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At least 1,045 records · Page 58

Characteristics of STP Pre-2004 Archived KE Basin Sludge Samples Before and After Re-Jarring in the RPL - April 2012

This report describes results of work performed in the Shielded Analytical Laboratory (SAL) at the Pacific Northwest National Laboratory’s (PNNL) Radiochemical Processing Laboratory (RPL) with archive K East (KE) Basin sludge samples obtained before the year 2004, with some of them composited and initially characterized five years ago (Delegard et al. 2011). The previously performed testing included the physical properties determinations for selected samples (settled and particle densities, water and solids concentrations), the pH, as well as identification of crystalline phases by X-ray diffractometry (XRD) for selected samples. Another objective of the previous characterization and testing campaign was to transfer some sludge composites and individual samples into new storage containers to overcome the embrittlement effect which develops in original glass containers as a result of extended exposure to high radiation fields and which increases probability of sample loss.

K Basin↗

BioWatch Sample Management System (SMS) Field Operator Guide

The BioWatch Sample Management System is software developed by Los Alamos National Laboratory to support the Department of Homeland Security BioWatch program. Field Operators use the software to keep track of samples and to provide information on the sample management process to other users and software programs within BioWatch. The information tracked about a sample includes the date and time the filter media is assembled in a filter holder, deployed to the field, placed in and removed from a collector, and received from the field, and identifies who performs each task. Field Operators can also use the software to prepare and print forms to document the chain-of-custody transfer of the samples. The BioWatch SMS Field Operator Guide provides easy-to-understand procedures for each task a Field Operator performs. This guide gives basic information about using the computer and other equipment, instructions about checking and editing data, and provides reference information, including appendices of error messages and solutions, words used interchangeably, and safety warnings plus a glossary and an index.

99 GENERAL AND MISCELLANEOUS↗

Analytical Results For MOX Colemanite Concrete Samples Received On September 4, 2013

The Mixed Oxide Fuel Fabrication Facility (MFFF) will use colemanite bearing concrete neutron absorber panels credited with attenuating neutron flux in the criticality design analyses and shielding operators from radiation. The Savannah River National Laboratory (SRNL) is tasked with measuring the total density, partial hydrogen density, and partial boron density of the colemanite concrete. SRNL received three samples of colemanite concrete for analysis on September 4, 2013. The average total density of each of the samples measured by the ASTM method C 642, the average partial hydrogen density was measured using method ASTM E 1131, and the average partial boron density of each sample was measured according to ASTM C 1301. The lower limits and measured values for the total density, hydrogen partial density, and boron partial density are presented. For all the samples tested, the total density and the boron partial density met or exceeded the specified limit. None of the samples met the lower limit for hydrogen partial density.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Results for the Independent Sampling and Analysis of Used Oil Drums at the Impact Services Facility in Oak Ridge, Tennessee

The U.S. Department of Energy (DOE) requested that Oak Ridge Associated Universities (ORAU), via the Oak Ridge Institute for Science and Education (ORISE) contract, perform independent sampling and analysis of used oils contained within eight 55 gallon drums stored at the former IMPACT Services facility, located at the East Tennessee Technology Park in Oak Ridge, Tennessee. These drums were originally delivered by LATA Sharp Remediation Services (LSRS) to IMPACT Services on January 11, 2011 as part of the Bldg. K-33 demolition project, and the drums plus contents should have been processed as non-hazardous non-radiological waste by IMPACT Services. LSRS received a certificate of destruction on August 29, 2012 (LSRS 2012a). However, IMPACT Services declared bankruptcy and abandoned the site later in 2012, and eight of the original eleven K-33 drums are currently stored at the facility. The content of these drums is the subject of this investigation. The original drum contents were sampled by LSRS in 2010 and analyzed for gross alpha, gross beta, and polychlorinated biphenyls (PCBs), using both compositing and grab sampling techniques. The objective of this 2013 sample and analysis effort was to duplicate, to the extent possible, the 2010 sampling and analysis event to support final disposition decisions. Part of that decision process includes either verifying or refuting the assertion that oils that are currently stored in drums at the IMPACT Services facility originated from Bldg. K-33 equipment.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Analytical Results For MOX Colemanite Concrete Samples Received On November, 2013

The Mixed Oxide Fuel Fabrication Facility (MFFF) will use colemanite bearing concrete neutron absorber panels credited with attenuating neutron flux in the criticality design analyses and shielding operators from radiation. The Savannah River National Laboratory (SRNL) is tasked with measuring the total density, partial hydrogen density, and partial boron density of the colemanite concrete. SRNL received two samples of colemanite concrete for analysis on November 21, 2013. The average total density of each of the samples measured by the ASTM method C 642, the average partial hydrogen density was measured using method ASTM E 1131, and the average partial boron density of each sample was measured according to ASTM C 1301. For all the samples tested, the total density and the boron partial density met or exceeded the specified limit. None of the samples met the lower limit for hydrogen partial density.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

