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At least 1,045 records · Page 58
All sourcesNASA NTRSDOE OSTI
NASA NTRS1995

Hot shocked gas along the jets of NGC 4258 (M106)

The ROSAT High Resolution Interferometer (HRI) and Position Sensitive Proportional Counter (PSPC) detectors have been used to study the soft X-ray emission of the nearby SABbc galaxy NGC 4258 (M106). The helically twisted, nuclear jets, previously detected in radio continuum and visual emission-line studies, are found to dominate the X-ray images. After correcting pointing errors of up to +/- 7 sec in our HRI observation, we find that the southeast jet is spatially unresolved transversely along much of its 2.5 min (5 kpc) length. The northwest jet is more diffuse, and the extensive radio 'plateaus' also emit X-rays. The energy spectrum of the jets from the PSPC exposure is noisy but is best fitted as a Raymond-Smith plasma with kT = 0.3 keV, log N(sub H) approximately = 20.0/sq cm, and luminosity 1.6 x 10(exp 40) ergs/s between 0.1 and 2.4 keV. Gas at this temperature can arise from planar shocks of 500 km/s and may have been entrained as the jets scrape along the molecular clous that are known to be adjacent to the jets. The range of radial velocities from our published visual emission-line spectra of the jet are consistent with such a shock speed. We estimate that the mass of hot gas in the jets is 6 x 10(exp 4) (1/cc/n(sub e)) solar mass, with n(sub e) the average electron density. The inferred pressure of hot gas in the southeast jet may be similar to the radio equipartition pressure and to the ambient pressure of the interstellar medium (ISM). The X-ray spectral fit is poor above 0.7 keV and requires an additional hard component that peaks near the nucleus.

Cecil, G.↗
NASA NTRS1995

Large Enhancements in the O/N2 Ratio in the Evening Sector of the Winter Hemisphere During Geomagnetic Storms

In this paper, we have looked for enhancements of the O/N2 ratio in data measured by the Dynamics Explorer 2 (DE 2) satellite in the middle latitudes of the winter hemisphere, based on a prediction that was made by the National Center for Atmospheric Research thermosphere/tonosphere general circulation model (NCAR-TIGCM) that such increases occur. The NCAR-TIGCM predicts that these enhancements should be seen throughout the low latitude region and in many middle latitude locations, but that the enhancements in O/N2 are particularly strong in the middle-latitude, evening-to-midnight sector of the winter hemisphere. When this prediction was used to look for these effects in DE 2 NACS (neutral atmosphere composition spectrometer) data, large enhancements in the O/N2 ratio (approx. 50 to 90%) were seen. These enhancements were observed during the main phase of a storm that occurred on November 24, 1982, and were seen in the same region of the winter hemisphere predicted by the NCAR-TIGCM. They are partially the result of the depletion of N2 and, as electron loss is dependent on dissociative recombination at F(sub 2) altitudes, they have implications for electron densities in this area. Parcel trajectories, which have been followed through the NCAR-TIGCM history file for this event, show that large O/N2 enhancements occur in this limited region in the winter hemisphere for two reasons. First, these parcels of air are decelerated by the antisunward edge of the ion convection pattern; individual parcels converge and subsidence occurs. Thus molecular-nitrogen-poor air is brought from higher to lower heights. Because neutral parcels that are found a little poleward of the equatorial edge of the eveningside convection pattern are swept inward toward the center of the auroral oval, the enhancements occur only in a very limited range of latitudes. Second, nitrogen-poor air is transported from regions close to the magnetic pole in the winter hemisphere. During geomagnetic storms, enhanced meridional winds are driven by the increased pressure-gradient force that is associated with intensified Joule heating in the auroral oval. These pressure-driven winds decrease rapidly on the dayside beyond the auroral oval where the parcels originate, limiting the region into which the parcels can be transported. Thus these two processes drive values of O/N2 in a limited region of the winter hemisphere, and reinforce only in the evening sector, causing large changes in this region.

