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NASA NTRS1992

Past and present water budget of Venus

Attention is given to a detailed analysis of Pioneer Venus large-probe neutral mass spectrometer data which confirm an earlier report that the abundance of Venus deuterium relative to hydrogen is two orders of magnitude larger than that of terrestrial deuterium. The D/H ratio in the bulk atmosphere of Venus today is found to be between 0.014 and 0.02. The argument that present-day HDO can be in a steady state with exogenous (cometary) sources is based on an underestimate of the hydrogen abundance and an overestimate of current escape rates. The large isotope ratio requires that Venus once had above-surface water amounting to at least a few tenths of a percent of a terrestrial ocean and has since lost almost all of the associated hydrogen.

Donahue, T. M.↗

DOE OSTI2024

Molybdenum Disulfide/Diselenide-Laser-Induced Graphene–Glycine Oxidase Composite for Electrochemical Sensing of Glyphosate

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Zribi, Rayhane [Department of Engineering, Univers↗

NASA NTRS2005

Overview of Icing Physics Relevant to Scaling

An understanding of icing physics is required for the development of both scaling methods and ice-accretion prediction codes. This paper gives an overview of our present understanding of the important physical processes and the associated similarity parameters that determine the shape of Appendix C ice accretions. For many years it has been recognized that ice accretion processes depend on flow effects over the model, on droplet trajectories, on the rate of water collection and time of exposure, and, for glaze ice, on a heat balance. For scaling applications, equations describing these events have been based on analyses at the stagnation line of the model and have resulted in the identification of several non-dimensional similarity parameters. The parameters include the modified inertia parameter of the water drop, the accumulation parameter and the freezing fraction. Other parameters dealing with the leading edge heat balance have also been used for convenience. By equating scale expressions for these parameters to the values to be simulated a set of equations is produced which can be solved for the scale test conditions. Studies in the past few years have shown that at least one parameter in addition to those mentioned above is needed to describe surface-water effects, and some of the traditional parameters may not be as significant as once thought. Insight into the importance of each parameter, and the physical processes it represents, can be made by viewing whether ice shapes change, and the extent of the change, when each parameter is varied. Experimental evidence is presented to establish the importance of each of the traditionally used parameters and to identify the possible form of a new similarity parameter to be used for scaling.

Anderson, David N.↗

NASA NTRS2017

Constraints on Climate and Habitability for Earth-like Exoplanets Determined from a General Circulation Model

Conventional definitions of habitability require abundant liquid surface water to exist continuously over geologic timescales. Water in each of its thermodynamic phases interacts with solar and thermal radiation and is the cause for strong climatic feedbacks. Thus, assessments of the habitable zone require models to include a complete treatment of the hydrological cycle over geologic time. Here, we use the Community Atmosphere Model from the National Center for Atmospheric Research to study the evolution of climate for an Earth-like planet at constant CO2, under a wide range of stellar fluxes from F-, G-, and K-dwarf main sequence stars. Around each star we find four stable climate states defined by mutually exclusive global mean surface temperatures (Ts); snowball (Ts ≤ 235 K), waterbelt (235 K ≤ Ts ≤ 250 K), temperate (275 K ≤ Ts ≤ 315 K), and moist greenhouse (Ts ≥ 330 K). Each is separated by abrupt climatic transitions. Waterbelt, temperate, and cooler moist greenhouse climates can maintain open-ocean against both sea ice albedo and hydrogen escape processes respectively, and thus constitute habitable worlds. We consider the warmest possible habitable planet as having Ts ∼ 355 K, at which point diffusion limited water-loss could remove an Earth ocean in ∼1 Gyr. Without long timescale regulation of non-condensable greenhouse species at Earth-like temperatures and pressures, such as CO2, habitability can be maintained for an upper limit of ∼2.2, ∼2.4, and ∼4.7 Gyr around F-, G-, and K-dwarf stars respectively, due to main sequence brightening.

