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At least 1,045 records · Page 58
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Prediction of Thermal Transport Properties of Materials with Microstructural Complexity

This project aims at overcoming the major obstacle standing in the way of progress in dynamic multiscale simulation, which is the lack of a concurrent atomistic-continuum method that allows phonons, heat and defects to pass through the atomistic-continuum interface. The research has led to the development of a concurrent atomistic-continuum (CAC) methodology for multiscale simulations of materials microstructural, mechanical and thermal transport behavior. Its efficacy has been tested and demonstrated through simulations of dislocation dynamics and phonon transport coupled with microstructural evolution in a variety of materials and through providing visual evidences of the nature of phonon transport, such as showing the propagation of heat pulses in single and polycrystalline solids is partially ballistic and partially diffusive. In addition to providing understanding on phonon scattering with phase interface and with grain boundaries, the research has contributed a multiscale simulation tool for understanding of the behavior of complex materials and has demonstrated the capability of the tool in simulating the dynamic, in situ experimental studies of nonequilibrium transient transport processes in material samples that are at length scales typically inaccessible by atomistically resolved methods.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Pilot Scale Operation and Testing of Syngas Chemical Looping For Hydrogen Production

The Syngas Chemical looping (SCL) process provides efficient and economic means to utilize the abundant fossil reserve of coal. The main problem associated with coal utilization is the CO 2 emissions resulting from its combustion. Even though CO 2 regulation or carbon tax is currently not in place, its enforcement is expected in the near future. Such a greenhouse gas emission control, if adopted in current power plant systems, will drive the efficiency down and increase the cost of electricity, due to the energy and capital-intensive nature of current CO 2 separation techniques. This highlights the need to develop technologies that present a solution to the rising cost of electricity in the future. The integrated gasification combined cycle (IGCC) presents an improvement to the above predicament, but it is capital intensive due to the extensive unit operations involved. The efficiency for a CO 2 capture incorporated IGCC system is around ~32%, resulting in approximately 45% increase in cost of electricity. This is definitely a better path to traverse than the conventional pulverized coal (PC) power plants as it has improved economics and efficiencies accompanied by product flexibility. The SCL process advances the benefits even further when integrated with the IGCC process. The SCL process removes the expensive WGS system and CO 2 separation columns, thereby saving on capital and operational expenses. This integration results in a 12 – 21% increase in efficiency accompanied by a reduction in cost of electricity by 15 – 28%, over conventional IGCC systems. Therefore, SCL process provides the best route to harness the energy from coal. The overall project objective was to construct and operate a syngas chemical looping pilot scale test unit at the NCCC. The project scope of work was divided into 3 phases. In Phase I, cold flow model studies using a 1:1 scale acrylic test unit constructed at Particulate Solids Research, Inc. (PSRI) was successfully completed confirming robust solid flow control is achievable in the non-mechanical system design. In Phase II, the high pressure, high temperature, chemical looping reactor was successfully designed with all necessary equipment and safety instrumentation/controls specified to allow for fabrication, site construction, and assembly to commence in Phase III. In Phase III, the SCL pilot plant was successfully assembled and all necessary functional checks and pre-startup safety reviews completed. During unit commission over the course of 200 hours of testing, operational issues were observed with premix burner used for system startup. With the grants awarded by the National Energy Laboratory (NETL) and the Ohio Development Services Agency (ODSA) under awards DE-FE0023915 and D-14-18, the SCL pilot unit underwent three auxiliary equipment modifications to resolve all of the startup operational issues encountered. The unit was successfully demonstrated with 300+hr continuous operation. Key results obtained include high syngas conversion of 97.95% with 16.03% oxygen carrier conversion in the moving bed reducer and >99% purity H 2 produced from the moving bed oxidizer.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2018

