Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “mass diffusivity”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,045 records · Page 58

Diurnal variations in the thermosphere. I - Theoretical formulation

A nonlinear perturbation theory is formulated for the solution of the multicomponent equations of energy, mass, and momentum conservation in the atmosphere. The theory is three-dimensional and includes the effects of heat conduction and advection, viscosity, ion drag, and diffusion. The theory is described as a superposition of mathematical modes obtained by expanding the physical quantities into vector and spherical harmonics. The coupling between the various modes, both linear and nonlinear, is included. The theory provides a basis for the treatment of the thermosphere and its interaction with the lower atmosphere, where 'mode coupling' is most important. As an example, a comparison is presented between one-dimensional and three-dimensional calculations of the fundamental mode of the diurnal component in the thermosphere. Coupling between the lowest modes is considered to describe the physical conditions of the lower thermosphere where inertia and Coriolis forces become dominant over the ion-drag and viscous forces. In this region, the latitude structures of the temperature, wind field, and diffusively controlled oxygen are shown to change significantly.

Harris, I.↗

X-ray studies of quasars with the Einstein Observatory

Results of an investigation of the X-ray properties of quasars conducted using the Einstein Observatory (HEAO 2) are reported. The positions, fluxes and luminosities of 35 known quasars were observed by the Einstein high-resolution imaging detector and the imaging proportional counter. Assuming optical redshifts as valid distance indicators, 0.5-4.5 keV X-ray luminosities ranging from 10 to the 43rd to 10 to the 47 ergs/sec are obtained, with evidence of very little cold gas absorption. Flux variability on a time scale of less than 10,000 sec is observed for the quasar OX 169, which implies a mass between 8 x 10 to the 5th and 2 x 10 to the 8th solar masses for the black hole assumed to be responsible for the emission. Preliminary results of the quasar survey also indicate that quasars contribute significantly to the diffuse X-ray background.

Tananbaum, H.↗

X-ray luminosities of B supergiants estimated from ultraviolet resonance lines

The Auger ionization model is used to estimate the X-ray luminosities of supergiants of spectral types from B1.5 to B9. It is found that the ion N+4 is not useful in the B spectral range, while the C IV and Si IV line strengths are excellent diagnostics of X-ray luminosity, being only slightly affected by the diffuse radiation field. For the ion abundance calculations, the X-ray radiation field was assumed to be like that observed in early B supergiants and mass loss rates were estimated using an extrapolation of radio observations of earlier OB supergiants. X-ray luminosities were derived that are consistent with Einstein observatory results. Derived X-ray luminosities show a general bolometric magnitude decrease from early to late B supergiants.

Odegard, N.↗

Spectral analysis of the intra-group medium in the NGC 2300 group

The results of spectral and spatial analysis of overlapping Rosat position sensitive proportional counter (PSPC) and Advanced Satellite for Cosmology and Astrophysics (ASCA) scanning imaging spectroradiometer (SIS) observations of the NGC 2300 group are presented. The spatial analysis of the co-added fields reveals that the diffuse X-ray gas can be traced to at least 25 arcmin. The temperature of the gas was found to be approximately 0.88 keV. The mass of gas within 0.33 Mpc is equal to 1.39 x 10(exp 12) solar mass. Comparing the mass of the galaxies plus the mass of hot gas the total mass of the system yields an observed baryonic fraction of 12 percent to 18 percent.

Davis, David S.↗

Development of an Advanced Computational Model for OMCVD of Indium Nitride

An advanced computational model is being developed to predict the formation of indium nitride (InN) film from the reaction of trimethylindium (In(CH3)3) with ammonia (NH3). The components are introduced into the reactor in the gas phase within a background of molecular nitrogen (N2). Organometallic chemical vapor deposition occurs on a heated sapphire surface. The model simulates heat and mass transport with gas and surface chemistry under steady state and pulsed conditions. The development and validation of an accurate model for the interactions between the diffusion of gas phase species and surface kinetics is essential to enable the regulation of the process in order to produce a low defect material. The validation of the model will be performed in concert with a NASA-North Carolina State University project.

