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All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

Overview and Initial Results of DIGMARS: Digging Iceland Geology for Mars Analog Research Science

Preserved in the sedimentary rocks of Mars is a rich record of ancient surface environments and burial diagenesis. Sequences of sandstones and mudstones that indicate sedimentation in deltaic and lacustrine environments have been encountered by the Curiosity rover in Gale crater and likely will be by the Perseverance rover in Jezero crater [1-3]. The compositional variability in these sedimentary rocks points to a complex diagenetic story that bears significantly on the basin history and early martian environment. Because interaction of percolating groundwaters and with unconsolidated sediments is a process commonly observed in lacustrine environments on Earth [4], groundwater has been invoked to develop a sedimentary history for Gale crater [e.g., 5-9]. Unique conceptual models, each with their own implications for the paleoenvironment and hydrologic conditions have been put forward. However, we currently lack a terrestrial reference frame for groundwater-driven diagenesis in a basalt dominated watersheds on Earth. The Digging Iceland Geology for Mars Analog Research Science (DIGMARS) project aims to close this research gap, with the goal of exploring groundwater-sediment interaction from lakes around Iceland. Here, we present the initial results for the 2021 field campaign and the laboratory analysis of aqueous and sediment samples.

M T Thorpe↗
NASA NTRSDate not supplied

The CheMin X-ray Diffractometer on MSL Curiosity: A Decade of Mineralogical Observations from Gale Crater, Mars

For more than a decade, the CheMin X-ray Diffraction instrument on the Mars Science Laboratory rover Curiosity has been returning quantitative mineralogical data from Gale crater, Mars. CheMin receives and analyzes sieved soil and powdered rock samples from Curiosity’s Sample Acquisition / Sample Processing and Handling (SA/SPaH) system. To date, 38 samples have been analyzed over the course of a 28 km transit. These samples document more than 600 vertical meters of flat-lying lacustrine, fluvial and aeolian sediments that comprise the lower part of the central mound of Gale crater (commonly called Mt. Sharp).The principal mineralogy of the sediments is basaltic, with evidence of early and late-stage diagenetic overprinting. The rocks in many cases preserve most of their primary mineralogy and sedimentary features, suggesting that they were never strongly heated or deformed. Using aeolian soil composition as a proxy for the composition of the deposited and lithified sediment, it appears that in many cases the diagenetic changes observed are principally isochemical. Exceptions to this include secondary nodules, calcium sulfate veining and rare alteration halos. A striking hematite-rich feature in lower Mt. Sharp called Vera Rubin Ridge is interpreted to be lake sediment diagenetically altered by silica-poor fluids. A surprising and as yet poorly understood observation is that nearly all of the 3.7 Gyr old sedimentary rocks analyzed to date are comprised of 25-50% X-ray amorphous material. Overall, this 600 m vertical section of sedimentary rock explored in lower Mt. Sharp documents a perennial shallow lake environment grading upward into alternating lacustrine/fluvial and aeolian environments. The mineralogical changes observed going up-section include a transition from trioctahedral to dioctahedral clay minerals and a transition from magnetite to hematite. More recently, in the last 150 m of section, CheMin has documented an overall decrease in clay minerals and increase in Fe3+ oxides and oxyhydroxides. The mineralogical changes observed in Gale crater may document the gradual drying out and oxidation of the martian hydrosphere.

CHEMIN↗
NASA NTRSDate not supplied

To Cage or Not to Cage Seagrass; Is There Even a Question?

