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SPINOFF 2000

For the past 42 years, NASA has made special efforts to ensure the widest possible dissemination of its research and technology developments. We share the wealth of technology developed for our missions with the nation's industries to contribute to US economic strength and quality of life. For the past 27 years, this publication has provided you with over 1,200 examples of products and services developed as a direct result of commercial partnerships between NASA and the business community. Examples have covered products from fire retardant materials and air pollution monitors to non-invasive cardiac monitors and sensors for environmental control. In the Technology Transfer and Outreach section of Spinoff 2000, we highlight the activities of our Ames Research Center's Commercial Technology Office (CTO). Their efforts to facilitate and support technology commercialization are representative of the CTO at each field center. Increased activities to accelerate the dissemination of technologies, speed up the process of patent licensing, quicken the release of software for beta testing, support and manage incubators, and hasten the collaboration with commercial and academic organizations will continue to maximize the earliest potential commercial utilization of NASA's new inventions and technologies. Spinoff 2000 is organized into three sections: (1) Aerospace and Development highlights major research and development efforts currently carried out at the 10 NASA field centers; (2) Commercial Benefits-Spinoffs describes commercially available products and services resulting from the transfer of NASA technology; and (3) Technology Transfer and Outreach features this year's center spotlight, NASA's Ames Research Center, and its commercialization efforts, as well as the mechanisms in place nationwide to assist US industry in obtaining, transferring, and applying NASA technology, expertise, and assistance.

Source record↗

Capillary electrophoresis-electrochemistry microfluidic system for the determination of organic peroxides

A microfluidic analytical system for the separation and detection of organic peroxides, based on a microchip capillary electrophoresis device with an integrated amperometric detector, was developed. The new microsystem relies on the reductive detection of both organic acid peroxides and hydroperoxides at -700 mV (vs. Ag wire/AgCl). Factors influencing the separation and detection processes were examined and optimized. The integrated microsystem offers rapid measurements (within 130 s) of these organic-peroxide compounds, down to micromolar levels. A highly stable response for repetitive injections (RSD 0.35-3.12%; n = 12) reflects the negligible electrode passivation. Such a "lab-on-a-chip" device should be attractive for on-site analysis of organic peroxides, as desired for environmental screening and industrial monitoring.

NASA Discipline Life Sciences Technologies↗

Understanding Fire Through Improved Technology

Aztec(TradeMark) is the commercial name for Southwest Sciences laser. The laser has coarse tuning ranges of 10 nanometers (nm) to 30 nm at wavelengths ranging from 630 nm to 2,300 nm, making it the only commercially available external cavity diode laser with wavelengths beyond 1,650 nm. The laser's high-speed tuning in both coarse and fine wavelength regimes allows for increased trace gas detection. With the automated coarse tuning option, the Aztec sweeps through its wavelength range in less than 1 millisecond. While some diode lasers can only detect one type, or species, of a trace gas, the Aztec's broad wavelength tuning provides access to multiple trace gas species. The Aztec has a wide range of applications for both NASA and commercial users, from protecting astronauts in space to improving combustion processes on Earth. It may serve as a new tool for planetary exploration, as it can detect a wide range of multiple gas species in planetary atmospheres. The laser could optically detect gaseous indicators of incipient fires on the International Space Station and Space Shuttle, as well as detect low concentrations of potentially toxic gases in spacecraft crew habitats. The laser could also provide more accurate fire detection in aircraft cargo compartments. Since the Aztec can detect several gases that only evolve during an actual fire, its implementation could reduce the large number of commercial aircraft landings that currently occur due to false alarms. Other applications include environmental and industrial process monitoring.