Cardelino, Carlos A.↗

Active Flow Control on a Boundary-Layer-Ingesting Inlet

Boundary layer ingestion (BLI) is explored as means to improve overall system performance for Blended Wing Body configuration. The benefits of BLI for vehicle system performance benefit are assessed with a process derived from first principles suitable for highly-integrated propulsion systems. This performance evaluation process provides framework within which to assess the benefits of an integrated BLI inlet and lays the groundwork for higher-fidelity systems studies. The results of the system study show that BLI provides a significant improvement in vehicle performance if the inlet distortion can be controlled, thus encouraging the pursuit of active flow control (AFC) as a BLI enabling technology. The effectiveness of active flow control in reducing engine inlet distortion was assessed using a 6% scale model of a 30% BLI offset, diffusing inlet. The experiment was conducted in the NASA Langley Basic Aerodynamics Research Tunnel with a model inlet designed specifically for this type of testing. High mass flow pulsing actuators provided the active flow control. Measurements were made of the onset boundary layer, the duct surface static pressures, and the mass flow through the duct and the actuators. The distortion was determined by 120 total pressure measurements located at the aerodynamic interface plane. The test matrix was limited to a maximum freestream Mach number of 0.15 with scaled mass flows through the inlet for that condition. The data show that the pulsed actuation can reduce distortion from 29% to 4.6% as measured by the circumferential distortion descriptor DC60 using less than 1% of inlet mass flow. Closed loop control of the actuation was also demonstrated using a sidewall surface static pressure as the response sensor.

Gorton, Susan Althoff↗

Simple Two-Dimensional Corrections for One-Dimensional Pulse Tube Models

One-dimensional oscillating flow models are very useful for designing pulse tubes. They are simple to use, not computationally intensive, and the physical relationship between temperature, pressure and mass flow are easy to understand when used in conjunction with phasor diagrams. They do not possess, however, the ability to directly calculate thermal and momentum diffusion in the direction transverse to the oscillating flow. To account for transverse effects, lumped parameter corrections, which are obtained though experiment, must be used. Or two-dimensional solutions of the differential fluid equations must be obtained. A linear two-dimensional solution to the fluid equations has been obtained. The solution provides lumped parameter corrections for one-dimensional models. The model accounts for heat transfer and shear flow between the gas and the tube. The complex Nusselt number and complex shear wall are useful in describing these corrections, with phase relations and amplitudes scaled with the Prandtl and Valensi numbers. The calculated ratio, a, between a two-dimensional solution of the oscillating temperature and velocity and a one-dimensional solution for the same shows a scales linearly with Va for Va less than 30. In this region alpha less than 0.5, that is, the enthalpy flow calculated with a two-dimensional model is 50% of a calculation using a one-dimensional model. For Va greater than 250, alpha = 0.8, showing that diffusion is still important even when it is confined to a thing layer near the tube wall.

Lee, J. M.↗

Dark Matter Constraints from Observations of 25 Milky Way Satellite Galaxies with the Fermi Large Area Telescope

The dwarf spheroidal satellite galaxies of the Milky Way are some of the most dark-matter-dominated objects known. Due to their proximity, high dark matter content, and lack of astrophysical backgrounds, dwarf spheroidal galaxies are widely considered to be among the most promising targets for the indirect detection of dark matter via gamma rays. Here we report on gamma ray observations of 25 Milky Way dwarf spheroidal satellite galaxies based on 4 years of Fermi Large Area Telescope (LAT) data. None of the dwarf galaxies are significantly detected in gamma rays, and we present gamma ray flux upper limits between 500MeV and 500 GeV. We determine the dark matter content of 18 dwarf spheroidal galaxies from stellar kinematic data and combine LAT observations of 15 dwarf galaxies to constrain the dark matter annihilation cross section. We set some of the tightest constraints to date on the annihilation of dark matter particles with masses between 2 GeV and 10TeV into prototypical standard model channels. We find these results to be robust against systematic uncertainties in the LAT instrument performance, diffuse gamma ray background modeling, and assumed dark matter density profile.

