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At least 1,045 records · Page 58

Technical consulting services for earth resources program

Evaluations of several sets of test data which show a normal amount of variability in gamma and Dmax on KODAK Aerial Duplicating Film (ESTAR Base) SO-467 are reported. Kodak is now furnishing to engineers at GSFC a full set of test data for each coating of SO-467 film. Glass-enclosed sensitometer step tablets which are being made for the Herrnfeld instrument at GSFC are discussed. These tablets include a gray scale and uniformity check areas as well as tribar resolution patterns imaged in a durable chromium layer. It is recommended that the Sioux Falls EDC procure four new enlarging printers and study the value and economics of a system for printer automation based on edge coding.

Source record↗

Iron-titanium-chromite, a possible new carrier of remanent magnetization in lunar rocks.

Magnetic measurements of synthetic titanchromites reveal a characteristic transition at low temperature, making it possible to identify the presence of titanchromites in lunar rocks 12063, 14321 (dark clasts), and 14310. It is shown that titanchromites with a high chromium content could be the carriers of intermediate stability natural remanent magnetization observed in lunar rocks. Such natural remanent magnetization is acquired by transition thermoremanent magnetization at low temperature and cannot be duplicated by laboratory thermoremanent magnetization imparted above room temperature. The latter process will not yield the correct lunar paleointensity.

Banerjee, S. K.↗

High-strength alloy with resistance to hydrogen-environment embrittlement

Alloy is precipitation-hardened, high-strength, and low-thermal-expansion materials. It is iron-based and contains nickel and chromium at lower levels than high-strength alloys. It is readily welded and brazed and has good oxidation resistance. Tests indicated there was no reduction of notched or smooth strength.

Mcnamara, T. G.↗

Measurement of radiation exposure of astronauts by radiochemical techniques

A cosmic radiation dose to the Apollo 17 crew of 1.3 R was calculated from the specific activities of Na-24 in their postflight urine specimens. The specific activities of K-42, Cr-51, Co60, and Sb-124, introduced by injection into the astronauts, are extremely high in these specimens. The Fe-59 and Cs-137 levels are also reported and appear to be normal. The concentrations of Na, K, Rb, Cs, Ca, Sr, Ba, Cr, Fe, Co, Ag, Au, Zn, Cd, Hg, Sn, As, Sb, Se, Br, Sc, La, Sm, Eu, Tb, Hf, Ta, and Th were measured in urine specimens from the Apollo 17 astronauts by neutron activation analysis. Strontium, barium, gold, cadmium, lanthanum, samarium, europium, terbium, thorium, and tin are reported for the first time. The concentrations or excretion rates of bromine and the alkali metals exhibit singificantly reduced postflight levels and are generally lower than values observed for previous missions. Chromium concentrations reflect radiochromium injections.

Brodzinski, R. L.↗

High temperature, low-cycle fatigue of copper-base alloys in argon. Part 1: Preliminary results for 12 alloys at 1000 F (538 C)

Short-term tensile evaluations at room temperature and 538 C and low-cycle fatigue evaluations at 538 C are presented for the following materials: Zirconium copper-annealed, Zirconium copper-1/4 hard, Zirconium copper-1/2 hard, Tellurium copper-1/2 hard, Chromium copper-SA and aged, OFHC copper-hard, OFHC copper-1/4 hard, OFHC copper-annealed, Silver-as drawn, Zr-Cr-Mg copper-SA, CW and aged, Electroformed copper-30-35 ksi, and Co-Be-Zr- copper-SA, aged. A total of 50 tensile tests and 76 low-cycle fatigue tests were performed using a strain rate of 0.2 percent per second.

Conway, J. B.↗

Influence of low temperatures of friction and wear

A brief review of studies on low-temperature friction are briefly reviewed. A facility and technique for studying friction both in air and in vacuum at temperatures of +20 and -190 C is described. Results of a wear study of structural steels operating together with chromium steel are presented. It is shown that reduction of the test temperature in vacuum leads in certain cases to marked increase of the wear magnitude and friction coefficient. This is associated not only with the general change of the mechanical properties of the materials but also with the influence of temperature reduction on the hardening and structural formation taking place in the surface layers during friction.