Eric T Wolf↗

NASA NTRS2014

Validation of Land Surface Temperature Products Derived from the Visible Infrared Imaging Radiometer Suite (VIIRS) Using Ground-based and Heritage Satellite Measurements

Thermal infrared satellite observations of the Earth's surface are widely used to retrieve Land Surface Temperature (LST) and monitor LST changes around the world. Since January 2012, the Visible Infrared Imaging Radiometer Suite (VIIRS) onboard the Suomi National Polar-Orbiting Partnership (S-NPP) has provided daily observations of LST with a spatial resolution of 750 m at nadir. Comparison of the standard VIIRS LST product with the equivalent daily standard product from the Moderate Resolution Imaging Spectroradiometer (MODIS) collection-5 and with ground-based measurements over vegetated and inland water surfaces showed good agreement. Analysis indicated the accuracy and precision of the VIIRS product over these cover types was 0.2 K and 2.0 K respectively provided the analyses included appropriate compensation for any spatial heterogeneity in LST within the validation site. However, comparisons between in situ LST and the VIIRS and MODIS LST.

Land surface temperature↗

NASA NTRS2017

Constraints on Climate and Habitability for Earth-like Exoplanets Determined from a General Circulation Model

Conventional definitions of habitability require abundant liquid surface water to exist continuously over geologic timescales. Water in each of its thermodynamic phases interacts with solar and thermal radiation and is the cause for strong climatic feedbacks. Thus, assessments of the habitable zone require models to include a complete treatment of the hydrological cycle over geologic time. Here, we use the Community Atmosphere Model from the National Center for Atmospheric Research to study the evolution of climate for an Earth-like planet at constant CO2, under a wide range of stellar fluxes from F-, G-, and K-dwarf main sequence stars. Around each star we find four stable climate states defined by mutually exclusive global mean surface temperatures (T(sub s)); snowball (T(sub s) ≼ 235 K), waterbelt (235 K ≼ T(sub s) ≼ 250 K), temperate (275 K ≼ T(sub s) ≼ 315 K), and moist greenhouse (T(sub s) ≽ 330 K). Each is separated by abrupt climatic transitions. Waterbelt, temperate, and cooler moist greenhouse climates can maintain open-ocean against both sea ice albedo and hydrogen escape processes respectively, and thus constitute habitable worlds. We consider the warmest possible habitable planet as having T(sub s) ∼ 355 K, at which point diffusion limited water-loss could remove an Earth ocean in ∼1 Gyr. Without long timescale regulation of non-condensable greenhouse species at Earth-like temperatures and pressures, such as CO2, habitability can be maintained for an upper limit of ∼2.2, ∼2.4, and ∼4.7 Gyr around F-, G-, and K-dwarf stars respectively, due to main sequence brightening.

Astrobiology↗

NASA NTRS2000

OCTS And Seawifs Bio-Optical Algorithm and Product Vaildattion and Intercomparison in US Coastal Waters

Monitoring the health of U.S. coastal waters is an important goal of the National Oceanic and Atmospheric Administration (NOAA). Satellite sensors are capable of providing daily synoptic data of large expanses of the U.S. coast. Ocean color sensor, in particular, can be used to monitor the water quality of coastal waters on an operational basis. To appraise the validity of satellite-derived measurements, such as chlorophyll concentration, the bio-optical algorithms used to derive them must be evaluated in coastal environments. Towards this purpose, over 21 cruises in diverse U.S. coastal waters have been conducted. Of these 21 cruises, 12 have been performed in conjunction with and under the auspices of the NASA/SIMBIOS Project. The primary goal of these cruises has been to obtain in-situ measurements of downwelling irradiance, upwelling radiance, and chlorophyll concentrations in order to evaluate bio-optical algorithms that estimate chlorophyll concentration. In this Technical Memorandum, we evaluate the ability of five bio-optical algorithms, including the current SeaWiFS algorithm, to estimate chlorophyll concentration in surface waters of the South Atlantic Bight (SAB). The SAB consists of a variety of environments including coastal and continental shelf regimes, Gulf Stream waters, and the Sargasso Sea. The biological and optical characteristics of the region is complicated by temporal and spatial variability in phytoplankton composition, primary productivity, and the concentrations of colored dissolved organic matter (CDOM) and suspended sediment. As such, the SAB is an ideal location to test the robustness of algorithms for coastal use.

Brow, Chirstopher↗

NASA NTRS1983

Mars - A contamination potential?

Three regions on Mars, Solis Lacus, Noachis-Hellespontus, and the Syrtis Major border areas, would appear to have generally less hostile environments than at the Viking lander sites. Significant soil moisture may extend to within about 1 cm of the surface. Water vapor pressures within the pore spaces may be near saturation, and brines may be physically segregated from pockets of relatively pure H2O. Temperatures reach above 0 C during southern spring and summer, with peak temperatures reaching +22 C. These regions should contain fewer oxidants, and primary synthesis of organics may occur. The potential for contamination of these sites by microbes transported from existing spacecraft should be assessed. The adequacy of proposed new planetary protection procedures for possible future United States Mars Surface Sample Return missions should also be assessed in light of these findings.

