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At least 1,045 records · Page 58
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Measurement of the abundance of several natural stratospheric trace constituents from high altitude aircraft

A summary report of the initial results obtained from near-infrared observations of the stratosphere from the Anglo-French SST Concorde is presented, together with the most recent results from previous flights aboard an Air Force NC-135. The measurements were made with a fast Fourier interferometer spectrometer operating in the 1.2- to 7.5-micron range of the infrared with a spectral resolution of 0.25 per cm. For the Concorde experiments, flight times and trajectories were selected which allowed the sun to be viewed near the horizon with the relative solar elevation angle held constant throughout the measurements. Results reported include the identification of features due to N2O, NO, NO2, CO, CO2, CH4, H2O and indications of their latitudinal variations.

Farmer, C. B.↗
NASA NTRS1973

Analysis of laser differential absorption remote sensing using diffuse reflection from the earth

A computer model analysis of an infrared laser differential absorption remote sensing technique (DARS) is presented. An infrared laser source operating at two or more wavelengths and a heterodyne detection system are considered to be mounted on either an aircraft or satellite platform to monitor the differential absorption between the laser source and the earth surface. The capability of this technique for measuring gas concentrations in the lower 5 kilometers of the atmosphere is emphasized. Numerical results are presented simulating measurements of vertical burdens of CO, NO, CH4, CO2, and O3. These results indicate that measurements of expected concentrations of these gases can be made with greater than 80% accuracy using realistic laser powers and system parameters.

Seals, R. K., Jr.↗
NASA NTRS1974

The 7.5- to 13.5-micron spectrum of Saturn

A medium-resolution spectrum of Saturn in the 7.5-13.5 micron range is presented. The observed low brightness temperature between 9 and 11 microns of about 100-105 K rules out gaseous NH3 as the dominant absorber in this spectral range. Absorption features due to PH3 may be present around 10 microns and cloud particles could be an important source of opacity in this wavelength range. There are strong indications of a temperature inversion in the upper atmosphere, including high brightness temperature in the 7.7-micron CH4 band, and possible emission from C2H6 around 12 microns.

Gillett, F. C.↗
NASA NTRS1974

A new upper limit for an atmosphere of CO2, CO on Mercury

High-resolution infrared spectra of Mercury (1.9-2.7 microns, resolution limit 0.134 wavelength/cm) obtained with the original 'Connes' interferometer at the Steward Observatory 90-inch telescope have provided a very sensitive test for the possible presence of a CO2, CO atmosphere. An improved upper limit of 0.12 cm-atm has been set for CO2, and a new upper limit of 0.05 cm-atm has been set for CO. Upper limits of similar magnitude can be established for CH4 and NH3. From the separation of the Mercury signal into reflected sunlight and thermal emission, we determine that the reflectivity decreases toward longer wavelengths and has a value of about 0.06 at 2.25 microns. Implications for the possible evolution of an atmosphere on Mercury are discussed.

Fink, U.↗
NASA NTRS1975

Infrared spectroscopy of Comet Kohoutek

Interferometry observations from 90-in. and 61-in. telescopes tracking the Comet Kohoutek are summarized. Laboratory reflection studies of ices potentially useful for future cometary work were conducted. The frosts studied included: H2O, CO2 NH3, H2S, CH4, NH4HS, and ammonia polysulfide. The frost spectra show remarkable changes with the temperatures, particularly in the case of hydrogen sulfide. Additional analysis found the variation in the H2S ice spectrum to be due to a phase change from a low temperature tetragonal unit cube to a higher temperature face-centered cubic structure. The spectra data indicate that if frost spectra are required for comparison with observed cometary or planetary absorption, the temperature of the frost must be matched.

Fink, U.↗
NASA NTRS1974

High resolution spectrophotometry of selected features in the 1.1 micron spectrum of Comet Kohoutek /1973f/

Fabry-Perot interferometry of Comet Kohoutek (1973f) at 1.1 microns with a resolution of 1.2 A showed emission features identified as OH and CN lines in addition to a strong Fraunhofer continuum. Central intensities have been derived for three cases (uniform, Gaussian, and Gaussian plus inverse-rho law) of brightness profiles in the comet coma. Limits for CH4, H2O, HeI, SiI and CrI are also derived.