Burns, A. G.↗
NASA NTRS2005

Solid State Digital Propulsion "Cluster Thrusters" For Small Satellites Using High Performance Electrically Controlled Extinguishable Solid Propellants (ECESP)

Electrically controlled extinguishable solid propellants (ESCSP) are capable of multiple ignitions, extinguishments and throttle control by the application of electrical power. Both core and end burning no moving parts ECESP grains/motors to three inches in diameter have now been tested. Ongoing research has led to a newer family of even higher performance ECESP providing up to 10% higher performance, manufacturing ease, and significantly higher electrical conduction. The high conductivity was not found to be desirable for larger motors; however it is ideal for downward scaling to micro and pico- propulsion applications with a web thickness of less than 0.125 inch/ diameter. As a solid solution propellant, this ECESP is molecularly uniform, having no granular structure. Because of this homogeneity and workable viscosity it can be directly cast into thin layers or vacuum cast into complex geometries. Both coaxial and grain stacks have been demonstrated. Combining individual propellant coaxial grains and/or grain stacks together form three-dimensional arrays yield modular cluster thrusters. Adoption of fabless manufacturing methods and standards from the electronics industry will provide custom, highly reproducible micro-propulsion arrays and clusters at low costs. These stack and cluster thruster designs provide a small footprint saving spacecraft surface area for solar panels and/or experiments. The simplicity of these thrusters will enable their broad use on micro-pico satellites for primary propulsion, ACS and formation flying applications. Larger spacecraft may find uses for ECESP thrusters on extended booms, on-orbit refueling, pneumatic actuators, and gas generators.

Sawka, Wayne N.↗
NASA NTRS2012

IDPs and Stardust

Interplanetary dust particles (IDPs) collected in the Earth s stratosphere and NASA Stardust mission samples constitute direct samples of diverse cometary bodies. These materials are among the least altered remnants of the original building blocks of the Solar System. Both cometary materials and primitive meteorites contain a broad diversity of organic compounds that appear to have formed in a range of environments, including the presolar cold molecular cloud, the solar nebula, asteroids and comet nuclei. Isotopic anomalies in H, C, and N are commonly observed in meteoritic organic matter, reflecting chemical processes at extremely low temperatures. These isotopic anomalies are also very heterogeneous on micrometer and even smaller spatial scales, suggesting that some presolar organic grains have survived the formation of the Solar System. Most recently, coordinated transmission electron microscopy and isotopic imaging studies have shown that isotopically anomalous organic globules having rounded and often hollow structures are abundant and widespread amongst the most primitive components of meteoritic materials. These studies suggest that such organic grains were among the most important primary building blocks of the Solar System.

Messenger, Scott R.↗
NASA NTRS2016

Modeling an Iodine Hall Thruster Plume in the Iodine Satellite (ISAT)

An iodine-operated 200-W Hall thruster plume has been simulated using a hybrid-PIC model to predict the spacecraft surface-plume interaction for spacecraft integration purposes. For validation of the model, the plasma potential, electron temperature, ion current flux, and ion number density of xenon propellant were compared with available measurement data at the nominal operating condition. To simulate iodine plasma, various collision cross sections were found and used in the model. While time-varying atomic iodine species (i.e., I, I+, I2+) information is provided by HP Hall simulation at the discharge channel exit, the molecular iodine species (i.e., I2, I2+) are introduced as Maxwellian particles at the channel exit. Simulation results show that xenon and iodine plasma plumes appear to be very similar under the assumptions of the model. Assuming a sticking coefficient of unity, iodine deposition rate is estimated.

Iodine↗
NASA NTRSDate not supplied

Characterization Of Early Solar System Aqueous Fluids

The most direct and convincing evidence for the presence of water and organic molecules on protoplanetary bodies is provided by fluid inclusions trapped in secondary minerals. Our research has demonstrated that early solar system fluids have survived as fluid inclusions in a few astromaterials that escaped significant shock, terrestrial alteration, and invasive sample handling. Our long-term goal is to measure bulk molecular and isotopic composition of individual fluid inclusions in meteorites and samples collected directly from asteroids to provide ground truth regarding the nature and evolution of aqueous fluids in the early solar system. Our current protocol is to locate candidate fluid inclusions using X-Ray Computed Tomography, and then make compositional measurements of individual fluid inclusions by coordinated Raman spectrometry, Transmission Electron Microscopy and, most recently, Time of Flight – Secondary Ion Mass Spectrometry.

