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At least 1,045 records · Page 58

An East to West Mineralogical Trend in Mars Exploration Rover Spirit Moessbauer Spectra of Home Plate

Home Plate is a light-toned plateau approx.90 m in diameter within the Inner Basin of the Columbia Hills in Gusev crater on Mars. It is the most extensive exposure of layered bedrock encountered by Spirit to date, and it is composed of clastic rocks of moderately altered alkali basalt composition, enriched in some highly volatile elements. Textural observations suggest an explosive origin and geochemical observations favor volcanism, probably a hydrovolcanic explosion [1]. Since it first arrived at Home Plate on sol 744, Spirit has circumnavigated the plateau (Fig. 1) and is now, since sol 1410, resting at its Winter Haven 3 location at the north end of Home Plate. Results: The MER Moessbauer spectrometers determine Fe oxidation states, identify Fe-bearing mineral phases and quantify the distribution of Fe among oxidation states and mineral phases [2]. Moessbauer spectra of Home Plate bedrock were obtained in five different locations from nine different targets (Fig. 1): Barnhill Ace, Posey Manager, and James Cool Papa Bell Stars at the northwest side of Home Plate; Pesapallo, June Emerson, and Elizabeth Emery on the east side; Texas Chili on the south side; Pecan Pie on the west side; and Chanute on the north side.

Schroder, C.↗

Comparing Volcanic Terrains on Venus and Earth: How Prevalent are Pyroclastic Deposits on Venus?

In the last several years, astronomers have discovered several exoplanets with masses less than 10 times that of the Earth [1]. Despite the likely abundance of Earth-sized planets, little is known about the pathways through which these planets evolve to become habitable or uninhabitable. Venus and Earth have similar planetary radii and solar orbital distance, and therefore offer a chance to study in detail the divergent evolution of two objects that now have radically different climates. Understanding the extent, duration, and types of volcanism present on Venus is an important step towards understanding how volatiles released from the interior of Venus have influenced the development of the atmosphere. Placing constraints on the extent of explosive volcanism on Venus can provide boundary conditions for timing, volumes, and altitudes for atmospheric injection of volatiles. In addition, atmospheric properties such as near-surface temperature and density affect how interior heat and volatiles are released. Radar image data for Venus can be used to determine the physical properties of volcanic deposits, and in particular, they can be used to search for evidence of pyroclastic deposits that may result from explosive outgassing of volatiles. For explosive volcanism to occur with the current high atmospheric pressure, magma volatile contents must be higher than is typical on Earth (at least 2-4% by weight) [2,3]. In, addition, pyroclastic flows should be more prevalent on Venus than convective plumes and material may not travel as far from the vent source as it would on Earth [3]. Areas of high radar backscatter with wispy margins that occur near concentric fractures on Sapho Patera [4] and several coronae in Eastern Eistla Regio [5] have been attributed to collapse of eruption columns and runout of rough materials.

Carter, Lynn M.↗

Differential Muon Tomography to Continuously Monitor Changes in the Composition of Subsurface Fluids

Muon tomography has been used to seek hidden chambers in Egyptian pyramids and image subsurface features in volcanoes. It seemed likely that it could be used to image injected, supercritical carbon dioxide as it is emplaced in porous geological structures being used for carbon sequestration, and also to check on subsequent leakage. It should work equally well in any other application where there are two fluids of different densities, such as water and oil, or carbon dioxide and heavy oil in oil reservoirs. Continuous monitoring of movement of oil and/or flood fluid during enhanced oil recovery activities for managing injection is important for economic reasons. Checking on leakage for geological carbon storage is essential both for safety and for economic purposes. Current technology (for example, repeat 3D seismic surveys) is expensive and episodic. Muons are generated by high- energy cosmic rays resulting from supernova explosions, and interact with gas molecules in the atmosphere. This innovation has produced a theoretical model of muon attenuation in the thickness of rock above and within a typical sandstone reservoir at a depth of between 1.00 and 1.25 km. Because this first simulation was focused on carbon sequestration, the innovators chose depths sufficient for the pressure there to ensure that the carbon dioxide would be supercritical. This innovation demonstrates for the first time the feasibility of using the natural cosmic-ray muon flux to generate continuous tomographic images of carbon dioxide in a storage site. The muon flux is attenuated to an extent dependent on, amongst other things, the density of the materials through which it passes. The density of supercritical carbon dioxide is only three quarters that of the brine in the reservoir that it displaces. The first realistic simulations indicate that changes as small as 0.4% in the storage site bulk density could be detected (equivalent to 7% of the porosity, in this specific case). The initial muon flux is effectively constant at the surface of the Earth. Sensitivity of the method would be decreased with increasing depth. However, sensitivity can be improved by emplacing a greater array of particle detectors at the base of the reservoir.