January 2012 Groundwater Sampling at the Gnome-Coach, New Mexico, Site (Data Validation Package)

Annual sampling was conducted January 18, 2012, to monitor groundwater for potential radionuclide contamination at the Gnome-Coach site in New Mexico. The sampling was performed as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PLN/S04351, continually updated). Well LRL-7 was not sampled per instruction from the lead. A duplicate sample was collected from well USGS-1 and water levels were measured in the monitoring wells onsite.

54 ENVIRONMENTAL SCIENCES↗

January 2011 Groundwater Sampling at the Gnome-Coach, New Mexico, Site (Data Validation Package)

Annual sampling was conducted January 19, 2011, to monitor groundwater for potential radionuclide contamination at the Gnome-Coach site in New Mexico. The sampling was performed as specified in the Sampling and Analysis Plan for U.S. Department of Energy Office of Legacy Management Sites (LMS/PLN/S04351, continually updated). Well LRL-7 was not sampled per instruction from the lead. A duplicate sample was collected from well USGS-1.Water levels were measured in the monitoring wells onsite.

54 ENVIRONMENTAL SCIENCES↗

May 2013 Groundwater and Surface Water Sampling at the Rio Blanco, Colorado, Site (Data Validation Package)

Annual sampling was conducted at the Rio Blanco, Colorado, site for the Long-Term Hydrologic Monitoring Program May 14-16, 2013, to monitor groundwater and surface water for potential radionuclide contamination. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location CER #1 Black Sulphur. Samples were analyzed for gamma-emitting radionuclides by high-resolution gamma spectrometry and for tritium using the conventional and enrichment methods.

54 ENVIRONMENTAL SCIENCES↗

May 2012 Groundwater and Surface Water Sampling at the Rio Blanco, Colorado, Site (Data Validation Package)

Annual sampling was conducted at the Rio Blanco, Colorado, site for the Long-Term Hydrologic Monitoring Program May 9-10, 2012, to monitor groundwater and surface water for potential radionuclide contamination. Sampling and analyses were conducted as specified in Sampling and Analysis Plan for the U.S. Department of Energy Office of Legacy Management Sites (LMS/PRO/S04351, continually updated). A duplicate sample was collected from location Johnson Artesian WL. Samples were analyzed for gamma-emitting radionuclides by high-resolution gamma spectrometry and for tritium using the conventional and enrichment methods. Results of this monitoring at the Rio Blanco site demonstrate that groundwater and surface water outside the site boundaries have not been affected by project-related contaminants.

54 ENVIRONMENTAL SCIENCES↗

Analysis of a Uranium Oxide Sample Interdicted in Slovakia (FSC 12-3-1)

We provide a concise summary of analyses of a natural uranium sample seized in Slovakia in November 2007. Results are presented for compound identification, water content, U assay, trace element abundances, trace organic compounds, isotope compositions for U, Pb, Sr and O, and age determination using the 234 U – 230 Th and 235 U – 231 Pa chronometers. The sample is a mixture of two common uranium compounds - schoepite and uraninite. The uranium isotope composition is indistinguishable from natural; 236 U was not detected. The O, Sr and Pb isotope compositions and trace element abundances are unremarkable. The 234 U – 230 Th chronometer gives an age of 15.5 years relative to the date of analysis, indicating the sample was produced in January 1997. A comparison of the data for this sample with data in the Uranium Sourcing database failed to find a match, indicating the sample was not produced at a facility represented in the database.

07 ISOTOPE AND RADIATION SOURCES↗

Analytical Results for MOX Colemanite Concrete Samples: Received on September 4, 2013

The Mixed Oxide Fuel Fabrication Facility (MFFF) will use colemanite bearing concrete neutron absorber panels credited with attenuating neutron flux in the criticality design analyses and shielding operators from radiation. The Savannah River National Laboratory (SRNL) is tasked with measuring the total density, partial hydrogen density, and partial boron density of the colemanite concrete. SRNL received three samples of colemanite concrete for analysis on September 4, 2013. The average total density of each of the samples measured by the ASTM method C 642, the average partial hydrogen density was measured using method ASTM E 1131, and the average partial boron density of each sample was measured according to ASTM C 1301. The lower limits and measured values for the total density, hydrogen partial density, and boron partial density are presented. For all the samples tested, the total density and the boron partial density met or exceeded the specified limit. None of the samples met the lower limit for hydrogen partial density.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Analytical Results for MOX Colemanite Concrete Samples: Received on November 21, 2013

