A mixing-flow reactor for time-resolved reaction measurements distributed in space
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Fluorescence lifetime experiments are a standard approach for measuring excited state dynamics and local environment effects. Here, we show that entangled photon pairs produced from a continuous-wave (CW) laser diode can replicate pulsed laser experiments without phase modulation. As a proof of principle, picosecond fluorescence lifetimes of indocyanine green are measured in multiple environments. Here, the use of entangled photons has three unique advantages. First, low power CW laser diodes and entangled photon source design lead to straightforward on-chip integration for a direct path to distributable fluorescence lifetime measurements. Second, the entangled pair wavelength is easily tuned by temperature or electric field, allowing a single source to cover octave bandwidths. Third, femtosecond temporal resolutions can be reached without requiring major advances in source technology or external phase modulation. Entangled photons could therefore provide increased accessibility to time-resolved fluorescence while also opening new scientific avenues in photosensitive and inherently quantum systems.
Optimal smoother derived for linear time-varying systems using measurements containing colored noise by means of calculus of variations
Synchronized Phase Angle Measurements (SPAMs) are widely used in power systems in the applications of situational awareness. However, the practical time shifts can lead to unexpected angle differences among Phasor Measurement Units (PMUs) manufactured from various vendors. Moreover, since most of PMUs calculate phase angle via Discrete Fourier Transform based approaches, this issue becomes even worse under the off-nominal frequency condition. To mitigate the impact of practical timing shift, this letter presents a fast method to rectify the SPAM for appropriate alignment. To verify the performance of the proposed method, laboratory and field tests have been conducted by implementing the method in PMUs and phasor data concentrators, respectively. The results demonstrate that the standard deviations of the phase angle differences have significantly decreased to 0.1$^{\circ }$ order with the adoption of the proposed method.
It is shown how a commercial time interval counter can be used to measure the relative stability of two signals that are offset in frequency and mixed down to a beat note of about 1 Hz. To avoid the dead-time problem, the counter is set up to read the time interval between each beat note upcrossing and the next pulse of a 10 Hz reference pulse train. The actual upcrossing times are recovered by a simple algorithm whose outputs can be used for computing residuals and Allan variance. A noise floor-test yielded a delta f/f Allan deviation of 1.3 times 10 to the minus 9th power/tau relative to the beat frequency.
It is shown how a commercial time interval counter can be used to measure the relative stability of two signals that are offset in frequency and mixed down to a beat note of about 1 Hz. To avoid the dead-time problem, the counter is set up to read the time interval between each beat note upcrossing and the next pulse of a 10 Hz reference pulse train. The actual upcrossing times are recovered by a simple algorithm whose outputs can be used for computing residuals and Allan variance. A noise floor-test yielded a delta f-f Allan deviation of 1.3 times 10 to the minus 9th power/tau relative to the beat frequency.
Time resolved exposure measurements inside the crew compartment have been made during recent shuttle missions with the USAF Radiation Monitoring Equipment-III (RME-III), a portable four-channel tissue equivalent proportional counter. Results from the first six missions are presented and discussed. The missions had orbital inclinations ranging from 28 degrees to 57 degrees, and altitudes from 200-600km. Dose equivalent rates ranged from 40-5300 micro Sv/dy. The RME-III measurements are in good agreement with other dosimetry measurements made aboard the vehicle. Measurements indicate that medium- and high- Linear Energy Transfer (LET) particles contribute less than 2% of the particle fluence for all missions, but up to 50% of the dose equivalent, depending on the spacecraft's altitude and orbital inclination. Isa-dose rate contours have been developed from measurements made during the ST-28 mission. The drift rate of the South Atlantic Anomaly (SAA) is estimated to be 0.49 degrees W/yr and 0.12 degrees N/yr. The calculated trapped proton and Galactic Cosmic Radiation (GCR) dose for the STS-28 mission were significantly lower than the measured values.
Optimal linear filter for continuous time-varying dynamic system, using measurements containing additive white noise
Measurement of isometric contraction and ejection time by vibrocardiogram of anesthetized dog
The Physiology Research Branch at Brooks AFB conducts both human and nonhuman primate experiments to determine the effects of microgravity and hypergravity on the cardiovascular system and to identify the particular mechanisms that invoke these responses. Primary investigative efforts in our nonhuman primate model require the determination of total peripheral resistance, systemic arterial compliance, and pressure-volume loop characteristics. These calculations require beat-to-beat measurement of aortic flow. This study evaluated accuracy, linearity, biocompatability, and anatomical features of commercially available electromagnetic (EMF) and transit-time flow measurement techniques. Five rhesus monkeys were instrumented with either EMF (3 subjects) or transit-time (2 subjects) flow sensors encircling the proximal ascending aorta. Cardiac outputs computed from these transducers taken over ranges of 0.5 to 2.0 L/min were compared to values obtained using thermodilution. In vivo experiments demonstrated that the EMF probe produced an average error of 15% (r = .896) and 8.6% average linearity per reading, and the transit-time flow probe produced an average error of 6% (r = .955) and 5.3% average linearity per reading. Postoperative performance and biocompatability of the probes were maintained throughout the study. The transit-time sensors provided the advantages of greater accuracy, smaller size, and lighter weight than the EMF probes. In conclusion, the characteristic features and performance of the transit-time sensors were superior to those of the EMF sensors in this study.