Precipitation Risk when Diluting DFLAW Feed Saturated in Aluminum Hydroxide

The technical bases to support the One System River Protection Project Integrated Flowsheet assumption for diluting staged Direct Feed Low-Activity Waste (DFLAW) from the Hanford waste tanks with raw river water must be assessed in light of the risk of aluminum hydroxide (gibbsite) precipitation prior to the subsequent transfer of tank contents into the Low-Activity Waste Pretreatment System (LAWPS) from days to months after dilution. The operational and mission impacts of using other dilution fluids such as inhibited water, demineralized water, or a 2 M sodium hydroxide solution also must be assessed. As a first step to help inform this investigation, a survey was conducted of Hanford waste-related tests documenting the processing of tank waste materials (solutions, salt cakes, sludges) or their simulants for instances of gibbsite dissolution and precipitation. Experience from the aluminum industry, particularly the Bayer process, also was surveyed to gain insight into the precipitation and dissolution of gibbsite in sodium hydroxide solutions. The dependence of aluminum concentration on hydroxide concentration in analyses of actual tank waste solutions also was surveyed for tanks that have a long-term static inventory and tanks suspected of containing or known to contain substantial gibbsite solid phase in their sludge solids. Finally, an experimental program is outlined to aid prediction of the outcomes of DFLAW staged feed dilution with respect to significant variables that influence gibbsite dissolution and precipitation. The results of these investigations are summarized in this report.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2013

Correlation between structural and opto-electronic characteristics of crystalline Si microhole arrays for photonic light management

By employing electron paramagnetic resonance spectroscopy, transmission electron microscopy, and optical measurements, we systematically correlate the structural and optical properties with the deep-level defect characteristics of various tailored periodic Si microhole arrays, which are manufactured in an easily scalable and versatile process on nanoimprinted sol-gel coated glass. While tapered microhole arrays in a structured base layer are characterized by partly nanocrystalline features, poor electronic quality with a defect concentration of 10{sup 17} cm{sup −3} and a high optical sub-band gap absorption, planar polycrystalline Si layers perforated with periodic arrays of tapered microholes are composed of a compact crystalline structure and a defect concentration in the low 10{sup 16} cm{sup −3} regime. The low defect concentration is equivalent to the one in planar state-of-the-art solid phase crystallized Si films and correlates with a low optical sub-band gap absorption. By complementing the experimental characterization with 3-dimensional finite element simulations, we provide the basis for a computer-aided approach for the low-cost fabrication of novel high-quality structures on large areas featuring tailored opto-electronic properties.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Patternable Mesoporous Thin Film Quantum Materials via Block Copolymer Self-Assembly: An Emergent Technology?

Recent developments in quantum materials hold promise for revolutionizing energy and information technologies. The use of soft matter self-assembly, for example, by employing block copolymers (BCPs) as structure directing or templating agents, offers facile pathways toward quantum metamaterials with highly tunable mesostructures via scalable solution processing. Here, we report the preparation of patternable mesoporous niobium carbonitride-type thin film superconductors through spin-coating of a hybrid solution containing an amphiphilic BCP swollen by niobia sol precursors and subsequent thermal processing in combination with photolithography. Spin-coated as-made BCP-niobia hybrid thin films on silicon substrates after optional photolithographic definition are heated in air to produce a porous oxide, and subsequently converted in a multistep process to carbonitrides via treatment with high temperatures in reactive gases including ammonia. Grazing incidence small-angle X-ray scattering suggests the presence of ordered mesostructures in as-made BCP-niobia films without further annealing, consistent with a distorted alternating gyroid morphology that is retained upon thermal treatments. Wide-angle X-ray scattering confirms the synthesis of phase-pure niobium carbonitride nanocrystals with rock-salt lattices within the mesoscale networks. Electrical transport measurements of unpatterned thin films show initial exponential rise in resistivity characteristic of thermal activation in granular systems down to 12.8 K, at which point resistivity drops to zero into a superconducting state. Magnetoresistance measurements determine the superconducting upper critical field to be over 16 T, demonstrating material quality on par with niobium carbonitrides obtained from traditional solid-state synthesis methods. Here. we discuss how such cost-effective and scalable solution-based quantum materials fabrication approaches may be integrated into existing microelectronics processing, promising the emergence of a technology with tremendous academic and industrial potential by combining the capabilities of soft matter self-assembly with quantum materials.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Observation of Topological Chirality Switching Induced Freezing of a Skyrmion Crystal

