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At least 1,045 records · Page 58

Upgrades of the ATLAS Zero Degree Calorimeter System for Run 3 at the Large Hadron Collider

Experimental studies of ultra-relativistic heavy ion collisions at the Large Hadron Collider (LHC) depend crucially on Zero Degree Calorimeters (ZDCs) that measure neutrons produced at near-beam rapidity in nucleus-nucleus collisions. In hadronic nuclear collisions these neutrons are mainly spectator neutrons, those that do not scatter from opposing nucleons during the collision. As a result, the ZDCs provide a vital probe of heavy ion collision geometry. The ZDCs are also essential in the study of ultra-peripheral collisions that are initiated by photons associated with the electric fields of one or both nuclei. Coherent photon emission typically leaves the photon emitter intact, making the observation of no ZDC signal, on one or both sides, a tag of such processes. The ATLAS ZDCs, built prior to Run 1 were substantially upgraded for LHC Run 3. The primary upgrades included replacement of the quartz Cherenkov radiator with $\text{H}_2$-doped fused silica rods; installation of fast air-core signal cables between the ZDC and the ATLAS USA15 cavern; new LED-based calibration system; and new electronics implemented for readout and fully-digital triggering. The ZDCs were also augmented with new "Reaction Plane Detectors" (RPDs) designed to measure the transverse centroid of multi-neutron showers to allow event-by-event reconstruction of the directed-flow plane in nuclear collisions. The Run~3 ZDC detectors, including the RPDs, are described in detail with emphasis on aspects that are new for Run~3.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

3C 279 Multiwavelength Monitoring: The Ground-Based Campaign - 2

The optically violently variable quasar 3C 279 was monitored simultaneously from radio to gamma-ray frequencies in 1992 December - 1993 January. We report a detailed study of the ground-based results from radio to optical wavelengths. These data show that 3C 279 has a typical blazar spectrum, slightly rising at radio frequency and then progressively steeper above a first turnover frequency between 37 and 90 GHz. In the millimeter wavelength region, a simple power law is not an adequate description of the spectrum. We suggest that the millimeter "shoulder" corresponds to an additional emission component, self-absorbed between 150 and 375 GHz, possibly associated with the detachment of a new Very Long Base Interferometry (VLBI) knot and with the start of radio flare. A flux increase of 20% over 20 days was observed at 37 and 90 GHz, while contemporaneously the R-band flux doubled in about two weeks. The lack of strong variability in contemporaneous X-ray light curves (possible X-ray variations are less than 30%) implies no direct (i.e., zero lag) correlation between the optical and X-ray fluxes. If X-rays are produced by inverse-Compton scattering of relativistic electrons on some seed photons, the above results exclude that the observed optical photons are the seeds and/or that the relativistic electrons radiating via synchrotron in the optical band are responsible for the scattering to X-ray energies. We suggest that the X-rays are instead produced through the inverse-Compton process by electrons of lower energy, which radiate via synchrotron in the radio to millimeter wave bands and which scatter either on the synchrotron photons themselves or on external photons.