Here, this study explores the relationship between experimentally observed inter-event time-interval distributions (TIDs) and measured dead times for pulses generated by a HPGe gamma detector and processed by a digital spectrometer. The system utilizes a fast and slow channel, pile-up rejector, trapezoid filtering, and flash analog-to-digital converter. The experimentally derived TIDs were compared with theory for validation. The results demonstrate that the theoretical model reliably describes measured TIDs up to 40% dead time. However, significant distortion effects become increasingly pronounced at higher input rates. It appears that the deviation between the measured and calculated time-interval distributions take the shape of higher-order convolutions of the TID, which represent the time difference between counts for more than two successive events. In this work, theoretical functions for the TID are expanded to reproduce measurements up to 90%. This refinement in the interpretation and treatment of the measured TIDs provides improved accuracy and precision in the prediction of the true event rate and measured dead time in the counter. Even though it reflects occasional count loss that is specific to the set-up, it is expected that a similar adjustment may be applicable to other detection systems as well.
Electrochemical impedance spectroscopy (EIS) is ubiquitously applied to identify physicochemical processes governing the performance of energy-conversion devices. However, deconvolution and interpretation of impedance phenomena are limited by measurement throughput and a dearth of scalable analysis methods. Here, we demonstrate an approach to quickly collect and coherently analyze large volumes of electrochemical data. In this study, we accelerate impedance characterization by combining rapid measurements in time and frequency domains, which are interpretably transformed using the distribution of relaxation times (DRT) and a new distribution of phasances (DOP) model. This method provides excellent agreement with EIS and decreases measurement time by an order of magnitude. High-throughput spectra are then distilled into detailed electrochemical maps. This approach is applied to a Li-ion battery and a protonic ceramic electrochemical cell as practical case studies, demonstrating how mapping can richly characterize physicochemical relationships that are difficult to decipher with conventional measurement and analysis methods.
A geodetic distance measuring apparatus which compensates for the refractive index of the atmosphere is discussed. A mode locked laser system with a laser device and its peripheral components is utilized to derive two mutually phase locked optical wavelength signals and one phase locked microwave CW signal which respectively traverse the same distance measurement path. The optical signals are comprised of pulse type signals. Phase comparison of the two optical wavelength pulse signals is used to provide the dry air density while phase comparison of one of the optical wavelength pulse signals and the microwave CW signal issued to provide wet or water vapor density of the air. The distance to be measured corrected for the atmospheric dry air and water vapor densities in the measurement path is computed from these measurements. A time interval unit is included for measuring transit time of individual optical pulses for resolving the phase ambiguity needed with the phase measurements to give the true target distance.
Measurements of solar irradiance fluctuations by the Active Cavity Radiometer (ACRIM) instrument onboard the Solar Maximum Mission (SMM) show variations on a time scale of about 5 minutes due to solar p-mode oscillations, as well as longer-term variations related to solar magnetic activity. The question was studied whether the p-mode frequencies change with time as a result of changing solar structure associated with the activity cycle. The ACRIM data on SMM are particularly well-suited for this purpose, because the instrument operated continuously from February 1980 to December 1980 and again from May 1984 to the present. The main activity entailed a detailed study of the observational data to determine if a change in the p-mode frequencies is evident from the time of solar maximum to that of solar minimum. It was concluded that the measured eigenfrequencies were significantly higher during the 1980 time frame than during the 1984 to 1986 time frame. The conclusion that there is significant change in the eigenfrequencies with the activity cycle remains only tentative, and needs confirmation from analysis of more data during the upcoming solar maximum.
The application of time-series radar measurements to accurately invert the thickness of saline ice is presented in this study. We describe briefly some experimental observations from the CRRELEX 93 campaign of sea ice.
Sequential scattering measurements are often performed under a fixed experimental-time budget, even though the expected count rate varies strongly across the measured coordinate. When the dwell time at each measurement position can be controlled independently, this variation creates a general resource-allocation problem: how should the available time be distributed to minimize the uncertainty of the reconstructed profile? We formulate this problem as a constrained variational optimization for measurements governed by Poisson counting statistics. When each measurement is treated independently, minimizing the averaged squared relative uncertainty yields an inverse-square-root intensity allocation. The formulation is then generalized to include correlations between neighboring measurements and an instrumental resolution operator, leading to an allocation criterion that equalizes the marginal reduction in posterior uncertainty per unit measurement time. Bonse–Hart ultra-small-angle neutron scattering (USANS), in which reciprocal space is sampled sequentially through analyzer-angle stepping, provides an experimentally grounded application. Computational benchmarking shows that the optimized allocation outperforms uniform-time and constant-relative-error strategies, while application to an experimentally measured graphite USANS profile from the Spallation Neutron Source, using Poisson resampling under alternative schedules, demonstrates how counting time should be redistributed toward weak-intensity regions under an identical total duration. The resulting framework applies to sequential scattering and related scanning measurements whenever local dwell times are adjustable and directly determine the measurement uncertainties, and when the relevant correlation and instrumental-response models are available.
A closed queueing network model is constructed to address workload effects on computer performance for a highly reliable unibus multiprocessor used in real-time control. The queueing model consists of multiserver nodes and a nonpreemptive priority queue. Use of this model requires partitioning the workload into task classes. The time average steady-state solution of the queueing model directly produces useful results that are necessary in performance evaluation. The model is experimentally justified with the Fault-Tolerant Multiprocessor (FTMP) located at the NASA AIRLAB. Extensive experiments are performed on FTMP with a synthetic workload generator (SWG) to directly measure performance parameters, such as processor idle time, system bus contention, and task processing times. These measurements determine values for parameters in the queueing model. Experimental and analytic results are then compared.