Magnetic skyrmions are topologically protected quasi-particles with a well-defined chirality. Control over their chirality is proposed as an additional feature for encoding data bits or as qubits in quantum computing due to their high efficiency and stability against achiral magnetic textures. Here it is shown that an in-plane magnetic field can be utilized to reshape the energy barriers between different skyrmionic bubbles (e.g., Bloch type, type-II) enabling spontaneous chirality fluctuations with a frequency that increases with the strength of the in-plane field. The insulating van der Waals ferromagnet CrBr3 is used as an archetypal system for low damping, reduced energy dissipation and a high number of magnetic phases to capture the chirality dynamics in real time through cryo-Lorentz transmission electron microscopy. It is observed that the interplay between the intrinsic Dzyaloshinskii–Moriya interaction and out-of-plane field biased the chirality dynamics, favoring one handedness over the other. A remarkable consequence of the spontaneous chirality switching mechanism is that it induces a freezing (or crystallization) process in the skyrmion lattice. As the bubbles fluctuate between Bloch and type-II they elongate and shrink parallel to the in-plane field. Subsequently, the overall lattice crystallizes along the in-plane field direction, inducing a phase transition from a disordered liquid state to a hexatic phase where skyrmions are highly ordered resembling that of a solid. The results indicate chirality as an active element in the creation of topologically protected skyrmion crystals unveiling pathways toward chiral spintronic device platforms with tunable embedded configuration.

2D Phase Transition↗
DOE OSTI2013

Three-Dimensional Reconstruction and Microstructure Modeling of Porosity-Graded Cathode Using Focused Ion Beam and Homogenization Techniques

In this study, microstructure of a porosity-graded lanthanum strontium manganite (LSM) cathode of solid oxide fuel cells (SOFCs) has been characterized using focused ion beam (FIB) and scanning electron microscopy(SEM) combined with image processing. Two-point correlation functions of the two-dimensional (2D) images taken along the direction of porosity gradient are used to reconstruct a three-dimensional (3D) microstructure. The effective elastic modulus of the two-phase porosity-graded cathode is predicted using strong contrast (SC) and composite inclusion (CI) homogenization techniques. The effectiveness of the two methods in predicting the effective elastic properties of the porositygraded LSM cathode is investigated in comparison with the results obtained from the finite element model (FEM).

25 ENERGY STORAGE↗
DOE OSTI2022

Assessing entropy for catalytic processes at complex reactive interfaces

When chemical reactions are accelerated by a catalyst, entropy differences between reactants and their transient intermediates can be the driving force behind the promotion or inhibition of desired and parasitic chemical pathways. Understanding and controlling catalytic processes therefore requires both a fundamental and practicable understanding of entropy in addition to enthalpy. In unstructured media such as the vapor phase equilibrated with sparsely covered surfaces, entropy can be adequately accounted for by well-established approaches based on translational, rotational, and harmonic vibrational partition functions. However, these approximations become inadequate in more complex condensed phase environments, e.g., solid liquid interfaces of confined reaction spaces. In this chapter, we provide an overview of the state-of-art in the computational quantification of entropy and its known ramifications on catalysis. The fundamental roles of thermodynamics and kinetics in catalysis are covered in enough detail to appreciate and contextualize the computational methods employed to compute chemically accurate estimates of entropy. These methods are discussed in appropriate detail and range from the ubiquitous harmonic oscillator approximation where entropy unrelated to high frequency oscillations is typically underestimated, to enhanced free energy sampling with molecular dynamics where the desired accuracy must be weighed against the associated computational cost of obtaining it. The rising importance of machine learning and artificial intelligence in accelerating methodological progress in this field is touched upon, as well. Finally, applications, successes, and pitfalls of using these methods are provided to showcase past and present accomplishments while clarifying where improvements in both understanding and methodology are still needed.