Source record↗

High Sensitivity, Low Power Nano Sensors and Devices for Chemical Sensing

The chemical sensor market has been projected to grow to better than $40 billion dollars worldwide within the next 10 years. Some of the primary motivations to develop nanostructured chemical sensors are monitoring and control of environmental pollution; improved diagnostics for consumption; improvement in measurement precision and accuracy; and improved detection limits for Homeland security, battlefield environments, and process and quality control of industrial applications. In each of these applications, there is demand for sensitivity, selectivity and stability of environmental and biohazard detection and capture beyond what is currently commercially available. Nanotechnology offers the ability to work at the molecular level, atom by atom, to create large structures with fundamentally new molecular organization. It is essentially concerned with materials, devices, and systems whose structures and components exhibit novel and significantly improved physical, chemical and biological properties, phenomena, and process control due to their nanoscale size. One such nanotechnology-enabled chemical sensor has been developed at NASA Ames leveraging nanostructures, such as single walled carbon nanotubes (SWNTs) and metal oxide nanobelts or nanowires, as a sensing medium bridging a pair of interdigitated electrodes (IDE) realized through a silicon-based microfabrication and micromachining technique. The DE fingers are fabricated on a silicon substrate using standard photolithography and thin film metallization techniques. It is noteworthy that the fabrication techniques employed are not confined to the silicon substrate. Through spin casting and careful substrate selection (i.e. clothing, glass, polymer, etc.), additional degrees of freedom can be exploited to enhance sensitivity or to conform to unique applications. Both in-situ growth of nanostructured materials and casting of nanostructured dispersions were used to produce analogous chemical sensing devices.

Li, Jing↗

Microbial Characterization and Comparison of Isolates During the Mir and ISS Missions

Spacecraft represent a semi-closed ecosystem that provides a unique model of microbial interaction with other microbes, potential hosts, and their environment. Environmental samples from the Mir Space Station (1995-1998) and the International Space Station (ISS) (2000-Present) were collected and processed to provide insight into the characterization of microbial diversity aboard spacecraft over time and assess any potential health risks to the crew. All microbiota were isolated using standard media-based methodologies. Isolates from Mir and ISS were processed using various methods of analysis, including VITEK biochemical analysis, 16s ribosomal identification, and fingerprinting using rep-PCR analysis. Over the first 41 months of habitation, the diversity of the microbiota from air and surface samples aboard ISS increased from an initial six to 53 different bacterial species. During the same period, fungal diversity increased from 2 to 24 species. Based upon rep-PCR analysis, the majority of isolates were unique suggesting the need for increased sampling frequency and a more thorough analysis of samples to properly characterize the ISS microbiota. This limited fungal and bacterial data from environmental samples acquired during monitoring currently do not indicate a microbial hazard to ISS or any trends suggesting potential health risks.

Fontenot, Sondra L.↗

Miniature Wireless Sensors Size Up to Big Applications

Like the environment of space, the undersea world is a hostile, alien place for humans to live. But far beneath the waves near Key Largo, Florida, an underwater laboratory called Aquarius provides a safe harbor for scientists to live and work for weeks at a time. Aquarius is the only undersea laboratory in the world. It is owned by the National Oceanic and Atmospheric Administration (NOAA), administered by NOAA s National Undersea Research Program, and operated by the National Undersea Research Center at the University of North Carolina at Wilmington. Aquarius was first deployed in underwater operations in 1988 and has since hosted more than 200 scientists representing more than 90 organizations from around the world. For NASA, Aquarius provides an environment that is analogous to the International Space Station (ISS) and the space shuttle. As part of its NASA Extreme Environment Mission Operations (NEEMO) program, the Agency sends personnel to live in the underwater laboratory for up to 2 weeks at a time, some of whom are crew members or "aquanauts" who are subjected to the same tasks and challenges underwater that they would face in space. In fact, many participants have found the deep-sea diving experience to be much akin to spacewalking. To maintain Aquarius, the ISS, and the space shuttle as safe, healthy living/research habitats for its personnel, while keeping costs in mind, NASA, in 1997, recruited the help of Conroe, Texas-based Invocon, Inc., to develop wireless sensor technology that monitors and measures various environmental and structural parameters inside these facilities.