To Cage or Not to Cage Seagrass; Is There Even a Question? Loraé T. Simpson1, Morgan K. Gilligan1, Douglas M. Scheidt2 1Florida Oceanographic Society, Stuart, FL; 2Herndon Solutions Group/NEMCON, Kennedy Space Center, FL Contact email: lsimpson@floridaocean.org Diminished water quality has led to the decline of seagrasses and their associated ecosystem services in the Banana River Lagoon (BRL), resulting in increased restoration initiatives. Restoration success may be hindered by herbivory and the addition of herbivore exclusion devices may limit grazing stress on newly established seagrasses. These structures may alter sediment dynamics, influencing seagrass productivity. To test whether herbivore exclusion devices impact restoration success and sediment dynamics, we caged half of our seagrass restoration plots in the BRL. Treatments were monitored monthly for seagrass growth, and at three months for porewater nutrients, sediment bulk density, and carbon to nitrogen ratio. On average, caged plots had 87% more seagrass cover and 81% taller blades than control plots, highlighting the importance of caging newly transplanted seagrasses. There was no significant difference in porewater or sediment characteristics between treatments, suggesting that pedogensis and nutrient cycling need extended monitoring to capture changes in temporal scales.

Indian River Lagoon↗
NASA NTRSDate not supplied

To Cage or Not to Cage Seagrass; Is There Even a Question?

Diminished water quality has led to the decline of seagrasses and their associated ecosystem services in the Banana River Lagoon (BRL), resulting in increased restoration initiatives. Restoration success may be hindered by herbivory and the addition of herbivore exclusion devices may limit grazing stress on newly established seagrasses. These structures may alter sediment dynamics, influencing seagrass productivity. To test whether herbivore exclusion devices impact restoration success and sediment dynamics, we caged half of our seagrass restoration plots in the BRL. Treatments were monitored monthly for seagrass growth, and at three months for porewater nutrients, sediment bulk density, and carbon to nitrogen ratio. On average, caged plots had 87% more seagrass cover and 81% taller blades than control plots, highlighting the importance of caging newly transplanted seagrasses. There was no significant difference in porewater or sediment characteristics between treatments, suggesting that pedogensis and nutrient cycling need extended monitoring to capture changes in temporal scales.

Indian River Lagoon↗
NASA NTRS2022

The 28 November 2020 Landslide, Tsunami, and Outburst Flood – A Hazard Cascade Associated With Rapid Deglaciation at Elliot Creek, British Columbia, Canada

We describe and model the evolution of a recent landslide, tsunami, outburst flood, and sediment plume in the southern Coast Mountains, British Columbia, Canada. On November 28, 2020, about 18 million m3 of rock descended 1,000 m from a steep valley wall and traveled across the toe of a glacier before entering a 0.6 km2 glacier lake and producing >100-m high run-up. Water overtopped the lake outlet and scoured a 10-km long channel before depositing debris on a 2-km2 fan below the lake outlet. Floodwater, organic debris, and fine sediment entered a fjord where it produced a 60+km long sediment plume and altered turbidity, water temperature, and water chemistry for weeks. The outburst flood destroyed forest and salmon spawning habitat. Physically based models of the landslide, tsunami, and flood provide real-time simulations of the event and can improve understanding of similar hazard cascades and the risk they pose. Plain Language Summary Glacier retreat exposes unstable slopes that can suddenly fail. We describe and model one such event with far-reaching consequences. The landslide mass (50 million tonnes, equivalent to the combined mass of all Canadian automobiles) entered and suddenly drained a 0.6-km2 alpine lake in the southern Coast Mountains of British Columbia. Displaced water destroyed salmon-spawning habitat over a distance of 8.5 km and created a plume of sediment and organic matter more than 60 km from the head of the fjord into which the floodwaters discharged. Physically based models are able to simulate the hazard cascade, and such models could be used to improve hazard and risk assessments of these events under future climate change.