satellite↗

Effect of Ram and Zenith Exposure on the Optical Properties of Polymers in Space

The temperature of spacecraft is influenced by the solar absorptance and thermal emittance of the external spacecraft materials. Optical and thermal properties can degrade over time in the harsh low Earth orbital (LEO) space environment where spacecraft external materials are exposed to various forms of radiation, thermal cycling, and atomic oxygen. Therefore, it is important to test the durability of spacecraft materials in the space environment. One objective of the Polymers and Zenith Polymers Experiments was to determine the effect of LEO space exposure on the optical properties of various spacecraft polymers. These experiments were flown as part of the Materials International Space Station Experiment 7 (MISSE 7) mission on the exterior of the International Space Station (ISS) for 1.5 years. Samples were flown in ram, wake or zenith directions, receiving varying amounts of atomic oxygen and solar radiation exposure. Total and diffuse reflectance and transmittance of flight and corresponding control samples were obtained post-flight using a Cary 5000 UV-Vis-NIR Spectrophotometer. Integrated air mass zero solar absorptance (s) of the flight and control samples were computed from the total transmittance and reflectance, and compared. The optical data are compared with similar polymers exposed to space for four years as part of MISSE 2, and with atomic oxygen erosion data, to help understand the degradation of these polymers in the space environment. Results show that prolonged space exposure increases the solar absorptance of some materials. Knowing which polymers remain stable will benefit future spacecraft design.

Yuanchun Li↗

Laboratory Astrophysics at NASA Ames: Recent Results and Advances

The Cosmic SImulation Chamber (COSmIC) facility was developed at NASA Ames to study, in the laboratory, neutral and ionized molecules and nanoparticles under the low temperature and high vacuum conditions representative of interstellar, circumstellar and planetary environments. COSmIC is composed of a Pulsed Discharge Nozzle expansion that generates a plasma in a free supersonic jet expansion coupled to highsensitivity, complementary in situ diagnostic tools, used for the detection and characterization of the species present in the expansion: a Cavity Ring Down Spectroscopy and fluorescence spectroscopy systems operating in the UV-Visible range, and a Reflectron Time-Of-Flight Mass Spectrometer (ReTOF-MS). We will present recent advances that were achieved in laboratory astrophysics using COSmIC. These include advances in the domain of the diffuse interstellar bands (DIBs) and in the formation of dust grains and aerosols from their gas-phase molecular precursors in environments as varied as circumstellar outflows and planetary atmospheres. An extension of the spectral response of the facility into the infrared (IR) range is in progress with the addition of a high-resolution near-IR to mid-IR CRDS system that will allow to further investigate cosmic molecules and grains with COSmIC. Acquisition of laser induced fluorescence spectra of cosmic molecule analogs and the laser induced incandescence spectra of cosmic grain analogs are also planned. Preliminary results in these fronts will presented and the implications of the on-going studies for astronomy will be addressed.

Laboratory↗

Modeling Electrolytic O2 Recovery from Metabolic CO2 for Advanced Closed Loop Life Support Systems in Extraterrestrial Human Missions

