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At least 1,045 records · Page 58

Methods and systems for syngas production and for efficient, flexible energy generation

Methods for producing syngas (e.g., H2 and CO) include introducing a stream comprising H2O and CO2 to a high-temperature co-electrolysis (HTCE) unit. A CO2 sweep gas is also introduced to the HTCE unit. Both H2O and CO2 are reduced in the HTCE unit to form the syngas and to form O2 that is swept away from the HTCE unit by the CO2 sweep gas, and the O2 and CO2 are then introduced to a combustion device (e.g., a gasifier), which may be configured to generate electrical power, as a result of combusting a carbonaceous fuel in the presence of the O2 and CO2. The HTCE unit is powered at least in part by power from an electricity-generating sub-system (e.g., at least one nuclear power plant). Related systems are also disclosed.

O'Brien, James E.↗

Achieving American Leadership in the Hydrogen Supply Chain Factsheet

Hydrogen has been identified as a key energy option to enable full decarbonization of the energy system. A secure, resilient supply chain will be critical to achieving emissions reductions and capturing the economic opportunity inherent in the energy sector transition. Electrolyzers and fuel cells are two critical components of the hydrogen supply chain that today are largely nascent industries with limited data on supply chain needs and constraints. This fact sheet summarizes findings from an accompanying report that is one in a series of deep dive assessments of the energy industrial base called for in Executive Order 14017 on America’s supply chains. The report identifies key considerations for the development of water electrolyzer and fuel cell supply chains and materials, focusing on polymer electrolyte and solid oxide technologies, to meet future demand for hydrogen produced by electrolysis and achieve U.S. decarbonization goals.

Source record↗

MEA Manufacturing R&D

This is our annual presentation on the HFTO-funded MEA Manufacturing R&D project, mainly focused on development of in-line quality inspection methods for high volume fabrication of fuel cell and electrolysis MEA materials.

DIRECT ENERGY CONVERSION,ENGINEERING↗

Lithium metal recovery and synthesis

A process and system for creating a lithium ion anolyte from lithium alloys. Metal and lithium alloys are processed to remove the metal with lithium from the alloy remaining. A lithium ion anolyte formed may be used in a process to form lithium metal. Alternatively, a process and system for recovering lithium from sources such as lithium alloys and lithium metal oxides and other feedstock such as recycled batteries into a thin lithium metal film via electrodeposition in an organic electrolyte contacting both anode (holder for lithium source) and cathode (substrate for lithium deposition) in a single-compartment electrolysis cell.

Ignacio de Leon, Patricia Anne↗

Highly sustained electrodes and electrolytes for salty alkaline and neutral water splitting

A corrosion resistant anode is provided for oxygen evolution reaction in water including chloride ions. The anode includes: (1) a substrate; (2) a passivation layer coating the substrate; and (3) an electrocatalyst layer coating the passivation layer. Polyanion adjusted alkaline seawater electrolyte for hydrogen generation by electrolysis is also provided.

Kenney, Michael J.↗

Integrated desiccant-based cooling and dehumidification

Integrated systems comprising both i) heat and mass exchange systems and ii) electrolysis stacks are disclosed, together with related methods of use. The disclosed systems cool and/or dehumidify air using two streams of salt solutions as liquid desiccants.

Woods, Jason David↗

Battery cell with safety layer

A battery cell comprising a composite water-responsive safety layer and/or composite water- and pH-responsive safety layer to protect against tissue damage and/or electrolysis, when the battery cell is exposed to aqueous solution or tissue, is provided. The composite water-responsive safety layer and/or composite water- and pH-responsive safety layer is adapted to change from a non-electronically conducting state to an electronically conducting state.

Pozin, Michael↗

The Power of Being Negative: Producing H2 and Sequestered Carbon from Biomass and Waste Resources

Hydrogen can serve as an enabler for decarbonizing our economy, especially for the transportation, manufacturing, and chemicals sectors. Low-carbon H2 can be generated through a number of pathways, including (1) steam methane reforming coupled with carbon capture and sequestration, (2) water electrolysis utilizing renewable electricity, (3) methane pyrolysis, and (4) biomass and waste conversion. However, only the biomass and waste conversion pathway offers a route to carbon-negative H2 when coupled with carbon capture and sequestration (CCS), thus providing both a service to our environment through carbon dioxide removal from the atmosphere and a valuable downstream product in H2.

biomass↗

Multi-scale Modeling Using IDAES

This presentation was delivered at the 2023 FECM / NETL Spring R&D Project Review Meeting. It demonstrated how the IDAES platform is enabling unique analyses across multiple scales. Focus areas included solid oxide fuel cell/solid oxide electrolysis cell-based integrated energy systems with the flexibility to produce both hydrogen and electricity as well as long term expansion planning of future decarbonized electricity grids.

