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At least 1,045 records · Page 58
All sourcesNASA NTRSDOE OSTI
NASA NTRS2008

Analytical Model of the Nonlinear Dynamics of Cantilever Tip-Sample Surface Interactions for Various Acoustic-Atomic Force Microscopies

A comprehensive analytical model of the interaction of the cantilever tip of the atomic force microscope (AFM) with the sample surface is developed that accounts for the nonlinearity of the tip-surface interaction force. The interaction is modeled as a nonlinear spring coupled at opposite ends to linear springs representing cantilever and sample surface oscillators. The model leads to a pair of coupled nonlinear differential equations that are solved analytically using a standard iteration procedure. Solutions are obtained for the phase and amplitude signals generated by various acoustic-atomic force microscope (A-AFM) techniques including force modulation microscopy, atomic force acoustic microscopy, ultrasonic force microscopy, heterodyne force microscopy, resonant difference-frequency atomic force ultrasonic microscopy (RDF-AFUM), and the commonly used intermittent contact mode (TappingMode) generally available on AFMs. The solutions are used to obtain a quantitative measure of image contrast resulting from variations in the Young modulus of the sample for the amplitude and phase images generated by the A-AFM techniques. Application of the model to RDF-AFUM and intermittent soft contact phase images of LaRC-cp2 polyimide polymer is discussed. The model predicts variations in the Young modulus of the material of 24 percent from the RDF-AFUM image and 18 percent from the intermittent soft contact image. Both predictions are in good agreement with the literature value of 21 percent obtained from independent, macroscopic measurements of sheet polymer material.

Cantrell, John H., Jr.↗
DOE OSTI2024

High-temperature Raman spectroscopy of K 2 Ca(CO 3 ) 2 bütschliite and Na 2 Ca 2 (CO 3 ) 3 shortite

Raman spectra of Na 2 Ca 2 (CO 3 ) 3 shortite and K 2 Ca(CO 3 ) 2 bütschliite were measured to 715°C and 740°C respectively, under vacuum. The vibrational spectra demonstrate that shortite converts to nyerereite (Na 2 Ca(CO 3 ) 2 ) and calcite at 535°C. This assemblage is stable to ~700°C, where nyerereite begins to decompose. Bütschliite converts to the isochemical phase fairchildite at 570°C, which is stable to 665°C, where it decomposes to an assemblage of K 2 CO 3 and CaO. The variation of anharmonicity between different vibrational modes of each of the low temperature phases is assessed, and these yield insights into inter-carbonate group couplings. In conclusion, both fairchildite and nyerereite exhibit spectral features consistent with extensive disordering.

58 GEOSCIENCES↗
NASA NTRS2016

Combining Photometry from Kepler and TESS to Improve Short-Period Exoplanet Characterization

Planets emit thermal radiation and reflect incident light that they receive from their host stars. As a planet orbits its host star the photometric variations associated with these two effects produce very similar phase curves. If observed through only a single bandpass, this leads to a degeneracy between certain planetary parameters that hinder the precise characterization of such planets. However, observing the same planet through two different bandpasses gives much more information about the planet. Here we develop a Bayesian methodology for combining photometry from both Kepler and the Transiting Exoplanet Survey Satellite. In addition, we demonstrate via simulations that one can disentangle the reflected and thermally emitted light from the atmosphere of a hot-Jupiter as well as more precisely constrain both the geometric albedo and day-side temperature of the planet. This methodology can further be employed using various combinations of photometry from the James Webb Space Telescope, the Characterizing ExOplanet Satellite, or the PLATO mission.

photometric variations↗
DOE OSTI2021

Analysis of Long-Term Quality Control Data for a 137 Cs Dosimetry Calibration Source

Strict quality assurance programs are required for many radiological applications, but these seldom exist for verifying dosimetry calibration sources. After initial characterization of a dosimetry calibration facility, quality control procedures are recommended to ensure the early detection of any changes or malfunctions. These also result in refined knowledge about average dose rate and experimental variations in dose delivery. This paper describes the implementation of a phase I quality control protocol for a 137 Cs dosimetry calibration source and includes an analysis of the resulting data collected over a 24-mo period. During this time, substantial data was collected to establish trial control limits. Air kerma rate measurements were obtained using an ion chamber and were adjusted for decay, corrected for ambient temperature, pressure and humidity, and then analyzed using quality control charts. Three variations of rational subgrouping methods were used in order to find assignable causes of error, and Nelson's Rules were followed to detect any non-random statistical variations. Measurements were subgrouped according to same-day measurements in order to detect positional errors as well as atmospheric correction errors. Additionally, measurements were subgrouped according to analogous experimental setups in order to detect failure in equipment or incorrect settings. Both were analyzed using the X-bar and R chart method. Similarly, individuals and moving ranges charts were used to carefully examine each position in order to observe any situational errors that may occur which include timing, positional, or interference errors. Each method was successful in identifying unique out-of-control data points that occurred during the phase I application of forming control limits. Furthermore, over the 24-mo period, enough data points were deemed in-control to establish reliable trial limits. Future experiments will include the phase II application of gaining more reliable measurements in order to fine-tune the limits, as well as performing a designed experiment, where variables are purposefully changed in order to test the variation of the data.