M. Geertsema↗
DOE OSTI2019

Experimental Preservation of Muscle Tissue in Quartz Sand and Kaolinite

Siliciclastic sediments of the Ediacaran Period contain exceptionally preserved fossils of macroscopic organisms, including three-dimensional casts and molds commonly found in sandstones and siltstones and some two-dimensional compressions reported in shales. The sporadic and variable associations of these exceptionally preserved macroscopic fossils with pyrite, clay minerals, and microbial fossils and textures complicate our understanding of fossilization processes. This hinders inferences about the evolutionary histories, tissue types, original morphologies, and lifestyles of the enigmatic Ediacara biota. In this work, we investigate the delayed decay of scallop muscles buried in quartz sand or kaolinite for 45 days. This process occurs in the presence of microbial activity in mixed redox environments, but in the absence of thick, sealing microbial mats. Furthermore, microbial processes that mediate organic decay and release the highest concentrations of silica and Fe(II) into the pore fluids are associated with the most extensive tissue decay. Delayed decay and the preservation of thick muscles in sand are associated with less intense microbial iron reduction and the precipitation of iron oxides and iron sulfides that contain Fe(II) or Fe(III). In contrast, muscles buried in kaolinite are coated only by <10 μm-thick clay veneers composed of kaolinite grains and newly formed K- and Fe(II)-rich aluminosilicate phases. Muscles that undergo delayed decay in kaolinite lose more mass relative to the muscles buried in sand and undergo vertical collapse. These findings show that the composition of minerals that coat or precipitate within the tissues and the vertical dimension of the preserved features can depend on the type of sediment that buries the muscles. Similar processes in the zone of oscillating redox likely facilitated the formation of exceptionally preserved macrofossils in Ediacaran siliciclastic sediments.

58 GEOSCIENCES↗
DOE OSTI2024

Using pollen in turbidites for vegetation reconstructions

Turbidites, deposited by sub-aqueous gravity flows, are common in sedimentary archives worldwide and present a unique challenge and opportunity when reconstructing past vegetation through pollen analysis. When sampling pollen from a sediment core for palaeovegetation records, it is common practice to target background sediments (i.e. pelagic sediment) and avoid sampling turbidites, as they are presumed to portray a misleading picture of past vegetation. This assumption stems from our limited understanding of pollen abundance and distribution through turbidites, meaning that palynologists overlook deposits that could potentially be used to reconstruct past vegetation and climate. We present pollen assemblage and sedimentological data from four recent (<150 years) deep marine turbidite deposits from the Hikurangi Subduction Margin, Aotearoa-New Zealand, with the aim of understanding the abundance and distribution of pollen in fine-grained turbidites. We find that pollen is diluted in the bases of turbidites, but despite this dilution, the proportions of different pollen taxa remain consistent through each turbidite. These results confirm that pollen can be sampled from turbidites for palaeovegetation reconstructions and that sampling the fine-grained upper parts of turbidites will provide the best pollen recovery.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2019

On the importance of phase saturation heterogeneity in the analysis of laboratory studies of hydrate dissociation

Methane hydrates (MHs) have been considered as the future source of energy because of its vast resource volume and high energy density. Energy recovery from MH-bearing sediments has attracted intensifying research activities. Fundamentally, heat transfer, fluid flow through porous media, and the kinetics of hydrate reaction are the three key processes controlling the behavior of MH dissociation and the associated fluid production. Earlier studies have suggested that heterogeneous spatial distribution of SH is inevitable in MH-bearing samples synthesized in laboratory. In this paper, we extend our study to analyze numerically the simulation results from the two realizations of the samples (homogeneous and heterogeneous) to identify differences in the fluid production and to determine if they are sufficiently different. Additionally, we conduct a sensitivity analysis and a statistical analysis on the key transport and kinetic rate parameters that could affect hydrate dissociation and fluid production in the context of a heterogeneous hydrate-bearing sample, in an effort to provide insights that could lead to improved designs for laboratory experiments and (possibly) field applications. Our results suggest that the approximation of an artificial hydrate-bearing core with heterogeneous phase saturations by an assumption of uniform phase saturation distributions results in practically similar fluid production profile except for the very early stage with maximum 20.0% deviation in the water production. From the sensitivity and statistical analysis, we determine that gas production depends strongly on the kinetic rate constant, K d 0 and the composite thermal conductivity of the hydrate-bearing sediments, λ θ ; while, water production is very sensitive to K d 0 and the absolute permeability of the sandy medium, k. Understanding the effect of phase heterogeneity and the relative importance of key parameters on the production behavior of hydrate-bearing sediments could provide basis for novel production technologies that lead to enhanced gas production and energy efficiency in the energy recovery process.