The International Space Station (ISS) is currently equipped with a complex, heavy, and power consuming system that recovers approximately 50% of O2 from metabolic CO2. Future long duration human missions to the Moon and Mars will necessitate a sustainable and highly efficient metabolic oxygen recovery system capable of yielding a minimum of 75% O2 recovery. A Macrofluidic Electrochemical Reactor (MFECR) technology development effort is currently underway at NASA Marshall Space Flight Center (MSFC) to significantly increase current metabolic O2 recovery efficiency, expand mission sustainability, and reduce complexity of the system. The novel design combines CO2 conversion to O2 along with C2H4 as byproduct and water electrolysis (currently conducted in two separate units) into a single compact unit that runs at standard conditions and is theoretically capable of generating O2 with a theoretical maximum metabolic CO2 conversion of 73% while consuming less than metabolic water. This paper presents a comprehensive multi-physic 3D model developed at MSFC on CO2 conversion to O2 and C2H4 at standard conditions via MFECR. The 3D spatial domain of the model is a replica of the actual MFECR’s 3D drawing generated for the MFECR fabrication and operated to recover O2 from CO2 yielding C2H4 as byproduct. Electrochemical (EC) physics that includes EC multicomponent reaction mechanisms, mass transport, and electrical current density distributions is coupled in the model with all the other physics phenomena involved in the MFECR’s process, such as two-phase flow, free and porous fluid regimes, multicomponent mass transfer, heat transfer, and DC electrical current generation along with Joule heating effect. The EC reaction sections of the MFECR consists of two porous gas diffusion electrodes (GDE) and an electrolyte serpentine channel sandwiched in the middle. The CO2 feeds the cathode serpentine channel and part of the O2 product is fed back to the anode serpentine chamber. An alkaline solution feeds the electrolyte serpentine chamber wetting the GDEs of both, the anode and cathode allowing the OH- ionic transport between them. The EC reactions in the cathode’s GDE yield C2H4 from CO2 and H2 from water while the EC reaction in the anode’s GDE yields O2. The authors will present in this paper the validation of the model using experimental data and the utilization of the validated model in building a reliable simulator that will not only assist the authors on the MFECR design but also the optimization of its operation in the ISS and future spatial human missions.

Jesus A Dominguez↗

Soft X-ray observations of the interacting galaxies NGC 1808 and NGC 1792

The soft X-ray emission from both galaxies NGC 1808 and NGC 1792, which we investigated using the ROSAT HRI and Position Sensitive Proportional Counter (PSPC), comes most probably from X-ray binaries and/or from hot ionized gas in powerful supernovae and supernova remnants. The distribution of the soft X-ray emission in NGC 1808, which is very well correlated with the distribution of 'radio knots' in the central starburst, suggests that hot gas dominates the emission in the ROSAT band. This is consistent with the results of PSPC observations by Junkes et al. The total soft X-ray luminosity in the ROSAT band of NGC 1808 of 1.2 x 10(exp 41) ergs/s is relatively high compared with other nearby starburst galaxies. Soft X-ray emission of diffuse hot ionized gas that is associated with the outflow traced by the conspicuous dust filaments protruding from the plane has been detected. Its luminosity in the ROSAT band is greater than or equal to 3 x 10(exp 39) ergs/s, i.e., several percent of the total soft X-ray luminosity. Thus, NGC 1808 is another example for a 'superwind' galaxy. The soft X-ray radiation from NGC 1792 is more likely to be dominated by a population of high-mass X-ray binaries or young powerful supernovae which are associated with the high-level star formation going on in the very prominent H II regions along its spiral arms, with possibly an additional contribution of diffuse hot ionized gas. The soft X-ray luminosities of individual sources lie in the range of 5 x 10(exp 38) to 2.7 x 10(exp 39) ergs/s, thus exceeding by far the Eddington luminosity of an accreting neutron star. The peaks of some of these soft X-ray luminous sources are offset with respect to the H II regions by a few hundred parsecs. Accordingly, if the soft X-ray sources should originate from the H II regions, their relative velocities with respect to the ambient medium have to be as high as approximately 100 km/s.

