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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,045 records · Page 58
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

Study of the effects of gaseous environmental on the hot corrosion of superalloy materials

Studies have been conducted to examine the effect of low concentrations of NaCl(g) on the high temperature oxidation behavior of complex superalloys and potential coating formulations modified by silicon and reactive element (i.e., yttrium and hafnium) additions. Depending on alloy composition, a variety of effects were thermogravimetrically produced. Aluminum free alloys such as MAR-M509 and Hastelloy X with molybdenum and tungsten in solid solution showed accelerated (or breakaway) kinetics similar to that observed for Ni-Cr alloys. For IN-792, an alloy high in chromium and low in aluminum, molybdenum and tungsten present in solid solution does not adversely affect oxidation kinetics in the presence of NaCl(g). On the other hand, nickel-base alloys high in aluminum and molybdenum are catastrophically attacked by NaCl-bearing atmospheres. Silicon additions were, in general, observed to slightly improve the oxidation resistance of Ni, Ni-40Cr and CoCrAlY compositions in NaCl(g)-bearing atmospheres. To the degree that processes responsible for Al2O3 whisker formation deleteriously affect protective scale adherence, the addition of yttrium or hafnium can inhibit such whisker growth.

Smeggil, J. G.↗
NASA NTRS1989

Electrocatalysts for oxygen electrodes in fuel cells and water electrolyzers for space applications

In most instances separate electrocatalysts are needed to promote the reduction of O2 in the fuel cell mode and to generate O2 in the energy storage-water electrolysis mode in aqueous electrochemical systems operating at low and moderate temperatures (T greater than or equal to 200 C). Interesting exceptions are the lead and bismuth ruthenate pyrochlores in alkaline electrolytes. These catalysts on high area carbon supports have high catalytic activity for both O2 reduction and generation (1,2). Rotating ring-disk electrode measurements provide evidence that the O2 reduction proceeds by a parallel four-electron pathway. The ruthenates can also be used as self-supported catalysts to avoid the problems associated with carbon oxidation, but the electrode performance so far achieved in the research at Case Western Reserve University (CWRU) is considerably less. At the potentials involved in the anodic mode the ruthenate pyrochlores have substantial equilibrium solubility in concentrated alkaline electrolyte. This results in the loss of catalyst into the bulk solution and a decline in catalytic activity. Furthermore, the hydrogen generation counter electrode may become contaminated with reduction products from the pyrochlores (lead, ruthenium). A possible approach to this problem is to immobilize the pyrochlore catalyst within an ionic-conducting solid polymer, which would replace the fluid electrolyte within the porous gas diffusion O2 electrode. For bulk alkaline electrolyte, an anion-exchange polymer is needed with a transference number close to unity for the Oh(-) ion. Preliminary short-term measurements with lead ruthenates using a commercially available partially-fluorinated anion-exchange membrane as an overlayer on the porous gas-fed electrode indicate lower anodic polarization and virtually unchanged cathodic polarization.

Prakash, Jai↗
NASA NTRS1989

Ionospheric dynamo theory for production of far ultraviolet emissions on Uranus

A model is presented to explain diffuse FUV emissions from the outer planets, specifically Uranus, in excess of those diffuse emissions that are currently explainable by scattering of sunlight and/or excitation by photoelectrons. These electroglow emissions in H Ly-alpha and H2 bands, which occur in the sunlit hemisphere slightly above the homopause, appear to require particle excitation in the 10- to 50-eV range. An in situ mechanism for accelerating photoelectrons (and ions is proposed, involving neutral wind dynamo generation of field-aligned currents analogous to what occurs in the earth's equatorial E and F regions. Sufficiently strong field-aligned currents are found in the model calculation for Uranus to produce a potential drop of about 100 eV or greater between the F peak and homopause, concentrated at lower altitudes, and capable in principle of accelerating photoelectrons (and ions) to the 10- to 50-eV energies required to explain the observed emissions. The fact that the excitation and ionization cross sections are larger than elastic scattering cross sections in an H2 atmosphere at these energies makes in situ acceleration feasible for the production of UV on the outer planets.

