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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,045 records · Page 58
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Performance Test Code for Determining and Reporting Annual Heat Rate and CO2 for Coal Fueled EGUs

This material is based upon work supported by the Department of Energy under Award Number DEFE0031933. The US Department of Energy (DOE) has retained the services of ASME Standards Technology LLC (ASME ST-LLC) to develop a standardized test method and calculation protocol for determining and reporting annual/long-term heat rate for coal-fueled plants electricity generating units. ASME ST-LLC has retained the services of McHale & Associates, Inc. and Licata Energy & Environmental Consultants, Inc. to provide the technical input to this study. This code applies to hydrocarbon fueled Rankine cycle power generating facilities of any size. It is intended to be used for the determination of continuous power output and heat rate of a generating facility in its operating load cycle and in its operational lineup during the reporting period.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2023

Pulverized Coal CO2 Capture Retrofit Database

This tool provides high-level analysis on the incremental costs for retrofitting pulverized coal plants with carbon dioxide capture and/or compression systems. Options are available to include costs of other technological improvements that would be required to comply with various environmental regulations when installing carbon capture technology. This model is based on the NETL report "Eliminating the Derate of Carbon Capture Retrofits." (2023). For the Excel spreadsheet tools associated with this report, please go to https://www.netl.doe.gov/energy-analysis/details?id=e7e822ff-18ac-4bc6-a052-0be3521b8789

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2023

Extension of Argonne’s Plant Dynamics Code (PDC) Capabilities to TerraPower Direct-Cycle Supercritical CO2 (“Pascal”) Nuclear Reactor Concept. Final CRADA report

Argonne National Laboratory (the Contractor) and TerraPower, LLC, (the Participant), entered into a Cooperative Research and Development Agreement (CRADA) to extend the Plant Dynamics Code (PDC) to model the Pascal reactor plant. PDC is the system-level computer code developed at Argonne, primarily for design and transient analysis of supercritical carbon dioxide (sCO2) energy conversion systems for various power plants. Pascal is a supercritical carbon dioxide (sCO2)-cooled direct-cycle nuclear power reactor under development by TerraPower. New features were added to the code to model components and systems specific to the Pascal plant and to make the code readily available as a tool for design, control, and safety analysis for this and other direct-cycle power plants. TerraPower provided design information of the Pascal reactor and the requirements for the development of the new PDC features. Argonne modified the PDC capabilities to introduce the new features.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2023

Conversion of Syngas and CO2 to Light Olefins using Multi-Functional Catalysts

This report describes our effort in developing a novel zeolite encapsulated metal nanoparticle catalyst for the conversion of syngas to light olefins. We have adopted a ligand assisted synthesis protocol in which first metal-amine was prepared using metal salts and suitable amine ligands. The stable metal-amine complex thus prepared was then used as the seed for the growth of zeolite in alkaline solution. We have optimized the synthesis condition as well as different amine ligand to identify the condition to obtain stable metal-amine complex. Upon synthesis of zeolite, metal particles are encapsulated inside the zeolite in a confined space. We have synthesized both Fe and Co catalyst inside silicalite and chabazite zeolite. Catalytic activity of these catalysts were evaluated for syngas conversion reaction and compared with a baseline catalyst. The activity trend of zeolite encapsulated catalyst show very different activity trend compared to the baseline catalyst. While a distribution of products with different carbon number was obtained with baseline catalyst, zeolite encapsulated catalyst show ethylene as the major product. While ~73% selectivity to C 2 -C 6 products were obtained with cahabazite encapsulated Fe catalyst, only 53% selectivity was obtained for the corresponding products with silica-alumina supported Fe catalyst. Not only higher selectivity, Fe-chabazite also produces only C 2 products (ethylene/ethane) while a distribution of products was obtained with Fe-SiAl catalyst. The significantly different reactivity associated with the chabazite encapsulated Fe catalyst was attributed to the confinement effect. We hypothesized that due to the small size of the pore, only ethylene was obtained as the product.

10 SYNTHETIC FUELS↗
DOE OSTI2024

Development of Transformational Solvents for CO2 Separations

The primary objective of this CRADA activity is to use a combined molecular modeling and experimental validation approach to refine and develop transformational solvents for carbon capture. PNNL’s role on this project is currently funded by the Department of Energy’s (DOE) Office of Fossil Energy (OFE). PNNL is developing advanced molecular modeling based on their CO2BOLs solvent platform as a demonstration solvent for the activity; the model was developed and compared against measured data for CO2BOL derivatives. Here, a CRADA with PNNL and GE will leverage their current molecular models and apply them to solvent classes that operate on carbamate chemistry, specifically GE’s aminosilicone solvent class. The molecular models will be used to predict physical and thermodynamic properties, such as viscosity, as a means to predict advanced formulations with reduced viscosity compared to current aminosilicone derivatives, enabling optimized thermodynamic and kinetic metrics for economical carbon capture for this class of materials. Together, PNNL and GE will develop a comprehensive means of linking molecular modeling parameters to intermediate physical properties as a means to improve solvent performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Novel microbial based enzymatic CO2 fixation mechanisms: Conformational control of enzymatic reactivity

The broad, long-term goal of the research is to provide insight into the mechanism of novel carboxylation and electron bifurcation reactions as paradigms to study how enzyme utilized protein conformational change to protect reactive intermediates and/or control the pathway in a catalytic cycle. catalyzed by enzymes involved in bacterial alkene, ketone, and epoxide metabolism. We are examining two paradigms in which conformational change is a key mechanistic feature of 1) protecting reaction intermediates that are sensitive to breakdown in the presence of water and 2) directing electron flow in reactions that split electron pairs along two pathways in reactions that fine tune metabolic efficiency in microbial metabolism. Both paradigms are of key importance in defining the molecular determinants of reactions relevant to CO 2 capture and fuel upcycling. In the first paradigm the compounds acetone and bicarbonate are activated by the addition of phosphate creating reaction intermediates (phosphoenolacetone and carboxyphosphate) that are very sensitive to breakdown in the presence of water. We are studying the mechanism of how the enzyme protects these reactive intermediates from water by encapsulating them upon their formation within a hydrophobic protein channel leading to an enzyme active site approximately 40 Å away. In the second paradigm, we are examining how the direction of electron transfer reactions can be modulated through protein conformational change that alters either the difference driving force or distance or both between electron transfer pathways in enzymes that catalyze electron bifurcation. We are using a combination of enzyme kinetics, mass spectrometry, spectroscopy, and structural analysis through X-ray diffraction and scattering methods to characterize the mechanism of conformational changes along the catalytic path. Within the context of the mission of the Department of Energy and the core activities of the Energy Biosciences, the results obtained in the study will reveal new insights into the fundamentals of novel carboxylation / CO 2 capture chemical transformations and electron transfer reactions that equate to biological fuel upcycling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