Source record↗

Summary of Terra and Aqua MODIS On-orbit Calibration and Characterization Results

The Moderate Resolution Imaging Spectroradiometer (MODIS) onboard NASA's EOS Terra spacecraft has been in operation for more than seven years since its launch in December 1999 and the MODIS onboard Aqua spacecraft has been in operation for more than 4.5 years since its launch in May 2002. Compared to its heritage sensors, such as AVHRR, CZCS, SeaWiFS, HIRS, and Landsat TM, the MODIS instrument was developed with improved spectral and spatial resolutions, and temporal scale or global coverage frequency. The two MODIS instruments are nearly identical with each collecting data in 36 spectral bands: 20 reflective solar bands (RSB) with center wavelengths from 0.41 to 2.2jm and 16 thermal emissive bands (TEB) from 3.7 to 4.4 microns. MODIS makes the Earth view observations with a scan angle range of +/-55 degree relative to instrument nadir and at three nadir spatial resolutions: 0.25km for bands 1-2.05km for bands 3-7, and 1km for bands 8-36, thus enabling complete global coverage of the Earth in less than 2 days. Both Terra and Aqua MODIS observations have been routinely used to generate a broad range of science data products that are widely distributed and extensively applied for the studies of the Earth's land, oceans, and atmosphere and for the monitoring of climate and environmental changes. It is obvious that the MODIS science data product quality strongly relies on sensor on-orbit performance and its capability of continuously tracking sensor response changes over time. Because of this, each MODIS was built with a comprehensive set of on-board calibrators (OBC) that include a solar diffuser (SD) for the RSB calibration, a blackbody (BB) for the TEB calibration, and a spectro-radiometric calibration assembly (SRCA) for the spatial (RSB and TEB) and spectral (RSB only) characterization. Most importantly, extensive and dedicated sensor calibration and characterization efforts have been constantly made by the MODIS Characterization Support Team (MCST) at NASA/GSFC. In this presentation, we will provide an overview of MODIS sensor operations since 1aunh and the onorbit calibration and characterization methodologies with emphasis on the differences between Terra and Aqua MODIS characteristics. We will summarize both Terra and Aqua MODIS onorbit calibration and characterization results, including their RSB and TEB detector noise characterization, the sensor response changes, and the corrections to the optics degradation. In addition to radiometric calibration performance, we will illustrate both sensors' spectral and spatial characterization results in terms of their band-to-band registrations and spectral band center wavelength shifts.

Xiong, X.↗

The MASSE Project: Applications of Biotechnology for Planetary Exploration

Automated life-detection experiments for solar system exploration have been previously. proposed and used onboard the. Viking, Mars lander,s, although. with ambiguous results. The recent advances in biotechnology such as biosensors, protein microarrays, and microfluidics alongside increased. knowledge in biomarker science have led to vastly improved sophistication and sensitivity for a new approach in life detection. The MASSE project has taken the challenge of integrating all of this knowledge into a new generation of interplanetary flight instrumentation for the main purpose.ot combining several mutually. confirming tests for life, organic/microbial contamination, prebiotic and abiotic chemicals into a small low powered instrument. Although the primary goal is interplanetary exploration, several terrestrial applications have become apparent specifically in point-of-care medical technology, bio-warfare, environmental sensing and microbial monitoring of manned space-flight vehicles.

Lynch, Kennda↗

Integrated Laser Characterization, Data Acquisition, and Command and Control Test System

Satellite-based laser technology has been developed for topographical measurements of the Earth and of other planets. Lasers for such missions must be highly efficient and stable over long periods in the temperature variations of orbit. In this innovation, LabVIEW is used on an Apple Macintosh to acquire and analyze images of the laser beam as it exits the laser cavity to evaluate the laser s performance over time, and to monitor and control the environmental conditions under which the laser is tested. One computer attached to multiple cameras and instruments running LabVIEW-based software replaces a conglomeration of computers and software packages, saving hours in maintenance and data analysis, and making very longterm tests possible. This all-in-one system was written primarily using LabVIEW for Mac OS X, which allows the combining of data from multiple RS-232, USB, and Ethernet instruments for comprehensive laser analysis and control. The system acquires data from CCDs (charge coupled devices), power meters, thermistors, and oscilloscopes over a controllable period of time. This data is saved to an html file that can be accessed later from a variety of data analysis programs. Also, through the LabVIEW interface, engineers can easily control laser input parameters such as current, pulse width, chiller temperature, and repetition rates. All of these parameters can be adapted and cycled over a period of time.