Udovenko, V. F.↗

Dynamic oxidation behavior at 1000 and 1100 C of four nickel-base cast alloys, NASA-TRW VIA, B-1900, 713C, and 738X

The superalloys NASA-TRW VIA, B-1900, 713C, and 738X were tested cyclically and isothermally for resistance to oxidation in high velocity gas streams for 100 hours at specimen temperatures of 1000 C and 1100 C. Alloys VIA and B-1900, which were the most oxidation resistant, displayed slight and very similar weight changes and metal losses. Alloy 713C also sustained only slight metal losses, but it exhibited some tendency to spall. Alloy 738X was found to be the most susceptible to cyclic oxidation; this resulted in heavy spalling, which in turn caused high weight losses and high metal losses. Oxidation test results are related to the amounts of chromium aluminum, and the refractory metals in the alloys investigated.

Sanders, W. A.↗

Development of fine diameter mullite fiber

Results are presented of a program to develop and evaluate mullite fiber with a mean diameter under two microns. The two micron fiber is produced by a blowing process at room temperature from a low viscosity (10-25 poise) solution. The blown fiber was evaluated for dimensional stability in thermal cycling to 1371 C, and was equivalent to the 5 micron spun B and W mullite fiber. An additive study was conducted to evaluate substitutes for the boron. Three levels of chromium, lithium fluoride, and magnesium were added to the standard composition in place of boron and the fiber produced was evaluated for chemical and dimensional stability in thermal cycling to 1371 C. The magnesium was the most chemically stable, but the chrome additive imparted the best dimensional stability.

Long, W. G.↗

Oxidative vaporization kinetics of Cr2O3 in oxygen from 1000 to 1300 C

Rates of oxidative vaporization of Cr2O3 on preoxidized resistively heated chromium were determined in flowing oxygen at a pressure of 0.115 Torr for temperatures from 1000 to 1300 C. Reaction controlled rates were obtained from experimental rates by a gold calibration technique, and these rates were shown to agree with those predicted by thermochemical analysis. The activation energy obtained for the oxidative vaporization reaction corresponded numerically with the thermochemical enthalpy of the reaction. A theoretical equation is given for calculating the rate from thermodynamic data using boundary-layer theory.

Stearns, C. A.↗

The Tucson meteorite

Tucson is an unusual iron meteorite which contains highly reduced silicate inclusions and elemental silicon and chromium in solution. The metal matrix of Tucson was found to be chemically uniform, suggesting that homogenization has occurred at elevated temperatures. The microstructure of the metal consists of plessite and thin ribbons of kamacite. Nickel and phosphorus concentrations indicate that kamacite nucleated along prior taenite grain boundaries at about 650 C, and grew upon cooling to 500 C. Kamacite growth calculations show that Tucson cooled at about 1 C/1000 yr, a rate which corresponds to a depth of burial at the center of a 15-km-radius parent body or closer to the surface of parent bodies of larger sizes. The shapes of the Tucson irons, and the presence and distribution of silicate inclusions in the Fe-Ni matrix appear to be a result of a solidification process.

Miyake, G. T.↗

Determination of copper, scandium, molybdenum, tin, lead, and iron group elements in lunar surface materials

Distribution regularities of copper, scandium, molybdenum, tin, lead, and iron group elements were investigated in basaltoid rocks of lunar and terrestrial origin. Samples of various regolith zones taken in the area of the Sea of Fertility were analyzed, along with samples of basic and ultrabasic rocks of the East African Rift for their content of the trace admixtures listed. Data obtained on the abundance of copper, scandium, molybdenum, tin, lead, cobalt, nickel, chromium, and vanadium in Luna 16 lunar surface material were compared with the abundance of these elements in samples of lunar rocks returned by Apollo 11, Apollo 12, and Apollo 14, with the exception of scandium; its content in the latter samples was considerably higher.

Pavlenko, L. I.↗

Genesis of lunar regolith

From comparing the mineral and chemical composition of regoliths with the compositions of primary magmatic lunar rocks, it is shown that mare regolith is enriched in aluminum and depleted in iron, titanium, and chromium. This effect cannot be accounted for only by the admixture of highland anorthositic material. The entire array of geochemical data points to the considerable role of depth-wise differentiation of the magmatic material in forming the composition of the primary lunar rocks and, naturally, the composition of the regolith. During regolith formation, processes of the effervescing of magma as it outflowed at the lunar surface were of primary importance. Impacts by micrometeorites represent another important factor.