Meisel, D. D.↗
NASA NTRS1974

Neptune - Observations of the H2 quadrupole lines in the /4-0/ band

The first measurement of Neptune's quadrupole H2 lines is reported. The equivalent widths of the S(0) and S(1) lines of the (4-0) band are given along with the corresponding widths measured from comparison spectra of Uranus taken on the same nights. These are interpreted in terms of both an inhomogeneous atmosphere overlying a reflecting layer and a homogeneous, semi-infinite, scattering atmosphere. Only the scattering model proves to be consistent with Neptune's spectrum in this wavelength region. The H2 abundance along the scattering mean free path is found to be less than the value for Rayleigh scattering in pure H2. This result is interpreted in terms of the presence of H2, CH4, and at least one other gas, instead of the more conventional interpretation in terms of the presence of an aerosol mixed with H2. Weak features in the continuum were observed. Their widths and the strength of the H2 features indicate that H2 is more abundant than the sum of the remaining gases in these atmospheres.

Trafton, L.↗
NASA NTRS1975

The effect of C/O ratio on the condensation of planetary material

The condensation temperatures of refractory silicates and oxides in a gas of cosmic composition are strongly dependent on the C/O ratio. As the ratio increases from 0.4 to 0.9, condensation temperatures of compounds such as Al2O3, Ca2Al2SiO7, MgAl2O4, Mg2SiO4, and MgSiO3 decrease by 50-100 degrees. As C/O increases from 0.9 to 1.0, these temperatures drop an additional 300-400 degrees. Other chemical differences result when C/O approximately equals or exceeds 0.9. A new suite of high-temperature minerals appears (graphite, CaS, Fe3C, SiC and TiN); the reaction CO + 3H2 yields CH4 + H2O proceeds to the right at higher temperatures; and iron, whose condensation temperature is unaffected, condenses at higher temperatures than any silicate or oxide.

Larimer, J. W.↗
NASA NTRS1975

Saturn's 3 nu 3 methane band - An analysis in terms of a scattering atmosphere

Using parameters recently measured in the laboratory, the shapes of manifolds belonging to the R-branch of Saturn's 3 nu 3 CH4 band were analyzed in terms of a homogeneous scattering model of Saturn's atmosphere, and the results were compared with those of an earlier analysis in terms of a reflecting-layer model. The resulting effective pressure is an order of magnitude smaller than for the reflecting-layer analysis, and the C/H ratio is an order of magnitude higher than the solar value. The overall fit of the theoretical profiles to the observed manifold shapes is distinctly worse, especially for R(7). Scattering evidently plays only a minor role in the formation of this band along Saturn's south-central meridian.

Trafton, L.↗
NASA NTRS1975

On the 23-micron feature in the spectrum of Jupiter

The spectroscopic activity of gaseous constituents in the Jovian atmosphere is investigated with a view toward absorption at 23 microns. Various possibilities for the source of this feature are excluded, particularly pressure-induced dipole transitions involving collisions between H2 and either CH4 or HD.

Fox, K.↗
NASA NTRS1974

Measurements of trace constituents from atmospheric infrared emission and absorption spectra, a feasibility study

The feasibility of detecting eight trace constituents (CH4, HCl, HF, HNO3, NH3, NO, NO2 and SO2) against the rest of the atmospheric background at various altitudes from infrared emission and absorption atmospheric spectra was studied. Line-by-line calculations and observational data were used to establish features that can be observed in the atmospheric spectrum due to each trace constituent. Model calculations were made for experimental conditions which approximately represent state of the art emission and absorption spectrometers.

Goldman, A.↗
NASA NTRS1976

Gas phase chemistry in comets

The significance of gas phase reactions in determining the nuclear structure of comets is discussed. The sublimation of parent molecules such as H2O, CH4, CO2, and NH3 from the surface of the nucleus and their subsequent photodissociation and ionization in forming observed cometary molecular species are elaborated.

Oppenheimer, M.↗
NASA NTRS1976

Polarization studies of Uranus

The whole-disk polarization of Uranus was measured over two apparitions in blue and red light. The behavior of the blue polarization as a function of phase angle is indicative of non-Rayleigh scattering. The red polarization phase curve, while not necessarily suggesting Rayleigh scattering, is at least consistent with that interpretation. One explanation of these data is that the blue radiation is scattered by the CH4 haze layer suggested by others for Uranus while red radiation, because of methane absorptions above this layer, does not penetrate to or scatter significantly from this haze layer. There is no whole-disk circular polarization, as expected, confirming other observations and theoretical predictions. In addition, polarization measurements of Comet West were carried out after perihelion. The results indicate that large particles are primarily responsible for the scattering of continuum light.