The Mixed Oxide Fuel Fabrication Facility (MFFF) will use colemanite bearing concrete neutron absorber panels credited with attenuating neutron flux in the criticality design analyses and shielding operators from radiation. The Savannah River National Laboratory (SRNL) is tasked with measuring the total density, partial hydrogen density, and partial boron density of the colemanite concrete. SRNL received two samples of colemanite concrete for analysis on November 21, 2013. The average total density of each of the samples measured by the ASTM method C 642, the average partial hydrogen density was measured using method ASTM E 1131, and the average partial boron density of each sample was measured according to ASTM C 1301. The lower limits and measured values for the total density, hydrogen partial density, and boron partial density are presented. For all the samples tested, the total density and the boron partial density met or exceeded the specified limit. None of the samples met the lower limit for hydrogen partial density.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A New On-the-Fly Sampling Method for Incoherent Inelastic Thermal Neutron Scattering Data in MCNP6

At thermal energies, the scattering of neutrons in a system is complicated by the comparable velocities of the neutron and target, resulting in competing upscattering and downscattering events. The neutron wavelength is also similar in size to the target's interatomic spacing making the scattering process a quantum mechanical problem. Because of the complicated nature of scattering at low energies, the thermal data files in ACE format used in continuous-energy Monte Carlo codes are quite large { on the order of megabytes for a single temperature and material. In this paper, a new storage and sampling method is introduced that is orders of magnitude less in size and is used to sample scattering parameters at any temperature on-the-fly. In addition to the reduction in storage, the need to pre-generate thermal scattering data tables at fine temperatures has been eliminated. This is advantageous for multiphysics simulations which may involve temperatures not known in advance. A new module was written for MCNP6 that bypasses the current S(α,β) table lookup in favor of the new format. The new on-the-fly sampling method was tested for graphite for two benchmark problems at ten temperatures: 1) an eigenvalue test with a fuel compact of uranium oxycarbide fuel homogenized into a graphite matrix, 2) a surface current test with a \broomstick" problem with a monoenergetic point source. The largest eigenvalue difference was 152pcm for T= 1200K. For the temperatures and incident energies chosen for the broomstick problem, the secondary neutron spectrum showed good agreement with the traditional S(α,β) sampling method. These preliminary results show that sampling thermal scattering data on-the-fly is a viable option to eliminate both the storage burden of keeping thermal data at discrete temperatures and the need to know temperatures before simulation runtime.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Results for the Fourth Quarter 2012 Tank 50 WAC Slurry Sample: Chemical and Radionuclide Contaminants

This report details the chemical and radionuclide contaminant results for the characterization of the 2012 Fourth Quarter sampling of Tank 50 for the Saltstone Waste Acceptance Criteria (WAC).1 Information from this characterization will be used by Waste Solidification Engineering (WSE) to support the transfer of low-level aqueous waste from Tank 50 to the Salt Feed Tank in the Saltstone Facility in Z-Area, where the waste will be immobilized. This information is also used to update the Tank 50 Waste Characterization System. The following conclusions are drawn from the analytical results provided in this report: The concentration of the reported chemical and radioactive contaminants were less than their respective WAC Limits and Targets, unless noted in this section. Norpar 13 and Isopar L have higher detection limits 5 compared with the Saltstone WAC 1 . The data provided in this report is based upon the concentrations in the sub-sample, and due to the limited solubility in aqueous solution, may not represent the concentrations of the analytes in Tank 50. Diisooctyl adipate (or diisooctyl hexanedioate) was measured at 1.30E+00 mg/L in one of two replicate measurements conducted on an at-depth sample. a The organic analysis of the at-depth sample was conducted at the request of SRR. 4 This analyte was below the detection limit in the surface sample. The low insoluble solids content increases the measurement uncertainty for insoluble species.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Results of Hg Speciation Testing on DWPF Batch 735 RCT and OGCT Samples

Eurofins Frontier Global Sciences, Inc. in Seattle, WA on behalf of the Savannah River Remediation (SRR) Mercury Task Team tasked the Savannah River National Laboratory (SRNL) with preparing and shipping samples for Hg speciation. The fifth shipment of samples was designated to include Defense Waste Processing Facility (DWPF) samples from Batch 735 including two Recycle Collection Tank (RCT) samples and one Off Gas Condensate Tank (OGCT) sample; both are described fully in Table 1. This work was requested by DWPF in a Technical Assistance Request (TAR).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Draft evaluation of the frequency for gas sampling for the high burnup confirmatory data project

