dimensional eye movements during galvanic stimulation. As predicted based upon roughly equal stimulation of ampullary nerves innervating the vertical canals, a substantial torsional component to the nystagmus is noted. The trajectory of torsional slow phases and nystagmus profile after the polarization provide insight into the central mechanisms that influence these responses.

Minor, Lloyd B.↗

Learning from Automation Surprises and "Going Sour" Accidents: Progress on Human-Centered Automation

Advances in technology and new levels of automation on commercial jet transports has had many effects. There have been positive effects from both an economic and a safety point of view. The technology changes on the flight deck also have had reverberating effects on many other aspects of the aviation system and different aspects of human performance. Operational experience, research investigations, incidents, and occasionally accidents have shown that new and sometimes surprising problems have arisen as well. What are these problems with cockpit automation, and what should we learn from them? Do they represent over-automation or human error? Or instead perhaps there is a third possibility - they represent coordination breakdowns between operators and the automation? Are the problems just a series of small independent glitches revealed by specific accidents or near misses? Do these glitches represent a few small areas where there are cracks to be patched in what is otherwise a record of outstanding designs and systems? Or do these problems provide us with evidence about deeper factors that we need to address if we are to maintain and improve aviation safety in a changing world? How do the reverberations of technology change on the flight deck provide insight into generic issues about developing human-centered technologies and systems (Winograd and Woods, 1997)? Based on a series of investigations of pilot interaction with cockpit automation (Sarter and Woods, 1992; 1994; 1995; 1997a, 1997 b), supplemented by surveys, operational experience and incident data from other studies (e.g., Degani et al., 1995; Eldredge et al., 1991; Tenney et al., 1995; Wiener, 1989), we too have found that the problems that surround crew interaction with automation are more than a series of individual glitches. These difficulties are symptoms that indicate deeper patterns and phenomena concerning human-machine cooperation and paths towards disaster. In addition, we find the same kinds of patterns behind results from studies of physician interaction with computer-based systems in critical care medicine (e.g., Moll van Charante et al., 1993; Obradovich and Woods, 1996; Cook and Woods, 1996). Many of the results and implications of this kind of research are synthesized and discussed in two comprehensive volumes, Billings (1996) and Woods et al. (1994). This paper summarizes the pattern that has emerged from our research, related research, incident reports, and accident investigations. It uses this new understanding of why problems arise to point to new investment strategies that can help us deal with the perceived "human error" problem, make automation more of a team player, and maintain and improve safety.

Woods, David D.↗

From Top to Bottom - the Multiwavelength Campaign of V824 Ara (HD 155555)

A great deal of progress has been made in recent years in decomposing the 2-D structure in the atmospheres of late-type stars. Doppler images of many photospheres single stars, T Tauri stars, Algols, RS CV(sub n) binaries to name a few - are regularly published (Strassmeier 1996; Richards and Albright 1996; Rice and Strassmeier 1996; Kuerster et al. 1994). Ultraviolet spectral images of chromospheres appear in the literature (e.g., Walter et al. 1987; Neff et al. 1989) but are less common owing to the difficult nature of obtaining complete phase coverage. Zeeman doppler images of magnetic fields are now feasible (e.g., Donati et al. 1992). Performing Doppler imaging of the same targets over many seasons has also been accomplished (e.g, Vogt et al. 1997). Even when a true image reconstruction is not possible due to poor spectral resolution, we can still infer a great deal about spatial structure if enough phases are observed. However, it is increasingly apparent that to make sense of recent results, many different spectral features spanning a range of formation temperature and density must be observed simultaneously for a coherent picture to emerge. Here we report on one such campaign. In 1996, we observed the southern hemisphere RS CV(sub n) binary V824 Ara (P=1(sup d).68, G5IV+K0V-IV-IV) over one complete stellar rotation with the Hubble Space Telescope and EUVE. In conjunction, radio and optical photometry and spectroscopy were obtained from the ground. Unique to this campaign is the complete phase coverage of a number of activity proxy indicators that cover source temperatures ranging from the photosphere to the corona.