Michalsky, J. J.↗
NASA NTRS1976

Planetary astronomy program

Visual photometric function data for Saturn's rings were analyzed in terms of elementary anisotropic scattering radiative transfer models which involve the Henyey-Greenstein function. Limits were placed on the combinations of single scattering albedo, and backscattering directivity, which are permitted by observation. Particles with lunar-like scattering properties were excluded by the analysis. Results are consistent with the ring particles being more-or-less pure, and spherical, conglomerates of H2O frost. Multicolor (5500 A-7600 A), narrow band (100 A), area scanning photometry was used to study the wavelength variation in the optical appearance of Uranus. Limb brightening was detected in two CH4 bands, i.e. 6190A and 7300A. Spectrophotometric observations and analysis of the asteroids and Raman spectroscopy of the atmosphere of Uranus are also briefly discussed.

Source record↗
NASA NTRS1975

The thermal structure of Jupiter. II - Observations and analysis of 8-14 micron radiation

Observations of Jovian limb structure at 8.11 and 8.45 microns are reported. These are used along with other limb structure and spectral data in the 8-14 micron region to derive a model of the thermal and cloud structure within the 1.0-0.01 bar pressure regime. The temperature is about 165 K at 1.00 bar, 108 K at 0.10 bar, and 143 K at 0.03 bar. In zones, an optically opaque cloud of NH3 exists near the 143 K (0.60 bar) level. A partly transparent haze of solid NH3 particles overlies the cloud. Belts are free of the cloud and have a much lower abundance of NH3 haze than the zones. The data are consistent with an NH3 gas abundance defined by saturation equilibrium, with a mixing ratio of 0.00015 deep in the atmosphere, and with a CH4 mixing ratio of 0.002, about three times the currently accepted value.

Orton, G. S.↗
NASA NTRS1975

Integrated investigation of the mixed origin of lunar sample 72161,11

The comminution-agglutination model and the solar-wind implantation-retention model are used to postulate the origins of the particulate components of lunar sample (72161,11), a submillimeter fraction of a surface sample for the dark mantle regolith at LRV-3. Grain-size analysis was performed by wet sieving with liquid argon, and analyses for CO2, CO, CH4, and H2 were carried out by stepwise pyrolysis in a helium atmosphere. The results indicate that the present sample is from a mature regolith, but the agglutinate content is only 30% in the particle-size range between 90 and 177 microns, indicating an apparent departure from steady state. Analyses of the carbon, methane, and hydrogen concentrations in size fractions larger than 149 microns show that the volume-correlated component of these species increases with increased grain size. It is suggested that the observed increase can be explained in terms of mixing of a dominant local population of coarser agglutinates having high carbon and hydrogen concentrations with an imported population of finer agglutinates relatively poor in carbon and hydrogen.

Basu, A.↗
NASA NTRS1976

Absolute rate constant determinations for the deactivation of O/1D/ by time resolved decay of O/1D/ yields O/3P/ emission

Absolute rate constants for the deactivation of O(1D) atoms by some atmospheric gases have been determined by observing the time-resolved emission of O(1D) at 630 nm. O(1D) atoms were produced by the dissociation of ozone via repetitive laser pulses at 266 nm. Absolute rate constants for the relaxation of O(1D) at 298 K are reported for N2, O2, CO2, O3, H2, D2, CH4, HCl, NH3, H2O, N2O, and Ne. The results obtained are compared with previous relative and absolute measurements reported in the literature.

Davidson, J. A.↗
NASA NTRS1976

New upper limits for atmospheric constituents on Io

A spectrum of Io from 0.86 to 2.7 microns with a resolution of 3.36 per cm and a signal to rms noise ratio of 120 is presented. No absorptions due to any atmospheric constituents on Io could be found in the spectrum. Upper limits of 0.12 cm-atm for NH3, 0.12 cm-atm for CH4, 0.4 cm-atm for N2O, and 24 cm-atm for H2S were determined. Laboratory spectra of ammonia frosts as a function of temperature were compared with the spectrum of Io and showed this frost not to be present at the surface of Io. A search for possible resonance lines of carbon, silicon, and sulfur, as well as the 1.08-micron line of helium, proved negative. Upper emission limits of 60, 18, 27, and 60 kilorayleighs, respectively, were established for these lines.

Fink, U.↗