61 RADIATION PROTECTION AND DOSIMETRY↗
NASA NTRS1989

Influence of solar activity on middle atmosphere associated with phases of equatorial quasi-biennial oscillation

Earlier studies on the influence of solar activity variations within a 11-year solar cycle on temperature changes in the middle atmosphere revealed that while the temperature in the mesosphere showed strong responses to changes in solar activity, the stratosphere remained almost unaffected. Recent studies showed that when the temperature data were grouped into east or west phase of the equatorial quasi-biennial oscillation (QBO) in stratospheric zonal wind, significant relationships of temperature in the lower stratosphere and troposphere could be obtained with 10.7 cm solar radio flux. Positive correlations in high latitude regions and negative correlations in mid-latitude and tropical regions were obtained during winter when the QBO was in its west phase. During the east phase, converse relationships were indicated. These results inspired this study on the response of solar activity in 11-year cycle on the temperature structure of the middle atmosphere in the two phases of equatorial QBO of zonal wind at 50 mb, in tropics, mid-latitude and antarctic regions.

Mohanakumar, K.↗
DOE OSTI2022

A fourth-order phase-field fracture model: Formulation and numerical solution using a continuous/discontinuous Galerkin method

Modeling crack initiation and propagation in brittle materials is of great importance to be able to predict sudden loss of load-carrying capacity and prevent catastrophic failure under severe dynamic loading conditions. Second-order phase-field fracture models have gained wide adoption given their ability to capture the formation of complex fracture patterns, e.g. via crack merging and branching, and their suitability for implementation within the context of the conventional finite element method. Higher-order phase-field models have also been proposed to increase the regularity of the exact solution and thus increase the spatial convergence rate of its numerical approximation. However, they require special numerical techniques to enforce the necessary continuity of the phase field solution. In this paper, we derive a fourth-order phase-field model of fracture in two independent ways; namely, from Hamilton’s principle and from a higher-order micromechanics-based approach. The latter approach is novel, and provides a physical interpretation of the higher-order terms in the model. In addition, we propose a continuous/discontinuous Galerkin (C/DG) method for use in computing the approximate phase-field solution. This method employs Lagrange polynomial shape functions to guarantee -continuity of the solution at inter-element boundaries, and enforces the required regularity with the aid of additional variational and interior penalty terms in the weak form. Finally, the phase-field equation is coupled with the momentum balance equation to model dynamic fracture problems in hyper-elastic materials. Two benchmark problems are presented to compare the numerical behavior of the C/DG method with mixed finite element methods.

42 ENGINEERING↗
DOE OSTI2020

Real-time observations of TRIP-induced ultrahigh strain hardening in a dual-phase CrMnFeCoNi high-entropy alloy

Abstract Strategies involving metastable phases have been the basis of the design of numerous alloys, yet research on metastable high-entropy alloys is still in its infancy. In dual-phase high-entropy alloys, the combination of local chemical environments and loading-induced crystal structure changes suggests a relationship between deformation mechanisms and chemical atomic distribution, which we examine in here in a Cantor-like Cr 20 Mn 6 Fe 34 Co 34 Ni 6 alloy, comprising both face-centered cubic ( fcc ) and hexagonal closed packed ( hcp ) phases. We observe that partial dislocation activities result in stable three-dimensional stacking-fault networks. Additionally, the fraction of the stronger hcp phase progressively increases during plastic deformation by forming at the stacking-fault network boundaries in the fcc phase, serving as the major source of strain hardening. In this context, variations in local chemical composition promote a high density of Lomer-Cottrell locks, which facilitate the construction of the stacking-fault networks to provide nucleation sites for the hcp phase transformation.