Huguenin, R. L.↗

NASA NTRS2012

Evaluating the Contribution of NASA Remotely-Sensed Data Sets on a Convection-Allowing Forecast Model

The Short-term Prediction Research and Transition (SPoRT) Center is a collaborative partnership between NASA and operational forecasting partners, including a number of National Weather Service forecast offices. SPoRT provides real-time NASA products and capabilities to help its partners address specific operational forecast challenges. One challenge that forecasters face is using guidance from local and regional deterministic numerical models configured at convection-allowing resolution to help assess a variety of mesoscale/convective-scale phenomena such as sea-breezes, local wind circulations, and mesoscale convective weather potential on a given day. While guidance from convection-allowing models has proven valuable in many circumstances, the potential exists for model improvements by incorporating more representative land-water surface datasets, and by assimilating retrieved temperature and moisture profiles from hyper-spectral sounders. In order to help increase the accuracy of deterministic convection-allowing models, SPoRT produces real-time, 4-km CONUS forecasts using a configuration of the Weather Research and Forecasting (WRF) model (hereafter SPoRT-WRF) that includes unique NASA products and capabilities including 4-km resolution soil initialization data from the Land Information System (LIS), 2-km resolution SPoRT SST composites over oceans and large water bodies, high-resolution real-time Green Vegetation Fraction (GVF) composites derived from the Moderate-resolution Imaging Spectroradiometer (MODIS) instrument, and retrieved temperature and moisture profiles from the Atmospheric Infrared Sounder (AIRS) and Infrared Atmospheric Sounding Interferometer (IASI). NCAR's Model Evaluation Tools (MET) verification package is used to generate statistics of model performance compared to in situ observations and rainfall analyses for three months during the summer of 2012 (June-August). Detailed analyses of specific severe weather outbreaks during the summer will be presented to assess the potential added-value of the SPoRT datasets and data assimilation methodology compared to a WRF configuration without the unique datasets and data assimilation.

Zavodsky, Bradley T.↗

DOE OSTI2020

Flow-induced oscillation patterns for two tandem cylinders with turbulence stimulation and variable stiffness and damping

Herein, the oscillation patterns of two 1-DOF cylinder oscillators, undergoing VIV and galloping, are investigated in a free surface water channel for 3.2 × 104 ≤ Re ≤ 1.2 × 10 5 . The cylinders are arranged in tandem and supported by springs for a range of different spring stiffness and damping parameters. The efficiency of a current energy converter (CEC), based on flow-induced oscillation (FIO) of multiple cylinders in tandem, is critically related to the cylinder oscillation patterns. Due to the limited number of studies on the FIO for multiple cylindrical or prismatic bodies, their oscillation patterns have neither been identified nor classified. The surfaces of the cylinders are modified by turbulence stimulation to enhance FIO. Three different center-to-center spacing, five stiffness, and six damping ratios, for a total of 90 sets of experiments were conducted. The current velocity range is from 0.34 m/s to 1.32 m/s. From more than 2000 tests, five major patterns, nine sub-patterns are identified and classified. The patterns are defined based on the amplitudes, frequencies and the phase angle differences between the two cylinders. The characteristics and mechanics of each oscillation pattern are explored and explained from the perspective of fluid-structure interaction (FSI). By systematically varying the parameters, the underlying hydrodynamic mechanisms, including the coupling level between vortices and cylinders, the shielding effect, the wake effect, and the stability states are revealed. Few preliminary observations on the connection between oscillation pattern and harnessed power by the tandem cylinders are reported.

42 ENGINEERING↗

DOE OSTI2024

A functional microbiome catalogue crowdsourced from North American rivers

Predicting elemental cycles and maintaining water quality under increasing anthropogenic influence requires knowledge of the spatial drivers of river microbiomes. However, understanding of the core microbial processes governing river biogeochemistry is hindered by a lack of genome-resolved functional insights and sampling across multiple rivers. Here we used a community science effort to accelerate the sampling, sequencing and genome-resolved analyses of river microbiomes to create the Genome Resolved Open Watersheds database (GROWdb). GROWdb profiles the identity, distribution, function and expression of microbial genomes across river surface waters covering 90% of United States watersheds. Specifically, GROWdb encompasses microbial lineages from 27 phyla, including novel members from 10 families and 128 genera, and defines the core river microbiome at the genome level. GROWdb analyses coupled to extensive geospatial information reveals local and regional drivers of microbial community structuring, while also presenting foundational hypotheses about ecosystem function. Building on the previously conceived River Continuum Concept, we layer on microbial functional trait expression, which suggests that the structure and function of river microbiomes is predictable. We make GROWdb available through various collaborative cyberinfrastructures, so that it can be widely accessed across disciplines for watershed predictive modelling and microbiome-based management practices.