Hudson, M. K.↗
NASA NTRS1989

Electrocatalysis for oxygen electrodes in fuel cells and water electrolyzers for space applications

In most instances separate electrocatalysts are needed to promote the reduction of O2 in the fuel cell mode and to generate O2 in the energy storage-water electrolysis mode in aqueous electrochemical systems operating at low and moderate temperatures (T greater than or equal to 200 C). Interesting exceptions are the lead and bismuth ruthenate pyrochlores in alkaline electrolytes. These catalysts on high area carbon supports have high catalytic activity for both O2 reduction and generation. Rotating ring-disk electrode measurements provide evidence that the O2 reduction proceeds by a parallel four-electron pathway. The ruthenates can also be used as self-supported catalysts to avoid the problems associated with carbon oxidation, but the electrode performance so far achieved in the research at Case Western Reserve University (CWRU) is considerably less. At the potentials involved in the anodic mode the ruthenate pyrochlores have substantial equilibrium solubility in concentrated alkaline electrolyte. This results in the loss of catalyst into the bulk solution and a decline in catalytic activity. Furthermore, the hydrogen generation counter electrode may become contaminated with reduction products from the pyrochlores (lead, ruthenium).

Prakash, Jai↗
NASA NTRS1990

HgZnTe-based detectors for LWIR NASA applications

The initial goal was to grow and characterize HgZnTe and determine if it indeed had the advantageous properties that were predicted. Researchers grew both bulk and liquid phase epitaxial HgZnTe. It was determined that HgZnTe had the following properties: (1) microhardness at least 50 percent greater than HgCdTe of equivalent bandgap; (2) Hg annealing rates of at least 2 to 4 times longer than HgCdTe; and (3) higher Hg vacancy formation energies. This early work did not focus on one specific composition (x-value) of HgZnTe since NASA was interested in HgZnTe's potential for a variety of applications. Since the beginning of 1989, researchers have been concentrating, however, on the liquid phase growth of very long wavelength infrared (VLWIR) HgZnTe (cutoff approx. equals 17 microns at 65K) to address the requirements of the Earth Observing System (EOS). Since there are no device models to predict the advantages in reliability one can gain with increased microhardness, surface stability, etc., one must fabricate HgZnTe detectors and assess their relative bake stability (accelerated life test behavior) compared with HgCdTe devices fabricated in the same manner. Researchers chose to fabricate HIT detectors as a development vehicle for this program because high performance in the VLWIR has been demonstrated with HgCdTe HIT detectors and the HgCdTe HIT process should be applicable to HgZnTe. HIT detectors have a significant advantage for satellite applications since these devices dissipate much less power than conventional photoconductors to achieve the same responsivity.

Patten, Elizabeth A.↗
NASA NTRS1994

Optically Addressable Spatial Light Modulators

Integrated multiple-quantum-well/Fabry-Perot structure provides high-contrast variation of reflection of reading beam, under control of writing beam. Periodic potential barriers separate photogenerated electrons from holes, leading to long recombination lifetimes and large concentrations of free charge carriers. Concentrations quench excitons or fill energy bands in quantum wells, altering absorption of reading beam.

Maserjian, Joseph↗
NASA NTRS1996

Silicon Carbide Transistor For Detecting Hydrocarbon Gases

Proposed silicon carbide variable-potential insulated-gate field-effect transistor specially designed for use in measuring concentrations of hydrocarbon gases. Devices like this prove useful numerous automotive, industrial, aeronautical, and environmental monitoring applications.