36 MATERIALS SCIENCE↗
NASA NTRS2018

Orientation Effects in Two-Phase Microgap Flow

The high power density of emerging electronic devices is driving the transition from remote cooling, which relies onconduction and spreading, to embedded cooling, which extracts dissipated heat on-site. Two-phase microgap coolersemploy the forced flow of dielectric fluids undergoing phase change in a heated channel within or between devices. Such coolers must work reliably in all orientations for a variety of applications (e.g., vehicle-based equipment), as well as in microgravity and high-g for other applications (e.g., spacecraft and aircraft). The lack of acceptable models andcorrelations for orientation- and gravity-independent operation has limited the use of two-phase coolers in suchapplications. Previous research has revealed that gravitational acceleration plays a diminishing role in establishing flow regimes and transport rates as the channel size shrinks, but there is considerable variation among the proposed microscale criteria and limited research on two-phase flows in low aspect ratio microgap channels. Reliable criteria for achieving orientation- and gravity-independent flow boiling would enable emerging systems to exploit this thermal management technique and streamline the technology development process.

orientation↗
NASA NTRS2021

Near-Global Variability of Stratospheric Water Vapor Observed by SAGE III/ISS

The Stratospheric Aerosol and Gas Experiment III instrument on the International Space Station (SAGE III/ISS) has been making high quality solar occultation measurements of stratospheric water vapor since June 2017. Here we evaluate the large-scale geophysical variability of the SAGE III/ISS water vapor measurements for the first 3 years of observations (2017–2020) as part of data validation for retrieval version 5.1 (v5.1). Detailed comparisons of SAGE III/ISS v5.1 with the Aura Microwave Limb Sounder (MLS) version 5 retrievals show overall excellent agreement in terms of seasonal mean structure and large-scale variability. SAGE III/ISS data capture the well-known seasonal variations in water vapor including the vertically propagating “tape recorder” in the tropics and lower stratospheric maxima linked to the NH summer monsoons. The high vertical resolution (∼2 km) measurements from SAGE III/ISS demonstrate contributions of the monsoons to the wet phase of “tape recorder” during the Northern Hemisphere (NH) summer. Interannual variations over the short data record are also consistent between SAGE III/ISS and MLS in the stratosphere between 16 and 30 km. We furthermore evaluate large-scale variations in relative humidity (RH) derived from the high vertical resolution SAGE III/ISS water vapor measurements, highlighting the detailed seasonal behavior and links to thermal structure near the tropical tropopause. Spatial distributions of RH at the cold point tropopause (CPT) show a close link between high RH and the minimum CPT temperature in both the NH winter and summer, consistent with temperature control of water vapor near the tropopause.

water vapor↗
NASA NTRS1987

Mercury - Wavelength and longitude dependence of polarization

The polarization-time variations noted in the present linear polarization observations of the integrated Mercury disk, with filters covering the 0.3-1.0 micron bandpass and between 53-130 deg of phase angle, may be accounted for in terms of longitude dependence through the variation of brightness or other properties over the surface. Kepler's equation for the eccentric anomaly was solved for each observation, and the true anomaly was used to find the subsolar longitude. The difference found in the polarization-albedo relations of Mercury and the moon indicates a difference in surface texture and/or composition.

Gehrels, T.↗
DOE OSTI2022

Validation of seismic velocity models in southern California with full-waveform simulations

SUMMARY Crustal seismic velocity models provide essential information for many applications including earthquake source properties, simulations of ground motion and related derivative products. We present a systematic workflow for assessing the accuracy of velocity models with full-waveform simulations. The framework is applied to four regional seismic velocity models for southern California: CVM-H15.11, CVM-S4.26, CVM-S4.26.M01 that includes a shallow geotechnical layer, and the model of Berg et al. For each model, we perform 3-D viscoelastic wave propagation simulations for 48 virtual seismic noise sources (down to 2 s) and 44 moderate-magnitude earthquakes (down to 2 s generally and 0.5 s for some cases) assuming a minimum shear wave velocity of 200 m s–1. The synthetic waveforms are compared with observations associated with both earthquake records and noise cross-correlation data sets. We measure, at multiple period bands for well-isolated seismic phases, traveltime delays and normalized zero-lag cross-correlation coefficients between the synthetic and observed data. The obtained measurements are summarized using the mean absolute derivation of time delay and the mean correlation coefficient. These two metrics provide reliable statistical representations of model quality with consistent results in all data sets. In addition to assessing the overall (average) performance of different models in the entire study area, we examine spatial variations of the models’ quality. All examined models show good phase and waveform agreements for surface waves at periods longer than 5 s, and discrepancies at shorter periods reflecting small-scale heterogeneities and near-surface structures. The model performing best overall is CVM-S4.26.M01. The largest misfits for both body and surface waves are in basin structures and around large fault zones. Inaccuracies generated in these areas may affect tomography and model simulation results at other regions. The seismic velocity models for southern California can be improved by adding better resolved structural representations of the shallow crust and volumes around the main faults.