Vinogradov, A. P.↗

Growth defects in thick ion-plated coatings

Industrial ion plating conditions were selected to deposit metallic coatings such as copper, gold, and chromium 2 micrometer thick on metal and glass substrates. The surface finishes of 304 stainless steel, copper, and brass were utilized with mechanically and electrolytically polished surfaces. Nodular growth occurred in these coatings during ion plating as revealed by scanning electron microscopy. Surface irregularities such as scratches, steps, ledges, and so forth are responsible for outward growth, the typical cone type, whereas surface contaminants and loosely settled foreign particles are responsible for lateral growth; namely, the extreme localized surface outgrowths. These defect crystallographic features create porosity in the coatings when subjected to stresses and strains.

Spalvins, T.↗

Deformation and annealing study of Nicraly

Extensive experiments were carried out on the ODS alloy Nicraly, (an alloy prepared by mechanical alloying and consolidating a powder blend consisting of 16% chromium, 4% aluminum, 2-3% yttria, balance nickel), in efforts to develop methods of controlling the grain size and grain shape of the material. The experiments fell into two general categories: variations in the annealing parameters using the as-extruded material as it was received, and various thermomechanical processing schedules (various combinations of cold work and annealing). Success was achieved in gaining grain size and grain shape control by annealing of the as-extruded material. By proper selection of annealing temperature and cooling rates, the grain size of the as-received material was increased almost two orders of magnitude (from an average grain dimension of 0.023 mm to 1.668 mm) while the aspect ratio was increased by some 50% (from 20:1 to 30:1). No success was achieved in gaining significant control of the grain size and shape of the material by thermo-mechanical processing.

Trela, D. M.↗

Hot corrosion evaluation of aluminide coated superalloys in support of an ASTM Round Robin program

Commercial aluminized coatings on substrates were hot corroded at 900 C in a 0.3 Mach burner rig with 5 ppm synthetic sea salt and at two cycling frequencies. Extensive post-exposure examinations were conducted on the corroded specimens such as metallography, X-ray diffraction, scanning electron microscopy, microprobe raster scans, and spectrographic analyses. Thermodynamic calculations were made of the equilibrium burner flame composition and the calculations were compared to the experimental findings. It was found that localized spalling of the coatings preceded coating failure. It is suggested that the spalling of the coatings is due to the formation of localized stresses caused by the depletion of chromium and aluminum in the coating or the enrichment of the coating with sulfur. For the materials and test conditions investigated, it was found that coating life is dependent only upon the initial coating thickness and not on the type of aluminized coating, the substrate, or the cycle frequency.

Santoro, G.↗

Chemical reactions of metal powders with organic and inorganic liquids during ball milling

Chromium and/or nickel powders were milled in metal chlorides and in organic liquids representative of various functional groups. The powders always reacted with the liquid and became contaminated with elements from them. The milled powders had specific surface areas ranging from 0.14 to 37 sq m/g, and the total contamination with elements from the milling liquid ranged from 0.01 to 56 weight percent. Compounds resulting from substitution, addition, or elimination reactions formed in or from the milling liquid.

Arias, A.↗

Structure and elevated temperature properties of carbon-free ferritic alloys strengthened by a Laves phase

A Laves phase, Fe2Ta, was utilized to obtain good elevated temperature properties in a carbon-free iron alloy containing 1 at. pct Ta and 7 at. pct Cr. Room temperature embrittlement resulting from the precipitation of the Laves phase at grain boundaries was overcome by spheroidizing the precipitate. This was accomplished by thermally cycling the alloys through the alpha to gamma transformation. The short-time yield strength of the alloys decreased very slowly with increase in test temperature up to 600 C, but above this temperature, the strength decreased rapidly. Results of constant load creep and stress rupture tests conducted at several temperatures and stresses indicated that the rupture and creep strengths of spheroidized 1 Ta-7 Cr alloy were higher than those of several commercial steels containing chromium and/or molybdenum carbides but lower than those of steels containing substantial amounts of tungsten and vanadium. When molybdenum was added to the base Fe-Ta-Cr alloy, the rupture and creep strengths were considerably increased.

Bhandarkar, M. D.↗