Shields, Virgil B.↗
NASA NTRS2000

Electrical Charging Hazards Originating from the Surface (ECHOS): Understanding the Martian Electro-Meteorological Environment

In 1999, the NASA/Human Exploration and Development of Space (HEDS) enterprise selected a number of payloads to fly to the Martian surface in an 03 opportunity (prior to the MPL loss). Part of a proposed experiment, ECHOS, was selected to specifically understand the electrical charging hazards from tribocharged dust in the ambient atmosphere, in dust devils, and in larger storms. It is expected that Martian dust storms become tribocharged much like terrestrial dust devils which can possess almost a million elementary charges per cubic centimeter. The ECHOS package features a set of instruments for measuring electric effects: a radio to detect AC electric fields radiating from discharges in the storm,a DC electric field system for sensing electrostatic fields from concentrations of charged dust grains, and a lander electrometer chain for determining the induced potential on its body and MAV (Mars Ascent Vehicle) during the passages of a charged dust storm. Given that electricity is a systemic process originating from wind-blown dust, we also proposed to correlate the electrical measurements with fundamental fluid/meteorological observations, including wind velocity and vorticity, temperature, and pressure. Triboelectricity will also affect local chemistry, and chemical-sensing devices were also considered a feature of the package. The primary HEDS objectives of the ECHOS sensing suite is to discover and monitor the natural electrical hazards associated with dust devils and storms, and determine their enviro-effectiveness on human systems. However, ECHOS also has a strong footprint in the overarching science objectives of the Mars Surveyor Program.

Farrell, W. M.↗
NASA NTRS1988

Kinetics of determination in the differentiation of isolated mesophyll cells of Zinnia elegans to tracheary elements

Mechanically isolated mesophyll cells of Zinnia elegans L. cv Envy differentiate to tracheary elements when cultured in inductive medium containing 0.5 micromolar alpha-naphthaleneacetic acid and 0.5 micromolar benzyladenine. The cells do not differentiate when cultured in medium in which the concentration of auxin and/or cytokinin has been reduced to 0.005 micromolar. Cells require an initial 24-hour exposure to inductive cytokinin and 56-hour exposure to inductive auxin for differentiation at 72 hours of culture. Freshly isolated Zinnia cells can be maintained in medium having low concentrations of both auxin and cytokinin for only 1 day without significant loss of potential to differentiate upon transfer to inductive medium. Initial culture for up to 2 days in medium having high auxin and low cytokinin, or low auxin and high cytokinin, allows full differentiation on the third day after transfer to inductive medium and potentiates the early differentiation of some cells.

Non-NASA Center↗
NASA NTRS2007

The Headache of Carbon Dioxide Exposures

Carbon dioxide (CO2), a natural product of human metabolism, accumulates quickly in sealed environments when humans are present, and can induce headaches, among other symptoms. Major resources are expended to control CO2 levels to concentrations that are tolerable to the crews of spacecraft and submersible craft. It is not practical to control CO2 levels to those found in the ambient environment on earth. As NASA looks ahead to long-duration missions conducted far from earth, difficult issues arise related to the management and effects of human exposure to CO2. One is the problem of pockets of CO2 in the habitat caused by excess generation of the gas in one location without a mechanism to purge the area with fresh air. This results in the crew rebreathing CO2 from their exhaled breath, exposing them to a much higher concentration of CO2 than whole-module measurements would suggest. Another issue is the potential increased sensitivity to CO2 in microgravity. For example, based on anecdotal information, it appears that space crews may be more susceptible than submarine crews to some of the subtle, yet adverse effects of CO2 exposure. Another issue, not unique to spaceflight, is the possibility of inter-individual differences in the susceptibility of crewmembers to CO2 exposure. Again, anecdotal reports from the International Space Station (ISS) crews suggest that certain individuals may experience a greater susceptibility. The implications associated with these issues are extremely important as NASA sets CO2 exposure limits that protect the crew from this compound s subtle adverse effects, without causing an unwarranted expenditure of resources to scrub CO2 from the habitat atmosphere.