Michael Zolensky↗
NASA NTRS1985

Photoionization of sodium atoms and electron scattering from ionized sodium

The polarized-orbital method of Temkin (1957) is applied using polarized orbitals determined from Sternheimer's equation to compute the photoionization cross sections of Na atoms from threshold to about 60 eV. The approximations involved in the analysis are explained in detail; the explicit forms of the integrals and matrix expressions are given in appendices; and the results are presented in tables and graphs. Good agreement is found with the results of Chang and Kelly (1975), and the possibility that small amounts of molecular vapor in Na-photoionization experiments are responsible for the discrepancies between calculated and measured cross sections is considered.

Dasgupta, A.↗
NASA NTRS1975

Fast metastable fragments produced by dissociative excitation of carbonyl sulfide

Dissociative excitation of OCS by electron impact has been studied using the method of translational spectroscopy. Time-of-flight distributions and excitation functions of the fast metastable fragments have been measured. The results are compared with similar measurements on CO2 and show that a variety of metastable fragments including CO(a 3Pi), S(5S), O(5S) as well as long-lived high-lying atomic and molecular Rydberg fragments can contribute to dissociation.

Van Brunt, R. J.↗
NASA NTRS1978

Artificially created holes in the ionosphere

The artificial creation of ionospheric holes by the release of highly reactive molecules into the F region is investigated. Through ion-atom interchange or charge transfer reactions, H2 or H2O reacts with O(+) to form OH(+) or H2O(+), respectively, which subsequently dissociatively recombines with electrons at a very rapid rate. The diffusion of H2 is also modified by chemical loss to the ambient atomic oxygen atmosphere. The limited spatial and temporal extent of the hole-making process allows several approximations to be made which permit three-dimensional analytic solutions of the continuity equations for the released particles, the O(+) and e(-) densities, and the intermediary molecular ions. A versatile formalism is developed whereby the hole-making capability of virtually any spatial-temporal configuration of released particles can be determined by convolving a set of destruction operators which can be viewed as Green's functions for the problem. As a specific application of the techniques developed, the modification of a winter nighttime ionosphere is described by simulating the release of 1000 kg of water vapor near a height of 300 km.

Mendillo, M.↗
NASA NTRS1986

Thioredoxins in evolutionarily primitive organisms

Thioredoxins are low molecular weight redox proteins, alternating between the S-S (oxidized) and SH (reduced) states, that function in a number of biochemical processes, including DNA synthesis, DNA replication, and enzyme regulation. Until recently, reduced ferredoxin was known to serve as the source of reducing power for the reduction of thioredoxins only in oxygenic photosynthetic cells. In all other organisms, the source of hydrogen (electrons) for thioredoxin reduction was considered to be NADPH. It was found that Clostridium pasteurianum, an anaerobic organism normally living in the soil unexposed to light, resembles photosynthetic cells in using ferredoxin for the reduction of thioredoxin. The results reveal the existence of a pathway in which ferredoxin, provides the reducing power for the reduction of thioredoxin via the flavoprotein enzyme, ferredoxinthioredoxin reductase. In related studies, it was found that Chromatium vinosum, an anaerobic photosynthetic purple sulfur bacterium, resembles evolutionarily more advanced micro-organisms in having an NADP-thioredoxin system composed of a single thioredoxin which is reduced by NADPH via NADP-thioredoxin reductase. The adoption of the NADP-thioredoxin system by Chromatium seems appropriate in view of evidence tha the organi sm utilizes ATP-driven reverse electron transport. Finally, results of research directed towards the identification of target enzymes of the ferredoxin/thioredoxin system in a cyanobacterium (Nostoc muscorum), show that thioredoxin-linked photosynthetic enzymes of cyanobateria are similar to those of chloroplasts. It now seems that the ferredoxin/thioredoxin system functions in regulating CO2 assimilation via the reductive pentose phosphate cycle in oxygenic but not anoxygenic photosynthetic cells.

