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All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Time-resolved Rotational Velocities in the Upper Atmosphere of WASP-33 b

While steady empirical progress has been made in understanding the structure and composition of hot-planet atmospheres, direct measurements of velocity signatures, including winds, rotation, and jets, have lagged behind. Quantifying atmospheric dynamics of hot planets is critical for a complete understanding of their atmospheres, and such measurements may even illuminate other planetary properties, such as magnetic field strengths. In this manuscript we present the first detection of the Balmer lines Hα and Hβ in the atmosphere of the ultra-hot Jupiter WASP-33 b. Using atmospheric models that include the effects of atmospheric dynamics, we show that the shape of the average Balmer line transmission spectrum is consistent with rotational velocities in the planet’s thermosphere of v{sub rot}=10.1{sub −1.0}{sup +0.8} km s{sup −1}. We also measure a low-significance day- to nightside velocity shift of −4.6{sub −3.4}{sup +3.4} km s{sup −1} in the transmission spectrum, which is naturally explained by a global wind across the planet’s terminator. In a separate analysis the time-resolved velocity centroids of individual transmission spectra show unambiguous evidence of rotation, with a best-fit velocity of 10.0{sub −2.0}{sup +2.4} km s{sup −1}, consistent with the value of v {sub rot} derived from the shape of the average Balmer line transmission spectrum. Our observations and analysis confirm the power of time-resolved transmission spectra with a high signal-to-noise ratio to measure the velocity structures in exoplanet atmospheres. The high rotational and wind velocities we measure highlight the need for more detailed 3D global climate simulations of the rarefied upper atmospheres of ultra-hot gas giants.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS2005

The Cheshire-cat-like Behavior of 2nu(sub 3) Overtone of Co2 near 2.134 micron: NIR Lab Spectra of Solid CO2 in H2O and CH3OH

Infrared (IR) spectra have demonstrated that solid H2O is very common in the outer Solar System, and solid carbon dioxide (CO2) has been detected on icy satellites, comets, and planetismals throughout the outer Solar System. In such environments, CO2 and H2O must sometimes be mixed at a molecular level, changing their IR absorption features. In fact, the IR spectra of CO2-H2O mixtures are not equivalent to a linear combination of the spectra of the pure materials. Laboratory IR spectra of pure CO2 and H2O have been published but a lack of near-IR spectra of CO2-H2O mixtures has made the interpretation of outer Solar System spectra more difficult. We present near infrared (IR) spectra of CO2 in H2O and in CH3OH compared to that of pure solid CO2 and find significant differences. Peaks not present in either pure H2O or pure CO2 spectra become evident. First, the CO2 (2nu(sub 3)) overtone near 2.134 micron (4685/ cm) that is not seen in pure solid CO2 is prominent in the spectrum of a CO2/H2O = 25 mixture. Second, a 2.74 micron (3650/ cm) dangling OH feature of water (and a potentially related peak at 1.89 micron) appear in the spectra of CO2-H2O ice mixtures, but may not be specific to the presence of CO2. Other CO2 peaks display shifts in position and increased width because of intermolecular interactions with water. Changes in CO2 peak positions and profiles on warming of a CO2/H2O = 5 mixture are consistent with 'segregation' of the ice into nearly pure separate components. Absolute strengths for absorptions of CO2 in solid H2O are estimated. Similar results are observed for CO2 in solid CH3OH. Since the CO2 ( 2nu(sub 3)) overtone near 2.134 micron (4685/ cm) is not present in pure CO2 but prominent in mixtures it may be a good observational indicator of whether solid CO2 is a pure material or intimately mixed with other molecules. Significant changes in the near IR spectrum of solid CO2 in the presence of H2O and CH3OH means that the abundance of solid CO2 in the outer Solar System may have been under-estimated in those environments where solid CO2 and H2O or CH3OH are mixed.