Dahlem, Michael↗

On the mechanism of intermolecular nitrogen-atom transfer from a lattice-isolated diruthenium nitride intermediate

Catalyst confinement within microporous media provides the opportunity to site isolate reactive intermediates, enforce intermolecular functionalization chemistry by co-localizing reactive intermediates and substrates in molecular-scale interstices, and harness non-covalent host–guest interactions to achieve selectivities that are complementary to those accessible in solution. As part of an ongoing program to develop synthetically useful nitrogen-atom transfer (NAT) catalysts, we have demonstrated intermolecular benzylic amination of toluene at a Ru 2 nitride intermediate confined within the interstices of a Ru2-based metal–organic framework (MOF), Ru 3 (btc) 2 X 3 (btc = 1,3,5-benzenetricarboxylate, i.e., Ru-HKUST-1 for X = Cl). Nitride confinement within the extended MOF lattice enabled intermolecular C–H functionalization of benzylic C–H bonds in preference to nitride dimerization, which was encountered with soluble molecular analogues. Detailed study of the kinetic isotope effects (KIEs, i.e., k H /k D ) of C–H amination, assayed both as intramolecular effects using partially labeled toluene and as intermolecular effects using a mixture of per-labeled and unlabeled toluene, provided evidence for restricted substrate mobility on the time scale of interstitial NAT. Analysis of these KIEs as a function of material mesoporosity provided approximate experimental values for functionalization in the absence of mass transport barriers. Here, we disclose a combined experimental and computational investigation of the mechanism of NAT from a Ru 2 nitride to the C–H bond of toluene. Computed kinetic isotope effects for a H-atom abstraction (HAA)/radical rebound (RR) mechanism are in good agreement with experimental data obtained for C–H amination at the rapid diffusion limit. These results provide the first detailed analysis of the mechanism of intermolecular NAT to a C–H bond, bolster the use of KIEs as a probe of confinement effects on NAT within MOF lattices, and provide mechanistic insights unavailable by experiment because rate-determining mass transport obscured the underlying chemical kinetics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Numerical simulation of axisymmetric turbulent flow in combustors and diffusors

A method for predicting turbulent flow in combustors and diffusers is developed. The Navier-Stokes equations, incorporating a turbulence kappa-epsilon model equation, were solved in a nonorthogonal curvilinear coordinate system. The solution applied the finite volume method to discretize the differential equations and utilized the SIMPLE algorithm iteratively to solve the differenced equations. A zonal grid method, wherein the flow field was divided into several subsections, was developed. This approach permitted different computational schemes to be used in the various zones. In addition, grid generation was made a more simple task. However, treatment of the zonal boundaries required special handling. Boundary overlap and interpolating techniques were used and an adjustment of the flow variables was required to assure conservation of mass, momentum and energy fluxes. The numerical accuracy was assessed using different finite differencing methods, i.e., hybrid, quadratic upwind and skew upwind, to represent the convection terms. Flows in different geometries of combustors and diffusers were simulated and results compared with experimental data and good agreement was obtained.

Yung, Chain Nan↗

Aerosol particles and the formation of advection fog

A study of numerical simulation of the effects of concentration, particle size, mass of nuclei, and chemical composition on the dynamics of warm fog formation, particularly the formation of advection fog, is presented. This formation is associated with the aerosol particle characteristics, and both macrophysical and microphysical processes are considered. In the macrophysical model, the evolution of wind components, water vapor content, liquid water content, and potential temperature under the influences of vertical turbulent diffusion, turbulent momentum, and turbulent energy transfers are taken into account. In the microphysical model, the supersaturation effect is incorporated with the surface tension and hygroscopic material solution. It is shown that the aerosol particles with the higher number density, larger size nuclei, the heavier nuclei mass, and the higher ratio of the Van't Hoff factor to the molecular weight favor the formation of the lower visibility advection fogs with stronger vertical energy transfer during the nucleation and condensation time period.