Grandi, P.↗

Bioblendstocks to Optimize Mixing Controlled Compression Ignition (MCCI) Engines

In this project, a team of researchers from the University of Massachusetts Lowell, the University of Maine, and Mainstream Engineering developed an integrated process for the product of bioblendstocks to optimize mixing controlled compression ignition (MCCI) engines. The objective was to improve the energy density, sooting propensity, and cetane number of base diesel fuel while maintaining cold weather behavior. The process converts woody biomass (e.g. sawmill residues) into bio-oil through selective fast pyrolysis; the bio-oil is then selectively upgraded to form selectively oxygenated, minimally-branched hydrocarbons using non-noble metal catalysts in combination with metal-catalyzed hydrogenation. Advanced predictive models, in conjunction with existing property databases, and experimental testing are used to evaluate overall bioblendstock properties and their impact on base diesel fuel. An iterative, targeted upgrading approach was implemented to optimize the proposed bioblendstock’s properties. Assessment methodologies included techno-economic analysis, life-cycle assessment, property testing, and engine testing. Ultimately, the project team successfully produced a viable bioblendstock while identifying critical process points related to scale-up efforts. It was found that producing pyrolysis oils at 500 degrees C and with pine particle sizes of 1-2 mm led to bio-oil with a higher yield (of approximately 45 wt%) and rich amounts of aromatic alcohols. The resultant pyrolysis oil was then upgraded using a sequence of mild hydrotreating, followed by catalytic etherification and esterification, followed by another final mild hydrotreating to produce a blendstock containing saturated species with a limited, but non-zero, amount of oxygen. The aromatic alcohols produced by pyrolysis were especially helpful in this regard, as the resulting bicycloethers and derivatives exhibited high cetane numbers. While most bulk properties of the bioblendstock met or exceeded targeted thresholds, viscosity and cloud point notably fell outside the expected range; this could be addressed by blending limits and/or through the use of additives that are commonplace in current refinding practices. Identification of a bioblendstock that can be produced economically at scale while improving the performance and emissions characteristics of internal combustion engines positively affects the economy by boosting domestic fuel production and the environment by decreasing harmful emissions and increasing efficiency.

09 BIOMASS FUELS↗

High-velocity iron absorption lines in supernova remnant 1006

The very strong, broad absorption lines of a sdOB star continuum shown in the International Ultraviolet Explorer spectrum of the Schweizer-Middleditch star projected near the center of supernova remnant SNR 1006 are investigated. It is found that strong Fe(+) resonance absorption lines are present whose centers show zero radial velocity while their profiles are broadened by approximately 5000-6000 km/s. Also identified are redshifted Si(+), Si(2+), and Si(3+) lines at velocities of approximately 5000 km/s. Results show that the absorptions must occur in the ejecta of the supernova. The strength and symmetric width of the Fe(+) line indicates that the bulk of the ejecta is iron, in agreement with the current theory for the origin of Type I supernova. It is suggested that the previous failure to detect strong Fe emission lines in the X-ray spectra of this and other young Type I SNRs may be a result of the ejecta not having had time to interact significantly with the ambient medium. In addition, the presence of redshifted adsorption lines due to supernova ejecta in its spectrum shows that this star is located behind the SNR and is not physically associated with it.

Wu, C.-C.↗

Study of Lightweight Ni-Co Alloy Mirrors Obtained by Electroforming Techniques

One contribution in reducing the costs of optics in space can be provided by production of ultralight mirrors. The decrease in the weight of the primary mirror of a telescope is anticipated to lead to the possibility of increasing the size of the telescopes, therefore increasing the amount and distance from which information is received. An electroplating process of ultralight replica mirrors from nickel sulfamate solution will be described. Based on an experimental setup with cylindrical symmetry, flat mirrors with a diameter of 7 inches and thickness of 1.5 mm are made from a Ni-Co alloy. The composition of the resulting deposit is analyzed using Rutherford Backscattering Spectrometry (RBS) and Proton Induced X-ray Emission (PIXE). In order to resolve Ni and Co, 10 MeV nitrogen ions are used as projectiles in the RBS measurements. Solution parameters monitored during the deposition process using optical absorption and polarography will be correlated with the final concentration of Ni and Co in the deposit. Bath parameters like temperature, current density, agitation level and acidity are chosen at certain values and maintained constant from one sample to another throughout the deposition process. The purpose of the experiment is to obtain mirrors with near zero stress, and predetermined composition and hardness. This study is an intermediate step in obtaining through the same process, but with a larger scale setup, ultralight large aperture replica mirrors.