Dempsey, Robert↗

Effect of Particle Non-Sphericity on Satellite Monitoring of Drifting Volcanic Ash Clouds

Volcanic eruptions loft gases and ash particles into the atmosphere and produce effects that are both short term (aircraft hazards, interference with satellite measurements) and long term (atmospheric chemistry, climate). Large (greater than 0.5mm) ash particles fall out in minutes [Rose et al, 1995], but fine ash particles can remain in the atmosphere for many days. This fine volcanic ash is a hazard to modem jet aircraft because the operating temperatures of jet engines are above the solidus temperature of volcanic ash, and because ash causes abrasion of windows and airframe, and disruption of avionics. At large distances(10(exp 2)-10(exp 4) km or more) from their source, drifting ash clouds are increasingly difficult to distinguish from meteorological clouds, both visually and on radar [Rose et al., 1995]. Satellites above the atmosphere are unique platforms for viewing volcanic clouds on a global basis and measuring their constituents and total mass. Until recently, only polar AVHRR and geostationary GOES instruments could be used to determine characteristics of drifting volcanic ash clouds using the 10-12 micron window [Prata 1989; Wen and Rose 1994; Rose and Schneider 1996]. The NASA Total Ozone Mapping Spectrometer (TOMS) instruments aboard the Nimbus-7, Meteor3, ADEOS, and Earth Probe satellites have produced a unique data set of global SO2 volcanic emissions since 1978 (Krueger et al., 1995). Besides SO2, a new technique has been developed which uses the measured spectral contrast of the backscattered radiances in the 330-380nm spectral region (where gaseous absorption is negligible) in conjunction with radiative transfer models to retrieve properties of volcanic ash (Krotkov et al., 1997) and other types of absorbing aerosols (Torres et al., 1998).

Krotkov, Nicholay A.↗

Diffusion Barriers to Increase the Oxidative Life of Overlay Coatings

Currently, most blades and vanes in the hottest section of aero gas turbine engines require some type of coating for oxidation protection. Newly developed single crystal superalloys have the mechanical potential to operate at increasingly higher component temperatures. However, at these elevated temperatures, coating/substrate interdiffusion can shorten the protective life of the coating. Diffusion barriers between overlay coatings and substrates are being examined to extend the protective life of the coating. A previously- developed finite-difference diffusion model has been modified to predict the oxidative life enhancement due to use of a diffusion barrier. The original diffusion model, designated COSIM, simulates Al diffusion in the coating to the growing oxide scale as well as Al diffusion into the substrate. The COSIM model incorporates an oxide growth and spalling model to provide the rate of Al consumption during cyclic oxidation. Coating failure is predicted when the Al concentration at the coating surface drops to a defined critical level. The modified COSIM model predicts the oxidative life of an overlay coating when a diffusion barrier is present eliminating diffusion of Al from the coating into the substrate. Both the original and the modified diffusion models have been used to predict the effectiveness of a diffusion barrier in extending the protective life of a NiCrAl overlay coating undergoing cyclic oxidation at 1100 C.

Nesbitt, James A.↗

Long-Term Cyclic Oxidation Behavior of Uncoated and Coated Re-108 and In-939 at 980 and 870 C

Very long-term cyclic oxidation behavior of Re-108 and ln-939 with and without a protective coating was evaluated at 980 and 870 C, respectively. Re-108 and ln-939 without a protective coating began to show rapid weight loss at 3000 h due to scale spallation, indicating the need for an oxidation protective coating for longer than thousands of hours of oxidative life. NiAl-base coatings of a vapor phase aluminide (VPA), a pack aluminide (CODEP), and a slurry paint aluminide (SERMALOY J) were applied on Re-108 and ln-939. VPA and CODEP on Re-108 and all three coatings on ln-939 showed excellent cyclic oxidation resistance out to 10000 hr. Coated alloys were annealed in an inert atmosphere to determine the loss of Al from the coating into the alloy substrate through diffusion. The Al loss from the coating through diffusion was twice as great as the Al loss through oxidation after 10000 h of cyclic exposure. Oxidation life of VPA-coated Re-108 was estimated by calculating the amount of Al initially available for protective oxidation and the amount of Al lost through oxidation and diffusion.