42 ENGINEERING↗
DOE OSTI2019

Climate change will pose challenges to water quality management in the St. Croix River basin

Responses of streamflow and nutrient export to changing climate conditions should be investigated for effective water quality management and pollution control. Using downscaled climate projections and the Soil and Water Assessment Tool (SWAT), we projected future streamflow, sediment export, and riverine nutrient export in the St. Croix River Basin (SCRB) during 2020-2099. Results show substantial increases in riverine water, sediment, and nutrient load under future climate conditions, particularly under the high greenhouse gas emission scenario. Intensified water cycling and enhanced nutrient export will pose challenges to water quality management and affect multiple Best Management Practices (BMPs) efforts, which are aimed at reducing nutrient loads in SCRB. In addition to the physical impacts of climate change on terrestrial hydrology, our analyses demonstrate significant reductions in ET under elevated atmospheric CO2 concentrations. Changes in plant physiology induced by climate change may markedly affect water cycling and associated sediment and nutrient export. Results of this study highlight the importance of examining climate change impacts on water and nutrient delivery for effective watershed management.

Climate change, Non-point source pollution, Stream↗
DOE OSTI2025

Hydrological Controls on Riverbed Methane Emissions: A Numerical Investigation of Hydrodynamic and Ebullitive Mechanisms from Site to Basin Scales

Methane production and emission from riverbed sediments constitute a significant yet underexplored component of the river methane budget. Despite their importance, a mechanistic and quantitative understanding of these processes under dynamic flow conditions remains elusive, particularly at the basin scale. In this study, we investigate the multiscale (site-to-basin) mechanisms governing methane emissions from riverbeds, focusing on the interplay between biogeochemical processes and hydrological dynamics. We developed a reactive transport model that integrates methane production with hydrodynamic and ebullitive pathways and coupled it with a basin-scale groundwater flow model to simulate methane emissions across scales. By incorporating key factors such as vertical hydrological exchange flow (VHEF), particulate organic carbon availability, sediment properties, and temperature sensitivity, our model captures the spatiotemporal variability of methane ebullition at both the site and basin scales. Our results reveal that methane ebullition is strongly modulated by VHEF, with lower flow rates promoting methane accumulation and subsequent ebullition. Sensitivity analyses underscore nonlinear responses of methane fluxes to environmental drivers. Furthermore, these findings emphasize the critical roles of sediment composition, hydrological exchange, and environmental conditions in shaping methane dynamics. Overall, this work advances our understanding of riverine methane emissions and offers insights for guiding climate models and mitigation strategies.

Fluxes↗
DOE OSTI2025

Blue Carbon Stocks Along the Pacific Coast of North America Are Mainly Driven by Local Rather Than Regional Factors

Coastal wetlands, including seagrass meadows, emergent marshes, mangroves, and temperate tidal swamps, can efficiently sequester and store large quantities of sediment organic carbon (SOC). However, SOC stocks may vary by ecosystem type and along environmental or climate gradients at different scales. Quantifying such variability is needed to improve blue carbon accounting, conservation effectiveness, and restoration planning. We analyzed SOC stocks in 1,284 sediment cores along >6,500 km of the Pacific coast of North America that included large environmental gradients and multiple ecosystem types. Tidal wetlands with woody vegetation (mangroves and swamps) had the highest mean stocks to 1 m depth (357 and 355 Mg ha −1 , respectively), 45% higher than marshes (245 Mg ha −1 ), and more than 500% higher than seagrass (68 Mg ha −1 ). Unvegetated tideflats, though not often considered a blue carbon ecosystem, had noteworthy stocks (148 Mg ha −1 ). Stocks increased with tidal elevation and with fine (<63 μm) sediment content in several ecosystems. Stocks also varied by dominant plant species within individual ecosystem types. At larger scales, marsh stocks were lowest in the Sonoran Desert region of Mexico, and swamp stocks differed among climate zones; otherwise stocks showed little correlation with ecoregion or latitude. More variability in SOC occurred among ecosystem types, and at smaller spatial scales (such as individual estuaries), than across regional climate gradients. These patterns can inform coastal conservation and restoration priorities across scales where preserving stored carbon and enhancing sequestration helps avert greenhouse gas emissions and maintains other vital ecosystem services.