Burgard, Anthony↗

Regenerative solid oxide stack

An individual solid oxide cell (SOC) constructed of a sandwich configuration including in the following order: an oxygen electrode, a solid oxide electrolyte, a fuel electrode, a fuel manifold, and at least one layer of mesh. In one embodiment, the mesh supports a reforming catalyst resulting in a solid oxide fuel cell (SOFC) having a reformer embedded therein. The reformer-modified SOFC functions internally to steam reform or partially oxidize a gaseous hydrocarbon, e.g. methane, to a gaseous reformate of hydrogen and carbon monoxide, which is converted in the SOC to water, carbon dioxide, or a mixture thereof, and an electrical current. In another embodiment, an electrical insulator is disposed between the fuel manifold and the mesh resulting in a solid oxide electrolysis cell (SOEC), which functions to electrolyze water and/or carbon dioxide.

30 DIRECT ENERGY CONVERSION↗

Integrated desiccant-based cooling and dehumidification

Integrated systems comprising both i) heat and mass exchange systems and ii) electrolysis stacks are disclosed, together with related methods of use. The disclosed systems cool and/or dehumidify air using two streams of salt solutions as liquid desiccants.

Woods, Jason David↗

Bifunctional porous non-noble metal phosphide catalyst for overall water splitting and methods of making and using same

A method of electrocatalytic water splitting by providing an anode and a cathode; and utilizing the anode and the cathode for alkaline water electrolysis. Each of the anode and the cathode comprises a uniform distribution of a bifunctional electrocatalyst comprising metallic phosphides on a conductive substrate. The metallic phosphides comprise arion phosphide (FeP) and dinickel phosphide (Ni 2 P). The bifunctional electrocatalyst promotes hydrogen evolution reaction (HER) at the cathode, and oxygen evolution reaction (OER) at the anode.

Ren, Zhifeng↗

Integrated desiccant-based cooling and dehumidification

Integrated systems comprising both i) heat and mass exchange systems and ii) electrolysis stacks are disclosed, together with related methods of use. The disclosed systems cool and/or dehumidify air using two streams of salt solutions as liquid desiccants.

Woods, Jason David↗

Data-driven Quasi-static Surrogate Models for Nuclear-powered Integrated Energy Systems

The integration of nuclear power into energy systems presents a promising avenue to address the growing global energy demands while minimizing greenhouse gas emissions. In this paper, we introduce a data-driven quasi-static surrogate model for nuclear-powered Integrated Energy Systems (IES) that comprises various components, including a small modular reactor (SMR), steam manifold, balance of plant (BOP), high-temperature steam electrolysis (HTSE), and district heating (DH) system. Traditional physics-based models for these components often entail significant computational resource and time consumption, necessitating the development of efficient surrogate models. The development of a complete surrogate model for the IES involves the creation of individual surrogate models for each component, leveraging machine learning techniques and simulated data. These isolated surrogate models are subsequently integrated, enabling a holistic view of the IES and reducing the computational burden associated with detailed physics-based simulations. This paper outlines the development process, validation, and the performance evaluation of the surrogate models. The exceptional performance, with low root-mean-squared errors and R-squared scores of at least 99.8% across all individual surrogate models, underscores their accuracy and practical applicability. These results demonstrate the potential of these models to expedite the analysis of nuclear-powered IES, offering insights that can shape future research and development efforts.

08 HYDROGEN↗

Enhancing Electrochemical CO2 Conversion by Controlling Electrocatalysts' Structure

Electrochemical reduction of CO2 (CO2R) to valuable, carbon-neutral chemical feedstocks and storable fuels driven by renewable electricity has been recognized as one of the promising pathways to mitigate the greenhouse effect, reduce global demand for fossil fuels, achieve carbon neutrality, and create sustainable energy. Tremendous ongoing efforts have focused on controlling the morphology, composition, structure, size, defects, etc., of the electrocatalysts to improve product selectivity, activity, and durability to approach the feasibility of practical applications (current density higher than 200 mA/cm2 and lifetime ~1,000 hr+). This presentation will discuss how the geometry and surface composition of novel copper- and tin-based catalysts would maximize the CO2 conversion to carbon monoxide and liquid formic acid/formate in both common aqueous H-cell and electrolyzer configurations. Several spectroscopic, microscopic, and electrochemical characterization tools have been utilized to correlate the changes in the structural, physico-chemical, and electronic properties with the catalytic activity. Our work provides additional electrocatalyst design considerations for high-performance CO2 electrolysis.