59 BASIC BIOLOGICAL SCIENCES↗

NASA NTRS2000

Galactic Noise and Passive Microwave Remote Sensing from Space at L-Band

The spectral window at L-band (1.4 GHz) is important for passive remote sensing of parameters such as soil moisture and ocean salinity best measured at long wavelengths. At L-band, radiation from extraterrestrial (galactic) sources is strong enough to warrant inclusion in calibration and retrieval algorithms and unlike the constant cosmic background is spatially variable. Previous estimates of the magnitude and distribution of this background radiation have been rather coarse, However, recent surveys of the radio sky at 1.4 GHz have made it possible to produce maps with sufficient spatial and radiometric accuracy to be relevant to remote sensing applications. This is of particular concern for remote sensing of sea surface salinity because the surface (water) is a good reflector and the salinity signal is relatively small. This paper presents a modem map of the radiometric sky at L-band and a solution to the problem of determining the portion of the sky seen by a radiometer in orbit. The data is derived from recent radio astronomy surveys and is presented as equivalent brightness temperature suitable for remote sensing applications. Examples using orbits and antennas representative of those contemplated for remote sensing of soil moisture and sea surface salinity from space are presented to illustrate the signal levels to be expected. Radiation near the galactic plane can exceed several kelvin.

LeVine, D. M.↗

DOE OSTI2026

Organic colloid composition in variable-redox porewaters within a mountainous floodplain

Redox gradients, often driven by changes in sediment moisture levels in porous, heterogeneous groundwater systems, create dynamic conditions that may promote the production and transport of colloids within natural waters. While much research has focused on the inorganic composition of colloids, the organic composition remains less well understood. Organic matter (OM) in colloids may associate with minerals, complex metal ions, and serve as an electron donor for microbial respiration; therefore, its composition is of high interest. We examined the composition of porewater OM along a redox gradient in a riparian soil located along the Slate River in Crested Butte, Colorado, USA as a function of depth (90, 130, 200, and 350 cm below ground surface). All depths were oxic to suboxic, except 200 cm, where the products of iron and sulfate reduction were observed concomitant with an increase in dissolved and/or colloidal OM, pH, alkalinity, and conductivity. We investigated the composition of porewater using correlated scanning transmission X-ray microscopy and transmission electron microscopy. We observed a change in the OM chemistry from carboxylate-rich at the 200 cm depth (where it was also enmeshed with non-crystalline iron) to phenol- and substituted-aromatic-rich at other depths. Radiocarbon dating revealed carbon in porewater at 200 cm was younger than depths above and below. Soil porewater can flow down into the underlaying gravel bed during baseflow conditions, thus we speculate whether riparian porewater could transport iron- and carboxylate-rich organic colloids into surrounding surface waters through the gravel bed conduit.

Alpine floodplain↗

DOE OSTI2026

Data from Stewart et al. 2026 "Organic Colloid Composition in Variable-Redox Porewaters within a Mountainous Floodplain"

alpine floodplain↗

DOE OSTI2020

Data from: Leaching losses of dissolved organic carbon and nitrogen from agricultural soils in the upper US Midwest