Lee, K. N.↗

Photochemistry of Oxygen Compounds in Neptune's Stratosphere

ISO SWS observations of H2O and CO2 on Neptune (Feuchtgruber et al. 1997, Nature 389, 159) coupled with ground based millimeter observations of CO (Marten et al., 1993, Ap. J. 406 285) provide strong constraints on the photochemistry of these compounds in Neptune's stratosphere. Additional constraints on the photochemistry and vertical mixing come from the rich suite of hydrocarbons observed by ISO: CH4, C2H2, C2H6 (Bezard, 1998, Ann. Geophysicae 16, Sup. III C1037), CH3 (Bezard, et al. Ap. J. 515, 868), and C2H4 (Encrenaz et al. this DPS). We will use a one-dimensional global average photochemical model to analyze these compounds. In particular, we will better constrain the estimated external flux of H2O to Neptune's stratosphere given in Feuchtgruber et al., which is important in understanding the source of the observed stratospheric CO2. Kingdoms will come and go, the relentless march of time will continue, all will be explained.

Romani, P. N.↗

Ion Temperature Enhancement in the Wake of Ionospheric Spacecraft

Enhancements of the temperature of electrons in spacecraft plasma wakes have been reported for numerous cases [Samir and Wrenn, 1972; Troy et al., 1975; Oran et al., 1975) and this phenomenon has been discussed both empirically (Samir and Stone, 1986; Stone and Samir, 1986) and theoretically (Singh et al., 1987). However, very few measurements seem to have been made of the ion temperature within plasma wakes--possibly because the great majority of ion measurements were focussed on obtaining geophysical parameters and, hence, were confined to the region ahead of the spacecraft. Recently, however, an enhancement of the temperature of ions was discovered in data obtained in the wake of the Space Shuttle during the Spacelab-2 mission (Sorensen et al., 1997). At the time of that publication, this was the only known observation of this type. Herein, we report an additional case of ion temperature enhancement in a plasma wake. The data were taken during the Tethered Satellite System Reflight mission (TSS-IR) in the wake of the tethered satellite during passive (no current flow) operations. The measurements were obtained with the Differential Ion Flux Probe, or DIFP (Stone, 1977 and Stone et al., 1985).

Samir, U.↗

Elemental Fractionation During Rapid Accretion of the Moon Triggered by a Giant Impact

Recently, Ida et al. made an N-body simulation of lunar accretion from a protolunar disk formed by a giant impact. One of their important conclusions is that the accretion time of the Moon is as short as one month. Such rapid accretion is a necessary consequence of the high surface density of a lunar mass disk accreting just beyond the Roche limit (about 3Re); the Safronov accretion time (a few days) is even shorter. The energy of accretion always exceeds the gravitational binding energy of newly arriving matter. Hence, without an energy sink, the accreting body is thermally unstable. For the Earth and other planets, radiation acts as the sink. However, in such a short accretion time, the Moon cannot radiate the accretional energy. Even radiating at a silicate cloudtop temperature of roughly 2000 K, it would take more than 100 yr to radiatively cool the Moon. The plausible alternative heat sinks are heat capacity, latent heat of vaporization, and thermal escape of the gas to space (i.e., hydrodynamic blowoff). The latter becomes plausible for the Moon because the scale height at 2000 K (about 300 km) is a significant fraction of the lunar radius. The early stages of lunar (or "lunatesimal") growth release relatively little energy and can occur simply by heating the material, especially if the accreting material is originally cold. However, the material is unlikely to be cold, because the disk itself is hot and cooling time is long, while the lunar accretion time iss very short. Therefore, the moon is likely to accrete condensed material just after it condenses. Accordingly, the newly accreted material will be on the verge of vaporization and will have very little heat capacity to spare. The immediate heat sink is the latent heat of vaporization. Most of the vapor will escape from the moon, because the thermal energy in the gas can be used to drive escape. However, vaporization is generally incomplete. the latent heat of vaporization exceeds the energy of accretion. Viewed globally, the accretional energy is about half the energy required to vaporize the entire Moon. Thus to first approximation, half of the Moon-forming material can be vaporized and lost during accretion. During this process, we would expect preferential loss of relatively volatile elements. Escape will retard the rate of accretion. To test these ideas, we computed detailed models of the thermal state of the Moon during accretion. We pay special attention to the structure of the silicate atmosphere and its loss rate by calculating the chemical species at equilibrium. We used the PHEQ program which includes 12 elements (H,O,C,Mg,Si,Fe,Ca, Al, Na,Ti, and N.) and 272 compounds (including ionic compounds). Because of the large heats of vaporization and ionization, the adiabatic atmosphere is nearly isothermal and massive escape is expected. The pressure of the atmosphere is determined by the balance between vaporization of a accreting material and escape. If the accretion time is one month, a 0.3 bar atmosphere is expected. Elemental fractionation depends strongly on the temperature of the accreting material. The initial temperature of the material can be estimated from the condition of gravitational instability in the protolunar disk. As shown by Ida et al, accretion starts when gravitational instability occurs when more than 99% of the material condenses. At this point, all of Ca, Al, Si, Mg, and Fe, and 95% of Na (probably K also), are in condensed phases. If the moon is formed from the accretion of such material, volatile elements such as Na, and K are retained by the moon only early in accretion. At later times, K and Na are lost and a fraction of the MG, Si and Fe is lost. However, refractory elements such as Ca and Al are retained and so achieve a mild degree (factor 2) of superabundance.