Coleman, Max↗

Energetic compound embodiments and methods of making and using the same

Disclosed herein are embodiments of an energetic compound and methods of making and using the same. Energetic compound embodiments disclosed herein exhibit physical and chemical properties that facilitate their use in various applications, such as high energy propellant plasticizers, melt-castable explosives, and the like. Efficient and safe method embodiments for making the disclosed energetic compound embodiments are described herein.

Chavez, David↗

Visualization and Quantification of Wind Induced Variability in Hydrogen Clouds Following Releases of Liquid Hydrogen: Preprint

Well characterized experimental data for consequence model validation is important in progressing the use of liquid hydrogen as an energy carrier. In 2019, the Health and Safety Executive (HSE) undertook a series of liquid hydrogen dispersion and combustion experiments as a part of the Pre-normative Research into the Safe Use of Liquid Hydrogen (PRESLHY) project. In partnership between the National Renewable Energy Laboratory (NREL) and HSE, time and spatially varying hydrogen concentration measurements were made in 25 dispersion experiments and 23 congested ignition experiments associated with PRESLHY WP3 and WP5, respectively. These measurements were undertaken using the hydrogen wide area monitoring system developed by NREL. During the 23 congested ignition experiments, high variability was observed in the measured explosion severity during experiments with similar initial conditions. This led to the conclusion that wind, including localized gusts, had a large influence on the dispersion of the hydrogen, and therefore the quantity of hydrogen that was present in the congested region of the explosions. Using the hydrogen concentration measurements taken immediately prior to ignition, the hydrogen clouds were visualized in an attempt to rationalize the variability in overpressure between the tests. Gaussian process regression was applied to quantify the variability of the measured hydrogen concentrations. This analysis could also be used to guide modifications in experimental designs for future research on hydrogen combustion behavior.

HSR&D↗

Direct Alpha Spectrometry of Nuclear Fallout

Advanced instruments and methods are under development to allow direct alpha spectrometry of nuclear fallout debris near the point of collection, to support nuclear forensics (NF). New approaches are needed to support NF in order to accelerate the process for data generation and reduce the overall timeline for decision making. Fallout debris at short time periods following detonation can be difficult to work with for alpha spectrometry, due to the presence of intense beta radiation originating from significant quantities of high-activity fission products. Intense beta radiation can challenge traditional silicon-based high-resolution alpha spectrometers. Addressing this, single-crystal (sc) chemical vapor deposition (CVD) produced diamond semiconductors have been studied for use for alpha spectrometry for assaying nuclear fallout debris. Tests have been performed using scCVD sensors to assay a variety of actinide-bearing samples. Sample preparation, when done, has been limited to pulverization using a mechanical ball mill. To reduce measurement times, multi-chip arrays of scCVD diamond semiconductor have been developed in form factors suitable for field deployment in support of NF objectives. These arrays have been tested using high-beta-activity sol gel surrogate nuclear explosive debris (SNED) containing varying concentrations of uranium and plutonium. Results from the use of scCVD detectors with sol gel SNED will be presented.

46 - INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AN↗

A study of explosive-induced fracture in polymethyl methacrylate (PMMA)