Kollias, Loukas↗
DOE OSTI2018

Solubility of U(VI) in chloride solutions. III. The stable oxides/hydroxides in MgCl 2 systems: Pitzer activity model for the system UO 2 2+ –Na + –K + –Mg 2+ –H + –OH – –Cl – –H 2 O(l)

Here we have developed new chemical, thermodynamic and activity models for the system UO 2 2+ –Na + –K + –Mg 2+ –H + –OH – –Cl – –H 2 O(l) within the Pitzer approach. The new thermodynamic model is based on previously reported data treated within the SIT approach for NaCl and KCl systems, as well as on new experimental data determined in this work for the MgCl 2 system. The solubility of uranium(VI) was studied in 0.01–5.15 mol·kg w –1 MgCl 2 solutions at pH m = 4.1–9.7 (with pH m = –log [H + ]). Experiments were performed under Ar atmosphere at T = (22 ± 2) °C. In all investigated systems, the solubility of U(VI) is controlled by metaschoepite, UO 3 ·2H 2 O(cr). In contrast to previously investigated NaCl and KCl systems, no ternary Mg–U(VI)–OH(s) solid phases formed in alkaline MgCl 2 solutions within the timeframe of this study (≤ 200 days). A very significant increase in the solubility (up to 3 log 10 -units) is observed in acidic to near-neutral pH m conditions when increasing MgCl 2 concentration from 0.01 to 5.15 mol·kg w –1 , which reflects the strong ion interaction processes taking place in concentrated MgCl 2 brines. The solubility of UO 3 ·2H 2 O(cr) in the investigated NaCl, KCl and MgCl 2 solutions is well described with the solubility and hydrolysis constants recommended by Altmaier et al., (2017) and NEA–TDB, and a Pitzer activity model derived in the present work. The latter model considers experimental data reported in the present study and available in the literature for NaCl, KCl and MgCl 2 systems (solubility, potentiometric and spectroscopic data), in combination with well-stablished estimation methods and correlations with SIT coefficients. Finally, chemical, thermodynamic and Pitzer activity models provided in this work for the system UO 2 2+ –Na + –K + –Mg 2+ –H + –OH – –Cl – –H 2 O(l) accurately describe all evaluated datasets, and represent an adequate tool for the calculation of U(VI) solubility and aqueous speciation in a variety of geochemical conditions including concentrated brine systems of relevance in salt-based repositories for nuclear waste disposal.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Solid secondary waste testing for maintenance of the Hanford Integrated Disposal Facility Performance Assessment - FY 2017

The Waste Treatment and Immobilization Plant (WTP) at Hanford is being constructed to treat 56 million gallons of radioactive waste currently stored in underground tanks at the Hanford site. Operation of the WTP will generate several solid secondary waste (SSW) streams including used process equipment, contaminated tools and instruments, decontamination wastes, high-efficiency particulate air filters (HEPA), carbon adsorption beds, silver mordenite iodine sorbent beds, and spent ion exchange resins (IXr) all of which are to be disposed in the Integrated Disposal Facility (IDF). An applied research and development program was developed using a phased approach to incrementally develop the information necessary to support the IDF PA with each phase of the testing building on results from the previous set of tests and considering new information from the IDF PA calculations. This report contains the results from the exploratory phase, Phase 1 and preliminary results from Phase 2. Phase 3 is expected to begin in the fourth quarter of FY17.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2018