Buchanan, B. B.↗
NASA NTRS1987

Pulsed source of energetic atomic oxygen

A pulsed high flux source of nearly monoenergetic atomic oxygen was designed, built, and successfully demonstrated. Molecular oxygen at several atmospheres pressure is introduced into an evacuated supersonic expansion nozzle through a pulsed molecular beam valve. An 18 J pulsed CO2 TEA laser is focused to intensities greater than 10(9) W/sq cm in the nozzle throat to generate a laser-induced breakdown. The resulting plasma is heated in excess of 20,000 K by a laser supported detonation wave, and then rapidly expands and cools. Nozzle geometry confines the expansion to provide rapid electron-ion recombination into atomic oxygen. Average O atom beam velocities from 5 to 13 km/s were measured at estimated fluxes to 10(18) atoms per pulse. Preliminary materials testing has produced the same surface oxygen enrichment in polyethylene samples as obtained on the STS-8 mission. Scanning electron microscope examinations of irradiated polymer surfaces reveal an erosion morphology similar to that obtained in low Earth orbit, with an estimated mass removal rate of approx. 10(-24) cu cm/atom. The characteristics of the O atom source and the results of some preliminary materials testing studies are reviewed.

Caledonia, George E.↗
NASA NTRS1990

Infrared reflectance measurements of the insulator-metal transition in solid hydrogen

Reflectance measurements on solid hydrogen to 177 GPa (1.77 Mbar) have been performed from near-infrared to ultraviolet wavelengths (0.5 to 3 eV). Above 150 GPa characteristic free-electron behavior in the infrared region is observed to increase sharply with increasing pressure. Analysis of volume dependence of the plasma frequency obtained from Drude-model fits to the spectra indicates that the pressure of the insulator-metal transition is 149 (+ or - 10) GPa at 295 K. The measurements are consistent with metallization by closure of an indirect gap in the molecular solid.

Mao, H. K.↗
NASA NTRS1992

Absorption band oscillator strengths of N2 transitions between 95.8 and 99.4 nm

Molecular nitrogen plays a central role in the energetics of the earth's upper atmosphere and is the major constituent of the atmospheres of the planetary satellites Titan and Triton. This paper reports a new set of absorption oscillator strengths measured at higher resolution for seven bands in the 95.8-99.4 nm region. The results are compared with earlier, lower resolution absorption measurements, electron scattering measurements, and calculations based on a deperturbation analysis of the excited states.

Stark, G.↗
NASA NTRS1994

Physical and chemical structure of the IC 63 nebula. 1: Millimeter and far-infrared observations

We present results of a (sub)millimeter and far-infrared study of the reflection/emission nebula IC 63, located close to the BO.5p star gamma Cas. The source has been mapped in the (12)CO 2 - 1 and 3 - 2, (13)CO 2 - 1, and CS 2 - 1 lines and shows a small molecular cloud less than 1'x 2' in extent, which coincides with the brightest optical nebulosity and IRAS 100 micrometer emission. IC 63 is therefore an excellent example of a nearby (d approximately = 230 pc), edge-on photon-dominated region (PDR). Various other molecules have been observed at the peak position through their rotational transitions, in order to probe the physical parameters and to derive abundances. The measured CO, HCO(+) HCN, CS and H2CO line ratios suggest that the cloud is warm, T approximately = 50 K, and dense, n (H2) approximately = 5 x 10(exp 4)/cu cm. Excitation of molecules by electrons may play a significant role in this PDR. On the basis of these physical conditions, column densities have been determined from the observed line strengths. Several different methods are discussed to constrain the H2 column density, including the use of measured submillimeter continuum fluxes. The resulting abundances of species such as CN and CS are similar to those found in cold, dark clouds like TMC-1 and L134N. However, the abundances of other simple molecules such as HNC, HCO(+) and possibly C2H are lower by factors of at least three, probably because of the enhanced photodissociation rates at a distance of 1.3 pc from a B star. Surprisingly, only the abundance of the H2S molecule appears enhanced. More complex, volatile molecules such as CH3OH CH3CN and HNCO, and the sulfur-oxides SO and SO2 have not been found in this cloud. Limited observations of molecules in the reflection nebulea NGC 2023 are presented as well, and the resulting molecular abundances are compared with those found for IC 63.