Stysley, Paul↗

Adaptive Sampling of Time Series During Remote Exploration

This work deals with the challenge of online adaptive data collection in a time series. A remote sensor or explorer agent adapts its rate of data collection in order to track anomalous events while obeying constraints on time and power. This problem is challenging because the agent has limited visibility (all its datapoints lie in the past) and limited control (it can only decide when to collect its next datapoint). This problem is treated from an information-theoretic perspective, fitting a probabilistic model to collected data and optimizing the future sampling strategy to maximize information gain. The performance characteristics of stationary and nonstationary Gaussian process models are compared. Self-throttling sensors could benefit environmental sensor networks and monitoring as well as robotic exploration. Explorer agents can improve performance by adjusting their data collection rate, preserving scarce power or bandwidth resources during uninteresting times while fully covering anomalous events of interest. For example, a remote earthquake sensor could conserve power by limiting its measurements during normal conditions and increasing its cadence during rare earthquake events. A similar capability could improve sensor platforms traversing a fixed trajectory, such as an exploration rover transect or a deep space flyby. These agents can adapt observation times to improve sample coverage during moments of rapid change. An adaptive sampling approach couples sensor autonomy, instrument interpretation, and sampling. The challenge is addressed as an active learning problem, which already has extensive theoretical treatment in the statistics and machine learning literature. A statistical Gaussian process (GP) model is employed to guide sample decisions that maximize information gain. Nonsta tion - ary (e.g., time-varying) covariance relationships permit the system to represent and track local anomalies, in contrast with current GP approaches. Most common GP models are stationary, e.g., the covariance relationships are time-invariant. In such cases, information gain is independent of previously collected data, and the optimal solution can always be computed in advance. Information-optimal sampling of a stationary GP time series thus reduces to even spacing, and such models are not appropriate for tracking localized anomalies. Additionally, GP model inference can be computationally expensive.

Thompson, David R.↗

Low Temperature Double-layer Capacitors with Improved Energy Density: An Overview of Recent Development Efforts

Electrochemical double-layer capacitors are finding increased use in a wide range of energy storage applications, particularly where high pulse power capabilities are required. Double-layer capacitors store charge at a liquid/solid interface, making them ideal for low temperature power applications, due to the facile kinetic processes associated with the rearrangement of the electrochemical double-layer at these temperatures. Potential low temperature applications include hybrid and electric vehicles, operations in polar regions, high altitude aircraft and aerospace avionics, and distributed environmental and structural health monitoring. State-of-the-art capacitors can typically operate to -40 C, with a subsequent degradation in power performance below room temperature. However, recent efforts focused on advanced electrolyte and electrode systems can enable operation to temperatures as low as -70 C, with capacities similar to room temperature values accompanied by reasonably low equivalent series resistances. This presentation will provide an overview of recent development efforts to extend and improve the wide temperature performance of these devices.

energy storage↗

Low Temperature Double-layer Capacitors with Improved Energy Density: An Overview of Recent Development Efforts

Electrochemical double-layer capacitors are finding increased use in a wide range of energy storage applications, particularly where high pulse power capabilities are required. Double-layer capacitors store charge at a liquid/solid interface, making them ideal for low temperature power applications, due to the facile kinetic processes associated with the rearrangement of the electrochemical double-layer at these temperatures. Potential low temperature applications include hybrid and electric vehicles, operations in polar regions, high altitude aircraft and aerospace avionics, and distributed environmental and structural health monitoring. State-of-the-art capacitors can typically operate to -40 C, with a subsequent degradation in power performance below room temperature. However, recent efforts focused on advanced electrolyte and electrode systems can enable operation to temperatures as low as -70 C, with capacities similar to room temperature values accompanied by reasonably low equivalent series resistances. This presentation will provide an overview of recent development efforts to extend and improve the wide temperature performance of these devices.