58 GEOSCIENCES↗
NASA NTRS1977

Variations in the spatial distribution of 11 Micron radiation from omicron Ceti

The spatial distribution of 11 micron radiation from omicron Ceti was observed at various phases of its light cycle using a stellar interferometer. Changes were seen which can be attributed to variation in the strength of thermal emission from circumstellar dust relative to the stellar continuum at 11 microns. These changes are shown to be correlated with the changes in luminosity of micron Ceti in such a way that dust grain emission at 11 microns was increased more than the continuum during the period of maximum luminosity. The degree of the change in dust grain emission implies that the maximum dust temperature is in the range of 500 K to 700 K during minimum stellar luminosity.

Sutton, E. C.↗
NASA NTRS1990

A model study of the response of mesospheric ozone to short-term solar ultraviolet flux variations

An investigation is conducted in order to determine the relative importance of several modeled processes in controlling the magnitude and phase of the mesospheric ozone response. A detailed one-dimensional modeling study of the mesospheric ozone response to solar UV flux variations is conducted to remove some of the deficiencies in previous studies. This study is also used to examine specifically the importance of solar zenith angle, self-consistent calculation of water vapor abundance, and temperature feedback with a nonlocal thermodynamic equilibrium radiation model. The photochemical model is described, and the assumptions made for the purpose of comparing model results with the observed ozone response obtained from a statistical analysis of Solar Mesosphere Explorer data (Keating et al., 1987) are discussed. The numerical results for the theoretical ozone response are presented. The results of selected time-dependent calculations are considered to illustrate the degree to which a relatively simple model of the mesosphere is able to capture the major characteristics of the observed response.

Summers, M. E.↗
NASA NTRS1980

Time spectral analysis of midlatitude disturbances in the Martian atmosphere

Time-spectral and cross-spectral analyses are used to investigate synoptic pressure variations in the Viking-2 pressure, wind, and temperature data for selected portions of the Mars fall, winter, and spring seasons. Estimates of the phase relationships between the highly coherent pressure, wind, and temperature oscillations are obtained, and found to be very similar to those expected for baroclinic waves and to those obtained from terrestrial surface data. Phase speeds and zonal wavenumbers are inferred by interpreting the pressure and meridional wind variations in terms of eastward-traveling quasi-geostrophic waves.

Barnes, J. R.↗
NASA NTRS2011

Solar UV Variations During the Decline of Cycle 23

Characterization of temporal and spectral variations in solar ultraviolet irradiance over a solar cycle is essential for understanding the forcing of Earth's atmosphere and climate. Satellite measurements of solar UV variability for solar cycles 21, 22, and 23 show consistent solar cycle irradiance changes at key wavelengths (e.g. 205 nm, 250 nm) within instrumental uncertainties. All historical data sets also show the same relative spectral dependence for both short-term (rotational) and long-term (solar cycle) variations. Empirical solar irradiance models also produce long-term solar UV variations that agree well with observational data. Recent UV irradiance data from the Solar Radiation and Climate Experiment (SORCE) Spectral Irradiance Monitor (SIM) and Solar Stellar Irradiance Comparison Experiment (SOLSTICE) instruments covering the declining phase of Cycle 23 present a different picture oflong-term solar variations from previous results. Time series of SIM and SOLSTICE spectral irradiance data between 2003 and 2007 show solar variations that greatly exceed both previous measurements and predicted irradiance changes over this period, and the spectral dependence of the SIM and SOLSTICE variations during these years do not show features expected from solar physics theory. The use of SORCE irradiance variations in atmospheric models yields substantially different middle atmosphere ozone responses in both magnitude and vertical structure. However, short-term solar variability derived from SIM and SOLSTICE UV irradiance data is consistent with concurrent solar UV measurements from other instruments, as well as previous results, suggesting no change in solar physics. Our analysis of short-term solar variability is much less sensitive to residual instrument response changes than the observations of long-term variations. The SORCE long-term UV results can be explained by under-correction of instrument response changes during the first few years of measurements, rather than requiring an unexpected change in the physical behavior of the Sun.