Jansen, David J.↗
NASA NTRS1978

Europa - Ultraviolet emissions and the possibility of atomic oxygen and hydrogen clouds

Emission signals from Europa with wavelength below 800 A were detected by the Pioneer 10 ultraviolet photometer. In the present paper, improved procedures for data reduction are used to determine the spatial region as well as the intensity of the suggested emission sources. The observations indicate a cloud with a radius of about 1.5 Jupiter radii and an apparent brightness of approximately 10 rayleighs for a wavelength of 500 A. It is argued that neutral oxygen atoms, along with neutral hydrogen, are produced through dissociation of water ice on the surface of Europa by particle impact. Electron impact ionization excitation of oxygen atoms in the resulting cloud then gives rise to the observed emission. The present source brightness and cloud radius results are used to estimate an oxygen column density of the order of 10 trillion per sq cm, while the density of atomic hydrogen is at most 100 billion per sq cm and 1 trillion per sq cm for molecular hydrogen.

Wu, F.-M.↗
NASA NTRS1982

Time-dependent calculations of Jupiter's ionosphere

Time-dependent calculations of the vertical distribution of protons in Jupiter's ionosphere show that the accumulation of protons in the topside ionosphere produced from solar ionizing radiation overwhelms the loss to vibrationally excited molecular hydrogen at vibrational temperatures as high at 1600 K. At 2500 K the ionization is decreased over the entire planet with little diurnal variation. For Voyager 1 then, unless the H2 vibrational temperature is as high as thousands of degrees and the topside density of H2 is asymmetric and larger by orders of magnitude, dynamical processes are more likely causes of the low electron densities seen in the nightside upper ionosphere. A calculation of the H3(+) density profile showed that the distribution above the turbopause is controlled by diffusion.

Chen, R. H.↗
NASA NTRS1991

A method of producing high quality oxide and related films on surfaces

Aluminum oxide or aluminum nitride films were deposited on molecular beam epitaxy (MBE) grown GaAS(100) using a novel cryogenic-based reactive thin film deposition technique. The process involves the condensation of molecular oxygen, ammonia, or other gases normally used for reactive thin film deposition on the substrate before the metal is deposited. The metal vapor is deposited into this layer and reacts with the molecular solid to form the desired compound or a precursor that can be thermally decomposed to generate the desired compound. The films produced by this method are free of impurities, and the low temperatures can be used to control the film and interfacial structure. The process can be easily integrated with existing MBE systems. Ongoing research using the same apparatus suggests that photon or electron irradiation could be used to promote the reactions needed to produce the intended material.

Ruckman, Mark W.↗
NASA NTRS1994

Theoretical Study of the Low-Lying States of TiHe(+),TiNe(+),TiAr(+),VAr(+),CrHe(+),CrAr(+),FeHe(+),FeAr(+),CoHe(+),and CoAr(+)

The potential energy curves for the manifold of molecular states dissociating to the lowest transition metal ion states derived from the 3d(sup n+1) and 3d(sup n)4s(sup 1) occupations have been determined for selected transition-metal ion- rare gas systems. These curves have been computed using large basis sets, and the state-averaged complete- active-space self-consistent-field/multireference configuration interaction level of electron correlation treatment. In general, the families of curves derived from the 3d(sup n+1) and 3d(sup n)4s(sup 1) metal occupations are disjoint; however, for Ti(+) there is a strong mixing of the 3d(sup 2)4s(sup 1) and 3d(sup 3) asymptotes, because of the small separation between the asymptotes. This mixing leads to a failure of single-reference-based techniques; this is discussed in the context of our previous single-reference-based treatments.

Partridge, Harry↗