Jones, Ruth↗

Studies of Long Period Variability in Neutron Star HMXB Systems

The purpose of this effort was to investigate the long term, quasi-periodic variability of the X-ray emission from the accreting X-ray pulsars LMC X-4 and SMC X-1. These high mass X-ray binary (HMXB) sources are known to vary in a nearly periodic fashion with cycle lengths of about 30 and 60 days respectively. The prevailing model for such behavior is that it is due to the precession of a tilted accretion disk around the neutron star which is the source of the X-ray emission. As the disk precesses, it periodically obscures the emitting region, resulting in reduced flux as observed at the Earth. The obscuration is not strictly periodic, as the disk precession period changes as the total mass and size of the disk change through variable accretion processes. This model is well established for the long-period variability in the X-ray pulsar Her X-1. With this work, my collaborators and I sought to test whether this model works for LMC X-4 and SMC X-1. Observations with the pointed instruments on the Rossi X-ray Timing Explorer (RXTE) were carried out in order to observe changes in the X-ray spectrum and total flux which were correlated with the long period cycles in these objects. One of the main predictions of the precessing disk model is that the periods of low emission are caused not by changes in the central source, but by increased absorption of that flux as seen at the Earth. Such behavior would be observed in the X-ray spectrum as a relative lack of low energy X-rays (which are more easily absorbed) as compared to high energy X-rays. This is what was observed for SMC X-1, landing strong support to the precessing disk model for this system. For LMC X-1, however, the absorption was consistent with zero at the time of minimum flux. The entire spectrum appeared to be equally reduced. This is not supporting evidence for the model. However, it also does not rule out a precessing disk. If at the time of minimum flux, the intervening disk is so thick that no flux, even high energy X-rays, can penetrate, and if there is material above the disk which can scatter X-rays, then a small scattered spectrum will be seen which is indistinguishable from the unobscured source flux. This is quite possibly the case in LMC X-1.

Heindl, William A.↗

A white-light /Fe X/H-alpha coronal transient observation to 10 solar radii

Multitelescope observations of the coronal transient of April 15-16, 1980 provide simultaneous data from the Solar Maximum Mission Coronagraph/Polarimeter, the Solwind Coronagraph, and the new Emission line Coronagraph of the Sacramento Peak Observatory. An eruptive prominence-associated white light transient is for the first time seen as an unusual wave or brightening in Fe X 6374 A (but not in Fe XIV 5303 A). Several interpretations of this fleeting enhancement are offered. The prominence shows a slowly increasing acceleration which peaks at the time of the Fe event. The white light loop transient surrounding the prominence expands at a well-documented constant speed to solar radii, with an extrapolated start time at zero height coincident with the surface activity. This loop transient exemplifies those seen above 1.7 solar radii, in that leading the disturbance is a bright N(e)-enhanced) loop rather than a dark one. This is consistent with a report of the behavior of another eruptive event observed by Fisher and Poland (1981) which began as a density depletion in the lower corona, with a bright loop forming at greater altitudes. The top of the bright loop ultimately fades in the outer corona while slow radial growth continues in the legs.

Wagner, W. J.↗

Autoionization and Dressing of Excited Excitons by Free Carriers in Monolayer WSe 2

We experimentally demonstrate dressing of the excited exciton states by a continuously tunable Fermi sea of free charge carriers in a monolayer semiconductor. It represents an unusual scenario of two-particle excitations of charged excitons previously inaccessible in conventional material systems. We identify excited state trions, accurately determine their binding energies in the zero-density limit for both electron- and hole-doped regimes, and observe emerging many-body phenomena at elevated doping. Combining experiment and theory we gain access to the intra-exciton coupling facilitated by the interaction with free charge carriers. We provide evidence for a process of autoionization for quasiparticles, a unique scattering pathway available for excited states in atomic systems. Finally, we demonstrate a complete transfer of the optical transition strength from the excited excitons to dressed Fermi-polaron states as well as the associated light emission from their nonequilibrium populations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Flame tube parametric studies for control of fuel bound nitrogen using rich-lean two-stage combustion