DeLand, Matthew, T.↗
NASA NTRS2018

Orientation Effects in Two-Phase Microgap Flow

The high power density of emerging electronic devices is driving the transition from remote cooling, which relies on con-duction and spreading, to embedded cooling, which extracts dissipated heat on-site. Two-phase microgap coolers employ the forced flow of dielectric fluids undergoing phase change in a heated channel within or between devices. Such coolers must work reliably in all orientations for a variety of applications (e.g., vehicle-based equipment), as well as in microgravity and high-g for other applications (e.g., spacecraft and aircraft). The lack of acceptable models and correlations for orientation- and gravity-independent operation has limited the use of two-phase coolers in such applications. Previous research has revealed that gravita-tional acceleration plays a diminishing role in establishing flow regimes and transport rates as the channel size shrinks, but there is considerable variation among the proposed microscale criteria and limited research on two-phase flows in low aspect ratio mi-crogap channels. Reliable criteria for achieving orientation- and gravity-independent flow boiling would enable emerging sys-tems to exploit this thermal management technique and streamline the technology development process. As a first step toward understanding the effect of gravity on two-phase microgap flow and transport, in the present effort the authors have studied the effect of evaporator orientation and mass flux on near-saturated flow boiling of HFE7100 in a 1.01 mm tall by 13.0 mm wide by 12.7 mm long microgap channel. Orientation-independence, defined as achieving similar critical heat fluxes, heat transfer coefficients, and flow regimes across evaporator orientations, was achieved for mass fluxes of 400 kg/m2-s and greater. The present results are compared to pub-lished criteria for achieving gravity-independence.

orientation↗
NASA NTRS2006

On the Observed Changes in Upper Stratospheric and Mesospheric Temperatures from UARS HALOE

Temperature versus pressure or T(p) time series from the Halogen Occultation Experiment (HALOE) on the Upper Atmosphere Research Satellite (UARS) have been extended and re-analyzed for the period of 1991-2005 and for the upper stratosphere and mesosphere in 10-degree wide latitude zones from 60S to 60N. Even though sampling from a solar occultation experiment is somewhat limited, it is shown to be quite adequate for developing both the seasonal and longer-term variations in T(p). Multiple linear regression (MLR) techniques were used in the re-analyses for the seasonal and the significant interannual, solar cycle (SC-like or decadal-scale), and linear trend terms. A simple SC-like term of 11-yr period was fitted to the time series residuals after accounting for the seasonal and interannual terms. Highly significant SC-like responses were found for both the upper mesosphere and the upper stratosphere. The phases of these SC-like terms were checked for their continuity with latitude and pressure-altitude, and in almost all cases they are directly in-phase with that of standard proxies for the solar flux variations. The analyzed, max minus min, responses at low latitudes are of order 1 K, while at middle latitudes they are as large as 3 K in the upper mesosphere. Highly significant, linear cooling trends were found at middle latitudes of the middle to upper mesosphere (about -2 K/decade), at tropical latitudes of the middle mesosphere (about -1 K/decade), and at 2 hPa (or order -1 K/decade).

Remsberg, Ellis E.↗
DOE OSTI2025

Unveiling the lithium-ion transport mechanism in Li{sub 2}ZrCl{sub 6} Solid-State Electrolyte {ital via} deep learning-accelerated molecular dynamics simulations.

Lithium zirconium chlorides (LZCs) present a promising class of cost-effective solid electrolytes for next-generation all-solid-state batteries. The unique crystal structure of LZCs plays a crucial role in facilitating lithium-ion mobility, which further affects the electrochemical performance. To understand the underlying mechanism governing ion transport, we employed deep learning-accelerated molecular dynamics simulation on Li2ZrCl6 (trigonal alpha- and monoclinic beta-LZC), focusing specifically on the zirconium coordination environment. Our results reveal that disordered alpha-LZC exhibits the highest ionic conductivity, while beta-LZC demonstrates significantly lower conductivity, closely aligning with experimental findings. The study confirms that across all phases, lithium migration proceeds via the site-to-site hopping mechanism, where variations in site residence times critically impact the overall ionic conductivity. In alpha-LZCs, lithium ions prefer to anisotropically diffuse across interlayers as the result of a lower energy barrier, driven primarily by collective diffusion. In contrast, lithium ions in beta-LZC primarily isotropically diffuse within the intralayer, hindered by higher energy barriers and determined by individual diffusion. The variation in ZrCl6 2- octahedral unit softening, induced by the specific layered arrangement of zirconium atoms, emerges as a critical determinant of the energy barriers across the LZC phases. These atomic-scale insights into the transport processes provide valuable guidance for the rational design and optimization of LZCs-based electrolytes, accelerating their practical application in advanced energy storage technologies.

Guo, Hanzeng↗