Bernstein, Max↗
DOE OSTI2020

Photoabsorption, photoionization, and Auger processes at the carbon K edge in C H 3 I

The dynamics of photoabsorption, photoionization, and the associated Auger decay have been investigated at the carbon K edge in methyl iodide (CH 3 I) using linearly polarized synchrotron radiation. Ion yield measurements were used to investigate transitions in the pre-edge region due to excitations into either unoccupied valence or Rydberg states. The assignment of these transitions was achieved through comparison with theoretical x-ray absorption spectra calculated using time-dependent density functional theory, within the Tamm-Dancoff approximation. Several of the Rydberg states belonging to series converging onto the C1s ionization limit exhibit significant vibrational structure that is also interpreted using theoretical calculations. The C1s in CH 3 I photoelectron spectrum was measured, and the observed vibrational structure was assigned with the aid of theoretical predictions. Polarization dependent, resonantly excited, valence shell photoelectron spectra were recorded at photon energies coinciding with the C1s → σ*, C1s → 6sa1 and C1s → 6pe transitions in CH 3 I , thereby allowing photoelectron angular distributions to be determined. The nonresonantly excited C(KVV) Auger electron spectrum was measured and some of the features observed at high kinetic energies were attributed to transitions into valence orbitals possessing significant iodine character. The contributions of participator and spectator Auger decay to the resonantly excited photoelectron spectra have been assessed. The influence of participator decay appears minor whereas spectator decay results in the enhanced population of satellite states.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2021

The Role of Hydrophobic Nodes in the Dynamics of Class A β-Lactamases

Class A β-lactamases are known for being able to rapidly gain broad spectrum catalytic efficiency against most β-lactamase inhibitor combinations as a result of elusively minor point mutations. The evolution in class A β-lactamases occurs through optimisation of their dynamic phenotypes at different timescales. At long-timescales, certain conformations are more catalytically permissive than others while at the short timescales, fine-grained optimisation of free energy barriers can improve efficiency in ligand processing by the active site. Free energy barriers, which define all coordinated movements, depend on the flexibility of the secondary structural elements. The most highly conserved residues in class A β-lactamases are hydrophobic nodes that stabilize the core. To assess how the stable hydrophobic core is linked to the structural dynamics of the active site, we carried out adaptively sampled molecular dynamics (MD) simulations in four representative class A β-lactamases (KPC-2, SME-1, TEM-1, and SHV-1). Using Markov State Models (MSM) and unsupervised deep learning, we show that the dynamics of the hydrophobic nodes is used as a metastable relay of kinetic information within the core and is coupled with the catalytically permissive conformation of the active site environment. Finally, our results collectively demonstrate that the class A enzymes described here, share several important dynamic similarities and the hydrophobic nodes comprise of an informative set of dynamic variables in representative class A β-lactamases.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1999

The ISO View of Star Forming Galaxies

ISO studies of normal galaxies in the local Universe have revealed basic new properties whose significant implications for the star formation process and cosmology are only starting to be understood. This review will touch on the general results of a statistical nature, and provide a quick summary of the profusion of exciting results on individual objects. In the mid-infrared, PHT-S has established that the spectra of star forming galaxies between 6 and-13microns are dominated by the Aromatic Features in Emission (AFE), and show little variation as a function of the heating intensity. The Carriers of the AFE (CAFE) are thus a universal component of dust with standard properties, and contribute between 10 and 25% of the total dust luminosity. In addition to AFE, the spectra show a low-level continuum detectable at wavelengths longer than 3.5microns whose origin is still under investigation. The mid-infrared colors formed as the ratio of flux densities in the 6.75micron and the 15micron bands of ISO-CAM remain essentially constant and near unity for quiescent and mildly active galaxies. As dust heating increases further, the 15micron flux increases steeply compared to 6.75microns, indicating that dust heated to 100K<T<200K becomes a significant component. Such hot dust is presumably located within or just outside HII regions. At the other end of the spectrum, photometry at 120-200microns using ISO-PHOT is starting to constrain the distribution of dust temperatures at the low end of the temperature scale. From LWS data, the far-infrared fine-structure lines of [CII] and [OI], which provide most of the cooling for warm atomic gas, show variations that have remained controversial in their interpretation. In particular, as the galaxy become more active in star formation, its [CII] flux weakens relative to total dust emission while the [OI] does not. This behavior has attracted much interest because it extrapolates to the most active galaxies, making them weaker in [CII] than previously expected. Several explanations for the effect have been advanced, and will be discussed in this review. Spectroscopy with SWS has measured molecular hydrogen in galaxies, providing a powerful handle on the warm molecular gas content. SWS and CAM-CVF studies targeting ionic fine-structure lines have demonstrated their value as diagnostics of the radiation field.