An experimental parametric study of rich-lean two-stage combustion in a flame tube is described and approaches for minimizing the conversion of fuel-bound nitrogen to nitrogen oxides in a premixed, homogeneous combustion system are evaluated. Air at 672 K and 0.48 MPa was premixed with fuel blends of propane, toluene, and pyridine at primary equivalence ratios ranging from 0.5 to 2.0 and secondary equivalence ratios of 0.5 to 0.7. Distillates of SRC-II, a coal syncrude, were also tested. The blended fuels were proportioned to vary fuel hydrogen composition from 9.0 to 18.3 weight percent and fuel nitrogen composition from zero to 1.5 weight percent. Rich-lean combustion proved effective in reducing fuel nitrogen to NO sub x conversion; conversion rates up to 10 times lower than those normally produced by single-stage combustion were achieved. The optimum primary equivalence ratio, where the least NO sub x was produced and combustion efficiency was acceptable, shifted between 1.4 and 1.7 with changes in fuel nitrogen content and fuel hydrogen content. Increasing levels of fuel nitrogen content lowered the conversion rate, but not enough to avoid higher NO sub x emissions as fuel nitrogen increased.

Schultz, D. F.↗

Relativistic induced Compton scattering in synchrotron self-absorbed sources

We present a model of the radio emission from synchrotron self-absorbed sources, including the effects of induced Compton scattering by the relativistic electrons in the source. Order of magnitude estimates show that stimulated scattering becomes the dominant absorption process when (kT(sub B)/m(sub e) c(exp 2))Tau(sub T) greater than or approximately 1.0. Numerical simulations demonstrate that relativistic induced Compton scattering limits the brightness temperature of a self-absorbed synchroton sources to T(sub B) less than or approximately 2 x 10(exp 11) nu(exp -1/p + 3) (sub zero, 9) gamma(exp p + 2/p + 5) (sub min) K, where gamma(sub min) is the low-energy cutoff to the relativistic electron distribution with a power-law index of p. It can also significantly flatten the radio spectrum. The radio spectrum of the core of 3C 279 is well matched by a model in which stimulated scattering is important, and the additional constraint T(sub B) less than 2 x 10(exp 11)K may be important to the interpretation of the broadband spectra in variable extragalactic compact radio sources. Stimulated scattering reduces the amplitude of the radio frequency variability relative to the X-ray variability, an effect which can be detected by multiwavelength variability studies. Data for a sample of resolved compact radio cores indicate that it is inconsistent to neglect induced Compton scattering when inferring the physical parameters of the sources. The necessary generalizations to the standard synchrotron self-Compton theory are p resented.

Sincell, Mark W.↗

The Sub-Neptune Desert and Its Dependence on Stellar Type: Controlled by Lifetime X-Ray Irradiation

Short-period sub-Neptunes with substantial volatile envelopes are among the most common type of known exoplanets. However, recent studies of the Kepler population have suggested a dearth of sub-Neptunes on highly irradiated orbits, where they are vulnerable to atmospheric photoevaporation. Physically, we expect this "photoevaporation desert" to depend on the total lifetime X-ray and extreme ultraviolet flux, the main drivers of atmospheric escape. In this work, we study the demographics of sub-Neptunes as a function of lifetime exposure to high-energy radiation and host-star mass. We find that for a given present-day insolation, planets orbiting a 0.3 solar mass star experience approximately 100 times more X-ray flux over their lifetimes versus a 1.2 solar mass star. Defining the photoevaporation desert as a region consistent with zero occurrence at 2 sigma, the onset of the desert happens for integrated X-ray fluxes greater than 1.43 times 10 (sup 22) to 8.23 times 10 (sup 20) as a function of planetary radii for 1.8 to 4 Earth radius. We also compare the location of the photoevaporation desert for different stellar types. We find much greater variability in the desert onset in the bolometric flux space compared to the integrated X-ray flux space, suggestive of photoevaporation driven by steady-state stellar X-ray emissions as the dominant control on desert location. Finally, we report tentative evidence for the sub-Neptune valley, first seen around Sun-like stars, for M&K dwarfs. The discovery of additional planets around low-mass stars from surveys such as the Transiting Exoplanet Survey Satellite (TESS) mission will enable detailed exploration of these trends.