The fracture response of geologic materials is of interest for applications, including geothermal energy harnessing and containment of underground explosions. To better understand the explosively induced fracture response of geomaterials, polymethyl methacrylate (PMMA) was used as a transparent rock surrogate to allow imaging of internal shock propagation and fracture growth processes. Experiments were conducted using high-speed shadowgraphy and photon Doppler velocimetry (PDV), which were compared to numerical simulations. Experiments measured fractures produced in 304.8mm × 304.8mm × 304.8mm PMMA cubes with two simultaneously initiated detonators. The cubes were subjected to varying amounts and directions of externally applied uniaxial stresses, including no stress, 2 MPa stress, and 20 MPa stress. The fracture radius as a function of time was extracted from the high-speed videos. Post-test images of the PMMA cubes aided in the determination of three-dimensional effects not directly imaged by the cameras. The surface velocity history and the shock response captured in PDV and the high-speed videos were compared to the simulated explosive-induced shock response. The simulation results indicate that the shock drives the fracture for the first 20 μs corresponding to a fracture radius of approximately 15 mm in the experiments. The gas-driven fracture extent was estimated analytically using an equilibrium stress distribution calculated after the shock wave propagation through the sample. Reduction in the gas pressure due to the leakage of the explosive products through the crack as a function of time was accounted for. In conclusion, the estimated fracture lengths were in agreement with the experimentally observed fracture lengths.

15 GEOTHERMAL ENERGY↗

Standoff trace explosives vapor detection at meter distances

Vapor detection is a noncontact sampling method, which is a less invasive means of explosives screening than physical swiping. Explosive vapor detection is a challenge due to the low levels of vapors available for detection. This study demonstrates that the parts-per-quadrillion sensitivity of atmospheric flow tube-mass spectrometry (AFT-MS) combined with a high-volume air sampler enables standoff detection of trace explosives vapor at distances of centimeters to meters. Standoff detection of explosives vapor was possible both upstream and downstream of the vapor source relative to room air currents. RDX vapor from a saturated source was detected at up to 2.5 m. Vapors from RDX residue and nitroglycerin residue were detected at distances up to 0.5 m. The sampling can be optimized by accounting for air movement in the room or environment, which could further extend standoff detection distances. In conclusion, using AFT-MS with a high-volume sampler could also be effective for standoff vapor detection of drugs and additional chemical threats and could be useful for security screening applications such as at mail facilities, border crossings, and security checkpoints.

47 OTHER INSTRUMENTATION↗

Space to Air High-Altitude Region Adjoint Neutron Transport

Neutrons from an atmospheric nuclear explosion can be detected by sensors in orbit. Current tools for characterizing the neutron energy spectrum assume a known source and use forward transport to recreate the detector response. In realistic scenarios the true source is unknown, making this an inefficient, iterative approach. In contrast, the adjoint approach directly solves for the source spectrum, enabling source reconstruction. The time–energy fluence at the satellite and adjoint transport equation allow a Monte Carlo method to characterize the neutron source’s energy spectrum directly in a new model: the Space to High-Altitude Region Adjoint (SAHARA) model. A new adjoint source event estimator was developed in SAHARA to find feasible solutions to the neutron transport problem given the constraints of the adjoint environment. This work explores SAHARA’s development and performance for mono-energetic and continuous neutron energy sources. In general, the identified spectra were shifted towards energies approximately 5% lower than the true source spectra, but SAHARA was able to capture the correct spectral shapes. Continuous energy sources, including real-world sources Fat Man and Little Boy, resulted in identifiable spectra that could have been produced by the same distribution as the true sources as demonstrated by two-dimensional (2D) Kolmogorov–Smirnov tests.

LaMere, Zachary W.↗

X-ray Pinhole Camera Measurements

The development of the rod pinch diode [1] has led to high-resolution radiography for dynamic events such as explosive tests. Rod pinch diodes use a small diameter anode rod, which extends through the aperture of a cathode plate. Electrons borne off the aperture surface can self-insulate and pinch onto the tip of the rod, creating an intense, small x-ray source (Primary Pinch). This source has been utilized as the main diagnostic on numerous experiments that include high-value, single-shot events. In such applications there is an emphasis on machine reliability, x-ray reproducibility, and x-ray quality [2]. In tests with the baseline rod pinch diode, we have observed that an additional pinch (Secondary Pinch) occurs at the interface near the anode rod and the rod holder. This suggests that stray electrons exist that are not associated with the Primary Pinch. In this paper we present measurements on both pinches using an x-ray pinhole camera. The camera is placed downstream of the Primary Pinch at an angle of 60° with respect to the diode centerline. This diagnostic will be employed to diagnose x-ray reproducibility and quality. In addition, we will investigate the performance of hybrid diodes relating to the formation of the Primary and Secondary Pinches.