Helou, George↗
DOE OSTI2020

Tunable Dopants with Intrinsic Counterion Separation Reveal the Effects of Electron Affinity on Dopant Intercalation and Free Carrier Production in Sequentially Doped Conjugated Polymer Films

Carrier mobility in doped conjugated polymers is limited by Coulomb interactions with dopant counterions. This complicates studying the effect of the dopant’s oxidation potential on carrier generation because different dopants have different Coulomb interactions with polarons on the polymer backbone. In this work, dodecaborane (DDB)-based dopants are used, which electrostatically shield counterions from carriers and have tunable redox potentials at constant size and shape. DDB dopants produce mobile carriers due to spatial separation of the counterion, and those with greater energetic offsets produce more carriers. Neutron reflectometry indicates that dopant infiltration into conjugated polymer films is redox-potential-driven. Remarkably, X-ray scattering shows that despite their large 2-nm size, DDBs intercalate into the crystalline polymer lamellae like small molecules, indicating that this is the preferred location for dopants of any size. These findings elucidate why doping conjugated polymers usually produces integer, rather than partial charge transfer: dopant counterions effectively intercalate into the lamellae, far from the polarons on the polymer backbone. Finally, it is shown that the IR spectrum provides a simple way to determine polaron mobility. Overall, higher oxidation potentials lead to higher doping efficiencies, with values reaching 100% for driving forces sufficient to dope poorly crystalline regions of the film.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Pulse shaping in strong-field ionization: Theory and experiments

Intense ultrafast pulses cause dissociative ionization and shaping the pulses may allow control of both electronic and nuclear dynamics that determine ion yields. We report on a combined experimental and theoretical effort to determine how shaped laser pulses affect tunnel ionization, the process that precedes many strong-field phenomena. We carried out experiments on Ar, N 2 , H 2 O, and O 2 using a phase-step function of amplitude 3/4π that is scanned across the spectrum of the pulse. In addition, we changed the amount of chirp in the pulses. Semiclassical as well as fully quantum mechanical time-dependent Schrödinger equation calculations are found to be in excellent agreement with experimental results. We find that precise knowledge of the field parameters in the time and frequency domains is essential to afford reproducible results and quantitative theory and experiment comparisons.

74 ATOMIC AND MOLECULAR PHYSICS↗
NASA NTRS1989

A study of electron impact excitation of NO. I - The vacuum ultraviolet from 40 to 170 nm. II - The middle ultraviolet from 170 to 270 nm

The electron impact induced fluorescence spectrum of NO at 200 eV was measured for the vacuum UV range (40-170 nm) and the mid-UV range (170-270 nm). The absolute electron impact excitation cross sections are studied by calibrating to the Ly-alpha cross section of H2. The cross section of the N I 120-nm transition by dissociative excitation is found to be 1.73 + or - 0.38 X 10 to the -18th sq cm. Measurements of the cross sections of other features in the vacuum UV and mid-UV are presented. A band model of the far-UV (120-170 nm) is developed. Also, it is found that great care must be taken if NO is the target for relative calibration in the Mid-UV using the molecular branching ratio techniques.

Ajello, J. M.↗
NASA NTRS2013

ERRATUM: FERMI Large Area Telescope Study of Cosmic-Rays and the Interstellar Medium in Nearby Molecular Clouds

In the published version of the paper, errors were made in calculating the exposure time due to an analysis mistake. While they do not affect gas emissivities of the R CrA and Cepheus & Polaris flare regions significantly (the differences are within the systematic uncertainty), that of the Chamaeleon region is increased by approx.20%. Although we claimed a difference of ∼50% in gas emissivity among these molecular cloud regions in the original paper, it is decreased to ∼30% (comparable to the sum of the statistical and systematic uncertainties) in the revised analysis. Therefore, our conclusion of the original paper, that a small variation (approx. 20%) of the CR density in the solar neighborhood exists, is not supported by the data if we take these uncertainties into account. On the other hand, the obtained XCO and XAv values, and the masses of gas calculated from them are not changed significantly (the differences are within the statistical errors). Errors and corrections in the original paper are summarized below. 1. In the Abstract (lines 5-6) and Section 3 (lines 4-5 in the 3rd paragraph) in the original paper, the gamma -ray emissivity above 250 MeV for the Chamaeleon region should be (7.2 +/- 0.1stat +/- 1.0sys) × 10(exp −27) photons/s/sr/H-atom, not (5.9 +/-0.1stat +0.9−1.0sys) × 10(exp −27) photons/s/sr/H-atom. 2. In the Abstract (lines 8-10), "Whereas the energy dependences of the emissivities agree well with that predicted from direct CR observations at the Earth, the measured emissivities from 250 MeV to 10 GeV indicate a variation of the CR density by approx.20% in the neighborhood of the solar system, even if we consider the systematic uncertainties." should be changed to "The energy dependences of the emissivities agree well with that predicted from direct CR observations at the Earth. Although the measured emissivities from 250 MeV to 10 GeV differ by approx.30% among these molecular cloud regions, the difference is not significant if we take the systematic uncertainty into account." 3. Table 1 and Figure 13, which show gas emissivities and spectra for the Chamaeleon region in the original paper, should be changed to the Table 1 and Figure 1 as shown below. 4. Figure 16, which compares Hi gas emissivities among several regions in the original paper, should be changed to Figure 2 as shown below. 5. The text from the line 13 to the last one in the first paragraph of Section 4.1, "The spectral shapes for the three regions..., indicating a difference of the CR density between the Chamaeleon and the others as shown in Figure 16." should be changed to the paragraph that follows. "The shaded area of each spectrum indicates the systematic uncertainty as described in Section 3. We note that the systematic uncertainty of the LAT effective area (5% at 100 MeV and 20% at 10 GeV; Rando et al. 2009) does not affect the relative value of emissivities. The effect of unresolved point sources is small; we have verified that the obtained emissivities are almost unaffected by decreasing the threshold for point sources from TS = 100 to TS = 50. We also confirmed that the residual excess of photons around (l = 280deg to 288deg, b = −20deg to −12deg; see the bottom panel of Figure 8) in the Chamaeleon region does not affect the local Hi emissivity very much. Thus the total systematic uncertainty is reasonably expressed by the shaded area shown in Fig. 1.