Planets and Satellites: Gaseous Planets↗

Alternate Fuels for Use in Commercial Aircraft

The engine and aircraft Research and Development (R&D) communities have been investigating alternative fueling in near-term, midterm, and far-term aircraft. A drop in jet fuel replacement, consisting of a kerosene (Jet-A) and synthetic fuel blend, will be possible for use in existing and near-term aircraft. Future midterm aircraft may use a biojet and synthetic fuel blend in ultra-efficient airplane designs. Future far-term engines and aircraft in 50-plus years may be specifically designed to use a low- or zero-carbon fuel. Synthetic jet fuels from coal, natural gas, or other hydrocarbon feedstocks are very similar in performance to conventional jet fuel, yet the additional CO2 produced during the manufacturing needs to be permanently sequestered. Biojet fuels need to be developed specifically for jet aircraft without displacing food production. Envisioned as midterm aircraft fuel, if the performance and cost liabilities can be overcome, biofuel blends with synthetic jet or Jet-A fuels have near-term potential in terms of global climatic concerns. Long-term solutions address dramatic emissions reductions through use of alternate aircraft fuels such as liquid hydrogen or liquid methane. Either of these new aircraft fuels will require an enormous change in infrastructure and thus engine and airplane design. Life-cycle environmental questions need to be addressed.

Daggett, David L.↗

Some recent coronal line observations of supernova remnants

Observations of optical coronal lines from the supernova remnants Puppis A and N 49 in the Large Magellanic Cloud carried out at Cerro Tololo and the Anglo-Australian Observatory are reported. The eastern section of Puppis A was searched for forbidden Fe X and Fe XIV emissions in order to confirm the previous detection of a lower temperature component of the X-ray source. Strong forbidden Fe XIV emission was detected in one region consistent with the position of the previously observed soft X-ray component, implying a cool localized component, possibly a relatively dense interstellar cloud interacting with the expanding shock front, superimposed on a more extended hotter region. The spectrum of N 49 showed a broad feature at 5303 A, identified with the forbidden Fe XIV line. Predictions of X-ray fluxes assuming a temperature of 2 x 10 to the 6th K and a density behind the shock front of 4/cu cm for hydrogen densities of zero and 10 to the 21st/sq cm lead to the suggestion that X-ray observations of N 49 may prove worthwhile.

Zarnecki, J. C.↗

Airglow response to vertically standing gravity waves

There is currently much interest in fluctuations of airglow emissions caused by atmospheric gravity waves. The fluctuations of brightness tend to be found in phase (or occasionally in antiphase) with the fluctuations of measured temperature, whereas current theory tends to anticipate substantial phase differences. We suggest here that the discrepancy results from failure of the common theoretical assumption that the relevant gravity waves are dominated by a single upgoing component: that, instead, there is an accompanying downgoing component of comparable magnitude, produced by reflection. In the case of total reflection, simple, steady state chemistry and vertical viewing, the phase difference is necessarily zero (or 180 deg).

Hines, Colin O.↗

Automated co-adding and energy calibration of large array microcalorimeter data with zero sample knowledge

State-of-the-art microcalorimeter spectrometers now contain large detector arrays with hundreds of individual pixels. Each individual pixel outputs a unique and non-linear response with respect to deposited energy. This work describes a pattern-recognition algorithm to combine these responses into a single energy-calibrated histogram, referred to as co-adding pixels. Photo-peaks from different pixels are matched together based upon how well the match aligns the centroids and heights of neighboring peaks. This usually results in around 100 co-adding calibration points from 30 to 300 keV for a several day acquisition of plutonium items with masses between 0.5 and 10 grams. An additional algorithm energy-calibrates this co-added spectrum using the fluoresced K x-ray emissions from a tantalum absorber and inherent x-ray escape peaks from the tin absorbers. Both algorithms operate without knowledge of the source and are fully automated. This work presents results from the acquisitions of high and low burnup plutonium, 10% enriched uranium, a 153 Gd calibration source, and a 57 Co+ 166m Ho calibration source. In all measurements, resolution defined as the full-width at half-maximum (FWHM) of photo-peaks is preserved between the individual pixel and co-added spectra at around 65 eV for incident photon energies between 60 and 208 keV. The energy calibration algorithm is approximate and yields a calibration curve off by an average of around 200 eV for incident photon energies between 60 and 208 keV.