emergent marsh↗
DOE OSTI2023

Spatial Study 2022: Surface Water Samples, Cotton Strip Degradation, and Hydrologic Sensor Data across the Yakima River Basin, Washington, USA (v3)

This dataset supports a broader study examining the drivers of spatial variability in sediment respiration rates in the Yakima River Basin. The dataset provides data and photos generated from sample collection during the same one-week period at 48 sites within multiple rivers throughout the Yakima River Basin in Washington, USA. The contents include surface water geochemistry data; river substrate grain size photos; stream depth data; manual chamber open channel respiration data; and field metadata (including qualitative information on instream and river corridor characteristics). Grain size photos can be used to improve estimates of channel substrate D50 data. The dataset also includes tensile strength and photos from cotton strip field degradation experiments; five-week sensor time series temperature, dissolved oxygen, pressure, pH, specific conductance, chlorophyll A, and turbidity data; plots of the sensor data; and R scripts used to generate the plots. Samples collected during this study were labeled as “Second Spatial Study” or “SSS.” A subset of data from the SSS samples were published in the contiguous United States (CONUS)-Scale Model-Sample (CM) study data package available at https://data.ess-dive.lbl.gov/view/doi:10.15485/1923689 that presents data from across the CONUS. SSS data published in the CM data package were not included in this data package. They include dissolved organic carbon (DOC, measured as non-purgeable organic carbon, NPOC), total nitrogen (TN), grain size, aerobic sediment respiration, dissolved oxygen (DO), and temperature. Parent IDs and Site IDs are consistent between the SSS and CM data packages, and they can be mapped directly so data across packages can be used together. Additionally, sensor data from a similar 2021 spatial study can be found at https://data.ess-dive.lbl.gov/view/doi:10.15485/1892052 and 2021 sample data can be found at https://data.ess-dive.lbl.gov/view/doi:10.15485/1898914. The 2021 spatial study had some sites in common with this 2022 spatial study. This dataset is comprised of three photo folders and one main data folder with six subfolders. The photo folders contain photographs and videos of cotton strip retrieval and sediment quadrats. The main data folder consists of (1) file-level metadata; (2) data dictionary; (3) field metadata; (4) total suspended solids (TSS) data and cotton strip tensile strength data and averages; (5) field protocol; (6) readme; (7) methods codes; (8) international generic sample number (IGSN) mapping file; (9) sensor installation methods summary; (10) stream depth and averages; and (11) Ultrameter data and averages. The Sonar subfolder consists of Sonar time-series depth data and a processing script. The BarotrollAtm, DepthHOBO, MantaRiver, miniDOT, and miniDOTManualChamber subfolders contain time-series data, plots, and summary files. All files are .csv, .pdf, .txt, .R, .Rmd, .jpg, .jpeg, .AVI, .mp4, or .mov. The data package was originally published in April 2023. It was updated in August 2023 (v2; modified files) and September 2024 (v3; modified files). See the change history section in the readme for details. We acknowledge the Yakama Nation as owners and caretakers of the lands where we collected these data. We thank the Confederated Tribes and Bands of the Yakama Nation Tribal Council and Yakama Nation Fisheries for working with us to facilitate sample collection and optimization of data usage according to their values and worldview.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Update of Erosion Conditions and Assessment of Mitigation Options for the L-Bar Site