Abe, Y.↗

Exercise Countermeasures for Bone Loss During Space Flight: A Method for the Study of Ground Reaction Forces and their Implications for Bone Strain

Effective countermeasures to prevent loss of bone mineral during long duration space flight remain elusive. Despite an exercise program on MIR flights, the data from LeBlanc et al. (1996) indicated that there was still a mean rate of loss of bone mineral density in the proximal femur of 1.58% per month (n=18, flight duration 4 - 14.4 months). The specific mechanisms regulating bone mass are not known, but most investigators agree that bone maintenance is largely dependent upon mechanical demand and the resultant local bone strains. A plausible hypothesis is that bone loss during space flight, such as that reported by LeBlanc et al. (1996), may result from failure to effectively load the skeleton in order to generate localized bone strains of sufficient magnitude to prevent disuse osteoporosis. A variety of methods have been proposed to simulate locomotor exercise in reduced gravity. In such simulations, and in an actual microgravity environment, a gravity replacement load (GRL) must always be added to return the exercising subject to the support surface and the resulting skeletal load is critically dependent upon the magnitude of the GRL. To our knowledge, GRLs during orbital flight have only been measured once (on STS 81) and it is likely that most or all prior treadmill exercise in space has used GRLs that were less than one body weight. McCrory (1997) has shown that subjects walking and running in simulated zero-G can tolerate GRLs of 1 if an appropriate harness is used. Several investigators have attempted to measure in vivo strains and forces in the bones of humans, but have faced ethical and technical limitations. The anteromedial aspect of the tibial midshaft has been a common site for the placement of strain gauges; one reason to measure strains in the anterior tibia is that this region is surgically accessible. Aamodt et al. (1997) were able to measure strains on the lateral surface of the proximal femur only because their experimental subjects were already scheduled for hip surgery. Lu et al. (1997) used an instrumented massive proximal femoral prosthesis along with electromyographic measurements to demonstrate that femoral forces depend on muscular activity. These analyses of in vivo bone mechanics are valuable. The invasive nature of the procedures involved, however, limits both the number of subjects and the number of strain gauge locations. Further, the results of these studies may be confounded by the inclusion of subjects with pathological conditions. Gross et al. (1992) measured strain at three locations on the equine third metacarpal and used those data to construct a computer model of the internal strain environment of the bone. An analogous placement of multiple gauges in living humans would be difficult and potentially hazardous because of the depth of soft tissue overlying the tibia and femur.