Leaching losses of dissolved organic carbon (DOC) and nitrogen (DON) from agricultural systems are important to water quality and carbon and nutrient balances but are rarely reported; the few available studies suggest linkages to litter production (DOC) and nitrogen fertilization (DON). In this study we examine the leaching of DOC, DON, NO3-, and NH4+ from no-till corn (maize) and perennial bioenergy crops (switchgrass, miscanthus, native grasses, restored prairie, and poplar) grown between 2009 and 2016 in a replicated field experiment in the upper Midwest U.S. Leaching was estimated from concentrations in soil water and modeled drainage (percolation) rates. DOC leaching rates (kg ha-1 yr-1) and volume-weighted mean concentrations (mg L-1) among cropping systems averaged 15.4 and 4.6, respectively; N fertilization had no effect and poplar lost the most DOC (21.8 and 6.9, respectively). DON leaching rates (kg ha-1 yr-1) and volume-weighted mean concentrations (mg L-1) under corn (the most heavily N-fertilized crop) averaged 4.5 and 1.0, respectively, which was higher than perennial grasses (mean: 1.5 and 0.5, respectively) and poplar (1.6 and 0.5, respectively). NO3- comprised the majority of total N leaching in all systems (59-92%). Average NO3- leaching (kg N ha-1 yr-1) under corn (35.3) was higher than perennial grasses (5.9) and poplar (7.2). NH4+ concentrations in soil water from all cropping systems were relatively low (<0.07 mg N L-1). Perennial crops leached more NO3- in the first few years after planting, and markedly less after. Among the fertilized crops, the leached N represented 14-38% of the added N over the study period; poplar lost the greatest proportion (38%) and corn was intermediate (23%). Requiring only one third or less of the N fertilization compared to corn, perennial bioenergy crops can substantially reduce N leaching and consequent movement into aquifers and surface waters.

09 BIOMASS FUELS↗

NASA NTRS1975

Hydrologic land use classification of the Patuxent River watershed using remotely sensed data

The Patuxent River Watershed is located in central Maryland between Baltimore and Washington, D.C. and is approximately 2330 sq km in area and 175 km long. This region is now at a critical point because of major concerns such as water management and quality, flooding and land use within the watershed. Data from the NASA-directed LANDSAT and Earth Resources Aircraft Programs were used to provide a new dimension in information collection and processing for the management of watersheds. Digital data from LANDSAT-1 were analyzed along with selected IR photography from U-2 flight number 74-060B taken 28 April 1974, which was digitized in three channels. Processing of the data was accomplished using a multispectral analysis system. Land use themes consisting of surface water, wetlands, forest, residential, cropland/pasture, urban, and extractive were developed and delineated through the watershed. Area measurements of watershed themes were obtained and will serve as a calibration input to a deterministic hydrologic model on a sub-watershed. Using the derived residential and urban theme areas from LANDSAT an estimated basin imperviousness was also calculated. Thematic maps were produced at 1:62,500 scale. Floodprone areas were also classified and delineated at a scale of 1:24,000. Comparison with standard floodprone area maps at the same scale have indicated a few areas of discrepancy. Such information can be used for updating or checking floodprone area boundaries as well as monitoring changes in floodplain areas.

Dallam, W. C.↗

NASA NTRS1989

Methane oxidation in Saanich Inlet during summer stratification

Saanich Inlet, British Columbia, an fjord on the southeast coast of Vancouver Island, typically stratifies in summer, leading to the formation of an oxic-anoxic interface in the water column and accumulation of methane in the deep water. The results of methane concentration measurements in the water column of the inlet at various times throughout the summer months in 1983 are presented. Methane gradients and calculated diffusive fluxes across the oxic-anoxic interface increased as the summer progressed. Methane distribution and consumption in Saanich Inlet were studied in more detail during August 1986. At this time, a typical summer stratification with an oxic-anoxic interface around 140 m was present. At the interface, steep gradients in nutrient concentrations, bacterial abundance and methane concentration were observed. Methane oxidation was detected in the aerobic surface waters and in the anaerobic deep layer, but highest rates occurred in a narrow layer at the oxic-anoxic interface. Estimated methane oxidation rates were suffcient to consume 100 percent of the methane provided by diffusive flux from the anoxic layer. Methane oxidation is thus a mechanism whereby atmospheric flux from anoxic waters is minimized.

Ward, B. B.↗

NASA NTRS1987

A coupled dynamic-thermodynamic model of an ice-ocean system in the marginal ice zone

Thermodynamics are incorporated into a coupled ice-ocean model in order to investigate wind-driven ice-ocean processes in the marginal zone. Upswelling at the ice edge which is generated by the difference in the ice-air and air-water surface stresses is found to give rise to a strong entrainment by drawing the pycnocline closer to the surface. Entrainment is shown to be negligible outside the areas affected by the ice edge upswelling. If cooling at the top is included in the model, the heat and salt exchanges are further enhanced in the upswelling areas. It is noted that new ice formation occurs in the region not affected by ice edge upswelling, and it is suggested that the high-salinity mixed layer regions (with a scale of a few Rossby radii of deformation) will overturn due to cooling, possibly contributing to the formation of deep water.

Hakkinen, Sirpa↗