The L-Bar former uranium milling site was remediated and closed per regulations and is now under the long-term stewardship of the U.S. Department of Energy, Office of Legacy Management (DOE/LM). Since assuming stewardship in 2004, DOE/LM has observed erosion and sedimentation processes at the L-Bar Site that will challenge meeting the design closure criteria in the long term, and therefore erosion control structures were installed in several areas. Portions of these structures were subsequently damaged by summer convective storm events and they are being redesigned. At the request of DOE/LM, Desert Research Institute (DRI) reviewed the proposed redesign plans of the erosion control structures. The purpose of this review is to support DOE/LM decisions regarding mitigation of ongoing erosion processes, including assessing possible repair of the existing erosion control structures, as well as plan for effective long-term site management. This design review is performed in reference to the Uranium Mill Tailings Radiation Control Act (UMTRCA) standards contained in 40 CFR 192.02 that require containment of residual radioactive material be effective for up to 1,000 years (if achievable, but certainly for 200 years), limit radon release, protect groundwater, and minimize future maintenance. The erosion control structures under review are not subject to the UMTRCA standard directly, but they contribute to the performance of the overall containment system by virtue of their relationship with the large diversion channels bounding the disposal cell. The 11 design drawings included in “Erosion Control Alternatives Analysis, L-Bar, New Mexico, Disposal Site, LTS-111-0043-08-002,” dated January 11, 2019, and listed in Appendix A, and supporting calculations in Weston (2019) are the focus of the review. Additionally, DOE/LM provided supporting data such as a 2018 photogrammetry-based digital elevation model of the site, precipitation records collected from an on-site weather station, and sedimentation records collected at an on-site basin. This assessment includes review of the proposed design to mitigate current site conditions but also addresses site changes between the initial erosion assessment report (Miller et al., 2012) and current conditions. The analysis is at a predesign engineering level and does not include development of hydraulic or sediment transport models. Site precipitation data are included in Miller et al. (2012). The natural conditions of the site, the design of site diversion systems, observed erosion at the site, and predesign engineering analysis are used to develop a holistic view of the challenges to L-Bar Site stability and possible responsive actions.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Spatial Mapping of Riverbed Grain-Size Distribution Using Machine Learning

Recent alluvial sediments in riverbeds play a significant role in controlling hydrologic exchange flows (HEFs) in river systems. The alluvial layer is usually associated with strong heterogeneity in physical properties (e.g., permeability and hydraulic conductivity), which affects local HEFs and therefore biogeochemical processes. The spatial distribution of these physical properties needs to be determined to inform the numerical models used to reveal the realistic hydro-biogeochemical behaviors. Such information can be obtained based on the intrinsic link between sediment grain-size distribution and hydraulic properties where sediment texture information is available. However, grain-size measurements are usually spatially sparse and do not have adequate coverage and resolution, particularly for a relatively large domain such as the Hanford Reach of the Columbia River. In this paper, we adopted machine learning (ML) approaches for categorizing and mapping the spatial distributions of riverbed substrate grain size and filling in missing areas of substrate data using the ML models along the reach. Such ML models for substrate size mapping were trained at 13,372 locations using measured substrate sizes along with observed and simulated attributes, including bathymetric attributes (e.g., elevation, slope, and aspect ratio) from LIDAR and bathymetric surveys, and hydrodynamic properties (e.g., water depth, velocity, shear stress, and their statistical moments). An ensemble bagging-based ML technique, Random Forest, was adopted to identify the most influential factors as predictors to develop the predictive models with over-fitting issues addressed. The models were evaluated with respect to each individual substrate size class and the lumped group, and then used to generate the final substrate size maps covering all the grid cells in the numerical modeling domain.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2021