James, John T.↗
NASA NTRS2022

Europan Molecular Indicators of Life Investigation (EMILI) for a Future Europa Lander Mission

The Europan Molecular Indicators of Life Investigation (EMILI) is an instrument concept being developed for the Europa Lander mission currently under study. EMILI will meet and exceed the scientific and technical/resource requirements of the organic composition analyzer identified as a core instrument on the Lander. EMILI tightly couples two complementary analytical techniques, based on 1) liquid extraction and processing with capillary electrophoresis and 2) thermal and chemical extraction with gas chromatography, to robustly detect, structurally characterize, and quantify the broadest range of organics and other Europan chemicals over widely-varying concentrations. Dual processing and analysis paths enable EMILI to perform a thorough characterization of potential molecular biosignatures and contextual compounds in collected surface samples. Here we present a summary of the requirements, design, and development status of EMILI with projected scientific opportunities on the Europa Lander as well as on other potential life detection missions seeking potential molecular biosignatures in situ.

Europa↗
NASA NTRSDate not supplied

Plasma Assisted Nutrient Recovery from Inedible Biomass via Ash Leaching

Sustaining a human presence on the Moon, Mars, or deep space will require closing loops on many life support systems. Some form of agriculture will be required because plants produce the vitamins, antioxidants, and essential oils in our diets that degrade over time in stored foods. In addition, they provide dietary fiber, revitalize air and purify water. It is estimated that 93 kg of plant nutrients are required to support one crew member per year. Growing plants will require recycling nutrients trapped in inedible plant stems, leaves and debris. We examined the effects of using thermal plasma and various carrier gases to breakdown inedible plant biomass and aid in nutrient recovery. Previous work demonstrated a thermally degrading environment such as a muffle furnace improved nutrient recovery from inedible biomass prior to an acid leaching process, however, a muffle furnace is an inefficient process. We tested the ability of a small scale, thermal plasma using carbon dioxide, nitrogen, or air as plasma carrier gases to degrade pelleted plant biomass. The gases were chosen to explore variations in recovery and potential chemical by-products. Plasma treated and untreated biomass was leached with different concentrations of acid to determine the extraction of nutrients (potassium, magnesium, calcium, and. phosphorus) for reuse in the crop production cycle. Results are presented showing the impact of plasma processing prior to acid leaching on recovery of plant nutrients.

Plasma↗
NASA NTRSDate not supplied

Evaluation of the Maximum Soluble Water Recovery from Pretreated Urine Brines in Low Earth Orbit

The Urine Processor Assembly (UPA) on the International Space Station recovers water from pretreated urine by thin-film, vacuum compression distillation (VCD). A number of iterative improvements to the distiller assembly (DA) have enabled increases in on-orbit water recovery and improved distillate water quality at on-orbit recoveries up to 87% by volume relative to the volume of pretreated urine. The phosphoric acid-based pretreatment formulation has enabled these higher recoveries on-orbit since May of 2016. Application of simple empirical chemistry models have allowed water recovery of sulfuric-acid pretreated urine from the Russian Orbiting segment to be distilled with phosphoric acid pretreated urine from the U.S. Orbiting Segment. Returned liquid brine from brine filters in the UPA brine loop have enabled empirical measurement of gypsum solubility as a function of recovery, conductivity, or mass density in the real brines of ISS. Calculations of maximum soluble recovery, MSR, are based on preventing the precipitation of gypsum, which is the first mineral to precipitate for both types of pretreated urine. A statistical urine model of urine composition provides an estimate of worst-case urine from a crew of three during one year of operations on ISS. The MSR is defined based on the worst-case concentrations of urinary calcium and urinary sulfate that are pretreated, pooled, and distilled. The potential to increase water recoveries above 87% without gypsum precipitation are evaluated. The potential benefits and costs of the addition of a conductivity sensor or a Coriolis mass flow meter to the brine loop are evaluated.

Dean L Muirhead↗
DOE OSTI2022

Study of Classifiers for U-235 Source Signatures Using Gamma Spectral Measurements

Signatures associated with low-level U-235 sources are studied from a classification analytics perspective, using NaI gamma-ray spectral measurements from detectors located at various distances from the source. Data sets collected at a shielded facility are utilized, wherein the source is introduced via a conduit into a formation of 21 NaI detectors deployed over 6 x 6 meters area in a formation of two concentric circles and one spiral. The activity levels in the spectral regions associated with potential U-235 signatures are estimated as counts at 1 second intervals, and are used as features to train classifiers for detecting the presence of the source. Eight different classifiers are trained and tested using the background and source measurements collected over multiple experimental runs. As expected, the classifier performance improved overall as measurements from the detectors closer to source are used, but also revealed unexpectedly low performance by two detectors that are identically produced and configured as others. Six of eight classifiers have an overall comparable performance, for example, three of them achieved zero training error and 99% detection at 4% false alarm rate for a detector located 1.3 meters away from the source. Also, larger training sets led to improved classification performance across all classifiers, and interestingly, the classifiers with the minimum training error did not necessarily achieve the highest classification performance on test data.