X-RAY, pinhole, camera, measurements, rod pinch di↗

A Hydrogen Ignition Mechanism for Explosions in Nuclear Facility Piping Systems

Hydrogen explosions may occur simultaneously with water hammer accidents in nuclear facilities, and a theoretical mechanism to relate water hammer to hydrogen deflagrations and explosions is presented herein. Hydrogen and oxygen generation due to the radiolysis of water is a recognized hazard in pipe systems used in the nuclear industry, where the accumulation of hydrogen and oxygen at high points in the pipe system is expected, and explosive conditions may occur. Pipe ruptures in nuclear reactor cooling systems were attributed to hydrogen explosions inside pipelines, i.e., Hamaoka, Nuclear Power Station in Japan, and Brunsbuettel in Germany. Prior to these accidents, an ignition source for hydrogen was not clearly demonstrated, but these accidents demonstrated that a mechanism was, in fact, available to initiate combustion and explosion. A new theory to identify an ignition source and explosion cause is presented here, and further research is recommended to fully understand this explosion mechanism.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Progenitor and close-in circumstellar medium of type II supernova 2020fqv from high-cadence photometry and ultra-rapid UV spectroscopy

ABSTRACT We present observations of SN 2020fqv, a Virgo-cluster type II core-collapse supernova (CCSN) with a high temporal resolution light curve from the Transiting Exoplanet Survey Satellite (TESS) covering the time of explosion; ultraviolet (UV) spectroscopy from the Hubble Space Telescope (HST) starting 3.3 d post-explosion; ground-based spectroscopic observations starting 1.1 d post-explosion; along with extensive photometric observations. Massive stars have complicated mass-loss histories leading up to their death as CCSNe, creating circumstellar medium (CSM) with which the SNe interact. Observations during the first few days post-explosion can provide important information about the mass-loss rate during the late stages of stellar evolution. Model fits to the quasi-bolometric light curve of SN 2020fqv reveal 0.23 M⊙ of CSM confined within 1450 R⊙ (1014 cm) from its progenitor star. Early spectra (<4 d post-explosion), both from HST and ground-based observatories, show emission features from high-ionization metal species from the outer, optically thin part of this CSM. We find that the CSM is consistent with an eruption caused by the injection of ∼5 × 1046 erg into the stellar envelope ∼300 d pre-explosion, potentially from a nuclear burning instability at the onset of oxygen burning. Light-curve fitting, nebular spectroscopy, and pre-explosion HST imaging consistently point to a red supergiant (RSG) progenitor with $M_{\rm ZAMS}\approx 13.5\!-\!15 \, \mathrm{M}_{\odot }$, typical for SN II progenitor stars. This finding demonstrates that a typical RSG, like the progenitor of SN 2020fqv, has a complicated mass-loss history immediately before core collapse.

Tinyanont, Samaporn (ORCID:0000000214814676)↗

Radionuclide Migration at a Plowshare Program Site: the Gasbuggy Underground Nuclear Test Site, San Juan County, New Mexico - 17019

Project Gasbuggy in northwest New Mexico was the first of three subsurface nuclear tests the U.S. Atomic Energy Commission conducted to evaluate the potential to enhance the production of natural gas from low-permeability geologic formations. In 1967, a 29-kiloton nuclear device was detonated in the Lewis Shale (marine shale and siltstone), 1,292 m below the land surface. The detonation vaporized a cavity into which overlying rock collapsed, forming a 101-m high rubble-filled chimney with a radius of 25 m. Explosion-generated fractures extended between 120 m and 150 m from the working point (detonation location). Most of the radionuclides generated from the explosion remain in the cavity melt glass or have decayed to negligible amounts; tritium radioactivity, however, is still high enough and potentially mobile enough to be of concern. Tritium is able to exchange with stable hydrogen and form liquid water and water vapor; under two-phase (liquid and gas) reservoir conditions the majority of tritium is stored as liquid water and volatilises only to restore equilibrium conditions as gas is removed. A numerical model was developed to examine the migration of tritium in both phases through the fractured shale and sandstone under present conditions. The results suggest that tritium has migrated only 110 m from the working point between 1967 and 2014. Although tritium is able to exchange between the gas and aqueous phases, the faster-diffusing gas phase is responsible for most of the tritium transport from the chimney. A hypothetical producing gas well located 340 m from the working point was added to the model to determine if tritiated water vapor (HTO) could migrate toward the well; results show that, because the low gas velocities could not compete with the high rate of radioactive decay, tritium would not reach the well. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Raman signatures of detonation soot