This report fulfills the M3 milestone M3FT-15SN0802041, “Draft Evaluation of the Frequency for Gas Sampling for the High Burn-up Storage Demonstration Project” under Work Package FT-15SN080204, “ST Field Demonstration Support – SNL”. This report provides a technically based gas sampling frequency strategy for the High Burnup (HBU) Confirmatory Data Project. The evaluation of: 1) the types and magnitudes of gases that could be present in the project cask and, 2) the degradation mechanisms that could change gas compositions culminates in an adaptive gas sampling frequency strategy. This adaptive strategy is compared against the sampling frequency that has been developed based on operational considerations. Gas sampling will provide information on the presence of residual water (and byproducts associated with its reactions and decomposition) and breach of cladding, which could inform the decision of when to open the project cask.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Green Ocean Amazon 2014/15 High-Volume Filter Sampling: Atmospheric Particulate Matter of an Amazon Tropical City and its Relationship to Population Health Field Campaign Report

Manaus, the capital of the Brazilian state of Amazonas, is developing very rapidly. Its pollution plume contains aerosols from fossil fuel combustion mainly due to vehicular emission, industrial activity, and a thermal power plant. Soil resuspension is probably a secondary source of atmospheric particles. The plume transports from Manaus to the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Climate Research Facility ARM site at Manacapuru urban pollutants as well as pollutants from pottery factories along the route of the plume. Considering the effects of particulate matter on health, atmospheric particulate matter was evaluated at this site as part of the ARM Facility’s Green Ocean Amazon 2014/15 (GoAmazon 2014/15) field campaign. Aerosol or particulate matter (PM) is typically defined by size, with the smaller particles having more health impact. Total suspended particulate (TSP) are particles smaller than 100 μm; particles smaller than 2.5 μm are called PM2.5. In this work, the PM2.5 levels were obtained from March to December of 2015, totaling 34 samples and TSP levels from October to December of 2015, totaling 17 samples. Sampling was conducted with PM2.5 and TSP high-volume samplers using quartz filters (Figure 1). Filters were stored during 24 hours in a room with temperature (21,1ºC) and humidity (44,3 %) control, in order to do gravimetric analyses by weighing before and after sampling. This procedure followed the recommendations of the Brazilian Association for Technical Standards local norm (NBR 9547:1997). Mass concentrations of particulate matter were obtained from the ratio between the weighted sample and the volume of air collected. Defining a relationship between particulate matter (PM2.5 and TSP) and respiratory diseases of the local population is an important goal of this project, since no information exists on that topic.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗

Report on Status of Shipment of High Fluence Austenitic Steel Samples for Characterization and Stress Corrosion Crack Testing

The goal of the Mechanisms of Irradiation Assisted Stress Corrosion Cracking (IASCC) task in the LWRS Program is to conduct experimental research into understanding how multiple variables influence the crack initiation and crack growth in materials subjected to stress under corrosive conditions. This includes understanding the influences of alloy composition, radiation condition, water chemistry and metallurgical starting condition (i.e., previous cold work or heat treatments and the resulting microstructure) has on the behavior of materials. Testing involves crack initiation and growth testing on irradiated specimens of single-variable alloys in simulated Light Water Reactor (LWR) environments, tensile testing, hardness testing, microstructural and microchemical analysis, and detailed efforts to characterize localized deformation. Combined, these single-variable experiments will provide mechanistic understanding that can be used to identify key operational variables to mitigate or control IASCC, optimize inspection and maintenance schedules to the most susceptible materials/locations, and, in the long-term, design IASCC-resistant materials. In support of this research, efforts are currently underway to arrange shipment of “free” high fluence austenitic alloys available through Électricité de France (EDF) for post irradiation testing at the Oak Ridge National Laboratory (ORNL) and IASCC testing at the University of Michigan. These high fluence materials range in damage values from 45 to 125 displacements per atom (dpa). The samples identified for transport to the United States, which include nine, no-cost, 304, 308 and 316 tensile bars, were relocated from the Research Institute of Atomic Reactors (RIAR) in Dimitrovgrad, Ulyanovsk Oblast, Russia, and received at the Halden Reactor in Halden, Norway, on August 23, 2016. ORNL has been notified that a significant amount of work is required to prepare the samples for further shipment to Oak Ridge, Tennessee. The preliminary work for sample shipment between Halden and Oak Ridge includes fabrication of an inner cask sample container, decontamination and preparation of a Type A container, preparation of new activity calculations, all necessary paperwork, and handling. ORNL will continue to work to track progress of sample preparation and shipment status, and to work toward an agreement that covers material shipping costs between the Halden Reactor and the Oak Ridge National Laboratory.

36 MATERIALS SCIENCE↗