Hung, R. J.↗

Analyses of ∼0.05–2 MeV Ions Associated with the 2022 February 16 Energetic Storm Particle Event Observed By Parker Solar Probe

We present analyses of 0.05–2 MeV ions from the 2022 February 16 energetic storm particle event observed by Parker Solar Probeʼs (PSP) ISeIS/EPI-Lo instrument at 0.35 au from the Sun. This event was characterized by an enhancement in ion fluxes from a quiet background, increasing gradually with time with a nearly flat spectrum, rising sharply near the arrival of the coronal mass ejection (CME)–driven shock, becoming nearly a power-law spectrum, then decaying exponentially afterward, with a rate that was independent of energy. From the observed fluxes, we determine diffusion coefficients, finding that far upstream of the shock the diffusion coefficients are nearly independent of energy, with a value of 10 20 cm 2 s −1 . Near the shock, the diffusion coefficients are more than 1 order of magnitude smaller and increase nearly linearly with energy. We also determine the source of energetic particles, by comparing ratios of the intensities at the shock to estimates of the quiet-time intensity to predictions from diffusive shock acceleration theory. We conclude that the source of energetic ions is mostly the solar wind for this event. We also present potential interpretations of the near-exponential decay of the intensity behind the shock. One possibility we suggest is that the shock was over expanding when it crossed PSP and the energetic particle intensity decreased behind the shock to fill the expanding volume. Over expanding CMEs could well be more common closer to the Sun, and this is an example of such a case.

Interplanetary particle acceleration↗

Optimization of Thin-Film Solar Cells for Lunar Surface Operations

Thin-film solar cells have been in production for decades, but technology has only recently advanced enough to allow for comparable efficiencies to traditional rigid cells. Some of the benefits of thin-films, such as lighter weight and being foldable, are particularly advantageous to space applications since mass and volume are key considerations of any flight project. Using these thin-film cells in space, however, is outside of their ground-based design criteria. This requires special care to be taken in designing the power generation system of a spacecraft around a thin-film solar cell, particularly in regards to thermal management. Without the diffusion of an atmosphere to mitigate solar load, the temperature of the panels can rapidly exceed their design specification. In this paper a design solution is presented that allows for thin-film solar cells to be used in a robotic lunar lander. Due to the low thermal mass and in-plane conductivity of thin films, it is difficult to remove waste heat by any other method than radiation. On the lunar surface this means angling the arrays to increase their view factor to space, which has the negative consequence of decreasing their power generation. An optimization was developed to balance the heat rejection and power generation of the cells, using constraints on the maximum cell temperature and minimum spacecraft power requirements. The resulting solar panel angle was then used as an input to the Thermal Desktop model to verify the final panel temperatures.

Breeding, Shawn↗

Stellar Mass Black Hole Formation and Multimessenger Signals from Three-dimensional Rotating Core-collapse Supernova Simulations

We present self-consistent 3D core-collapse supernova simulations of a 40 ${M}_{\odot }$ progenitor model using the isotropic diffusion source approximation for neutrino transport and an effective general relativistic potential up to `0.9 s postbounce. We consider three different rotational speeds with initial angular velocities of ${{\rm{\Omega }}}_{0}=0$, 0.5, and 1 rad s -1 and investigate the impact of rotation on shock dynamics, black hole (BH) formation, and gravitational wave (GW) signals. The rapidly rotating model undergoes an early explosion at ~250 ms postbounce and shows signs of the low $T/| W| $ instability. We do not find BH formation in this model within ~460 ms postbounce. In contrast, we find BH formation at 776 ms postbounce and 936 ms postbounce for the nonrotating and slowly rotating models, respectively. The slowly rotating model explodes at ~650 ms postbounce, and the subsequent fallback accretion onto the proto–neutron star (PNS) results in BH formation. In addition, the standing accretion shock instability induces rotation of the PNS in the model that started with a nonrotating progenitor. Assuming conservation of specific angular momentum during BH formation, this corresponds to a BH spin parameter of a = J/M = 0.046. However, if no explosion sets in, all the angular momentum will eventually be accreted by the BH, resulting in a nonspinning BH. The successful explosion of the slowly rotating model drastically slows down the accretion onto the PNS, allowing continued cooling and contraction that results in an extremely high GW frequency (f ~ 3000 Hz) at BH formation, while the nonrotating model generates GW signals similar to our corresponding 2D simulations.

79 ASTRONOMY AND ASTROPHYSICS↗