emissivities↗
NASA NTRS1984

Wavenumber dependent investigation of the terrestrial infrared radiation budget with two versions of the LOWTRAN5 band model

Two versions of the LOWTRAN5 radiance code are used in a study of the earth's clear sky infrared radiation budget in the interval 30 per cm (333.3 microns) to 3530 per cm (2.8 microns). One version uses 5 per cm resolution and temperature dependent molecular absorption coefficients, and the second uses 20 per cm resolution and temperature independent molecular absorption coefficients. Both versions compare well with Nimbus 3 IRIS spectra, with some discrepancies at particular wavenumber intervals. Up and downgoing fluxes, calculated as functions of latitude, are displayed for wavenumbers at which the principle absorbers are active. Most of the variation of the fluxes with latitude is found in the higher wavenumber intervals for both clear and cloudy skies. The main features of the wavenumber integrated cooling rates are explained with reference to calculations in more restricted wavenumber intervals. A tropical lower tropospheric cooling maximum is produced by water vapor continuum effects in the 760-1240 per cm window. A secondary upper tropospheric cooling maximum, with wide meridional extent, is produced by water vapor rotational lines between 30-430 per cm. Water vapor lines throughout the terrestrial infrared spectrum prevent the upflux maximum from coinciding with the surface temperature maximum.

Charlock, T. P.↗
NASA NTRS1994

Synthesized spectra of turbulent clouds

A comparison has been made of the velocity structure of non-star-forming dense molecular clouds and the output of a 512(exp 3) hydrodynamic code for compressible gas displaying features of turbulence. A remarkable similarity exists between the interstellar line profiles and the velocity profiles found by integrating, with an optically thin assumption, through subsections of the simulation. This similarity is in terms of both the structure of individual spectra, showing skewness, multiple peaks, and wings, and also the variations of the spectra from point to point. It is possible to see the origin of the various velocity substructures and how they correlate with regions of high density and velocity divergence, or regions of high vorticity, by deprojecting individual spectra of the simulation. It is found that the interstellar medium spectra are best represented by the epoch of the simulation in which the energy spectrum is essentially Kolmogorov-like and initially developed shocks have been largely converted into vorticity structures. Further, it is found that the vorticity peaks ascribed to intermittency contribute to the non-Gaussian features and wings of the line profile, but at an intensity level that is weak compared to the contribution of the bulk of the flow.

Falgarone, E.↗
NASA NTRS2013

A New Nearby Pulsar Wind Nebula Overlapping the RX J0852.0-4622 Supernova Remnant