Nguyen Phan, Thuy Duong↗

In-line, High-Throughput Quality Monitoring for Fuel Cell and Electrolyzer Components Based on Transmission and Reflection Imaging

During the manufacturing of fuel cell and electrolyzer membranes and membrane electrode assemblies (MEAs), real-time, in-line, high-throughput optical-based quality monitoring methods are essential for detecting defects and monitoring thickness variations, thus improving the performance and increasing the durability of fuel cell and electrolyzer in the hydrogen industry. For the MEAs with very opaque coatings, optical transmission-based imaging has been developed and applied in the Roll-to-Roll system using a flashlight and a high-sensitivity CCD camera. We observed high signal-to-noise ratio images while the Roll-to-Roll system ran at 5 ft/min. The entire sample image could quickly be recovered from the discrete frames using customized Python codes for automatic frame cropping and stitching. We detected significant non-uniformities in our experimental MEAs specimen. For fuel cell and low-temperature electrolysis (LTE) transparent membranes, we used optical reflectance hyperspectral imaging with interference fringe-based thickness mapping. We set up a hyperspectral camera to measure various rolls of commercial membranes. The measurement results are analyzed to find the thickness distribution of each roll and to check for defects. Transmission and reflection imaging-based quality monitoring techniques demonstrated in this project can be widely used in the mass production environment to improve the production yield and performance of hydrogen devices.

DIRECT ENERGY CONVERSION,ENGINEERING↗

Demonstrating Advanced Nuclear Energy Solutions for Net Zero

Background/Objectives. The aggressive goals being set by nation states, communities, and private industry for decarbonization of grid electricity, industrial heat sources, and transportation around the world are imperative to mitigating the devastating effects that we are seeing from climate change. Although many of these goals focus on accomplishments by 2035 or 2050, the decisions that we make today won’t just impact the landscape of energy systems for the next 20 or 30 years—they will shape the world’s environment for centuries to come. That means that we can’t just focus on technologies that will get us to 2050, but technologies that will withstand our energy demands over that long-ranging future. Success will require us to utilize all of the clean energy resources that we have available to meet demands for electricity, heat, and steam, and we will need energy carriers such as hydrogen that do not emit additional greenhouse gases at the point of use. Nuclear energy, ranging from technologies in service today to advanced, higher temperature and modular systems that will be in service this decade, will provide a robust complement to renewable energy resources that operate variably. Researchers across the U.S. Department of Energy laboratory complex are working to advance multiple aspects of these clean energy solutions, with many focusing on integrated energy system solutions that leverage all available clean energy assets to meet wide-ranging energy demands. Approach/Activities. Nuclear energy is a proven, zero-emission option during operation that can provide consistent, dispatchable power to meet electricity demands while also providing high-quality heat that can meet energy demands beyond the electricity sector. Energy system design should seek to maximize these assets. As a dispatchable energy source with a small land utilization footprint, nuclear energy can be collocated with renewable resources, and the smaller systems that will be deployed this decade (ranging from a few megawatts to hundreds of megawatts) can be installed right where that energy is needed. Integrated nuclear and renewable systems will enhance power grid reliability and resilience, and they will help stabilize the grid through their increasingly flexible operation. Licensing, installation, and broad adoption of these advanced nuclear energy systems are expected to progress significantly in the 2020s, but this may be longer than desired by some stakeholders wishing to implement impactful clean energy decisions today. However, one must recall that nuclear energy systems will operate for 80 or more years, as is being demonstrated by current fleet nuclear systems. The nuclear community is extremely thorough in reviewing these systems with regard to safety and security; these efforts ensure that the deployed systems will continue to provide reliable, resilient energy over that operational lifetime. That investment of time up front will ensure that we can support energy demands over the centuries to come. While advanced nuclear technologies move through this process, communities and private industry may choose to install renewable generation systems that can later be coupled to the complementary nuclear systems as they become available—thus moving closer to the net zero goals in the near term. Choosing technologies and deployment configurations that allow small modular nuclear powerhouses to be added to these “energy parks” as they become available will ensure that advanced technologies can be readily adopted to support growing demands for clean energy. Results/Lessons Learned. The primary focus of integrated energy systems (IES) research is to assess the technical and economic potential of novel multi-input, multioutput solutions that are expected to enhance energy system flexibility, reliability, and resilience as we pursue a clean energy transition. Various energy applications and product streams beyond electricity are being evaluated, ranging from generation of potable water to production of hydrogen, fertilizers, synthetic fuels, and various chemicals. In early FY23 Idaho National Laboratory (INL) will commission thermal energy generation systems that emulate nuclear fission energy input using electric heating and will allow for integrated system testing with thermal energy storage, hydrogen production via high temperature electrolysis (HTE), and power systems hardware to demonstrate operation of a clean energy park within a microgrid or larger grid infrastructure, supporting up to 450 kW of heat input via electric heating and demonstrating operation of HTE systems at the multi-hundred kW scale. This presentation will highlight the wide array of RD&D being conducted at INL and partner laboratories to develop and deploy nuclear and renewable-based IES that will be key to achieving our net zero goals, including both computational and experimental demonstrations. By working with key collaborators in industry, analytical st

08 HYDROGEN↗