Peterman, M.↗

New Potential Sources for Black Onaping Carbon

One intriguing and important issue of the Sudbury Structure concerns the source of the relatively large amount of C in the Onaping Formation Black member. This dilemma was recently addressed, and the conclusion was reached that an impactor could not have delivered all of the requisite C. Becker et al. have suggested that much of the C came from the impactor and reported the presence of interstellar He "caged" inside some fullerenes that may have survived the impact. So, conceivably, the C inventory in the Sudbury Structure comes from both target and impactor materials, although the known target rocks have little C. We discuss here the possibility of two terrestrial sources for at least some of the C: (1) impact evaporation/dissociation of C from carbonate target rocks and (2) the presence of heretofore-unrecognized C-rich (up to 26 wt%) siliceous "shale," fragments, which are found in the upper, reworked Black member. Experimental: Hypervelocity impact of a 0.635-diameter Al projectile into dolomite at 5.03 km/s (performed at the Ames Research Center vertical gun range) produced a thin, black layer (= 0.05 mm thick) that partially lined the crater and coated impactor remnants. Scanning electronic microscope (SEM) imagery shows this layer to be spongelike on a submicron scale and Auger spectroscopic analyses yield: 33% C, 22% Mg, 19% 0, and 9% Al (from the projectile). Elemental mapping shows that all of the available 0 is combined with Ca and Mg, Al is not oxidized, and C is in elemental form. Dissociation efficiency of C from CO2 is estimated to be <10% of crater volume. Raman spectroscopy indicates that the C is highly disorganized graphite. Another impact experiment [4] also produced highly disordered graphite from a limestone target (reducing collector), in addition to small amounts of diamond/lonsdaleite/chaoite (oxidizing collector). These experiments confirm the reduction of C from carbonates in impact vapor plumes. Observational: SEM observations and microprobe analyses of small, black shalelike inclusions in the upper Black Onaping indicate high C contents (7-26 wt% avg. = 16%). They contain mostly quartz and carbonaceous matter with small amounts of altered K-feldspar, clays, Fe oxide, and a sulfide. No evidence of shock is seen in quartz, and overall characteristics indicate a natural, lightly metamorphosed carbonaceous shale or mudstone that probably existed as a preimpact rock in the target region and distal fragments washed in during early crater filling. Fragments range in size from tens of microns to cm and increase in abundance in the upper Black toward the Onwatin contact, although their distribution is highly irregular. This increase corresponds to an increase in "organic" C with increasingly negative delta-13 C values and S, together with a decrease in fullerene abundance. In addition, we have found soot in acid-demineralized residues of the Onwatin but not in the Onaping samples. These data could be consistent with impact plume and atmospheric chemical processes, with possible diageneric ovedays. We are analyzing carbonaceous fractions of the Onaping and Onwatin to determine diagnostic C isotopic signatures Analyses by Whitehead et al. on bulk samples revealed no definitive source or processes, although delta-13 C values for "organic" C overlapped those for some meteorites. Discussion: If impact evaporation of Sudbury target carbonates did occur, then where are the carbonates? Distal carbonate (limestone/dolostone) exposures of the Espanola Formation (Huronian Supergroup) are generally thin-bedded, although remnants that partially encompass the Sudbury Crater are variable in thickness and may locally reach 250 m . If a carbonate thickness of 100-200 in existed at the target site, then copious amounts of C could have been reduced by impact processing of carbonates and also C-shale, depending on the efficiency of the processing and the amount of postimpact oxidation. Conclusion: The Sudbury crater offers a unique opportunity to study preserved characteristics of immediate carbonaceous fallback matter and particles of short-term residency in the impact plume as well as dust/aerosols from postimpact atmospheric processing.

Bunch, T. E.↗

Participation in the Consolidated Infrared Spectrometer (CIRS) as Co-Investigator

During the period under review, Owen-pursued the question of a determination of N-15/N-14 in the atmosphere of Saturn, to be carried out by CIRS when Cassini is in orbit about the planet. There are presently no determinations of this important isotope ratio in Saturn, but a study of the 10 microns spectral region of Jupiter has led to the identification of (N-15)H3 lines with the short Wavelength Spectrometer (SWS) of ISO. The resulting determination was a value of N-15/N-14 = 1.9 (+0.9/-1.0) x 10(exp -3) for this giant planet. This number is decidedly lower than the terrestrial value of 3.66 x 10(exp -3) for molecular nitrogen in the Earth's atmosphere. It is much lower than a direct measurement of N-15/N-14 =5 (+2 /-1) x 10(exp -3) in the solar wind by Kallenbach et al. The latter discrepancy is especially surprising in that Jupiter and the sun are expected to have identical isotope ratios: deep mixing on the sun that would dredge up products of nucleosynthesis from the solar interior is not known to occur. Both Fouchet et al. and Kallenbach et al. suggested that some as yet unknown fractionation process in Jupiter's upper atmosphere might act to enrich N-14 above the NH3 clouds, at the 400 mb pressure level corresponding to the ISO observation. A new measurement of the nitrogen isotopes on Jupiter has just become available from the in situ mass spectra recorded by the Galileo Probe Mass Spectrometer. It is N-15/N-14 = 2.3 +/- 0.3 x 10(exp -3). This determination refers to a pressure level greater than 0.8 mb, weighted toward 2 bars. This new result validates the essential correctness of the Fouchet et al. measurement while greatly reducing the uncertainty. It thus appears that the Kallenbach et al. value must somehow be in error. Further support for this conclusion comes from the upper limit of N-15/N-14 less than 2.8 x 10(exp -3) set for solar wind nitrogen implanted in lunar grains.