Catalytic Processes for Production of α,ω-diols from Lignocellulosic Biomass

In this project, we have demonstrated and developed a multi-step catalytic process for production of 1,5-PDO and 1,6-HDO starting from white birch as shown in Scheme 1. First, lignocellulosic biomass was converted into cellulose, furfural and solid lignin via the TriVersa ProcessTM developed by Glucan Biorenewables LLC. GlucanBio fractionated biomass into a solid high purity stream of cellulose (>90% purity and >90% recovery) and a concentrated liquid phase of solubilized hemicellulose (>90% of hemicellulose solubilized) in Task A (See Table 1). The hemicellulose was then converted into furfural (>85% yield) without any purification step. Furfural was converted into 1,5-PDO by four catalytic steps as shown in Scheme 1 in Task B1-3(See Table 1): i) Furfural was hydrogenated into THFA, ii) THFA was dehydrated to dihydropyran (DHP), iii) DHP was hydrated to 2-hydroxytetrahydropyran (2-HY-THP) and 2-HY-THP dimers and 4) 5-hydoxyvaleraldehyde (5-HY-Val) was hydrogenated into 1,5-PDO. This pathway will be referred to in this report as the dehydration, hydration, and hydrogenation (DHH) route. A total yield of >80% 1,5-PDO was achieved via this new DHH pathway, which surpasses the >50% 1,5-PDO yields over traditional noble catalysts.

09 BIOMASS FUELS↗
DOE OSTI2019

Electrogenerative Reactors for Process Intensified Cogeneration of Power and Liquid Fuel from Shale Gas

With the abundance of natural gas and its primary components of methane, ethane and propane, there is the opportunity to convert these light alkanes to higher-value products. The growth in natural gas supply in the U.S. has increased substantially since the mid-2000s due to advances in horizontal drilling and hydraulic fracturing. As petroleum prices are volatile, natural gas resources are progressively attractive as alternative fuel sources. However, many of these shale gas wells are in regions of the U.S. that are remote and costly to transport to petrochemical and refining centers. In addition, much of this shale gas is “wet gas” that contains condensable amounts of ethane. While dedicated ethane gas pipelines have been built to get a small fraction of this gas to market, they are very capital intensive and compete for existing land use. As a result of this Phase I project, we developed a process to convert ethane to a transportable liquid fuel. This was achieved by implementing process intensification for this gas-to-liquids approach; we use novel eletrogenerative reactors in a two-step process rather than multi-step well-known technologies such as Fisher-Tropsch synthesis. These reactors borrow on well proven solid oxide fuel cell technology. Therefore, when produced in mass will be a very low-cost modular chemical reactor. This project demonstrated that EcoCatlaytic’s catalysts are highly selective towards ethylene and are compatible with anode materials. These integrated catalysts with the anode were able to maintain stable activity under ethane. Process simulations demonstrate an energy savings while producing gasoline and electricity for a modular system that produces 1,000 bbl/day gasoline. The system, not only produces gasoline, but also generates electricity which is a very valuable commodity in the remote shale gas facilities. This process could potentially allow remote natural gas producers to upgrade their feedstock to valuable gasoline on-site rather than flaring.

03 NATURAL GAS↗
DOE OSTI2021

Conversion of CO 2 into Synthetic Graphite

Carbon Dioxide (CO 2 ) can be utilized as a source for producing synthetic graphite. Our method converts CO 2 into solid carbon. These CO 2 -sourced solid carbon have an anisotropic property that allow them to be graphitized into synthetic graphite. Our patented thermal catalytic process uses carbon dioxide and hydrogen as the feedstocks for the reaction, producing solid carbon material, with distilled water as the sole byproduct. The process is designed as a closed loop, where all feedstock gases entering the reactor are converted into durable bulk carbons and water, with no emissions. These carbons materials can be sintered into a solid structure and then thermally annealed, taking the carbon atoms from a disordered state to a highly ordered state of graphitic material – producing synthetic graphite structures. Phase 1 will prove that these bulk carbons can be sintered into a machinable solid carbon structure, which will then be annealed into a fully graphitic solid structure. Standard analytics will be done to verify the extent of graphitization (Raman, XRD). Proving this CO 2 -sourced carbon pathway to synthetic graphite structures will give the US a domestic supply route for this critical material and remove reliance on foreign sources. In addition, since the synthetic graphite structure is made from CO 2 -sourced carbon, this is also a method to mitigate CO 2 . Graphite structures are used in high temperature and high friction applications, for example, as anodes for steel refining, for brake pad linings, as neutron reflectors in nuclear reactors.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Simultaneous reaction and separation of chemicals