Context. Energetic pulsars can be embedded in a nebula of relativistic leptons which is powered by the dissipation of the rotational energy of the pulsar. The object PSR J0855􀀀4644 is an energetic and fast-spinning pulsar (E' = 1.1 x 10(exp 36) erg/s, P=65 ms) discovered near the South-East rim of the supernova remnant (SNR) RXJ0852.0-4622 (aka Vela Jr) by the Parkes multibeam survey. The position of the pulsar is in spatial coincidence with an enhancement in X-rays and TeV gamma-rays, which could be due to its putative pulsar wind nebula (PWN). Aims. The purpose of this study is to search for di use non-thermal X-ray emission around PSR J0855-4644 to test for the presence of a PWN and to estimate the distance to the pulsar. Methods. An X-ray observation was carried out with the XMM-Newton satellite to constrain the properties of the pulsar and its nebula. The absorption column density derived in X-rays from the pulsar and from different regions of the rim of the SNR was compared with the absorption derived from the atomic (HI) and molecular ((12)CO) gas distribution along the corresponding lines of sight to estimate the distance to the pulsar and to the SNR. Results. The observation has revealed the X-ray counterpart of the pulsar together with surrounding extended emission thus confirming the existence of a PWN. The comparison of column densities provided an upper limit to the distance of the pulsar PSR J0855-4644 and the SNR RX J0852.0-4622 (d less than or equal to 900 pc). Although both objects are at compatible distances, we rule out that the pulsar and the SNR are associated. With this revised distance, PSR J0855-4644 is the second most energetic pulsar, after the Vela pulsar, within a radius of 1 kpc and could therefore contribute to the local cosmic-ray e-/e+ spectrum.

overlapping↗
DOE OSTI2021

Gaia EDR3 Reveals the Substructure and Complicated Star Formation History of the Greater Taurus-Auriga Star-forming Complex

The Taurus-Auriga complex is the prototypical low-mass star-forming region, and provides a unique testbed of the star formation process, which left observable imprints on the spatial, kinematic, and temporal structure of its stellar population. Taurus’s rich observational history has uncovered peculiarities that suggest a complicated star-forming event, such as members at large distances from the molecular clouds and evidence of an age spread. With Gaia, an in-depth study of the Taurus census is possible, to confirm membership, identify substructure, and reconstruct its star formation history. We have compiled an expansive census of the greater Taurus region, identifying spatial subgroups and confirming that Taurus is substructured across stellar density. There are two populations of subgroups: clustered groups near the clouds and sparse groups spread throughout the region. The sparse groups comprise Taurus’s distributed population, which is on average older than the population near the clouds, and hosts subpopulations up to 15 Myr old. The ages of the clustered groups increase with distance, suggesting that the current star formation was triggered from behind. Still, the region is kinematically coherent, and its velocity structure reflects an initial turbulent spectrum similar to Larson’s Law that has been modified by dynamical relaxation. Overall, Taurus has a complicated star formation history, with at least two epochs of star formation featuring both clustered and distributed modes. Given the correlations between age and spatial distribution, Taurus might be part of a galaxy-scale star-forming event that can only begin to be understood in the Gaia era.

47 OTHER INSTRUMENTATION↗
NASA NTRS1994

Atmospheric effects on the risetime and waveshape of sonic booms

Accurate prediction of human response to sonic booms from proposed HSCT aircraft depends on a knowledge of the waveshape and risetime of the boom at the ground. In previous work, we have developed a numerical technique to predict the combined effects of molecular absorption and finite wave distortion on the sonic boom as it propagates from the aircraft to the top of the turbulent boundary layer. We have more recently developed a scattering center based model to calculate the effects of turbulence on the sonic boom waveform as it propagates through this boundary layer. Calculations have been performed using single scales of turbulence and compared to measurements at Edwards AFB in the late 1960's. A model of the atmosphere involving two scales each for convective and mechanical turbulence has been developed and fit to meteorological data collected during JAPE 2. Scattering calculations employing this model underpredict the number of unperturbed waveforms. In order to develop a more realistic model of the atmosphere, the JAPE 2 meteorological data has been fit to a von Karman spectrum. Results of scattering using this multi-scale model will be presented. The combination of finite wave effects with turbulent scattering predictions includes the principal effects of the atmosphere on the sonic boom from the HSCT.

Raspet, Richard↗
DOE OSTI2023

Lattice vibrations and energy landscape of the isoelectronic semiconductor series CuBr, ZnSe, GaAs, and Ge: The special case of CuBr and its $\mathcal{d}$-level chemistry