Owen, Tobias C.↗

Long-Term Cyclic Oxidation Behavior of Uncoated and Coated Re-108 and In-939 at 980 and 870 C

Very long-term cyclic oxidation behavior of Re108 and In939 with and without a protective coating was evaluated at 980 and 870 C, respectively. Re-108 and In-939 without a protective coating began to show a rapid weight loss at 3000 h due to scale spallation, indicating the need for an oxidation protective coating for longer than thousands of hours of oxidative life. NiAl-base coatings of a vapor phase aluminide (VPA), a pack aluminide (CODEP), and a slurry paint aluminide (SERMALOY J) were applied on Re-108 and In-939. The VPA and CODEP on Re-108 and all three coatings on In-939 showed excellent cyclic oxidation resistance out to 10,000 h. Coated alloys were annealed in an inert atmosphere to determine the loss of Al from the coating into the alloy substrate through diffusion. The Al loss from the coating through diffusion was twice as great as the Al loss through oxidation after 10,000 h of cyclic exposure. The oxidation life of VPA-coated Re-108 was estimated by calculating the amount of Al initially available for protective oxidation and the amount of Al lost through oxidation and diffusion.

Lee, K. N.↗

Single Particle Transport Through Carbon Nanotube Wires: Effect of Defects and Polyhedral Cap

The ability to manipulate carbon nanotubes with increasing precision has enabled a large number of successful electron transport experiments. These studies have primarily focussed on characterizing transport through both metallic and semiconducting wires. Tans et al. demonstrated ballistic transport in single-wall nanotubes for the first time, although the experimental configuration incurred large contact resistance. Subsequently, methods of producing low contact resistances have been developed and two terminal conductances smaller than 50 k-ohms have been repeatably demonstrated in single-wall and multi-wall nanotubes. In multi-wall nanotubes, Frank et al. demonstrated a resistance of approximately h/2e(exp 2) in a configuration where the outermost layer made contact to a liquid metal. This was followed by the work of de Pablo et al. where a resistance of h(bar)/27e(exp 2) (approximately 478 ohms) was measured in a configuration where electrical contact was made to many layers of a multi-wall nanotube. Frank et al. and Pablo et al. note that each conducting layer contributes a conductance of only 2e(exp 2)/h, instead of the 4e(exp 2)/h that a single particle mode counting picture yields. These small resistances have been obtained in microns long nanotubes, making them the best conducting molecular wires to date. The large conductance of nanotube wires stems from the fact that the crossing bands of nanotubes are robust to defect scattering.

Anantram, M. P.↗

Numerical Simulation of One- And Two-Phase Flows In Propulsion Systems

In this report, we present some results of problems investigated during joint research between the Hampton University (HU) Fluid Mechanics and Acoustics Laboratory (FM&AL), NASA Glenn Research Center (GRC) and the Hyper-X Program of the NASA Langley Research Center (LaRC). This work is supported by joint research between the NASA GRC/HU FM&AL and the Institute of Mechanics at Moscow State University (IM/MSU) in Russia under a Civilian Research and Development Foundation (CRDF) grant, #RE1-2068. The main areas of current scientific interest of the FM&AL include an investigation of the proposed and patented advanced methods for aircraft engine thrust and noise benefits. These methods are based on nontraditional 3D (three dimensional) corrugated and composite nozzle, inlet, propeller and screw designs such as the Bluebell and Telescope nozzles, Mobius-shaped screws, etc. These are the main subject of our other projects, of which one is the NASA MURED's (Minority University Research and Education Division) FAR (Faculty Awards for Research) Award, #NAG-3-2249. Working jointly with this project team, our team also analyzes additional methods for exhaust jet noise reduction. These methods are without essential thrust loss and even with thrust augmentation. The research is focused on a wide regime of problems in the propulsion field as well as in experimental testing and theoretical and numerical simulation analyses for advanced aircraft and rocket engines. The FM&AL Team uses analytical methods, numerical simulations and experimental tests at the Hampton University campus, NASA and IM/MSU. The main results obtained by FM&AL team were published in the papers and patents.

Gilinsky, Mikhail M.↗