Rao, Nageswara↗
DOE OSTI2024

Kick Signatures Through Advanced Multi-Phase Data

Existing downhole geophysical sensors, like those used in LWD, offer an opportunity for early kick detection, but they are not currently used for detection or characterization. Downhole acoustic measurements also have the potential for providing reliable gas leak detection based on their high sensitivity to low concentrations of gas present in a gas-liquid mixture. This effort seeks to close a data knowledge gap through numerical simulation and use this data to aid in development of a low-cost, fast, and reliable early kick detection technology for preventing blowouts based on the acoustic signature.

Carney, Janine↗
DOE OSTI2024

Elucidating the corrosion mechanism of commercial Ni-based Superalloys in UCl3 containing-chloride Molten Salt Systems

Molten salt reactors (MSRs) have gained renewed interest, providing several advantages over their predecessors, including the capability to consume spent fuels, enhancing the environmental sustainability of the uranium fuel cycle. For example, molten chloride fast reactors (MCFRs) can reach criticality with molten chloride spent fuel containing high concentrations of impurities, such as actinide products like uranium chloride (UCl3). However, the redox potential of chloride molten salt fuels may change in the presence of these impurities, dictating their corrosivity and in turn the corrosion performance of structural components, such as those constructed from nickel (Ni)-based alloys. The purpose of this investigation is to assess the extent of corrosion of Ni-based alloy, Inconel 617, when exposed to UCl3-LiCl-KCl eutectic salt. Inconel 617 one of only six structural materials that are fully qualified by the American Society for Mechanical Engineers (ASME) Boiler and Pressure Vessel Code for high-temperature nuclear reactor components, making it a technologically mature material to consider for constructing MCFRs. Inconel 617 specimens were submerged in a static LiCl-KCl-UCl3 eutectic salt mixture heated at 700 C for 1000 h under an inert atmosphere. Upon completion, the extent of corrosion was analyzed through a multi-modal characterization approach spanning the engineering to nanoscale, employing computed tomography, focused-ion beam, and transmission electron microscopy techniques. Results from this investigation will enhance our understanding of property-to-performance relationships of candidate structural materials for MSRs with respect to corrosion resistance and interactions between the salt and alloy interface.

36 MATERIALS SCIENCE↗
DOE OSTI2022

A review study of rare Earth, Cobalt, Lithium, and Manganese in Coal-based sources and process development for their recovery

The world’s majority predominantly relies on foreign sources for supplying critical minerals. This renders the countries susceptible to supply chain disruption and urges them to develop alternative sources to compete in technological advancements. Among many proven newly identified sources, coal and coal-based materials present their opportunities. Due to the complex structure of coal, many mineral forms can be found in coal-related sources, including critical element-containing minerals. Among the fifty critical elements and minerals defined by the USGS, the rare earth elements, cobalt, lithium, and manganese, are particularly significant as they have enormous importance in high-technology product development. These critical metals can be found in high concentrations in coal-derived sources, such as coal refuse, coal combustion products, and coal acid mine drainage, and be recovered through various separation techniques. Further, this study aims to advance the understanding of these elements' extraction and commercial potential from coal and coal-related sources and help address the world's challenges in the critical mineral supply chain. The concentrations and occurrences of these four commodities in coal-related sources were first reviewed. Later, their recovery processes were discussed, and a conceptual process flowsheet was proposed to selectively recover the rare earth elements, lithium, cobalt, and manganese from coal-based sources.

58 GEOSCIENCES↗