Here we have examined the lattice vibrations and the energy landscape of the isoelectronic diamond and zincblende semiconductor series CuBr, ZnSe, GaAs, and Ge. Vibrations are found to be an increasing function of ionicity, with the cation sublattice always vibrating more strongly than the anion sublattice. These findings are consistent with density functional theory (DFT) calculations of the energy landscape and temperature-dependent molecular dynamics simulations of the atomic-position fluctuations. For CuBr, inclusion of the Cu 3d Hubbard U term is found necessary to stabilize the zincblende structure and to bring its vibrational amplitudes into agreement with experiment. In addition, vibrations are found to strongly affect the CuBr near-edge x-ray absorption fine structure that we have successfully modeled by including displacements in our theoretical Bethe-Salpeter equation calculations. Reverse Monte Carlo structural refinements using large atomic configurations to simultaneously fit x-ray absorption and x-ray total-scattering data support these conclusions, and they reveal strong Cu-Br first-neighbor correlations and asymmetric distributions of interatomic distances in the temperature ranges of both negative and positive thermal expansion. Delineation of the CuBr valence band photoelectron spectrum into its Cu 3d and Br 4p states uniquely reveals their covalent mixing and further supports the DFT results.

36 MATERIALS SCIENCE↗
NASA NTRS2000

Massive Star Formation in NGC4038/4039: HII Regions and Supernova Remnants in "The Antennae"

The nearest merger, NGC4038/4039 ("The Antennae, Arp244), is undergoing a starburst apparently triggered and driven by the ongoing interaction. The system provides an excellent laboratory to study star formation processes because well-studied and nearby (21 Mpc assumed here). Models of the interaction suggest that the interaction's first periapse occurred 200 Myr ago, and that final coalescence will occur in another 100 Myr. Blue and H alpha images show a continuous loop of bright knots around the NGC4038 (northern) nucleus, continuing down through the NGC4039 (southern) nucleus. Recent HST V and I images resolve the star-forming knots into several thousand blue compact clusters, with ages 5Myr for the youngest clusters. Far Ultraviolet (lambda 1500A) observations directly detect O and B stars in regions of low extinction; the total mass of young stars so observed is approximately 8 x 10 (exp 5) solar mass. FIR observations imply a star formation rate of approximately 5 M (sub 0) dot yr (sup -1) or greater. We used the VLA at 6 and 4 cm to obtain high resolution radio images of the star-formation regions in NGC4038/4038. We used high resolution imaging to identify compact radio emitting regions and spectral indices of the compact regions to differentiate between thermal sources such as HII regions (flat spectra) and supernova, remnants (steep spectra). We found that compact radio sources produce approximately 12% and/sim 25 strongest radio emission occurs between the galaxies, at an optically unremarkable location near but not coincident with an extremely red cluster. The radio peak is at a location of intense star formation (as detected in the mid-IR, reference?) and of dense molecular gas. We identify 115 individual compact 6cm radio sources and 63 individual 4 cm sources in the system, to a limiting luminosity of approximately 2 x 10 (exp 1) 8 W Hz (sup -1) (or /sim4x the luminosity of Cas A). Of the strongest sources, for which the h flux densities are large enough to measure spectral indices with reasonable errors, we find that one third have nominally flat radio spectra (presumeable dominated by thermal emission from HII regions) and two thirds have nominally steep spectra (presumeably dominated by synchrotron emission from supernova, remnants). For the thermal sources, we derive typical masses of 10 (exp 4) to 10 (exp 5) solar mass in massive young stars and ionized gas masses of 10 (exp 3) - 10 (exp 4) solar mass. From the steep-spectrum sources, we derive a total system supernova rate of 0.2-0.3 yr (sup -1), about an order of magnitude larger than that expected from the currently observed O-star population. Taken together, these suggest that that a large number of O stars may have formed in the system in a short-lived burst, less than 10 (exp 6) yr in duration and about 3-4 Myr ago.

Neff, S. G.↗
DOE OSTI2022

Stochastic exciton-scattering theory of optical line shapes: Renormalized many-body contributions

Spectral line shapes provide a window into the local environment coupled to a quantum transition in the condensed phase. In this paper, we build upon a stochastic model to account for non-stationary background processes produced by broad-band pulsed laser stimulation, as distinguished from those for stationary phonon bath. In particular, we consider the contribution of pair-fluctuations arising from the full bosonic many-body Hamiltonian within a mean-field approximation, treating the coupling to the system as a stochastic noise term. Herein, using the Itô transformation, we consider two limiting cases for our model, which lead to a connection between the observed spectral fluctuations and the spectral density of the environment. In the first case, we consider a Brownian environment and show that this produces spectral dynamics that relax to form dressed excitonic states and recover an Anderson–Kubo-like form for the spectral correlations. In the second case, we assume that the spectrum is Anderson–Kubo like and invert to determine the corresponding background. Using the Jensen inequality, we obtain an upper limit for the spectral density for the background. The results presented here provide the technical tools for applying the stochastic model to a broad range of problems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