Soot generated from the detonation of nine explosives was investigated with Raman microspectroscopy and high-resolution transmission electron microscopy (HRTEM). The first order bands, located at approximately 1,580 (G), 1,350 (D1), 1,620 cm –1 (D2), 1,500 (D3), and 1,200 (D4), are used to provide information on the carbon allotropes and defects. The intensity ratios and the full-width at half-maximum provide an indication of the disorder in the material. The Raman spectra of soot acquired from the detonation of nine explosives showed differences which can be used to identify the precursor explosive. Overall, most differences in the spectra were correlated with the presence of amorphous carbon in the soot. In additional to identification of distinct bands in the spectra via deconvolution, principal component analysis was also used to differentiate the different types of soot. HRTEM performed on soot samples with different explosive precursors identified several distinct allotropes of carbon such as nanodiamonds, carbon onions, graphite fibers, and amorphous carbon.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

A Swift Look at SN 2011fe: The Earliest Ultraviolet Observations of a Type Ia Supernova

We present the earliest ultraviolet (UV) observations of the bright Type Ia supernova SN 2011fe/PTF11kly in the nearby galaxy M101 at a distance of only 6.4 Mpc. It was discovered shortly after explosion by the Palomar Transient Factory and first observed by Swift/UVOT about a day after explosion. The early UV light is well-defined, with approx. 20 data points per filter in the 5 days after explosion. With these early UV observations, we extend the near-UV template of SNe Ia to earlier times for comparison with observations at low and high redshift and report fits from semiempirical models of the explosion. We find the early UV count rates to be well fit by the superposition of two parabolic curves. Finally, we use the early UV flux measurements to examine a possible shock interaction with a non-degenerate companion. We find that even a solar mass companion at a distance of a few solar radii is unlikely at more than 95% confidence.

Oates, Samantha↗

Use of synchrotron-based radiography to diagnose pulsed power driven wire explosion experiments

We describe the first use of synchrotron radiation to probe pulsed power driven high energy density physics (HEDP) experiments. Multi-frame x-ray radiography with interframe spacing of 704 ns and temporal resolution of < 100 ps was used to diagnose the electrical explosion of different wire configurations in water including single copper and tungsten wires, parallel copper wire pairs and copper x-pinches. Such experiments are of great interest to a variety of areas including equation of state studies and high pressure materials research, but the optical diagnostics that are usually employed in these experiments are unable to probe areas behind the shock wave generated in the water, as well as the internal structure of the exploding material. The x-ray radiography presented here, performed at beamline ID19 at ESRF, was able to image both sides of the shock to a resolution of up to 8 µm, and phase contrast imaging (PCI) allowed fine details of the wire structure during the current driven explosion and the shock waves to be clearly observed. These results demonstrate the feasibility of pulsed power operated in conjunction with synchrotron facilities, as well as an effective technique in the study of shock waves and wire explosion dynamics.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Estimating Explosion Yields Using Moment Tensor Solutions and Seismic Moment

We report seismic moment, a measurable and well-understood quantity of seismic sources, is used to estimate the yield of explosions. Application of such a method in the past, as in the manner of m b -derived yields, has been complicated by the effect of variations in the explosion working point, depth, and secondary source effects (such as spalling and tectonic release) on the observed moment. We start using the full (six-element) moment tensor solution, which can capture the relevant source physics and, at least in theory, better isolate the primary explosion source. The moment-to-yield ratio is then estimated using an explosion source model which, provided with emplacement conditions, can relate the two parameters. We discuss the major sources of uncertainty associated with the method, and calibrate it with chemical and nuclear explosions at the Nevada National Security Site. We then apply the method to published moment tensor solutions for the six declared North Korean nuclear explosions that occurred between 2006 and 2017. The results are mostly consistent with other yield estimates made using a variety of high-frequency methods. This technique is a new approach to estimating explosive yield and simple to implement, as much of the complexity is captured by the source models.

58 GEOSCIENCES↗