The reaction rate of hydrocarbon pyrolysis can be increased to produce solid carbon and hydrogen by the use of molten materials which have catalytic functionality to increase the rate of reaction and physical properties that facilitate the formation and contamination-free separation of the solid carbon. Processes, materials, reactor configurations, and conditions are disclosed whereby methane and other hydrocarbons can be decomposed at high reaction rates into hydrogen gas and carbon products without any carbon oxides in a single reaction step. The process also makes use of specific properties of selected materials with unique solubilities and/or wettability of products into (and/or by) the molten phase to facilitate generation of purified products and increased conversion in more general reactions.

McFarland, Eric W.↗
DOE OSTI2020

Manganese: The overlooked contaminant in the world largest mine tailings dam collapse

Manganese (Mn) is an abundant element in terrestrial and coastal ecosystems and an essential micronutrient in the metabolic processes of plants and animals. Mn is generally not considered a potentially toxic element due to its low content in both soil and water. However, in coastal ecosystems, the Mn dynamic (commonly associated with the Fe cycle) is mostly controlled by redox processes. Here, we assessed the potential contamination of the Rio Doce estuary (SE Brazil) by Mn after the world’s largest mine tailings dam collapse, potentially resulting in chronic exposure to local wildlife and humans. Estuarine soils, water, and fish were collected and analyzed seven days after the arrival of the tailings in 2015 and again two years after the dam collapse in 2017. Using a suite of solid-phase analyses including X-ray absorption spectroscopy and sequential extractions, our results indicated that a large quantity of Mn II arrived in the estuary in 2015 bound to Fe oxyhydroxides. Over time, dissolved Mn and Fe were released from soils when Fe III oxyhydroxides underwent reductive dissolution. Due to seasonal redox oscillations, both Fe and Mn were then re-oxidized to Fe III , Mn III , and Mn IV and re-precipitated as poorly crystalline Fe oxyhydroxides and poorly crystalline Mn oxides. In 2017, redox conditions (Eh: -47 ± 83 mV; pH: 6.7 ± 0.5) favorable to both Fe and Mn reduction led to an increase (~880%) of dissolved Mn (average for 2015: 66 ± 130 μg L -1 ; 2017: 582 ± 626 μg L -1 ) in water and a decrease (~75%, 2015: 547 ± 498 mg kg -1 ; 2017: 135 ± 80 mg kg -1 ) in the total Mn content in soils. The crystalline Fe oxyhydroxides content significantly decreased while the fraction of poorly ordered Fe oxides increased in the soils limiting the role of Fe in Mn retention. The high concentration of dissolved Mn found within the estuary two years after the arrival of mine tailings indicates a possible chronic contamination scenario, which is supported by the high levels of Mn in two species of fish living in the estuary. Our work suggests a high risk to estuarine biota and human health due to the rapid Fe and Mn biogeochemical dynamic within the impacted estuary.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Micrometer-sized Magnetite Synthesis using Fe(OH)2(s) as a Precursor for Technetium Sequestration from Liquid Nuclear Waste Streams