Supercapacitors↗

Natural Environment Corrosion Testing at the Kennedy Space Center Beachside Atmospheric Corrosion Test Site

This presentation will provide an overview of how NASA has been conducting corrosion testing in the Natural Marine Environment at the Kennedy Space Center, Florida, U.S. The following questions will be addressed: What factors should be considered when selecting and constructing a test site? What are the attributes of a good test site? Is more severe always better? What environmental parameters should be monitored? How frequently? What factors should be considered when designing test specimens? Are current test standards sufficient? How do diurnal, annual and other fluctuations in corrosivity influence tests? How are test results interpreted? Can they be quantified?

Corrosion↗

Networked Array Recorder (NeAR) Microphones for Field-Deployed Phased Arrays

An innovative edge-computing concept known as NeAR (Networked Array Recorder) has been developed to provide enhancements to existing field-deployable microphone phased arrays utilized for aeroacoustic flyover measurements of airframe and propulsive noise sources. The proposed system allows for the elimination of multiple miles of sensor wiring in an array installation, thereby improving the scalability of the overall system, increasing the fault-tolerance of the hardware, and reducing the effort needed to build-up and tear-down an array in the field. A demonstration of the NeAR concept was performed at Edwards Air Force Base in California in March – April, 2018, where twelve individual NeAR microphones were deployed as a piggyback on a conventional phased array system deployed for airframe noise flyover testing. The microphones operated successfully during the demonstration with good time history and spectral correlations shown between the NeAR units and conventional microphones located nearby in the array. The NeAR concept has spinoffs beyond its use for phased arrays, including applications in remote environmental sensing and noise monitoring.

Cull.iton, William G.↗

Preface, special issue of “20th Anniversary of Terra Science”

The Terra satellite, launched in December 1999 as the flagship mission of the Earth Observing System, is an international mission carrying instruments developed by the United States, Japan, and Canada. These instruments, the Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER), Clouds and Earth’s Radiant Energy System (CERES), Multi-angle Imaging SpectroRadiometer (MISR), Moderate-resolution Imaging Spectroradiometer (MODIS), and Measurements of Pollution in the Troposphere (MOPITT), provide valuable observations to investigate the interconnections between Earth's land, atmosphere, ocean, snow and ice, and energy balance, and have yielded the first global and seasonal measurements of the Earth system for long-term monitoring of climate and environmental change. Over the past 20 years and with more than 100,000 orbits, Terra’s observations have greatly enhanced our understanding of the Earth's climate and the effects of human activity and natural disasters on communities and ecosystems.

Lahouari Bounoua↗

Great Salt Lake Health & Air Quality: Monitoring Lakebed Exposure and its Impact on Air Quality and Environmental Hazards in the Great Salt Lake Watershed

The Great Salt Lake (GSL) is a terminal saline lake located in northern Utah, USA. Water inflow has declined rapidly over the last forty years due to human withdrawals and climate change. Lake levels have been lowered which has exposed over 50% of the lakebed to erosion. There is a public health risk tied to the subsequent increased frequency and intensity of regional dust storms caused by airborne lakebed dust under specific meteorological conditions.

Piper Christian↗

Great Salt Lake Health & Air Quality: Monitoring Lakebed Exposure and its Impact on Air Quality and Environmental Hazards in the Great Salt Lake Watershed

The Great Salt Lake (GSL) is a terminal saline lake located in northern Utah, USA. Water inflow has declined rapidly over the last forty years due to human withdrawals and climate change. Lake levels have been lowered which has exposed over 50% of the lakebed to erosion. There is a public health risk tied to the subsequent increased frequency and intensity of regional dust storms caused by airborne lakebed dust under specific meteorological conditions.

Piper Christian↗