47 OTHER INSTRUMENTATION↗

Stabilized photoemission from organic molecules in zero-dimensional hybrid Zn and Cd halides

This work explores the utilization of a photoactive organic cation for the preparation of R 2 MCl 4 (M = Zn, Cd; R = (E)-4-styrylpyridinium, C 13 H 12 N + ). Here, the zero-dimensional crystal structures of R 2 MCl 4 contain isolated tetrahedral anions [MCl 4 ] 2– separated by the organic cations R + , leading to flat bands around the optical band gap. In R 2 MCl 4 , the inorganic band gaps are sufficiently large to accommodate the organic molecular levels within, and therefore, the optical properties of R 2 MCl 4 are determined by the organic cation. Our combined optical spectroscopy and density functional theory (DFT) studies confirm the attribution of the bright green photoluminescence demonstrated by R 2 MCl 4 to the organic molecular emission. Importantly, the incorporation of the photoemissive organic cation R + into the hybrid framework in R 2 MCl 4 leads to a nearly two-fold enhancement of the light emission efficiency with the measured photoluminescence quantum yield (PLQY) values of 6.04%, 10.40% and 11.21% for RCl, R 2 ZnCl 4 and R 2 CdCl 4 , respectively. In addition, the crystal structure of the hybrid R 2 MCl 4 ensures a stabilized PL emission, preventing the occurrence of the harmful organic photodimerization, which is a notorious problem for this class of organic emitters.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Seasonal variation in methane ebullition in a temperate hydropower reservoir impacts annualized estimates

Estimates of ebullitive methane (CH4) emissions from reservoirs are highly uncertain, often based on spatial and temporal upscaling from a limited number of sampling sites and periods. While some of these estimates may adjust for seasonal variation in temperature, they rarely account for drawdown and the resulting changes in site depth and the areal extent of the reservoir. In Douglas Reservoir (Tennessee, USA), we conducted monthly sampling of 20 sites over 1 year to capture temporal and spatial variation in CH4 ebullition. We then compared various approaches for obtaining annualized, whole-reservoir ebullition estimates. CH4 ebullition fluxes were zero-inflated and highly skewed, with fluxes rising appreciably above zero in July and peaking in autumn. Estimates that did not account for drawdown overestimated annualized rates by 20%, though with high uncertainty. Seasonal variability and hotspots strongly influence annualized ebullition estimates and are important to account for in inventories and global upscaling.

Cardall, Anna [Brigham Young University]↗

The optically thick C III spectrum. I - Term populations and multiplet intensities at lower optical depths

The C III spectrum is studied quantitatively under both optically thin and optically thick conditions, yielding term populations and line/multiplet intensities for column lengths from zero to 10 exp 18/sq cm. The roles of escape probabilities and line profiles in the calculation are discussed in some detail. It is shown that use of the fully integrated escape factor, rather than the more appropriate monodirectional escape probability, can lead to appreciable errors in calculated intensities. The results for populations and intensities make it possible to identify two unassigned features in the solar EUV spectrum of Vernazza and Reeves (1978) as C III multiplets, and to establish that an unidentified infrared solar feature at 8500.32 A, seen in both absorption (Fraunhofer) and emission (chromospheric) spectra, is the C III transition 2s3s(1S)-2s3p(1P). Voigt parameters for the C III lines and multiplets, obtained by a modified semiclassical method are tabulated. A new, unambiguous notation for the numerous line ratios present in a typical spectrum, which is argued to be an improvement over present arbitrary notations, is proposed and used.

Bhatia, A. K.↗