Systematic batch experiments under variable adjusted physicochemical conditions were conducted to explore optimization of micrometer-sized magnetite synthesis for Tc sequestration from radionuclide waste streams using Fe(OH)2(s) as the precursor. Extensive solid characterization using x-ray diffraction and spectroscopic methods was performed to assess changes in particle morphology and size distribution, as well as Tc speciation and incorporation, in the produced mineral phases. The results show that the solution pH, temperature, and oxidation kinetics play key roles in the final mineral products. Micrometer-sized magnetite crystals (0.62-0.96 µm on average) with well-defined dodecahedral or octahedral structures were synthesized under near neutral (~pH 8) or alkaline (~pH13) conditions at 75 °C, respectively; whereas goethite dominated the end products at room temperature. An increase in pH at 75 °C improved Tc removal from 27% (near neutral pH) to 42% (alkaline pH), but the removal process remained inhibited by redox competitive Cr(VI) present in the waste streams. By adding additional Fe(II) to the system, Tc sequestration was dramatically improved to up to 87% without observable changes in the solid product. The sequestrated Tc existed as TcO2·2H2O and/or Tc(IV) incorporated into magnetite, where extended X-ray absorption fine structure (EXAFS) spectroscopy showed that more Tc was incorporated into magnetite at elevated temperatures and pH conditions, with complete Tc(IV) incorporation into magnetite occurring under 75 °C-pH 13 conditions. Our results indicate that optimal micrometer-sized magnetite can be produced for Tc sequestration by reacting Fe(OH)2(s) with a waste stream simulant under elevated pH (~13) and temperature (75 °C) conditions. The incorporation of reduced Tc(IV) into stable micrometer-sized magnetite provides a viable supplemental immobilizing technology that may be used to improve nuclear waste treatment and disposal needs.

Wang, Guohui↗
DOE OSTI2018

Microstructure and Mechanical Properties of a Ag Micro-Alloyed Mg-5Sn Alloy

Effects of 1.5 wt.% Ag addition and solid solution + artificial ageing at 160 °C on the microstructure and mechanical properties of a Mg-5Sn alloy have been studied. The results show that Ag addition has significantly hardened the solution-treated Mg-5Sn alloy. During the ageing process, the hardness increase rate and the strength and ductility of the Mg-5Sn alloy at each state are also improved by Ag addition. The improved strengthening behavior is primarily attributed to the refinement distribution of the Mg{sub 2}Sn precipitates, the enhanced precipitation process, and the synergistic strengthening effect of Mg{sub 2}Sn and a metastable plate DO{sub 19} phase formed at lower ageing temperature. For each solution-treated alloy, the strength and ductility are higher than the corresponding cast ones. Ageing further enhances the yield strength, and the ductility of the Mg-5Sn-1.5Ag alloy is also increased after ageing. The fracture surfaces of the both peak-aged alloys exhibit the characteristic of a mixture of quasi-cleavage and ductile fracture.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Full-Scale Vessel Testing for the Hanford Waste Treatment and Immobilization Plant - 18333

Concerns over the mixing performance of the planned pulse jet mixed (PJM) vessels for high-solids applications in the Hanford Waste Treatment and Immobilization Plant (WTP) Pretreatment (PT) Facility, led to the development of a standard high-solids vessel (SHSV) design and full-scale vessel testing program. The SHSV is intended as a potential replacement for several high-level waste feed receipt and lag storage vessels (High-Level Waste Facility lag storage and feed blending process), ultrafiltration feed preparation vessels (ultrafiltration process system), and plant wash vessels (plant wash and disposal system). The SHSV concept uses multiple smaller vessels (60 500 L - 79 500 L nominal batch size) to replace larger vessels, providing redundancy, improved mixing (PJM design and spargers), monitoring (multi-level bubblers), reduced material at risk, and improved structural features. The SHSV also requires qualification of a single vessel design for high solids Newtonian and non-Newtonian slurry processing, rather than having to qualify earlier multiple vessel designs. An Integrated Technical Team consisting of the U.S. Department of Energy, Bechtel National, Inc., and independent experts was established to accelerate and provide oversight and direction of the test program and SHSV qualification. Qualification of the SHSV for mixing has now been achieved through a comprehensive full-scale vessel testing program conducted in 2017 with a prototypic SHSV under a set of most adverse design conditions, in conjunction with additional engineering analyses. This paper will present an overview of the SHSV, results from the three-phase full-scale vessel test and qualification program completed in September 2017, and the management program to achieve resolution of the PJM mixing technical issue. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