On the Cycling of 231 Pa and 230 Th in Benthic Nepheloid Layers

The naturally-occurring radionuclides protactinium-231 ( 231 Pa) and thorium-230 ( 230 Th) are produced at approximately uniform rates in the ocean and thought to be removed from the water column through a reversible exchange with settling particles. Recent measurements along the U.S. GEOTRACES North Atlantic transect (GA03) revealed two features which are at odds with current understanding about 231 Pa and 230 Th cycling in the ocean: (i) a sharp decrease in dissolved 231 Pa ( 231 Pa d ) and 230 Th ( 230 Th d ) activities with depth below 2000-4000 m and (ii) very high particulate 231 Pa ( 231 Pa p ) and 230 Th ( 230 Th p ) activities near the bottom, at a number of stations between the New England continental shelf and Bermuda. Concomitant measurements of light attenuation from beam transmissometry showed that both features occur in benthic nepheloid layers (BNLs), which suggests that these features may stem, at least partly, from the presence of resuspended sediment in the deep water column. Here we explore the behaviour of 231 Pa and 230 Th in BNLs by using (i) radionuclide, optical, and hydrographic data from the western segment of GA03 (west of Bermuda) and (ii) a simplified model of particle and radionuclide cycling that includes a lateral particle source. First, the BNLs observed at GA03 stations are characterized from measurements of the beam attenuation coefficient converted to particle concentrations. At all stations, particle concentrations below the clear water minimum were the highest in the bottom mixed layer, whose thickness ranged from 95 to 320 m, and decreased generally with height above the bottom. The thickness of strong BNLs varied from 482 to 1358 m and the vertical integral of particle concentration in excess to that at the clear water minimum varied from 1 x 10 4 to 2 x 10 6 mg m −2 , among different stations. Second, the particle-radionuclide model is fitted to data from stations GT11-04 (New England continental rise) and GT11-08 (Hatteras abyssal plain), where samples for radionuclide analyses were collected in the BNL. The model can reproduce simultaneously the increase of particle concentration with depth, the low 231 Pa d and 230 Th d in the BNLs, and the high 231 Pa p and 230 Th p near the bottom. According to the model, at heights less than about 300 m above the seafloor, the dissolved phase was set primarily by a balance between adsorption and desorption, with vertical turbulent mixing playing a secondary role, whilst the particulate phase behaved largely as a non-reactive constituent supplied laterally and transported vertically by particle settling and turbulent mixing. Sensitivity tests with the model suggest that lateral particle sources near continental slopes and similar reliefs can produce significant biases both in the 230 Th normalization method and in the interpretation of sediment 231 Pa/ 230 Th records. Our findings yield insights into the influence of sediment resuspension and transport on 231 Pa and 230 Th in the deep ocean and highlight the need for considering these processes in paleoceanographic applications.

Nepheloid layer↗
NASA NTRS2023

Satellite-Derived Estimates of Suspended CaCO3 Mud Con-Centrations from the West Florida Shelf Induced by Hurricane Ian

In the days following the passage of Hurricane Ian over the West Florida Shelf, a large plume of calcium carbonate (CaCO3) mud slurry was observed extending from west of the Dry Tortugas and curving to the east into the Straits of Florida. This discreet target offered a unique opportunity to quantify the suspended mass of CaCO3 in the slurry. Estimating the concentration of sediment in a plume of suspended CaCO3 by satellite sensor observations has been stymied up to now owing to a lack of in situ suspended sediment measurements during storm events, as “sea truth” data for such events is difficult to acquire. However, the Particulate Inorganic Carbon (PIC) standard product provided by the NASA Ocean Biology Distributed Active Archive Center (OBDAAC) is based on Moderate Resolution Imaging Spectroradiometer (MODIS) observations of a plume of coccolith chalk released from a ship in the “Chalk-Ex” experiment. Due to the similarities (particle size, mineralogy, and reflectance properties) of the suspended chalk features and the Ian-induced slurry, we utilized this data product to make initial estimates of the concentration of suspended sediment in the plume.

