Identification of a cellularly active SIRT6 allosteric activator
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Here, we developed a simultaneous spin-coating/solvent-annealing process and demonstrated morphology optimization for PTB7 based organic photovoltaics. This novel processing method enhances the edge-on crystalline content in thin films and induces the formation of weak PCBM aggregates. As a result, the efficiency of polymer solar cells increased from 9.2% to a certified high efficiency of 9.61%, owing to an enhanced short-circuit current (J sc , 18.4 mA cm –2 vs. 17. 5 mA cm –2 ) and an improved fill factor.
Metal–organic layers stabilize Fe II or Co II -terpyridine diradical complexes to catalyze alkylazide C sp3 –H amination and benzylic C–H borylation, respectively.
Tunable peptoid assembly directs the control over structure and function of Pd nanomaterial catalysts.
We report an unusual series of discrete iodosyl- and iodoxyarene adducts of Co( ii ) including detailed studies of their O-transfer reactivity and mechanism.