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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Orbital controlled band gap engineering of tetragonal BiFeO 3 for optoelectronic applications
Bismuth ferrite BiFeO 3 (BFO) is an important ferroelectric material for thin-film optoelectronic sensing and potential photovoltaic applications. Its relatively large band gap, however, limits the conversion efficiency of BFO absorber-based PV devices. In this study, based on density functional theory calculations we demonstrate that with well-designed Fe-site elemental substitution, tetragonal BFO can exhibit a much lower fundamental band gap than conventional rhombohedral BFO without forming in-gap electronic states and unravel the underlying mechanisms. Cation atomic size, electronegativity, and crystallographic symmetry are evidenced as critical parameters to tailor the metal 3d – oxygen 2p orbital interactions and thus intrinsically modify electronic structure, particularly, the shape and character of the valence and conduction band edges. With reduced band gap, improved mobility, and uncompromised ferroelectric and magnetic ground states, the present results provide a new strategy of designing high symmetry BFO for efficient optoelectronic applications.
Electronic structure and magnetism in g-C{sub 4}N{sub 3} controlled by strain engineering
Regulation of magnetism and half-metallicity has attracted much attention because of its potential in spintronics. The magnetic properties and electronic structure of graphitic carbon nitride (g-C{sub 4}N{sub 3}) with external strain are determined theoretically based on the density function theory and many-body perturbation theory (G{sub 0}W{sub 0}). Asymmetric deformation induced by uniaxial strain not only regulates the magnetic characteristics but also leads to a transformation from half-metallicity to metallicity. However, this transition cannot occur in the structure with symmetric deformation induced by biaxial strain. Our results suggest the use of strain engineering in metal-free spintronics applications.
Effects of Exhaust Gas Recirculation and Boost Pressure on Reactivity Controlled Compression Ignition Engine at High Load Operating Conditions
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Nano-microstructural control of phonon engineering for thermoelectric energy harvesting
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Poly(oxymethylene) Ethers as a High Cetane, Low Sooting Biofuel Blendstock for Use in Medium to Heavy Duty Mixing Controlled Compression Ignition Engines
Compression ignition (CI) engines are currently the most common prime mover for medium and heavy duty vehicles; these engines contribute roughly a quarter of US greenhouse gas emissions from transportation, and even higher percentages of particulate and nitrogen oxide emissions. As a result, there have been significant efforts made to reduce these emissions, particularly through selection of low-emissions alternative fuels. Oxymethylene ethers (OMEs) are a class of molecule, typically structured R-O-(CH2O)n-R', which have been considered as a possible blendstock in CI fuels for the goal of soot reduction. Generally, past work has focused on methyl-terminated OMEs, CH3-O-(CH2O)n-CH3, which by virtue of containing no C--C bonds, produce negligible soot. These molecules show significant reductions in soot emission from engines when blended in moderate to high ratios with traditional diesels, however, they have been shown to have inferior physical properties and poor compatibility with some legacy systems. Recent theoretical work has shown that OMEs with non-methyl alkyl groups may have superior performance, albeit at the cost of increased soot formation. In this work, a variety of OMEs with terminating alkyl groups from methyl to butyl are considered for their suitability as CI fuels. The synthesis of these extended OMEs is studied, including formation of n=1 OMEs from common chemical sources, and extension of the chain length to heavier molecules, via reactions over acidic ion exchange resins. Following the synthesis, the properties of these OMEs are studied with respect to their engine applicability. It is found that heavier (propyl- and butyl-terminated) OMEs have superior properties for diesel compatibility, particularly in reactivity, volatility, and water solubility. Extended-alkyl OMEs are found to have higher soot production than methyl-terminated OMEs, but remain superior to diesel soot production on a per-unit-energy basis. A sample of a butyl-terminated OME mixture, n=2-4, is selected as the ideal OME blend for close compatibility with legacy diesel systems. This mixture is blended with certified diesel and tested for ASTM D975 compatibility, passing all required tests but lubricity; decreased heat of combustion is observed but not governed by the diesel standard. Fundamental combustion tests of various mid-weight OMEs are performed in a rapid compression machine, where it is shown that low-temperature chemistry causes a region of decreased dependence of ignition delay on temperature, consistent with methyl-terminated OME behavior. An isopropyl-terminated OME is observed to have low reactivity compared to other OMEs; this fuel is investigated via further rapid compression machine testing and CFR engine testing. It is found that this OME has strong negative-temperature-coefficient ignition behavior - a first for OMEs - and has reactivity lower than other OMEs, but insufficient for direct spark ignition engine testing.
Computerized parts list system coordinates engineering releases, parts control, and manufacturing planning
Computerized parts list system compiles and summarize all pertinent and available information on complex new systems. The parts list system consists of three computer subroutines - list of parts, parts numerical sequence list, and specifications list.
ATM optical contamination study - Reaction control system rocket engine space plume flow fields Interim report
Apollo telescopic experiment contamination by space vehicle exhaust products
New model performance index for engineering design of control systems
Performance index includes a model representing linear control-system design specifications. Based on a geometric criterion for approximation of the model by the actual system, the index can be interpreted directly in terms of the desired system response model without actually having the model's time response.
Control vane for engine exhaust flow
Vane solves problem of hot-gas exhaust impingement on curved-duct exteriors, shielding, and other nearby structure components. To eliminate secondary egress of exhaust, curved vane is placed upstream of engine exhaust duct and in close proximity to exhaust exit to induce free-stream flow more in line with exit.
Modular instrumentation system for real-time measurements and control on reciprocating engines
An instrumentation system was developed for reciprocating engines. Among the parameters measured are the indicated mean effective pressure, or theoretical work per cycle, and the mass fraction burn rate, a measure of the combustion rate in the cylinder. These computations are performed from measured cylinder pressure and crankshaft angle and are available in real time for the experimenter. A 100 or 200 consecutive-cycle sample is analyzed to reduce the effect of cyclic variations in the engine. Data are displayed in bargraph form, and the mean and standard deviation are computed. Other instruments are also described.
Phase-angle controller for Stirling engines
An actuator includes a restraint link adapted to be connected with a pivotal carrier arm for a force transfer gear interposed between the crankshaft for an expander portion of a Stirling engine and a crankshaft for the displacer portion of the engine. The restraint link is releasably trapped hydraulic fluid for selectively establishing a phase angle relationship between the crankshaft. A second embodiment incorporates a hydraulic coupler for use in varying the phase angle of gear-coupled crank fpr a Stirling engine whereby phase angle changes are obtainable.
A new approach to soot control in Diesel engines by fuel-drop charging
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Application of polynomial techniques to multivariable control of jet engines
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Alternatives for linear multivariable control with turbofan engine theme problem
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Computer-controlled xenon ion engine operation
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Electric auxiliary power unit for Shuttle evolution
The Space Shuttle Orbiter currently uses three hydrazine fueled auxiliary power units (APUs) to provide hydraulic power for the vehicle aerodynamic surface controls, main engine thrust vector control, landing gear, steering, and brakes. Electric auxiliary power units have been proposed as possible replacements to the hydrazine auxiliary power units. Along with the potential advantages, this paper describes an Electric APU configuration and addresses the technical issues and risks associated with the subsystem components. Additionally, characteristics of an Electric APU compared to the existing APU and the direction of future study with respect to the Electric APU is suggested.