remote sensing↗
DOE OSTI2019

Development of a Testbed for Pipeline Flushing - 19409

Pipelines which carry radioactive waste within the DOE complex should be properly flushed, particularly in the cases where stationary or moving beds of solid sediment occur, or lines are prone to hydrogen gas buildup. Present guidelines establish a minimum for the amount of water used for post-transfer flushing operations to achieve satisfactory cleaning of pipelines. However, further studies are needed to limit the amount of water used for flushing operations, thus minimizing the consequent downstream waste. These efforts are significantly helpful to DOE waste remediation sites by preserving tank storage, preventing additional waste processing, and minimizing dilution and changes in waste chemistry. An experimental pipe loop designed for study of non-Newtonian slurry flushing is currently being developed at the Florida International University (FIU). The testbed is designed to investigate parameters that effect the efficiency of flushing operations. The objective is to find flush velocity values/modes which lead to satisfactory cleaning of transport lines with a minimum amount of water usage. The developed methodologies will be streamlined according to the demands from both Hanford and Savannah River sites. A test matrix containing parameters such as pipeline length, flow rate, and simulant composition (solid concentration, rheology, particle size and density) has been developed. In the initial phase of testing, material composition and loop length will be fixed to a mixture of 17 wt% kaolin in water (to attain density, viscosity, and yield stress in the applicable range to operations at Savannah River and Hanford sites) and 165 feet, respectively. This matrix provides a parametric study on the flush velocity. Prescribed velocities in this test matrix comply with the maximum and minimum recommended flush velocity values by the flushing guidelines for Hanford waste (RPP-RPT-59600, Rev. 0, SRNL-STI-2015-00014, TFC-ENG-STD-26, REV C-1). Efforts will focus on creating repeatable sediment beds inside the pipeline in both fully-flooded and gravity-drained systems. Bed characterization (i.e., measurement of sediment height, solids concentration, and rheology) will be conducted to ensure consistency of initial conditions between tests. A combination of Pulse-Echo technique, Coriolis meter, and optical inspections will be used to accomplish initial bed characterization (ensuring consistency between tests), control/monitor density variations (initial bed creation, flush velocity control, and post-flush evaluations), and serve as reference (validation of PulseEcho and pipe surface cleanness evaluation), respectively. This paper will present the details of the development of the test loop and the test matrix. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2020

Field Test Bed for Vadose-Zone Monitoring Approaches - 20404

In the Central Plateau at the U.S. Department of Energy Hanford Site, a large inventory of contaminants resides in unsaturated sediments within the approximately 100-meter-thick vadose zone, posing a potential continuing risk to groundwater. Vadose zone remedies used to address these contaminants will require performance monitoring to provide feedback during implementation and for long-term verification that remedial action objectives have been met. Passive approaches may also need long-term monitoring to demonstrate that the flux of contaminants from the vadose zone to the groundwater are below thresholds established to meet groundwater protection goals. Collection of physical (e.g., groundwater or sediment) samples is a common method for identifying contaminant concentration distributions, but this approach is limited by the number of locations and the frequency with which data can be collected. In situ vadose zone measurements have evolved over the past few years to include key measurements of water content, soil water pressure, temperature, and chemical concentration. However, the current generation of sensors is designed for relatively short-term use in near-surface soils or sediments. Geophysical methods have been evolving but are also limited in that they have not been designed for the specific long-term vadose zone monitoring needs at the Hanford Site. Overall, monitoring under unsaturated conditions can be difficult due to the need to install and maintain instrumentation over a large area and depth and the need to identify preferential flow pathways due to geologic and chemical heterogeneities over long periods. Thus, a vadose zone monitoring test bed was initiated to address these challenges and identify cost-effective approaches for implementation and postclosure monitoring of the deep vadose zone. The monitoring test bed is expected to provide valuable field-scale information for the design of vadose zone monitoring systems. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